Surfactant is: A. Н2О B. NaCl C. C2H5OH D. HNO3 E. K4Fe[(CN)6] ANSWER: C How many times will the surface activity of surfactant increase according to the increasing of the hydrocarbon radical on group – СН2? A. in 2.5 times; B. in 3,5 times C. in 1,5 times; D. in 4,5 times; E. in 5,5 times ANSWER: B What is the dimension (unit) of the surface tension? A. Dynes /m2 B. Dynes.m2 C. Dynes/kJм2 D. J/ m2 E. J kg/m2 ANSWER: D What is name of the substances which decrease the surface tension when their concentration is growing? A. Hydrophilic. B. Hydrophobic C. Surfactant D. Unsurfactant E. Selection ANSWER: C What is the name of the interaction between molecules inside one phase? A. Adhesion B. Surface tension C. Cohesion D. Wetting E. Capillary condensation ANSWER: C The process of wetting is: A. Endotermic B. Reverse C. Exotermic D. Isochoryc E. Isotermic ANSWER: C What can surfactants do? A. increase the surface tension on the interface of phases B. reduce surface tension on the interface of phases C. increase the energy of the surface molecules D. do not change the surface tension on the interface of phases E. increase free energy of the surface on the interface of phases ANSWER: B The change in concentration of one or more components in the surface layer of sorbent is called A. Absorption B. Adsorption C. Desorption D. Chemosorption E. Capillary condensation ANSWER: B What’s phenomenon observed when carbon dioxide absorption of calcium oxide? A. Absorption B. Adsorption C. Desorption D. Chemisorption E. Capillary condensation ANSWER: D What’s phenomenon observing when the all volume of the liquid phase absorb the inert gas? A. Absorption B. Adsorption C. Desorption D. Chemisorption E. Capillary condensation ANSWER: A The chromatography is based on the phenomenon of: A. Osmosis B. Adsorption C. Electrophoresis D. Electrolysis E. Coagulations ANSWER: B The chromatography is the method of the analysis which is grounded on the redistribution of the substance between: A. Moving and nonmoving phases B. Two moving phases which don’t mix between each other. C. Liquid and solid phases D. Liquid and gas phases E. Solid and gas phases ANSWER: A What’s characterizing a chemosorption: A. The process is reversible process B. The heat of process is low C. The heat of process is high D. It doesn’t require any an active energy E. All process ANSWER: C What’s characterizing an physical adsorption: A. It forms multimolecules layer B. It forms unimolecular layer C. Surface compound are formed D. The process is irreversible process E. The heat of process is high ANSWER: A The suspension of what adsorbent is used for removal of intoxication caused by alkaloid poisoning? A. activated charcoal B. silica C. bentonite D. caoline E. starch ANSWER: A If the solute is adsorbed more strongly than the solvent, it is A. negative adsorption B. positive adsorption C. chemisorption D. cohesion E. wetting ANSWER: B The surface of which adsorbent is covered by Si-OH groups? A. cellulose B. activated carbon C. formaldehyde resin D. silica E. talc ANSWER: D Which adsorbent is used for surfactants adsorption from polar solvents. A. Silica gel. B. Activated charcoal. C. Graphite D. Talc. E. None ANSWER: A Application of an activated charcoal in medical practice based on its: A. Strong adsorption capacity; B. Hydrophobic properties; C. Hydrophilic properties; D. Minor density; E. Solubility in water ANSWER: A Dependence of an adsorption from the concentration of solution or pressure at the same temperature is described by: A. Gibb’s equation B. Helmholts’s equation C. Stephen Brunauer’s equation D. Langmuir’s equation E. Shyshkovskiy’s equation ANSWER: D Choose a synonym for limiting adsorption: A. Adsorption capacity B. Specific occupancy C. Adsorption capacity D. Capacity of monolayers E. Degree of surface coverage ANSWER: D What adsorbents are called the molecular sieves? A. soot B. phenol-formaldehyde resins C. zeolite D. clay E. activated charcoal ANSWER: C What factor prevents adsorptive interaction with the adsorbent. A. Reducing the temperature B. Incureasing pressure C. Increasing temperature D. Any factors do not affect E. Increasing concentration ANSWER: C In pharmaceutical practice widely used adsorbents. An important characteristic of adsorbents is the specific surface area, which is defined as A. The area of the interface B. The area of one particle. C. The ratio of the surface area of the phase separation to the mass of the dispersed phase D. The ratio of the surface area of the phase separation to the mass of one particle E. The ratio of the surface area of the interface to the square of one particle ANSWER: C The microcrystals of hard soluble substance in the center of micelle form: A. aggregate B. diffuse layer of contrions C. grain D. layer of potential determining