普通化學授課綱要 授課節次:第__1__週上課 課程主題: Keys To The Study of Chemistry 講授目的: Chemistry is an experimental science. Challenge students to sharpen their skills of observation and measurement, constantly relating laboratory work to concepts discussed in lecture. 授課綱要: (一) The Study Chemistry Why study chemistry ? (二) Measurement in Scientific Study How science is down ? (三) Significant Figures in Chemical Calculation (四) Element Kingdom Representative elements , Transition elements , Inner transition elements , Radioactive elements and Artificial elements (五) Classifying Matter and Some Key Terms (六) Nomenclature for elements and its symbol (七) Basic Chemical Technology – Separation of Mixture 1. Some basic chemical technology 2. How to determine the physical properties of a specific substance ? 普通化學授課綱要 授課節次:第__2__週上課 課程主題: Inorganic Compound 講授目的:1.To learn some tools of chemistry concerning nanoscale technology 2.To familiar with the name of inorganic compound and its constituent 授課綱要: (一) The Discovery of Atomic Structure (二) Rutherford’s Model of the Atom (三)The scanning tunneling microscope ( STM ) (四) Atomic Number and Atomic Mass (五) Mass Spectrometry (六) Mole , ion (七) Inorganic Compound – Naming and formulas (八) Molecular Compound– Naming and formulas 普通化學授課綱要 授課節次:第__3__週上課 課程主題: The Major Classes of Chemical Reaction 講授目的: This chapter discusses three different types of chemical reactions in aqueous solution: precipitation reactions, acid-base reactions, and oxidation-reduction reactions. These reactions are often written as net ionic equations. As a consequence, it is necessary to know the difference between strong and weak electrolytes and nonelectrolytes. You can predict the outcome of each of these reactions if you know the solubility rules, can recognize acids and bases, and know how to assign oxidation numbers to compounds. You are also shown how to balance oxidation-reduction reactions with either the oxidation number method or the method of half reactions. Finally, you will apply the concepts you learned in earlier chapters about stoichiometry to the reactions which are discussed in this chapter. 授課綱要: 1. 2. 3. 4. 5. 6. General Properties of Aqueous Solution Precipitation Reactions Acid-Base Reactions Oxidation-Reduction Reactions Concentration of Solution Solution Stoichiometry and Chemical Analysis 普通化學授課綱要 授課節次:第__4__週上課 課程主題: Applications of Aqueous Equilibria 講授目的: The concepts found in this chapter will be applied to various chemical systems A state of chemical equilibrium is achieved when, with time, the concentrations of both the reactants and products in a reversible reaction level off at constant, equilibrium values. This study of chemical equilibria will explore several aspects of equilibrium mixtures. Students will study the relationship between the concentration of the reactants and products as well as how to determine the equilibrium concentrations knowing the initial concentrations. You will also study which factors can be employed to change the composition of an equilibrium mixture. Finally, you will examine the link between chemical equilibrium and kinetics. 授課綱要: 1.Chemical Equations 2. Some Simple Patterns of Chemical Reactivity 3. The Mole 4. Empirical Formulas from Analysis 5. Quantitative Information from Balanced Equations 7. Limiting Reactants 8. Evaluating the Success of a Synthesis : Percent Yield 普通化學授課綱要 授課節次:第__5__週上課 課程主題: Quantum Theory and Electromagnetic Radiation 講授目的: This chapter explains why the elements, when placed in order of properties. This periodicity can be understood by examining the theory used to describe the electronic structure of atoms. This chapter begins the examination of this theory by introducing electromagnetic radiation and the properties of waves. You will then discover how both light and matter can have dual (both wave and particle) properties. With this information, you are introduced to quantum mechanics and quantum numbers, a mathematical theory used to describe the probability of finding an electron in an atom. You are then shown how to use quantum mechanics to determine the electronic configuration of the elements. Finally, you will apply this knowledge to learn how atoms in the same group in the periodic table have similar electronic configurations and how these electronic configurations affects periodic properties such as atomic radii, ionization energy and electron affinity . 