REVIEW OF OIL AND WASTE STREAMS IN THE PORT OF BOURGAS CHRISTO KARAGYOZOV 1, MARIANA KARAIVANOVA1, VENCISLAV IVANOV2 1 University “Prof. Dr A. Zlatarov” Bourgas,e-mail: chcar@abv.bg 2 Maritime Administration of Bourgas, Bulgaria ABSTRACT The present paper reviews the oil spillages in the Port of Bourgas and its water area. The possible accidents during loading, discharging and other operations of oil tankers or oil product carriers are analyzed, as well as the types of oil and oil product pollutants. Special treatment is given to the operations in the “Rosenetz” oil terminal. The methods and equipment used to prevent pollution and to clean the polluted water areas are described. The organization of collection and treatment of oil spills and pollution from other sources is given in detail. Keywords: Oil spillage, Ships, Garbage, Bilge waters. 1. INTRODUCTION The Black Sea is an inner, almost closed sea, which is connected to the world ocean only by the Bosphorus (see Figure1). The Bulgarian Black Sea coast is on the southwest of the sea. The Black Sea is open to pollution coming from 17 countries situated on the border between Europe and Asia. The International Convention for the Prevention of Pollution from Ships MARPOL has classified the Black Sea as a “special area” [MARPOL - 1973/1978]. The Convention treats as “special” those areas where, “due to reasons related to their oceanographic and ecological conditions and the specificity of the maritime transport, special and compulsory measures have to be taken in order to prevent the sea from oil pollution”. This internationally acknowledged fact requires further measures for the preservation of the ecological balance of the Black Sea. In view of the future increase in the production of crude oil in the Black Sea region, the reconstruction of the old and the building of new oil pipelines on Russian and Georgian territory leading to the sea coast, the possible risk of large-scale pollution in the almost closed Black Sea has grown dramatically. Big amounts of spilt oil could float to the Bulgarian coast and considerably endanger the international tourist industry. Big rivers, like the Danube and the Dnieper, carry huge quantities of chemical pollutants, such as phosphorus and nitro compounds, which have strong negative effects on the marine flora and fauna. On the other hand, the intensive marine transport, including crude oil, oil and other chemical products, additionally aggravate the ecological situation in the region [Bakan and Buyukgungor, 2000]. The above-mentioned issue was the subject of the Odessa declaration of the ministers of the Black Sea countries and the programme for ecological management and protection of the Black Sea. 123 Bourgas Figure 1. Black Sea region [http://www.blackseaweb.net/]. In view of the above-mentioned agreements between the Black Sea countries, the present report is particularly pertinent in terms of the possible serious pollution of the sea by oil during transportation, loading and discharging operations and the storage of crude oil and oil products. 2. SOURCES OF POLLUTION OF THE WORLD OCEAN AND THEIR CHARACTERISTICS 2.1. Basic sources of pollution with oil and oil products The basic sources of pollution with oil and oil products are presented in Figure 2. Sources of pollution of the marine environment with oil products 37% 45% Land based Atmospheric Natural 2% 7% 9% Oil rigs Shipping Figure 2. Percentage distribution of the sources of pollution of the world ocean [Response to marine oil spills, The international tanker owners pollution federation ltd, 1997]. According to their origin, they are classified as: Land based sources: industrial or communal, which comprise about 37% of the total amount of oil products entering the marine environment; Atmospheric sources: they comprise about 9% of the total amount of oil products entering the marine environment; 124 Natural sources: situated on the territory of the respective basin; they comprise about 7% of the total amount of oil products entering the marine environment; Oil rigs and exploration products: they comprise about 2% of the total amount of oil products entering the marine environment; Shipping: according to statistics the percentage of pollution due to shipping is about 45% globally, 12% of which is due to tanker accidents and 33% to routine shipping operations. 2.2. Classification of oil spillage due to shipping Depending on the amount of oil products spilt during shipping, spillages are classified as follows [Response to marine oil spills, The international tanker owners pollution federation ltd, 1997]: Small: amounts of spilt oil products under 7 tonnes. Such spillage is mainly due to routine operations, such as loading and discharging of tankers, bunkering, illegal discharge of bilge waters, dry docking, etc; Medium: spillages of between 7 and 700 tonnes. The majority of these result from the grounding and accidents of tankers; Large: these are spillages of oil and oil products exceeding 700 tonnes. This classification of oil spillage is illustrated in Figure 3. It shows the percentages of the different types of spillage according to the statistics about the world ocean [Oil Transportation by Tankers, 1975]. Comparative analysis of the spillage from tankers as a result of routine operations and accidents in the world ocean large (>700t), % loading and discharging bunkering medium (7-700t), % collision grounding small (<7t), % 0% 20% 40% 60% 80% 100% number of spillages, % Figure 3. Comparative analysis of the spillage from tankers as a result of routine operations and accidents in the world ocean. 