ions E. adsorption layer of contrions ANSWER: A What is characterized of Brownian motion of dispersed systems particles? A. average displacement B. diffusion coefficient. C. Speed sedimentation. D. zeta-potential. E. Speed coagulation. ANSWER: A When a strong beam of light is passed through a MnO2 sol's solution the there is available the following phenomenon: A. scattering of light; B. interference of light; C. light reflection; D. Optimal anisotropy E. No one ANSWER: A Many drugs are dispersed systems. Which type of dispersed systems are emulsions? A. L-L B. L-S C. S-S D. S-L E. G-L ANSWER: A In the pharmacy there are often used medicines such as suspensions. Which type of disperse systems is this? A. S-L B. G-g. C. G-L. D. L-L. E. L-G. ANSWER: A Hydrosols of sulfur, cholesterol are obtained by the adding alcohol solutions of these substances to water. What the method is used? A. Changing the solvent. B. Chemical condensation. C. condensation of steam. D. mechanical dispersion. E. Chemical condensation. ANSWER: A The structural unit of the colloidal solution of medicinal substance is. A. micelle B. molecule C. atom D. ion E. zwitter-ion ANSWER: A Dispersed systems are used in pharmaceutical practice. The method of confirmation of the colloidal state is the passage of light through the system. According to that the beam of light: A. scattering in the form of a luminous cone B. affects C. absorbed D. undergoes refraction E. penetrates into the particle ANSWER: A Some drugs are colloidal solutions. Colloidal dispersion systems are the systems which include, the next size of particles: A. 10-9- 10-7 m B. 10-7-10-4 m C. 10-4 m D. 10-9 m E. 10-9- 10-4 m ANSWER: A In the pharmacy practice, there is used the microheterogeneous systems with a liquid dispersion and solid disperse phase. This dosage form is: A. Suspension B. foam C. powder D. Aerosol E. Emulsion ANSWER: A Emulsion, ointment, pasta, etc., can be prepared by crushing of solid and liquid substances in suitable environment. This method is called A. dispersion B. condensation C. sedimentation D. coagulation E. adhesion ANSWER: A Sol Al(OH)3 was received by a converting a freshly prepared precipitate of Al(OH)3 by a small quantity of HC1 solution. Which is the method of the sol preparation? A. Chemical peptisation B. chemical condensation C. Washing solvent D. Mechanical dispersion E. physical condensation ANSWER: A In pharmaceutical manufacturing practices are widely used drugs in the form of colloid-disperse systems. What method of sol obtaining belongs to the physical condensation? A. Exange of a solvent B. Recovery C. Oxidation D. hydrolysis E. double exchange ANSWER: A For purification of the colloidal solution is used such method as: A. Dialysis B. Titration; C. Electrodialysis; D. Ultrafiltration; E. Ultracentrifugation ANSWER: D What from of dispersion system is the smoke (G-gas, L-Liquid, S-solid)? A. G/S; B. S/S; C. L/L; D. S/G; E. G/L ANSWER: D System with size dispersed phase particle less 10-9 m is: A. True solution; B. Microheterogeneous; C. Macroheterogeneous; D. Homogeneous; E. Colloidal solution. ANSWER: A The average molecular mass of colloidal particles can be accurately determined by A. measurement of osmotic pressure B. tyndall effect C. brownian movement D. flocculation value E. coagulation value ANSWER: A The process of separation of colloids by passing through semi-permeable membrane is called A. filtration B. electrophoresis C. dialysis D. ultrafiltration E. none of the above ANSWER: C Medicines are often prepared as suspension. Which of the following phenomena characterize suspension? A. А. diffusion B. В, sedimentation C. С. osmosis D. Brownian movement E. Е. Opalescence ANSWER: B Free dispersion systems are A. Gel B. Foam C. Emulsion D. Ointment E. Past ANSWER: C Osmotic pressure of colloid systems… A. is very low B. doesn’t change according to the increasing of temperature C. is very high D. very strongly change at the light E. no correct answer ANSWER: A How does the Brownian motion change according to the increasing of the colloid particle radius? A. increase its fluctuating motion B. the Brownian motion decreases C. the Brownian motion increase D. the fusion increase E. the sedimentation goes slowly ANSWER: B What the potential predetermines colloid stability? A. chemical B. electrode C. electro kinetic (zeta) D. deffuse E. thermodynamics ANSWER: C What the phenomena is not electro kinetic? A. standard electrode potential B. electrophoresis C. electro-osmosis D. streaming potential E. sedimentation potential ANSWER: A The electrophoretic mobility is more when: A. the lesser net charge on the particle and the lesser the value of Zeta-potential B. the more particle mass C. the more viscosity of the dispersed medium D. the more concentration of the opposite