Unit Design For Chemistry Thermodynamics Developed by Ghada Amer Name of My Charter: Pontiac Academy for Excellence 1 Understanding by Design Unit Design Worksheet Unit Title: Thermodynamics Topic: Thermodynamics Course: Chemistry Grade(s): 11-12 Name: Ghada Amer Stage 1 - Desired Results Established Goals: Content Goals: 1. C2.2e Compare the entropy of solids, liquids, and gases. 2. C2.3a Explain how the rate of a given chemical reaction is dependent on the temperature and the activation energy. 3. C2.3b Draw and analyze a diagram to show the activation energy for an exothermic reaction that is very slow at room temperature. 4. C3.1a Calculate the ΔH for a given reaction using Hess’s Law. 5. C3.1b Draw enthalpy diagrams for exothermic and endothermic reactions. 6. C3.2a Describe the energy changes in photosynthesis and in the combustion of sugar in terms of bond breaking and bond making. 7. C3.4B Explain why chemical reactions will either release or absorb energy. 8. C3.4d Draw enthalpy diagrams for reactants and products in endothermic and exothermic reactions. 9. C3.4e Predict if a chemical reaction is spontaneous given the enthalpy (ΔH) and entropy (ΔS) changes for the reaction using Gibb’s Free Energy, ΔG = ΔH - TΔS (Note: mathematical computation of ΔG is not required.) 10. C3.4f Explain why some endothermic reactions are spontaneous at room temperature. Literacy Goals (CCSS): Reading/Writing/Speaking: RST 11-12.5 Analyze how the text structures information or ideas into categories or hierarchies, demonstrating understanding of the information or ideas. RST 11-12.4 Determine the meaning of symbols, key terms, and other domain-specific words and phrases as they are used in a specific scientific or technical context relevant to grades 11–12 texts and topics. RST 11-12.7 - Integrate and evaluate multiple sources of information presented in diverse formats and media (e.g., quantitative data, video, multimedia) in order to address a question or solve a problem. RST 11-12.7 - Integrate and evaluate multiple sources of information presented in diverse formats and media (e.g., quantitative data, video, multimedia) in order to address a question or solve a problem. RST 11-12.9 Synthesize information from a range of sources (e.g., texts, experiments, simulations) into a coherent understanding of a process, phenomenon, or concept, resolving conflicting information when possible. RST 11-12.4 Determine the meaning of symbols, key terms, and other domain-specific words and phrases as they are used in a specific scientific or technical context relevant to grades 11–12 texts and topics. RST 11-12.4 Determine the meaning of symbols, key terms, and other domain-specific words and phrases as they are used in a specific scientific or technical context relevant to grades 11–12 texts and topics. RST 11-12.4 Determine the meaning of symbols, key terms, and other domain-specific words and phrases as they are used in a specific scientific or technical context relevant to grades 11–12 texts and topics. 2 RST 11-12 7 - Integrate and evaluate multiple sources of information presented in diverse formats and media (e.g., quantitative data, video, multimedia) in order to address a question or solve a problem. RST 11-12.5 Analyze how the text structures information or ideas into categories or hierarchies, demonstrating understanding of the information or ideas. WHST.11-12.2 Write informative/explanatory texts, including the narration of historical events, scientific procedures/ experiments, or technical processes. WHST.11-12.2a Introduce a topic and organize complex ideas, concepts, and information so that each new element builds on that which precedes it to create a unified whole; include formatting (e.g., headings), graphics (e.g., figures, tables), and multimedia when useful to aiding comprehension. WHST.11-12.8 Gather relevant information from multiple authoritative print and digital sources, using advanced searches effectively; assess the strengths and limitations of each source in terms of the specific task, purpose, and audience; integrate information into the text selectively to maintain the flow of ideas, avoiding plagiarism and overreliance on any one source and following a standard format for citation. SL.11-12.2 Integrate multiple sources of information presented in diverse formats and media (e.g., visually, quantitatively, orally) in order to make informed decisions and solve problems, evaluating the credibility and accuracy of each source and noting any discrepancies among the data. SL.11-12.5 Make strategic use of digital media (e.g., textual, graphical, audio, visual, and interactive elements) in presentations to enhance understanding of findings, reasoning, and evidence and to add interest. Understandings: Students will understand that Essential Questions: 1. What is entropy in matter? 1. there are different entropy trends in terms of solids, 2. Why is activation energy of a chemical reaction dependent on temperature? liquids, and gases. 2. energy is required to transform a substance from one state of matter to another. Energy is required to start a reaction. 3. How does energy and temperature change during an exothermic reaction versus an endothermic reaction? 