授課綱要: 1.Electromagnetic Radiation and Matter 2.Planck’s Quantum Theory 3.The Bohr Model 4.The Quantum Mechanical Model of the Atom 5.Quantum Number, Energy , and Orbitals 6. Atomic Electron Configurations 7. Ion Electron Configuration 9. Periodic Trends : Atomic Radii 10. Periodic Trends :Ionization Energy 11. Periodic Trends :Electron Affinity 12. 普通化學授課綱要 授課節次:第__6__週上課 課程主題: Models of Chemical Bonding 講授目的: This chapter concentrates on the reasons ionic bonds are formed and the energies involved in the formation of these bonds. You will learn that the underlying reason for the formation of ions and ionic compounds is the valence-shell configuration of the elements, which determines the amount of energy needed for losing or gaining electrons. Knowing the periodic trends in the energies for ion formation, you will learn how to predict which elements form cations or anions and if the formation of ionic compounds is energetically favorable. You will also learn about the Born-Haber cycle, a series of hypothetical steps used to calculate the overall energy involved in the formation of ionic compounds. Finally, you will learn about the chemistry of the group 1A - 3A, 7A, and 8A elements and how the chemistry of these elements is governed by the octet rule. 授課綱要: 1.Chemical Bonds, Lewis Symbols, and the Octet Rule 2. Ionic Bonding 3.Covalent Bonding 4. Bond Polarity and Electronegativity 5. Drawing Lewis Structures 6.Formmal Charge 7. Resonance Structures 8. Exceptions to the Octet Rule 9 Strengths of Covalent Bonds 普通化學授課綱要 授課節次:第__7__週上課 課程主題: Molecular orbital in covalent bonding and Molecular Polarity 講授目的: To understand this bonding concept, students need to first learn about the a useful tool for visualizing the interactions of electrons in a molecule. Students will also learn how to determine the type of bonding that occurs in a molecule based on bond polarities, to predict the relative importance of resonance structures based on formal charge calculations, and to determine molecular shapes using VSEPR theory. Once you have mastered molecular shape determinations, you will be able to apply this knowledge to valence bond theory and to ascertain the type of hybridization predicted by valence bond theory. Finally, you will be introduced to molecular orbital theory, a more sophisticated and, at times, more accurate bonding description. 授課綱要: 1. Using Molecular Models 2. Valence Bond Theory 3. VSEPR Bond Theory 4. Hybridization of Atomic Theory 5. Multiple Covalent Theory 6. Molecular Orbital 7. Molecular polarity 普通化學授課綱要 授課節次:第__8__週上課 課程主題: Organic Chemistry 講授目的: In this chapter you will begin to explore the ability of carbon atoms to bond together, forming a vast array of compounds, such as long chains and rings. You will learn to draw the structures of and apply the IUPAC rules of nomenclature for the simple hydrocarbons. You will classify molecules based upon the functional groups present and learn the general properties of the different classes of molecules. Finally, you will learn how to predict the products and write balanced chemical equations for reactions involving the different classes of molecules. The last part ends with selected topics in an examination of the main classes of biomolecules: proteins, carbohydrates, lipids, and nucleic acids. Your detailed study of these molecules includes the molecular handedness of amino acids and carbohydrates, the levels of protein structure, and the cyclic structures of monosaccharides. You will also examine the lock and key model of enzyme action and the Watson-Crick model for base pairing in DNA. 授課綱要: 1.Some General Characteristics of Organic Molecule 2.Classification of Hyrocarbons 3. Alkanes a. Structures of Alkanes b. Structural Isomers c. Nomenclature of Alkanes d. Cycloalkanes 4. Unsaturated Hydrocarbons a. Addition Reactions b.Mechanism of Addition Reactions 5. Aromatic Hydrocarbons 6. Functional Groups: Alcohols and Ethers 7. Compounds with a Carbonyl Group 8. Chirality in Organic Chemistry 9. Introduction of Biochemistry Proteins , Carbohydrates , lipids ,Nucleic Acids 普通化學授課綱要 授課節次:第__9__週上課 課程主題: 期中考 講授目的:(希望學生學會神麼) 授課綱要:(請條列該堂課之授課大綱內容) 普通化學授課綱要 授課節次:第__10__週上課 課程主題: Chemical Technology - Spectrometry 講授目的:How to use the modern equipment for determining a specific substance ? This chapter also can be allied with the topic of quantum theory. 授課綱要: 1.X-Ray Spectra 2 Atomic Absorption Spectroscopy 3 Atomic Emission Spectroscopy (AES, OES) 4.IR Spectrometry 5.Ultraviolet (UV) and Visible 6. Nuclear Magnetic Resonance 普通化學授課綱要 授課節次:第__11__週上課 課程主題: Thermochemistry 講授目的: Students will learn how to calculate the internal energy of the system using PV work and how the internal energy of the system is related to the enthalpy (H) of the system. He and she will spend much of the rest of the chapter exploring how to use specific heat calculations in the laboratory and how to use Hess's law, standard heats of formation and bond dissociation energies to calculate heats of reaction. 