Session Title: Session Leader: Pollution, Contaminants and Water Quality I Gib Chase Presenter: Presentation: Clayton McCoy Groundwater Discharge in the Coastal Zone: Quantification Methods and Contributions to Nearshore Geochemical Budgets cam0928@ecu.edu Email: Abstract: The continental shelf of Louisiana often experiences hypoxic conditions in summer months due to nutrient loading generally accepted as a product of landscape changes and land use practices within the Mississippi River watershed. Action plans to reduce nutrient loading and long term monitoring plans do not address the potential source of nutrients delivered to the continental shelf via groundwater discharge. The neglect of this potential source of nutrients could hamper long term progress and complicate strategic plans aimed at reducing hypoxic conditions in the region. Over the past decade, submarine groundwater discharge (SGD) in the coastal zone has become a topic of interest among the scientific community. SGD can occur anywhere an aquifer is hydraulically connected to the ocean and is discharged to the water column via nearshore seepage, seepage through a confining unit, or submarine spring. Considering groundwater is typically elevated in nutrients relative to surface water, SGD could be a substantial and overlooked component of nearshore geochemical budgets. This presentation reports the results of a project to determine SGD rates along the continental shelf of Louisiana using radon as a geochemical tracer of groundwater. Analysis of the data suggests that topography driven groundwater discharge is not a significant contributor to the geochemical budget of the region although previous research indicates SGD could contribute upwards of 40% of that which is discharged from the Mississippi. Management implications of SGD in the coastal zone include accurate assessment of discharge and potential inclusion of coastal nutrient budgets. Presenter: Presentation: Email: Abstract: Gunnar Lauenstein Characterizing the Magnitude and Extent of Coastal Contamination Associated with Hurricanes Katrina and Rita gunnar.lauenstein@noaa.gov The EPA, NOAA, FDA, and USGS are coordinating an environmental impact assessment of Hurricanes Katrina and Rita to characterize the magnitude and extent of coastal contamination and ecological effects from these storms. This talk provides an overview of efforts to characterize the fate and composition of the runoff from the hurricane events and to collect samples to assess the risk to seafood safety, focusing on the NOAA National Status and Trends Program Mussel Watch Project Contaminant Monitoring (Mussel Watch). Mussel Watch’s 20-year time series for over 120 contaminants in mussels from over 300 sites nationwide provides a long-term baseline for contaminant levels in the affected region. Two NOAA cruises (Sept. 13-16 and Sept. 24-Oct. 4) collected data to assess whether contaminant signatures from Katrina are significantly different from historic levels, and from neighboring regions. Scientists collected and analyzed sediment and oyster tissue samples for a standard suite of analytes, including conventional pesticides, metals, PAHs, and PCBs. Toxicity tests (Microtox and P450 assays) were conducted on the sediment samples. Sediment samples were also analyzed for concentrations of polybrominated flame retardants, the insecticide Fipronil, and Clostridium perfringens, a pathogenic microorganism widely distributed in the environment where spores of the organism persist in soil, sediments, and areas subject to human or animal fecal pollution. Water samples were analyzed for the triazine herbicide Atrazine, and for additional bacterial and viral indicators of fecal contamination. Preliminary results will be presented. Presenter: Presentation: Email: Abstract: Ruth Kelty Minimizing Human Health and Ecological Risks Posed by Mercury Contamination in the Gulf of Mexico ruth.kelty@noaa.gov The significant risk of mercury to human and ecosystem health constitutes a major resource management issue. The most common route of mercury exposure is ingesting mercury in fish and other seafood. Survey data have indicated that at least 300,000 U.S. newborns per year are exposed in utero to sufficient mercury placing them at risk of neurological diminishment (e.g., lower IQ). In 2004, EPA and FDA issued an advisory about fish consumption for women who might become pregnant, women who are pregnant, nursing mothers, and young children. Since mercury travels in a complex manner from power plants and other atmospheric sources through ecosystems and food chains, progress in implementing protective measures or management strategies has been hampered by a general lack of cohesive, inter-disciplinary knowledge, particularly of the inputs, occurrence, transformations, cycling, and food chain transfer in the coastal and marine waters. Stakeholders are demanding that health risks and economic impacts to fishing interests be reduced. In response, NOAA scientists are coordinating research programs to develop scientific information and tools for use in minimizing human health and ecological risks posed by mercury contamination. This talk will provide an overview of their approach, from monitoring mercury concentrations to determining mercury source, fate, and cycling to characterizing human health and ecological risk, to improving outreach to reduce those risks. Current efforts focus on the Gulf of Mexico, future work may build on long-term research in the Florida Everglades and importance of wetlands in the accumulation and food web-transfer in aquatic systems.