3. OIL SPILLAGES IN THE BLACK SEA PORT OF BOURGAS The transportation of crude oil in the Black Sea region is about 189 million tonnes per year (1995 data), the main sea routes being Novorossiysk – Costanta, Bourgas – Novorossiysk – Bourgas, Constanta – Poti – Constanta, Bourgas – Poti, Varna – Tuapse. The major risk for oil pollution accidents are the ports and the oil installations including oil terminals, pipelines, etc. In the region under the jurisdiction of the State Maritime Administration, Bourgas, the largest risk of oil pollution accidents comes from the Bourgas oil port, because it handles crude oil, petrol, diesel oil, mono and diethylene glycol, benzene, acrylonitrile, styrene and other chemical products [Official Site of Port Administration Agency, BG]. 125 3.1. “Rosenetz” Oil Terminal 3.1.1. Sources of pollution with oil and oil products The “Rosenetz” Oil terminal (also known as Bourgas oil port) is located on the southern coast of the Bourgas bay 8 km away from the city. It is operated by “Luckoil Bourgas” and has its own company procedure for dealing with accidents which result in the pollution of the marine environment with oil and/or harmful chemical liquids. Currently, the company does not have its own means and equipment to cope with pollution from spillage. The activities of limiting and cleaning the polluted areas are performed by the marine waters cleaning directorate, Bourgas branch. The inflow of sludge water in the “Rosenetz” Oil terminal is as follows: Contaminated ballast water from oil tankers; Washing water from the handling of oil and oil products tankers; Contaminated ballast water from tankers carrying chemical substances; Washing water from the handling of tankers carrying chemical substances. The Oil port does not possess the necessary equipment for the storage and treatment of such waters as required by the MARPOL [MARPOL - 1973/1978] convention. For this reason the Regional Inspectorate for the Protection of the Environment disallowed the acceptance of such oily sludge as of 1996. At present the situation is the following: At the “Rosenetz” oil terminal, there is a network of installations for the partial treatment of sludge water (sewage water, faecal matter, industrial water, etc.) (Figure 4). It is evident from the diagram that the ballast water from piers 1A and 1B is collected in underground tank 3 which has a capacity of 10 000 m3. The tank is made of steel and is buried underground, which is a potential risk to the environment in the future. A separate tank 4 has been planned and is being built, where the water contaminated with chemical substances from pier 1C will be collected. The contaminated ballast water is passed through distribution shaft 6 to oil separator 7. The latter has a capacity of 648 m3, 432 m3 of which working capacity, with the following dimensions: length 36 m, width 6 m and depth 3 m. The actual state of the oil separator does not allow for its efficient functioning. It could be said that, practically, it is useless. The contaminated ballast water treated in the oil separator is passed through the second distribution shaft 8 into the so-called primary oxidation lakes 9 and 10 and oxidation lake 11. After the lakes the water passes into a reedy water area, where it is finally cleaned and goes into the sea. Positions 2, 5 and 12 on the scheme present supporting tanks. It is clear from the above that the method and range of equipment and installations used in the treatment of ballast and other wastes cannot guarantee the safety of the environment because the treatment is incomplete. There is an urgent necessity to construct a new network of installations and use a new method for the treatment and recycling of contaminated ballast water, which according to “Luckoil – Neftochim” should have the following capacity: ballast water contaminated with oil - up to 50,000 m3 per annum; ballast water contaminated with chemicals - up to 40,000 m3 per annum; sewage water contaminated with oil - up to 86,000 m3 per annum; sewage water contaminated with chemicals - up to 18,000 m3 per annum; contaminated rain water - up to 40 m3/h. The design capacity of the equipment for the treatment of all oil contaminated waters has to be 80 m3/h, and those contaminated by chemicals – up to 40 m3/h. During the exploitation of the “Rosenetz” oil terminal there have been local leakages and spills of oil, oil products and chemicals due to accidents, repairs and other activities, and as a result part of the soil on the site is polluted. 126 3 5 4 T-1 T-19 (T- 3 , T-4* ) 1A 1B 1C 6 8A 7 8 9 12 2 * (T-1-T-19 ) 11 10 The Black sea Legend: 1.A,B,C piers; 2. tank for petroleum products; 3. underground tank for sludge water T-3 – 10 000 m3 underground steel and concrete tank for oil contaminated water; T-4* – 10 000 m3 underground steel and concrete tank for water contaminated with chemical products; * in the future this type of sludge water is to be treated separately 4. crude oil tank; 5. 6. 7. 8. 8A. 9. 10. 11. 