charge ions E. the more charge of the particle and the value of zeta-potential ANSWER: E What is the electro-osmosis? A. the motion of particles of the dispersible phase B. the motion of polar liquid through a membrane or other porous structure under the influence of an applied electric field C. the diffuse motion of particles D. the motion of particles of dispersible phase at centrifuging process. E. the motion of particles of the dispersible phase in electric field ANSWER: B What is happened if the charge of the colloid particles is positive, at electrophoresis –process? A. they move to the cathode B. they move to the anode C. they stay at the beginning of the start D. the precipitate E. they coagulate ANSWER: A What the net charge of the colloidal particles (micelle) of Fe(OH)3 in the water solution of FeCl3: A. positive charge B. negative charge C. without charge D. micelle exists in isoelectric point E. precipitate out ANSWER: A The determination of electrokinetic (zeta) potential is… A. V/m B. V/m2 C. V D. Wt E. J/V ANSWER: C The coagulation power of an electrolytes ions depend on: A. mole fraction concentration of sol B. the charge of coagulation ions C. the viscosity of the dispersed medium D. the level of the dispersion of sol E. pressure ANSWER: B Coagulation power of an electrolyte is directly proportional to the: A. viscosity of the dispersed medium B. degree of dissociation C. dissociation constant D. valency of its ions E. none of the above ANSWER: D Pharmacist prepared protargol which is the colloidal solution of silver (I) oxide. For the increasing its stability pharmacist added high molecular compound (protein). Using the meaning of gold number (mg) choose high molecular compound that has the highest protection ability. A. gelatin – 0,035 B. egg’s albumin – 2,5 C. dextrin – 100,0 D. saponins – 35,0 E. none of the above ANSWER: A Choose the structural and the mechanical behavior of the dispersion systems: A. diffusion, viscosity B. osmotic pressure, elasticity C. elasticity, transparency D. viscosity, elasticity E. diffusion, strength ANSWER: D Which is value inversely proportional to viscosity? A. fluidity B. strength C. elasticity D. plasticity E. diffusion ANSWER: A What is the name the phenomena when the sheared system is allowed to stand, it eventually regains its original structure? A. asymmetropy B. thixotropy C. rheopexy D. mechanical stability E. sedimentation stability ANSWER: B The slow flow with constant viscosity without the destruction of the structure of the system is called ... A. creep B. strength C. elasticity D. plasticity E. diffusion ANSWER: A The science which is study about deformation and flow of matter, and its study has contributed much towards clarifying ideas concerning the nature of colloidal systems is called….. A. surface chemistry B. colloidal chemistry C. rheology D. phase analysis E. kinetics ANSWER: C The determination of viscosity is…. A. N/mol B. N*s C. mol/s D. J/mol E. Pа*s ANSWER: E The viscosity is increase when… A. temperature reduced B. surfactants exist in solution C. reduced the particle concentration D. reduced the activation energy E. рН = 7 ANSWER: A Measuring the viscosity is the base of the following analysis method: A. nefelometry B. stalahmometry C. osmometry D. electrophoresis E. viscosometry ANSWER: E The relative viscosities of two liquids can be determined by using of a: A. Stock’s viscometer B. Lengmuir’s viscometer C. Vant Hoff’s viscometer D. Ostwald’s viscometer E. none of the above ANSWER: D The pressure at any instant driving the liquid through the capillary is proportional to its… A. concentration B. pressure C. Brownian movement D. temperature E. density ANSWER: E What’s the name of process which characterizes the coming of drops together in close association in emulsion? A. coagulation B. flocculation C. sedimentation D. coalescense E. diffusion ANSWER: D Choose the surfactant which will the best stabilize emulsion of the type “oilwater”: A. ethanol; B. sodium sulfate; C. casein D. potassium chloride E. benzene ANSWER: C A lot of medicines are the dispersion system. Which of the type of the dispersed system has emulsion? A. liquid – liquid B. liquid – solid C. solid – solid D. solid – liquid E. gas – liquid ANSWER: A For increasing stability of the suspension to add… A. gelatin B. glucose C. ethanol D. sodium chloride E. none of the above ANSWER: A For what dispersion system sedimentation exists? A. suspension B. solution of high molecular compound C. solution of nonelectrolytes D. solution of electrolytes E. foams ANSWER: A Which of the type of the dispersed system has foams? A. liquid/liquid B. liquid/gas C. solid/liquid D. solid/solid E. gas/liquid ANSWER: E Some foams can freeze on the air (hemostatic sponge). Which of the type of the dispersed system has