Chemistry 107: Survey of Chemistry Fall 2006 Chem 107 is the first of a 3 quarter series covering the fundamental concepts of inorganic, organic, and biological chemistry and is intended primarily for students in various healthrelated programs. While no previous chemistry is required, high school chemistry or Chem 101 (100) is strongly recommended. Chem 107 requires modest proficiency with algebra; as such Math 65 is a prerequisite. The suggested reading level for Chem 107 is Read 98 (or higher placement) and a ‘C’ or better in English 099 (or higher placement) is required. Chem 107 will develop the central concepts of measurement and determination of physical properties; scientific and analytical methodology, the nature of atoms, molecules, and ions; bonding between atoms and molecules; mass relationships and stoichiometry; solubility and solution chemistry. Additionally, Chem 107 will focus on chemical reactivity in terms of equilibrium and kinetics. Acids, bases, and pH will be considered in some depth, and oxidation and reduction will also be developed. The course will be presented within a framework of practical relevance, and should provide a “chemical scaffold” on which to interpret physical phenomena, with examples geared towards the health science student. Chemistry 107 fulfills the requirements for a general education core class at WWCC. Instructor: Shane Hendrickson Office: Room 43, Phone: (509) 527-4558 e-mail: shane.hendrickson@wwcc.edu Office hours: M,F 1:30-3:00; T,W,Th 4:30-6:00; or by appointment Required Texts: Introduction to General, Organic, and Biochemistry, 8th edition, F. A. Bettelheim, W. H. Brown, M. K. Cambell and S. O. Farrell. Brooks/Cole (2007)1. Laboratory Experiments for General, Organic, and Biochemistry, 6th edition, F. A. Bettelheim, and J. M. Landesberg. Brooks/Cole (2007). Time & Location Lecture: M, T, W, F from 11:30-12:20 in Room 402 Laboratory: Th from 1:30-4:20 in Room 227 1 7th edition, Introduction to General, Organic, and Biochemistry, 7 th edition, F. A. Bettelheim, W. H. Brown, and J. March. Brooks/Cole (2004) is acceptable. Grading: The Grading for Chem 107 will be as follows 3 Examinations2 Exam I = 100 points (20%) Exam II = 100 points (20%) Final Exam = 100 points (20%) 10 Laboratory Experiments: 10 Labs(10 points/Lab) = 100 points (20%) 2 Quizzes: 2 Quizzes(20 points/Quiz) = 40 points (8%) 6 Group Exercises/Homework Assignments: 6 HW(10 points/HW) = 60 points (12%) Total graded* points = 500 *non-extra credit Grades will be assigned as a percentage of total points possible, as follows: Percentage 91-100 89-90.9 86-88.9 82-85.9 80-81.9 77-79.9 73-76.9 70-72.9 68-69.9 65-67.9 <65 Grade A AB+ B BC+ C CD+ D F As may be noted from the above, the course is not graded on a Gaussian distribution. I reserve the right to normalize the grades upward if the class average falls below a C+. However, the more likely occurrence will be the assigning of additional problems for extra credit 2 Exams will be a combination of multiple choice, short answer (generally mathematically based), and fill in the blank. Questions for the examinations will be taken from material covered in lecture (≥ 90%) and reading assignments (≤ 10%). Schedule of Tests: Section I: Physical Properties of Substances; Atomic & Molecular Structure; Mass Relationships and Stoichiometry – Friday, 10/13 Section II: Solution Chemistry; Behavior of Gases; Reaction Rate & Equilibrium – Friday, 11/03 Section III: Acids, Bases, and Salts; Nuclear Chemistry (Final Examination) – Friday, 12/08, 11:30 to 1:30 am, Room 402 Make-up Examinations Make-up