Ch11 Homework Key

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H Ch 11 Homework

Stoichiometry:

1.

How many liters of ammonia gas(NH

3

) can be produced by the reaction of 4000 L of

Nitrogen w excess Hydrogen?

8000 L

2.

If 1800 L of acetylene (C

2

H

2

) is burned, how many liters of CO

2

are formed?

3600 L

3.

Electrolysis of water produced 500 L of Hydrogen. What volume of Oxygen was also produced?

250 L

4.

If 200 L of carbon monoxide react with 400 L of Oxygen, how many liters of carbon dioxide will be formed?

200 L CO

2

5.

How many liters of Oxygen at .78 atm and 34

C are required to react with 55 L of

Hydrogen at the same conditions?

27.5 L H

2

6.

When 70 g of H

2

O

2

are decomposed, how many liters of oxygen are formed?

2H

2

O

2

2H

2

O + O

2

23.07 L O

2

7.

If 40 g of Aluminum react with 60 g of hydrochloric acid, how many liters of

Hydrogen are produced?

18.7 L H

2

8.

How many grams of potassium chlorate are required in the preparation of 90 L of

Oxygen at 1.20 atm and 45

C?

336.72 g KClO

3

9.

How many grams of Sodium Peroxide must react with water to produce 35 L of

Oxygen at 5

C and 660 mmHg?

2 Na

2

O

2

+ 2 H

2

O

4 NaOH + O

2

207.48 g Na

2

O

2

10.

Calculate the number of liters of Oxygen needed to react with 75 g of Aluminum.

46.7 L

11.

If 35 g of Sulfur react with 80 L of Oxygen, how many liters of Sulfur Dioxide would be produced?

24.5 L SO

2

12.

Oxygen was originally produced by the decomposition of Mercuric Oxide (HgO).

What volume of O

2

at 15

C and .98 atm can be produced from 2.36 g of HgO?

.13 L

13.

If 32 g of Sodium are added to 25 L of Chlorine at 45 psi and 300 K, how many grams of salt would be produced?

80.7 g NaCl

Collection Over Water:

1.

11 g of potassium chlorate is decomposed and the resulting oxygen is collected over water. What volume of oxygen would be collected at .93 atm and 25 °C?

P = 683 mmHg; V = 27.22 L; 3.68 L O

2

2.

20 g of potassium bromide is mixed with 10 L of chlorine at 34 psi and 20 °C. What volume of bromine vapor can be collected over water at these conditions?

KBr limiting; V

2

= 10.4 L; .88 L Br

2

3.

16.7 ml of liquid water is electrolyzed. The resulting gases are sent to 2 different tanks that are initially filled with water. The hydrogen tank is at 30 °C and the oxygen tank is at 70 °C. Which tank must have the larger volume? Atmospheric pressure on this day is 710 mmHg.

H

2

= 25.87 L

O

2

= 20.87 L

Density

1.

What is the density of Oxygen at STP? Nitrogen?

1.42 g/L; 1.24 g/L

2.

What is the density of Fluorine at STP and at 30

C and 725 Torr?

1.70 g/L; 1.46 g/L

3.

Find the density of Freon 12 (CF

2

Cl

2

) at 315 K and .945 atm.

4.38 g/L

Grahams Law

1.

If Hydrogen will diffuse at a rate of .3 m/s at certain conditions, how fast will Oxygen diffuse at those conditions?

.075 m/s

2.

How much faster will Carbon Monoxide diffuse as compared to Carbon Dioxide?

1.25

3. What is the relative rate of diffusion of Fluorine to Chlorine?

1.36:1

Review:

1.

47 g of magnesium oxide is heated and decomposes. How many liters of oxygen are produced at 582.3 mmHg at 300 K? What if the oxygen was collected over water?

32.15L,18.89 L; 33.69 L,19.79 L

2.

What is the density of carbon monoxide at 27 psi and 200 °C?

1.32 g/L

3.

If you combine 30 g of hydrogen with 15 liters of chlorine at 744 Torr and 73°F, how many of mL of liquid HCl (density 1.18 g/mL) would be produced?

24.82 L

36.9 mL

4.

Chlorine diffuses at .15 m/s. How fast will Ne diffuse at the same conditions?

.28 m/s

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