MATERIAL SAFETY DATA SHEET PREMTEC U-200 B SERIE I. GENERAL INFORMATION MANUFACTURER WHMIS CLASSIFICATION PREMILEC INC. 870, Cure Boivin Boisbriand, Quebec J7G 2A7 CLASS D DIVISION 1B, 2B CLASS E Phone (450) 437-0123 PRODUCT NAME: 24 hours emergency number only (613) 996-6666 (Canutec) CHEMICAL FAMILY: Mixture of amine compounds Current Issue Date January 2004 CHEMICAL NAME: N.B.: PREMTEC U-200B SERIE N/A, Product is a Mixture This MSDS becomes invalid as soon as a new edition has been published. II. HAZARDOUS INGREDIENTS CHEMICAL & COMMON NAME Chemical Identity is Proprietary *Diethyltoluenediamine CAS# 68479-98-1 WT% 40-70 20-50 OSHA PEL N/A N/A ACGIH TLV N/A N/A *Designates a toxic chemical as defined by Sara Title III, Section 311,312,313 (40 CFR 372). Boiling Range: Vapor Pressure (mmHg): Specific Gravity: Vapor Density (air=1): % Volatile (volume): Evap. Rate (BuOAc=1): Volatile Organic Content (VOC): Solubility (Specify Solvents): Appearance and Odour: III. PHYSICAL CHARACTERISTICS No data No data 1,0 No data No data No data N.A. No data Clear amber liquid; characteristic amine odour. Can be pigmented, coloured. IV. FIRE & EXPLOSION DATA Flash Point: Above 275F(135C) Flammable Limits (% In Air): No data Extinguishing Media: Dry chemical, foam carbon dioxide, halogenated agents. Water or foam can cause frothing. Special Fire-Fighting Procedures: Use water to cool fire exposed containers. Wear self-contained breathing apparatus, with full-face piece and protective clothing. Unusual Fire and Explosion Hazards: None known. Reactivity: Product is stable under normal conditions. Hazardous Polymerization: Will not occur. Conditions to Avoid: None known. Hazardous Decomposition Products: Combustion Products: Toxic levels of ammonia. Oxides of nitrogen, carbon and some aldehydes and ketones may also be produced. V. STABILITY AND REACTIVITY Incompatibility: Strong oxidizers, air water. Isocyanates. Acids. Reactivity conditions: Product is stable; hazardous polymerisation will not occur. Material supports combustion. Hazardous products of Decomposition: By fire: carbon monoxide, carbon dioxide. Oxides of nitrogen. Amine. Traces of ammonia vapours. Other aliphatic fragments which have not been determined. VI. HEALTH HAZARDS Primary routes of Entry: Eye contact, inhalation, ingestion, skin contact. ACUTE HEALTH EFFECTS: Eye Contact: Will cause irritation, burning, or chemical burns. Inhalation: Vapours or mist are irritating and may cause nasal discharge, coughing and discomfort in hose, throat and chest. Severe overexposure may result in difficulty breathing, headache, nausea, vomiting, drowsiness and lung damage. Ingestion: Ingestion of this product is expected to be toxic. Oral LD50=485 mg/kg. Skin Contact: This product can be toxic by dermal absorption. Dermal LD50=700mg/kg. (U-200 B SERIE) / 2 VII. EMERGENCY FIRST AID PROCEDURES Eye Contact: Wash with clean water for at least fifteen minutes; get medical attention. Inhalation: Move individual to fresh air. If breathing has stopped apply artificial respiration; get medical attention immediately. Ingestion: INDUCE VOMITING immediately by giving two glasses of water or milk to drink; stick finger-sown throat. Never give anything to an unconscious person. Get medical attention immediately. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing and decontaminate shoes before reuse. Chronic Health Effect: Prolonged or repeated overexposure may result in lung damage. Aggravated by Exposure: Pre-existing lung or skin conditions could be aggravated by repeated exposure. VIII. SPILL OR LEAK PROCEDURES Material Spilled or Released: Ventilate area. Avoid breathing vapour. Use of self-contained breathing apparatus may be required in confined or enclosed areas. Contain any spills with dikes or absorbents to prevent migration and entry into sewers of streams. Take up small spills with dry chemical absorbent. Large spills may be taken up with pump or vacuum and finished off with dry chemical absorbent. Waste Disposal Method: Dispose of material in accordance with all federal, state and local regulations. IX. SPECIAL PROTECTION DATA Respiratory Protection: trainers in their proper use. Ventilation: Protective Gloves: Eye Protection: Other Protection Clothing or Equipment: clothing. Wear MSHA/NIOSH approved respirator for organic vapours. Ensure workers are Mechanical ventilation, adequate to keep exposure below TLV is recommended. Neoprene or nitrile rubber. Goggles or full face shield. Eyewash fountain and safety shower should be accessible; impervious protective (U-200 B SERIE) / 3 X. HANDLING & STORAGE DATA Precautions Handling and Storage: Store in a well ventilated, cool, dry area. Purge with nitrogen and close container when not in use. Other Precautions: Store in original container; keep tightly closed. Do not reuse container for other purposes. KEEP OUT OF REACH OF CHILDREN. XI. OTHER INFORMATION TSCA Information: WHMIS Information: All ingredients are on the TSCA Chemical Substance Inventory. Not all ingredients are confined on the Canadian DSL (Domestic Substances List). XII. SHIPPING DATA T.D.G. classification: Amines, liquid, corrosive UN 3066, Class 8 Packing Group III Emergency telephone number :(613) 996-6666 CANUTEC XII. PREPARATION OF MSDS Approved by: Title: Date: N.A. Not applicable N.D. Not determined N.E. Not established Mario Lefebvre Technical Manager January 2004 (U-200 B SERIE) / 4