exams will be considered only if you approach me before the scheduled exam with an exceptional, documentable excuse. Documentation is mandatory before a make-up examination will be provided. If you miss an exam and have not notified me beforehand you will receive a zero for that exam. Due to time constraints, make-up examinations will not be given for poor test performance. Excusal from Final In the event a student has only to pass the final to receive an A for the course, he or she is excused from taking the final examination. Since the total number of graded (non-extra credit) points in the course is 500, .91(500) = 455 points are required for an A. As a passing score for the final is 65, 390 points (455 – 65) accumulated prior to the final is required to have the examination waived. This corresponds to 97.5% of graded points (390/400) on all other work. All other work must be turned in to exercise this option. Behavior You are students who have elected to pursue professional careers in the health sciences. As such, little needs be said concerning behavior. You should be mindful of creating distractions, as they only impede your fellow students’ chances of success. Please note that questions are never considered a distraction, but must be limited to the topic at hand. Flagrant disruptive behavior will result in dismissal from class; failure to depart will result in the loss of 5 points for every minute the dismissed student remains. As a courtesy to others, cell phones should be turned off, or switched to vibrate only in the event an emergency call is anticipated. Cheating will not be tolerated under any circumstances. My standing policy is to give a score of 0 for any exam a student is caught cheating on. As each exam is worth 20%, and the division of letter grades roughly corresponds to 10% of the total points available, cheating on an exam will cost you no less than 2 letter grades. Disabilities If you are a student with a disability and would like to request an accommodation, please see me and/or make an appointment with Claudia Angus, Disabilities Coordinator (527-4262, Office 133H, e-mail:claudia.angus@wwcc.edu) as soon as possible. Additional information may be found via the following series of links from the WWCC website: old website current students student services disability services. All allowances must be approved by the Disabilities Coordinator. Tentative Schedule of Lecture Topics, Quizzes and Examinations Section I: Physical Properties of Substances, Atomic & Molecular Structure; Mass Relationships and Stoichiometry Week 1 Day Monday, 9/18 Tuesday, 9/19 Wednesday, 9/20 Thursday, 9/21 Friday, 9/22 Subject Course Introduction; Extra Credit Survey & Quiz (1.1, 1.2) Course Introduction Continued, Extra Credit Quiz Review (1.1, 1.2) Physical Properties and Their Measurement (1.3, 1.4) Laboratory 1: Check-In; Safety Considerations; Experiment 1 Laboratory measurements Physical Properties and Their Measurement Continued (1.3, 1.4) Week 2 Day Monday, 9/25 Tuesday, 9/26 Wednesday, 9/27 Thursday, 9/28 Friday, 9/29 Subject Unit Conversions and Dimensional Analysis; States of Matter (1.5, 1.6) Mass, Volume and Density; Temperature Conversions (1.4, 1.7) Heat, Temperature, and Energy; Temperature Conversions Revisited (1.4, 1.8, 1.9) Laboratory 2: Experiment 2 - Density determination Matter, Mixtures, and Atomic Structure (2.1, 2.2, 2.3, 2.4) Week 3 Day Monday, 10/02 Tuesday, 10/03 Wednesday, 10/04 Thursday, 10/05 Friday, 10/06 Subject Atomic Structure and the Periodic Table (2.4, 2.5, 2.6, 2.7) Chemical Bonds3: Formation of Ions from Atoms; Ionic