foams? A. gas/solid B. gas/liquid C. liquid/liquid D. liquid/gas E. solid/liquid ANSWER: A The stable foams you can obtain by adding …. to water: A. alcohols B. short-chain fatty acids C. oil D. saponins E. dyes ANSWER: D Suspension filtration through the porous membrane leads to the formation of A. past B. foam C. powder D. sol E. crystalline substance ANSWER: A Past – is A. the maximum concentrated emulsions B. the maximum concentrated suspensions C. foams which have the tendency for the liquid films to drain and become thinner D. coagulation of aerosol E. emulsion of the liquid metals in water ANSWER: B For what type of emulsion can you use hydrophilic emulsifier? A. water/oil B. oil/water C. diluted D. concentrated E. liquid metals in water ANSWER: B Which of the following coarse dispersion system don’t contain the stabilization factors? A. Aerosol B. suspension C. emulsion D. foam E. none of the above ANSWER: A Which of the following dispersion system is porous? A. gas/solid; B. liquid/gas; C. liquid/liquid; D. solid/gas; E. gas/liquid. ANSWER: A Which of the following optical property is the most intensive in suspensions? A. scattering of the light B. absorption of light C. refracted light D. light transmission E. none of the above ANSWER: A What type of emulsion is the butter? A. suspension B. emulsion oil/water C. emulsion water/oil D. sol E. past ANSWER: C What type of the dispersion system is juice? A. suspension B. emulsion oil/water C. emulsion water/oil D. sol E. past ANSWER: A What type of the dispersion system are pasts? A. diluted suspension B. emulsion oil/water C. emulsion water/oil D. jelly emulsion E. concentrated suspension ANSWER: E What type of the dispersion system is milk? A. suspension B. emulsion oil/water C. emulsion water/oil D. sol E. past ANSWER: B What type of the dispersion system are clouds? A. foam B. hydrosol C. aerosol D. suspension E. powder ANSWER: C What type of the dispersion system is baby powder? A. suspension B. foam C. powder D. sol E. past ANSWER: C If emulsion better dissolve in water than in benzene that means this emulsion is… A. diluted B. concentrated C. high concentrated D. oil/water E. water/oil ANSWER: D If emulsion good conduct electric current that means this emulsion is... A. diluted B. concentrated C. high concentrated D. oil/water E. water/oil ANSWER: D What are gels? A. a colloidal system in which a liquid is dispersed in a liquid B. a colloidal system in which a gas is dispersed in a solid C. a colloidal system in which a liquid is dispersed in a solid D. a colloidal system in which a solid is dispersed in a liquid E. none of the above ANSWER: C What’s the name of gel formation process? A. gelation B. precipitation C. sedimentation D. coagulation E. flocculation ANSWER: A What the charge has the carboxyhemoglobin (рН at the isoelectric point is 6,87), is placed in the buffer solution with рН=7,21? A. positive B. negative C. neutral D. 6,87 E. 1 ANSWER: B The macromolecule’s solutions are widely used in Pharmacy. What is the property of the true solution the macromolecule’s solutions have? A. Brownian movement B. present of the surface division C. scattering of light D. the great value of relative viscosity E. thermodynamic stability ANSWER: E The viscosity of HMC solution is: A. higher than viscosity of the colloidal solution B. equilibrium to the viscosity of the low molecular compounds C. equilibrium to the viscosity of water D. equilibrium to the viscosity of the colloidal solution E. less than viscosity of the colloidal solution ANSWER: A At the isoelectric point the protein charges: A. negative B. positive C. neutral D. 1 мV E. 1 мV ANSWER: C The salting out effect depends on A. molecular mass of electrolytes B. the movement rate of the ions C. temperature D. hydration degree E. duration of the action ANSWER: D Oncotic pressure of blood dues to the present of: A. low molecular compounds B. non-electrolytes C. protein’s components D. Water E. surfactants ANSWER: C The pH of the isoelectric point is 4,7. At wich рН macroion of the protein moves to the cathode? A. 7,0 B. 11,5 C. 5,0 D. 4,7 E. 3,5 ANSWER: E At the weakening of the protective action of the proteins the cholesterol deposits on the walls of the blood vessels due to the aggregation of its particles, this phenomenon is A. peptization B. sensibilize C. coagulation D. syneresis E. thixotropy ANSWER: C The method, which involves the removal of the low molecular weight impurities from colloidal systems and solutions of HMC by the diffusion through a semipermeable membrane is called: A. electrodyalysis B. decantation C. compensatory dialysis D. dialysis E. ultrafiltration ANSWER: D The swelling process of HMC is described by the kinetic equation of the… A. 0 order B. Fractional order C. 1 order D. 2 order E. 3 order ANSWER: C