基础
功能金属-有机化合物的合成与研究
研究
成果
名称
联系
人
展树中
电
话
电子邮件
13650761066
shzhzhan@scut.edu.cn
本课题涉及到金属-有机化学，材料化学等，属于化学与材料的交叉领域。
学科
领域
功能有机-金属化合物之所以成为当今多学科交叉领域的研究热点而倍受人们
关注，一方面这种化合物具有复杂的电子构型和结构、奇特的物理和化学性质，
其研究涉及物理、化学、材料及生物科学等多学科领域；另一方面它在催化剂、
应用
背景
新型功能材料的开发，生命科学的研究等方面也具有重要意义。
1）合成出一系列功能金属-有机化合物。
2）测试它们的组成，结构和性质。
3）化合物光，电和磁性能的研究和应用。
创新
点
1. Qi-ying Lv ， Wei Li, Shu-Zhong Zhan*, Jian-Ge Wang, Jiayin Su.
Chemistry of tetracyanoethylene (TCNE): from TCNE to dicyanomethylacetate. J.
Organomet. Chem., 2008， 693，1155-1158. (SCI, IF =2.53)
2. Shuzhong Zhan*, Desheng Sun, Jiange Wang, Jieyu Zhou, AnQi Liang.
Synthesis, crystal structures and magnetic properties of a series of new
cyano-bridged complexes derived from templates [Ni(CN)4]2- and [Co(III)(CN)6]3-.
J. Coord. Chem., 2008, 61, 550-562. (SCI, IF =1.03)
3. Yongqin Song, Qiying Lv，Shuzhong Zhan*, Jianwen Xu.
[Cu2(-Cl)(-dppm)2(2-TCNQ)}
代表
,
a charge transfer compound derived from a
donor with a copper dimer. Inorg. Chem. Commun., 2008, 11, 672-674. (SCI, IF
=1.90)
性论
文
4. Wei Li，Shu-zhong Zhan*, Jian-ge Wang, Wen-yuan Yan, Yuan-fu Deng. The
isolation
and
properties
of
an
unexpected
cyano-bridged
complex
[Cl3CoII(-CN)CoII(dppm)2(H2O)]C2H5OH. Inorg. Chem. Commun., 2008, 11,
681-683. (SCI, IF =1.90)
5. Carl Redshaw, Shuzhong Zhan, Sophie H. Dale, Mark R.J. Elsegood.
Bis(imido) rhenium complexes bearing C- or N-capped ‘tripodal’ ligands: Biversus tri-dentate ligation. Inorg. Chem. Commun. 2008, 11, (in press; DOI:
10.1016/j.inoche.2008.03.020) (SCI, IF =1.90)
6. Shu-zhong Zhan*, Jian-ge Wang, Bing Long, Hai-xia Shu, Wen-yuan Yan,
Xin-jia Feng. The assembly, synthesis and properties of a trinuclear cyano-bridged
CuII-MoIV-CuII complex. J. Coord. Chem., 2008, 61, (in press, 论文编号：
GCOO-257195). (SCI, IF =1.03)
7. Shu-zhong Zhan*, Wei Li, Jian-ge Wang, An-qi Liang, Yuan-fu Deng.
Assembly of cyano-bridged Cu(II)/Cu(II) and Cu(I)/Cu(II) compounds obtained by
controlled ration of cyanide. J. Organometallic Chem., 2007, 692, 3568-3573.
(SCI, IF =2.52)
8. Shu-zhong Zhan*, Jian-ge Wang, Yong-qin Song, Qi-ying Lv, You Song, Jia-yin
Su, Wen-yuan Yan. Assembly, structure and magnetic property of one cyano- and
oxamidato-bridged mixed valence CuI/CuII complex. Inorg. Chem. Commun., 2007,
10, 1019-1022. (SCI, IF =1.90)
9. Shuzhong Zhan*, Wei Li Bai-Mu Wang, et al. Synthesis, crystal structure,
magnetic properties and electrochemical behavior of the mixed valence compound
[CuI(CN)3CuII(dipn)]. J. Coord. Chem., 2007, 60, 2747-2754. (SCI, IF =1.03)
10.
Shuzhong
Zhan*,
Kaibei
Yu,
Jiang
Liu.
[NiII(tn)2]5[FeIII(CN)6]2[FeII(CN)6]10H2O: A 3-dimensional dimetallic polymer
exhibiting ferromagnetic interaction. Inorganic Chem. Commun., 2006, 9,
1007-1010. (SCI, IF =1.90)
11. Shuzhong Zhan*, Jiange Wang, Bangtun Zhao, Zhiyuan Huang, Minlang Cai.
Poly[bis[bis(ethylenediamine)copper(II)]-tetra--cyano-[tetracyanomolybdate(IV)]].
Acta Cryst. E.，2006, E62，m1845-m1846. (SCI)
12.
Shuzhong
Zhan,
Ying-Jun
Zhang,
Jiange
Wang.
Bis-O[N(2-hydroxyethyl)-imino-methyl-phenol]Mn(IV)hemisolvate hydrate. Acta
Cryst. E.，2006, E62，m2713-2714. (SCI)
13. E. Goto, R. A. Begum, Shuzhong Zhan, T. Tanase, K. Tanigaki, K. Sakai.
Linear, redox-active Pt6 and Pt2Pd2Pt2 clusters. Angew. Chem. Int. Ed., 2004, 43,
5029-5032. (SCI, IF =10.23)
14. T. Tanase, E. Goto, R. A. Begum, M. Hamaguchi, Shuzhong Zhan, M. Lida, K.
Sakai. Reactive rigid-rod organometallic polymers involving linear triplatinum
units connected by -conjugated bisisocyanides. Organometallics, 2004, 23,
5975-5988.
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