3. temperature is directly proportional to energy lost or gained. 4. How can you calculate Enthalpy using Hess’s Law? 4. ΔH can be calculated and it interprets the magnitude. 5. How can you represent exothermic and endothermic reactions in a diagram? 5. construction and interpretation of data and graphs provides information for enthalpy of endothermic and exothermic reactions 6. How is energy involved in the combustion of sugar in photosynthesis? 6. entropy trends regarding photosynthesis and bond 7. How can you determine if a chemical reaction will release or absorb energy? breaking in chemical compounds can be identified. 7. description of the entropy trends in terms of solids, 8. How do you create an enthalpy diagram for reactants and products? liquids, and gases. 8. their interpretations of the energy diagrams they drew, 9. How can Gibb’s Free Energy tell us if a chemical reaction is spontaneous or not? for enthalpy of various reactants and products in exothermic and endothermic reactions. 9. calculations of entropy and enthalpy determine whether 10. Why are most endothermic reactions spontaneous at room temperature? a reaction is spontaneous, using Gibb’s Free Energy 10. entropy trends in terms of solids, liquids, and gases can indicate whether a reaction is spontaneous or not. 3 Students will know how Students will be able to 1. to solve for Entropy of solids, liquids, and gases. 1. state the equation and what each variable in the ▲S equation means. 2. to calculate activation energy and predict if it will increase or decrease based on rate of reaction and temperature change. 1. describe the entropy trends in terms of solids, liquids, 3. variables affect activation energy. 2. show the relationship between activation energy, and gases. temperature, and the rate of reaction using a given formula 4. to compute using a calculator the Enthalpy value given known variables. 5. to d raw and interpret graphs and tables given data. 6. photosynthesis is an example of thermodynamics. 3. understand how Activation Energy is dependent on reaction rates and temperature variables. 7. to predict and explain how energy is an important variable in chemical reactions. 4. calculate Enthalpy using the given equation, for reactions with different temperatures, entropy, etc. to identify if a chemical reaction has absorbed or released energy. 5. construct and interpret graphs and tables of data for enthalpy of endothermic and exothermic reactions to identify if a chemical reaction is spontaneous or not given Entropy, Enthalpy, or Gibbs Free Energy variables. 6. write out the equation of photosynthesis. 8. 3. interpret data from graphs and chart diagrams. 6. explain how sugar is involved in photosynthesis. 6. explain how bonds break and re-bond to form new compounds through the photosynthesis process. 9. to decide if a reaction is spontaneous or not. 7. explain how energy, which already exists or being produced, has a direct impact on our body, plants, fuel, and even homes. 8. explain why chemical reactions release and/or absorb energy. 9. explain the relationship between entropy and enthalpy to make a reaction spontaneous. 9. (Using Gibb’s Free Energy), calculate the free energy and state whether or not the reaction is spontaneous. 10. explain what makes a reaction spontaneous. Unit Enduring Understanding: Unit Question: 1. Students will understand that all chemical reactions involve energy. How do chemical reactions play a major role in our everyday life in terms of energy? 2. Students will learn how to calculate different forms of energy and interpret their meanings in regards to the data calculated. 4 Stage 2 - Assessment Evidence Performance Tasks: Goal: As a group complete a power point presentation on thermodynamics, including how to calculate Enthalpy, Entropy, and Gibbs Free Energy. Must include data from a previous experiment(s), diagrams, charts, and an elaborate interpretation of concepts. Role: Presenter/lecturer of information and researcher. Audience: Students in 11-12 grade (i.e. their classmates) Situation: You are a group of scientists and you must educate your peers on the principles of thermodynamics, and include various concepts as discussed and practiced over the last few weeks of class. Product: Thermodynamics Research Project in the form of a Power Point Presentation. Standards: Presented in a Power Point Presentation. Your work will be judged on the given rubric. Key Criteria: Science Research PowerPoint Rubric Objectives Less than Desirable Satisfactory Excellent! Best Effort Technology Skills-Demonstrates use 0-4 points of PowerPoint to present research Includes few of the topic required elements, less than 4 slides(containing few titles, facts, or pictures) 7 points Includes most of the required elements, 4-6 slides(mostly contains titles, facts, and/or pictures) 10 points Includes all of the required elements, 7-10 slides (containing titles, facts, and/or pictures) Knowledge Content- Demonstrates understanding of the topic and utilizes the appropriate terminology to communicate understanding throughout presentation 0-8 points Includes little important