vs. Covalent Bonds; Electronegativity and Polarity (4.1, 4.2, 4.4, 4.5, 4.7) Naming Ionic and Covalent Compounds (4.3, 4.6, 4.8) Laboratory 3: Experiment 3 - Separation of the components of a mixture; Homework 1 Due Lewis Structures; Resonance; Geometry of Covalent Molecules; Polarity (4.7, 4.9, 4.10, 4.11); Quiz 1 Week 4 Day Monday, 10/09 Tuesday, 10/10 Wednesday, 10/11 Thursday, 10/12 Friday, 10/13 Subject Group Exercise (Part of Homework 2, in Science Learning Center) Chemical Reactions4: Determining Formula and Molecular Weight; the Mole Concept (5.1, 5.2, 5.3) Chemical Equations and Mass Relationships in Chemical Reactions (5.4, 5.5) Homework 2 Due Laboratory 4: Experiment 6 - Formula of a metal oxide Examination 1 (proctored in Rm 287) Section II: Solution Chemistry; Behavior of Gases; Reaction Rate and Equilibrium Week 5 Day Monday, 10/16 Tuesday, 10/17 Wednesday, 10/18 Thursday, 10/19 Friday, 10/20 3 4 Subject The Gas Laws and O2 , CO2 Transport (6.1, 6.2, 6.3, 6.4, 6.5) Intermolecular Forces, States of Matter, and Phase Changes (6.7, 6.8, 6.9, 6.10) Solutions vs. Suspensions; Solubility; Molarity and Other Measures of Solution Concentration (7.1, 7.2, 7.3, 7.4, 7.5) Laboratory 5: Experiment 12 - Molar mass of a volatile liquid Group Exercise (Part of Homework 3) Chapter 3 in 7th edition Chapter 4 in 7th edition Week 6 Day Monday, 10/23 Tuesday, 10/24 Wednesday, 10/25 Thursday, 10/26 Friday, 10/27 Subject Dilutions; Water as Solvent; Osmosis (7.6, 7.7, 7.8) Reaction Rates: Measurement and Collision Theory (8.1, 8.2) Activation Energy; Changing the Rate of Chemical Reactions (8.3, 8.4) Laboratory 6: Experiment 14 - Solubility and Solutions Group Exercise (Part of Homework 3) Week 7 Day Monday, 10/30 Tuesday, 10/31 Wednesday, 11/01 Thursday, 11/02 Friday, 11/03 Subject Reaction Equilibrium and the Equilibrium Constant (8.5, 8.6) Relating Equilibrium and Kinetics; LeChatelier’s Principal (8.7, 8.8) Review for Examination 2; Homework 3 Due Laboratory 7: Experiment 16 - Factors Affecting Reaction Rates Examination 2; Last Day to Drop Section III: Acids, Bases, & Salts; Nuclear Chemistry Week 8 Day Monday, 11/06 Tuesday, 11/07 Wednesday, 11/08 Thursday, 11/09 Friday, 11/10 Subject Acid and Base Strength; BrØnstead-Lowry Acids and Bases; Conjugate Acid-Base Pairs (9.1, 9.2, 9.3) Chemical Equilibrium in Acid-Base Reactions; Properties of Acids and Bases; pH and pOH (9.4, 9.5, 9.6, 9.7, 9.8) Titration; Buffers & Buffer Capacity; The Relation Between Ionization and Solubility (9.9, 9.10, 9.11) Laboratory 8: Experiment 18 - pH and Buffer Solutions Homework 4 Due Holiday - Veteran’s Day Week 9 Day Monday, 11/13 Tuesday, 11/14 Wednesday, 11/15 Thursday, 11/16 Friday, 11/17 Subject Titration; Buffers & Buffer Capacity; The Relation Between Ionization and Solubility Continued (9.9, 9.10, 9.11) Common Buffer Combinations; Acid/Base Balance (9.11, 9.12) Group Exercise; Advising Day Laboratory 9: Experiment 19 - Analysis of vinegar by titration Homework 5 Due Quiz 2 Week 10: Thanksgiving Holiday – WWCC Closed Week 11 Day Monday, 11/27 Tuesday, 11/28 Wednesday, 11/29 Thursday, 11/30 Friday, 12/01 Subject Isotopes and Radiation (3.1, 3.2) Common Decay Pathways; Half-life and Carbon Dating (3.3, 3.4) Detecting Radiation; Health Considerations (3.5, 3.6, 3.7) Laboratory 10: Experiment 20 - Analysis of Antacid Tablets Radionucleotides in Medicine, Irradiated Foods, Atomic Energy (3.7, 3.8, 3.9) Week 12 Day Monday, 12/04 Tuesday, 12/05 Friday, 12/08 Subject Student Interest Topics Homework 6 Due Review for Final (Chapters 1-9) Final Examination; Lab 10 Due