12. untreated materials storage; distribution shaft; oil separator; distribution shaft; level gauge; primary oxidation lake; primary oxidation lake; oxidation lake and reed lake; settling tank. Figure 4. Diagram of the flow and treatment of sludge water in the Oil port. 3.1.2. Soil Contamination and Activities for its Re-cultivation The contamination of the soil is due mainly to sewage leakages, overflow of sewer shafts, pipeline punctures, cleaning of tanks, contamination of the soil and soil bank coating of tanks, as well as the exploitation of the oxidation lake on the territory of the Oil terminal. These contaminations belong to the so-called “old ecological damages” to deal with which “Luckoil – Neftochim Bourgas” has endorsed a Recovery Measures Plan. The preparation of a detailed project for the elimination of the old ecological damages has been assigned to “Niproruda” Ltd. The total area of soil contaminated with oil products is 66,495 m2; The amount of soil to be replaced is 26,598 m3; The amount of surface deposited sediments is 9,212 m3; The total amount of soil to be excavated is 35,810 m3. The following activities have been planned for the recovery of the contaminated soil (according to Niproruda’s Baseline project). 127 Survey and stabilization of the areas – by means of geodetic polarographic method survey; Vertical levelling of the polluted areas in zones 8, 9 and 10. In combined zone 8,9,10 a temporary depot for the storing of polluted soil substrates and construction rubbish is built. The vertical levelling will aim to achieve a shape of relief of the polluted areas close to the natural; Establishing the amount of earth mass to be replaced. The site has been divided into two sub-sites: - Sub-site А – 14,084 m3 earth mass to be replaced; - Sub-site B – 12,514 m3 earth mass to be replaced. According to Ordinance No 26/1996 concerning the recovery of damaged terrains and the improvement of low productive lands, removal and utilization of the humus layer, recovery has two stages: technical and biological. Technical recovery comprises a system of technical activities aiming to prepare the terrain, to facilitate and ensure the success of the biological recovery. a) Technical recovery of the site The main task of the technical recovery is to create the necessary conditions for the development of vegetation and to reduce the risk of deep infiltration of pollutants. The technical recovery will have the following stages: Removal of contaminated soils. Replacement of soil substrates with established contamination over the allowable concentration. They will be removed from all zones mentioned with a total area of F=66,495 m2 up to a depth of 0.4 m. The removed earth mass will be transported to the first oxidation lake; Backfilling of the areas with suitable geological materials – gravel and concrete will be used; Improvement of the quality of the soil substrate. This is done through the introduction of soil ameliorators by using: Peat (sphagnum): 2 m3/decare (рН= 3,5-4); Manure: 4 t/decare. b) Biological recovery Biological recovery aims to stabilize the soil. It is carried out after the end of the technical recovery at a time of the year which favours the development of vegetation, e.g. March in spring or September or October in autumn. A mixture of perennial grasses suitable for the given conditions will be used: unpretentious, with a strong root system and good soil stabilizing effect. Meadow fescue (Festuca pratensis); Perennial ryegrass (Lolium perene); Trefoil (Lotus corniculatus). If the technical and biological recoveries are carried out timely and properly, the following ecological results can be expected: Limiting the effects of the pollution of the area with oil and oil products; Incorporation of the recovered areas in the natural landscape; Minimising the effect of the water and wind erosion processes; Providing conditions for the development of plant and animal life; Improvement of the local environment and living conditions. 128 3.2. Pollution of the Port of Bourgas with oil products 3.2.1. Rubbish Classification The main flows of rubbish into the port of Bourgas are as follows [Vasilev at al. 1999]: Rubbish from the motor vessels permanently staying in the port and from those which visit it; Rubbish from the routine port activities and from the other companies on its territory. Ships’ rubbish can be of the following types [Vasilev at al. 1999]: Rubbish containing oil products, such as: o used lubricating and machine oil; o oil residues; o bilge waters; o contaminated ballast from oil tanks. Rubbish containing harmful liquids generated as a result of washing the tanks of chemical products carriers; Ships’ garbage: These are domestic food waste, packaging, glass and plastic bottles, sanitary waste, paper, cardboard, etc. To this category also belong garbage from the ship’s maintenance – oily rags and cloth, garbage from the ship’s engine; and Mechanisms, damaged and replaced parts, packaging materials – paper, cardboard, metal, ashes and fireproof materials, debris of old paint and rust. Of the same kind are cargo refuse and garbage related to the cargo – cargo fastening materials such as timber, pallets, etc, as well as fishing nets, ashes and slag from the ships’ incinerators. The following types of rubbish are collected, transported and made harmless in the port of Bourgas [Vasilev at al. 1999]: Oil containing refuse; Ships’ garbage. 