information, lacking either in relevance or accuracy 14 points Includes most of the needed information, lacking in either amount or accuracy 20 points Includes much needed information, is relevant and accurate Participation and Respect within Group- Demonstrates that can effectively work with a group to find and organize information to share with their peers, group members share in the responsibilities of the task 0-4 points Little participation or lack of respect for group members 7 points 10 points Usually participated and Almost always respected group members participated and respected group effort Spelling and Grammar0-4 points Demonstrates interest in presenting Five or more misspellings information in an accurate and and mistakes correct manner 7 points Less than 5 misspellings and mistakes 10 points Everything is spelled correctly and there are no mistakes Presentation - Demonstrates the ability to communicate their research and understanding to the class 7 points Presentation is organized and all group members participate 10 points Presentation is fluid and effective in helping class develop understanding of topic 0-4 points Presentation is unorganized and delivered without confidence Score: 5 Earned Points Other Evidence: Before During After KWL – Students will list what they know and what they want to know about thermodynamics. Journals – Students will complete daily journal reflections and take notes when necessary. Brainstorming – Students will discuss what they know about thermodynamics by breaking down the word and coming up with various meanings. Lab Investigations – Students will complete one or more lab investigation(s) exploring heat transfer. Unit Test – Students will be given a test after the unit has been completed and Presentations have been given Quick Writes – Before each lesson students will be asked to write their thoughts and questions for the day pertaining to the objectives. Pretest – Students will be given an assessment to understand their knowledge on the unit before any instruction is given. Daily Assignments – Students will be given vocabulary assignments and calculation problems. Power Point Project – Students will create a Power Point Presentation (as a group) of this unit. This will include various concepts, experimental data, vocabulary, and applications in the “real world”. Observations – Students will write down any observations in their journals as witnessed in class or during their labs. Think-Pair-Share – Students will work in pairs to discuss vocabulary and reinforce rules as they are introduced. Quizzes – Give short quizzes or Exit Cards - to show mastery of concepts needed before moving to the next concept. Describe the assessment/s and state the prompt if applicable. xF xS What type of scoring tools will be used for evaluation? □ Analytic rubric □ Holistic rubric X Criterion rubric □ Checklist X Answer Key □ Other Student Self-Assessment and Reflection: Students will write down their questions and or comments of the day’s events. They will write their questions about any topics or problems they have and they will discuss them as a class the following day. Students will also write down any observations they experienced during labs and/or lecture presentations. 6 Stage 3 - Learning Plan Differentiated Instruction: Level C: Complete #1 and choose 3 more of the following activities for a total of (40 points) 1. Make vocabulary cards – 10 points 2. Write a summary of the Principles of Thermodynamics – 10 points 3. Compare and contrast Endothermic and Exothermic reactions in essay form – 10 points 4. Write a one page essay on the four laws of thermodynamics – 10 points 5. Re-write all your notes taken in class, as an outline – 10 points Level B: Complete all of the following successfully for a total of (45 points) 1. Lab investigation – 15 points 2. Complete the worksheet packet and write a reflection paragraph on what you have learned – 15 points 3. Construct a graph and include the data table and calculate Enthalpy, Entropy, and Gibb’s Free Energy using the lab investigation data – 15 points Level A: Complete Both – GRASP plus the Unit Test – 110 points total 1. Unit Test – 50 points 2. Group Power Point Presentation – 60 points Learning Activities: Where/Why/What – Where are we going? Students will have a list of objectives posted at the beginning of the lesson. Students will also become aware of the final project and be given the list of expectations and rubric. Why? Students will be able to understand that energy is never lost it is only converted to a different form. What? Students will have a complete understanding of what thermodynamics is and be able to apply it to every day applications of energy. Hook/Hold – I will hook the student’s attention by demonstrating various reactions which involve both absorption of heat and loss of heat. I will prove how both types of reactions have total energy equal before the reaction and after the reaction. I will hold their interest through practical lab investigations where they will perform hands on applications of thermodynamic laws. Equip – Students will be equipped to succeed in this unit by giving them various prior