授課綱要: 1. Forms of Energy and Their Interconversions Thermochemical Definitions:E = q + w The Sign Conventions of q,w, and E Determining Energy Change in a System First Law of Thermodynamics 2. Enthalpy: Heats of Reaction and Chemical Change Change in Enthalpy = H Drawing Enthalpy Diagrams and Determining the Sign of H Special H’s of Reactions Contributions to Kinetic and Potential Energy 3. Calorimetry: Laboratory Measurement of Heats of Reaction (q) Specific Heat Capacity and Molar Heat Capacity A Coffee-Cup Calorimeter A Bomb Calorimeter Calculating the Amount of Heat from the Specific Heat Capacity 4. Stoichiometry of Thermochemical Equations 5. Hess’s Law of Heat Summation 6. Standard Heats of Reaction (H0rxn) Standard Enthalpies of Formation The Future of Energy Utilization 普通化學授課綱要 授課節次:第__12__週上課 課程主題: Chemical Thermodynamics 講授目的:To evaluate the directionality of chemical reactions and its optimal condition . 授課綱要: 1.Spontaneous Processes 2.Entropy and the Second Law of Thermodynamics 3.The Molecular Interpretation of Entropy - Third law of thermodynamics 4.Entropy Changes in Chemical Reactions 5.Gibbs Free Energy 6. Free Energy and Temperature 7.Free Energy and the Equilibrium Constant 普通化學授課綱要 授課節次:第__13__週上課 課程主題: Chemical Kinetics 講授目的:To change common student misconceptions such as 1. Students often assume that reaction orders may be determined from stoichiometric coefficients. 2. Students often confuse intermediates and transition states. 3, Students often confuse adsorption and absorption. 授課綱要: 1.Factors that Affect Reaction Rates 2.Reaction Rates 3.Concentration and Rate 4.The Change of Concentration with Time 5.Temperature and Rate 6.Reaction Mechanisms 7.Catalysis 普通化學授課綱要 授課節次:第__14__週上課 課程主題: Coordination Chemistry 講授目的: This chapter examines the properties and chemical behavior of transition-metal compounds with particular emphasis on coordination compounds. Students begin with a review of the electronic configurations of the transition elements and how these configurations affect the properties and oxidation states. Finally, he(or she) will get the different bonding theories that are used to explain the color and magnetism of these complexes. 授課綱要: 1.Coordination compounds and Werner's coordination theory 2.The Nature of Coordination Compounds a. The Structure of Coordination Compounds b. What are the coordination number and the oxidation state of the central atom in the complexes ? c. Coordination Number and Geometry d. Chelate 3.Naming Complex Ions and Coordination Compounds 4.Isomers in Complex Ions and Coordination Compounds 5. Crystal field theory a. d-level splitting b. Spectrochemical series c. How to predict the magnetic properties of a complex d. Color of transition metal complex 6. Some of the biological Mechanism in living system 普通化學授課綱要 授課節次:第__15__週上課 課程主題: Colloid Chemistry(I) 講授目的: Choosing the right architecture, these colloidal systems are able to solve problems that can not be solved by standard molecular systems. 授課綱要: 1.Colloidal State 2.Types of Colloids 3.General Characteristics a. Large surface area / mass unit b. Surface energy c. Adsorption d. Surface charge e. Electric double layer 4.Stability for colloid 5.Utilization 普通化學授課綱要 授課節次:第__16__週上課 課程主題: Colloid Chemistry(II) 講授目的: Choosing the right architecture, these colloidal systems are able to solve problems that can not be solved by standard molecular systems. 授課綱要: 7. Strategy of Preparation a. Electric Disintegration b. Mechanical Disintegration c. Peptization 8. Coagulation a. Coagulant b. Thermal agitation c. Electric coagulation 7. Protective Colloids a. Viscous agent b. Emulsifier (Emulsifying agent ) c. Surfactants d. Function 普通化學授課綱要 授課節次:第__17__週上課 課程主題: Nuclear Chemistry 講授目的:The kinetics of radioactive decay can be allied with the treatment of first-order kinetics ,and nuclear fission and fusion can be considered in a comprehensive unit on energy sources and uses. To realize the effects of ionizing radiation on matter and the risk of some biological hazards 授課綱要: 1.Radioactivity & Types of Radioactive Decay 2.Patterns of Nuclear Stability 3.Rates of Radioactive Decay 4.Detection of Radioactivity 5.Energy Changes in Nuclear Reactions 6.Nuclear Fission 7.Nuclear Fusion 8.Biological Effects of Radiation