2.2. Waters 2.2.1. Sources and pollution level Both the number and magnitude of pollution sources of the natural waters in the Republic of Moldova decreased, comparing to the 1980s and the early 1990s. However, the main sources of pollution remained the same: municipal waste water treatment plants; agriculture; livestock raising; runoff waters from residential areas and industrial sites; non-sewered population, communal dump sites. A particular major transboundary pollution source is the hydropower station at Novodnestrovsk (Ukraine), which caused drastic changes of the temperature regime of the Dniester river within the Republic of Moldova and, consequently, heavily impacted the natural river ecosystems. Only some of the point sources of pollution, mentioned above, are monitored (mainly the waste water treatment plants). Fig. 2.6. Number of water users and issued water use permits 2001 2000 1999 1998 1997 2002 1996 1992 1995 1982 1994 0 Irrigation 1993 500 Domestic use 1992 322 1000 Abstracted water Industrial use 4500 4000 3500 3000 2500 2000 1500 1000 500 0 1991 1500 Users that were issued a permit million m3 1012 2000 1021 1690 2500 1990 Users that must obtain a permit 2577 3000 2636 According to the current legislation, the water users must operate according to requirements set in the water use permits. Those stipulate the volume of water that can be used and set limit values for the discharge of pollutants contained in the waste water. During the last decade, the number of water users decreased dramatically, following the general drop in economic activity (see fig. 2.6). Fig. 2.7. Data on water use The volume of abstracted water was continuously decreasing (to 918 million m3 in 2001), due to lower demand from the industrial sector and quasi complete cessation of irrigation (fig. 2.7). Consequently, the amount of waste water also decreased. In 2001, 753 million m3 of wastewater were discharged to the receiving water bodies, including 569 million m3 of cooling water from the Dnestrovsk power station and 207 million m3 of domestic and industrial waste waters from municipal wastewater treatment plants (fig. 2.8). The latter decreased two-fold comparing to 1990. Despite the general reduction of wastewater discharges to the surface waters, the discharge limit values for main pollutants were, per total, exceeded The total volume of treated wastewater discharged into the three main rivers, namely Dniester, Prut and Bic, amounted to 149.4 million m3 (fig. 2.9). Comparing to 1990, the discharge into the above rivers has been reduced 1.7, 3.9 and 1.6 times, respectively. 3000 300 Total wastewater Adequately treated Treated in WWTPs r. Prut 250 2000 million m3 million m3 2500 r. Dniester 1500 1000 r. Bic 200 150 100 500 50 00 0 19 90 19 91 19 92 19 93 19 94 19 97 19 98 19 99 20 00 20 01 20 98 19 96 19 94 19 92 19 19 90 0 Fig. 2.8. General data on wastewater discharges Fig. 2.9. Volume of treated wastewater discharged into the surface waters Basing on water users’ reports, one can estimate that the discharges of biodegradable substances, suspended solids, oil products, ammonium and phenols decreased considerably during the last years. For example, the total amount of organic pollutants (characterised by BOD) discharged to river Dniester and river Bic was under the admissible level while in river Prut the requirements were exceeded due to discharges from poorly working wastewater treatment plant in Ungheni in 1999-2001 (fig. 2.10). The same picture can be noticed for suspended solids (fig. 2.11). r. Dniester r. Prut r. Bic DLV r. Dniester 8 7 5 4 3 2 1 19 90 19 91 19 92 19 93 19 94 19 97 19 98 19 99 20 00 20 01 0 Index Index 6 r. Prut r. Bic DLV 4,5 4 3,5 3 2,5 2 1,5 1 0,5 0 1990 1991 1992 1993 1994 1997 1998 1999 2000 2001 Fig. 2.11. Discharge of suspended solids to the surface waters Fig. 2.10. Pollution of the main rivers with biodegradable matter (BOD) The amount of oil products discharged into the Dniester and Bic rivers continuously decreased since 1994 but still does not meet the existing requirements (fig. 2.12). A similar situation can be noticed for ammonium discharges to the rivers Dniester and Prut. The ammonium pollution index (discharged de-facto/discharge limit) for river Bic shows a pollution level exceeding the admissible value (fig. 2.13). The same is valid for phenol discharges to the Dniester and Bic rivers (fig. 2.14). Data for river Prut are not available. r. Dniester r. Bic 25 r. Prut DLV r. Dniester r. Bic 7 r. Prut DLV 6 20 Index Index 5 15 4 3 2 10 1 20 01 20 00 19 99 19 98 19 97 19 94 19 93 19 92 19 90 20 01 20 00 19 99 19 98 19 97 19 94 19 93 19 92 19 91 19 90 0 19 91 0 5 Fig. 2.12. Discharge of oil products into the surface waters Fig. 2.13. Discharge of ammonium into the surface waters r. Dniester r. Bic DLV 20 18 16 14 12 10 8 6 4 2 0 700 600 WWTP<400 500 WWTP>400 400 300 200 100 Fig. 2.14. Discharges of phenols into the surface waters 02 01 20 00 20 99 20 19 98 19 97 19 96 90 19 19 20 00 19 98 19 94 0 19 92 19 90 Index By the 1990s, approximately 580 biologic wastewater treatment plants (WWTPs) have been constructed in Moldova. According to the inventory undertaken by the State Ecological Inspectorate in 2001, only 330 are physically available, the rest of them were destroyed. Out of these, only 106 WWTPs are in operation (fig. 2.15). They are located as follows: 57 in the Dniester basin, 25 in the Prut basin, 15 in the catchment area of the Danube lakes and 9 in the Black Sea basin. Due to poor laboratory capacity of the regional environmental authorities (Territorial Ecological Agencies, ATE) the discharges from many of the WWTPs could not be properly monitored (fig. 2.16). Fig. 2.15. Number of WWTPs in operation 120 Index WWTPs 100 11 40 6 8 10 57 50 20 15 8 7 3 ATE Gagauzia 9 ATE Tighina ATE Chisinau ATE Soroca 13 5 ATE Orhei 11 0 AME Chisinau 20 50 SE Taraclia 27 ATE Cahul 45 100 54 ATE Ungheni 80 100 ATE Balti 40 100 ATE Lapusna 60 ATE Edinet Procente 80 Fig. 2.16. Index of analytical control of WWTPs operation in 2002 In 2002, only 57 out of 106 operating WWTPs have undergone laboratory checks of their effluent quality and in only 36 cases the impact of the effluents on the receiving water bodies have been estimated. Groundwater The pollution of groundwater with nitrogen compounds is a growing concern in Moldova. Deep groundwater layers often show a high content of ammonia while shallow groundwater is increasingly polluted with nitrate. It is not unusual to find in many shallow wells concentrations of nitrate of hundreds of mg/l. Both natural and anthropogenic factors are at the origin of this situation. A major source of pollution with nitrogen is land fertilization. From the total amount of applied fertilizer, the plants uptake does usually not exceed 15-20%. As a result of denitrification processes in soil, an other part of the nitrogen is eliminated into the atmosphere in gaseous form. Generally, between 7 and 60% of the total nitrogen fertilizers is lost in gaseous form; the plants capture between 22 and 55% of nitrogen while the losses through runoff and infiltration may be in the range of 1-20%. Less than 1-5% of nitrogen is retained in the aeration zone. The amount of nitrate going into the shallow groundwater depends on the composition and thickness of the filtration layer. An other major source of groundwater pollution with nitrate is human and livestock waste.