knowledge concepts and giving them ongoing analysis tools and assessments in order to check for understanding and not allowing them to fall behind in new concepts and applications. Rethink/Revise - Students will be able to rethink and revise their work and understanding through think/pair/share, KWL, daily assignments, and class discussions. Evaluate - Students will self-evaluate through KWL during the unit and journal reflections. Students will have ongoing evaluations from lab investigations, class assignments and after the unit test and their group presentation. Tailor - Learning will be tailored by using differentiated instruction using various activities and teaching styles and modified for all IEP/ESL students including accommodations to provide extended time and group work when possible. Organize - The unit will be organized so that students have a brief review of law of conservation of energy and then learn essential vocabulary and key concepts pertinent to understanding all new concepts introduced. Frequent vocabulary review and quizzes will be used to check for understanding before moving on to new concepts. 7 Essential Vocabulary Absorb – to take up or receive by chemical or molecular action. Activation – the process whereby something is prepared or excited for a subsequent reaction. Activation energy – the energy that must be overcome in order for a chemical reaction to occur Bond – to hold together or cohere, from or as from being bonded, as bricks in a wall or particles in a mass Combustion – rapid oxidation accompanied by heat and, usually, light. Endothermic – noting or pertaining to a chemical change that is accompanied by an absorption of heat (opposed to exothermic ). Energy – the capacity of a body or a system to do work. Enthalpy (ΔH) – a quantity associated with a thermodynamic system, expressed as the internal energy of a system plus the product of the pressure and volume of the system, having the property that during an isobaric process, the change in the quantity is equal to the heat transferred during the process Entropy (ΔS) – (on a macroscopic scale) a function of thermodynamic variables, as temperature, pressure, or composition, that is a measure of the energy that is not available for work during a thermodynamic process. A closed system evolves toward a state of maximum entropy. (in statistical mechanics) a measure of the randomness of the microscopic constituents of a thermodynamic system. Symbol: S Exothermic – (“outside heating”) describes a process or reaction that releases energy from the system, Gibb’s Free Energy, ΔG= ΔH – TΔS – also known as free enthalpy[1] to distinguish it from Helmholtz free energy) is a thermodynamic potential that measures the “usefulness” or process-initiating work obtainable from a thermodynamic system at a constant temperature and pressure. Hess’s Law – states that energy changes are state functions. Photosynthesis – the complex process by which carbon dioxide, water, and certain inorganic salts are converted into carbohydrates by green plants, algae, and certain bacteria, using energy from the sun and chlorophyll. Room temperature – a comfortable temperature range indoors, usually considered to be 68 to 77°F (20 to 25°C). Spontaneous – arising from internal forces or causes; independent of external agencies; self-acting. Sugar – a member of the same class of carbohydrates, as lactose, glucose, or fructose. Temperature – a measure of the warmth or coldness of an object or substance with reference to some standard value. The temperature of two systems is the same when the systems are in thermal equilibrium. 8 Sequencing the Learning Monday Tuesday Wednesday Thursday Friday KWL – Thermodynamics Students will be given vocabulary terms to complete. Quick Write Thermodynamics Quick Write Thermodynamics Quiz Think, Pair, Share Think, Pair, Share Level C activities Level C activities Write a Summary of Thermodynamics Compare and Contrast Endothermic and Exothermic Reactions or Intro to Thermodynamics and prior knowledge Brainstorm What Thermodynamics Means Journal Writing – Students will be asked to keep journals for notes and reflections Thermodynamics Lecture and note taking in journals. Think, Pair, Share Level C activities Exit Card Exit Card Level B Activities – Worksheet Packet Assigned Rubric given for final presentation Write a Page Essay on the four laws of thermodynamics Quick Write – 3-2-1 What three things have you learned today, what 2comments do you have and what is one question you still have Monday Tuesday Wednesday Thursday Friday Think – Pair-Share KWL Level A Activity Level A Activity Presentations Due Level B Activity – Lab Investigation Level B Activity Lab Investigation Quick Write Level C Activity – Vocabulary Review Journal Entry Journal Entry Worksheet – Level B Activity Exit Card Level A Activity Presentations Due Group Power Point Presentations. Journal Entry Group Power Point Presentations. Journal Entry Class Discussion Monday Students will work on their Power Point Presentations -Computer Day- Tuesday Wednesday Review Day Level A Activity Level B Activity Worksheet Packet – Review of Calculation Problems Unit Test Exit Cards 9