3.2.2. Oil containing refuse The processing of the oil containing refuse is done by a company authorized to perform such activity as required by the Law for the restriction of the harmful influence of refuse on the environment, after an order issued by the ship through its shipping agent [Vasilev at al. 1999]. It is collected by oil-collecting barges and kept in mobile temporary stores or barrels. There are two such barges with a capacity of 16 m3/h functioning in the port of Bourgas. They can only be used in sheltered water area. Another vessel which is used for the same purpose is the “Rusalka”, a bilge water collecting barge with a capacity of 140 m3/h and a separator on board to recycle the water. It also has 1,000 m of oil booms. The “Rusalka” has good seafaring characteristics and can operate in open waters. The collected oil containing waters are kept on a floating store. After that they are loaded onto a tank truck and carried to the recycling plant in Varna. The approximate amount of oil containing ship waters collected in the Port of Bourgas in 2002 is shown in Figure 5. The diagram shows both ships sludge and bilge waters. In the Port of Bourgas the flows of hold waters of the visiting ships are collected and treated by the Marine waters protection and cleaning directorate. This company is directly responsible to the Ministry of Transport and has branches in Varna and Bourgas. For example, in 1997 and 1998 the branch in Bourgas collected and treated the hold waters of: 1997 – 340 ships; 1998 – 213 ships. 129 Ships refuse containing oil products collected in the Port of Bourgas in 2002, by month m3 100 80 60 bilge waters sludge 40 20 D ec e m be r er t ob O ct ne Ju pr il A ug us A Fe br ua ry 0 Figure 5. Ships oily refuse in the Port of Bourgas in 2002. 3.2.3. Handling and Cleaning of Oil Spills The collection of hold waste waters is a slow process: for smaller ships – up to 16 m3/h. The water is collected in two barges, each of which has a capacity of 1,000 m3. After the separation the recycled oil products are sold to licensed companies and transported by rail or truck tanks. The oil products are used for furnace fuel or are returned to the oil refinery. The fee for the collection of hold waste waters is $70/h or $5/m3 collected oil contaminated water. At present, the hold water contaminated with chemicals is not collected. A relatively high risk of pollution is present in the water areas of the Ship repairing yard and the Bourgas Shipbuilding yard. The two companies observe respectively the Ordinance for the way of working with rubbish from ship repair and the Plan for fighting with pollution of the marine environment with oil and other chemical substances. During the whole year, the background pollution in the Port of Bourgas area is generally created mainly by land based sources: the outflow of the city sewage – mainly through the “Vaya” overflow canal and the sewage pipe at berth 5A in the “East” port terminal, especially after torrential rains; other risky areas are the berths and the water areas in the ship repairing and Shipbuilding yards, as well as berth 23 in the West terminal, which has often been drained after being flooded with rain water. Figure. 6 presents a line diagram of the collection and treatment of contaminated hold water from the handled ship. For the handling and cleaning of oil spills, which were 8 in 1997 and 3 in 1998 in the central port area with an amount of 8,5 m3, the company has 1,500 m of oil booms, which are insufficient in length and quality – they are made of inflammable materials. Figure 7 shows a line diagram of the handling of oil spills. 130 RIEW Figure 6. Line diagram of the treatment of hold waters; (MA - Maritime Administration; RIEW Regional Inspectorate of Environment and Water). RIEW Figure 7. Line diagram of the handling of oil spills; (MA - Maritime Administration; RIEW Regional Inspectorate of Environment and Water). 3.2.4. Ships’ Garbage As for the solid garbage, the Port of Bourgas deals with the domestic, packaging materials, plastic and glass bottles, paper and cardboard as presented in the following chart: For example line diagram of solid garbage and the amounts collected food rubbish can be seen in Figures 8 and Figures 9 respectively. Ship Collection and transportation Disinfection site Deposition Depot Bratovo in barrage or truck Figure 8. Line diagram of solid garbage. 131 300 10 200 food rubbish food rubbish, bags Au gu st Se pte mb er Oc tob er No ve mb er De ce mb er Ju ly Ju ne M arc M ay 0 Ap ril 0 h 100 Ja nu ary Fe br ua ry 5 number of bags 3 m 15 Figure 9. Amounts of food rubbish collected in the Port of Bourgas in 2002, by month. 3.2.5. Handling of Refuse from Port Operations Figure 10 presents a line diagram of the handling of refuse from port operations. The waste industrial water from the port with amount of 19 240 m3 passes through an oil separator with a capacity of 80 m3 per day and the flows into the city sewage system and is recycled in the city waste water recycling plant. For the whole period of exploitation of the Port of Bourgas, there has not been a record of oil or oil products spillage in the port water area. This confirms the importance of coordination between all offices and companies to prevent spills in the water area of the Bourgas oil port and the Bay of Bourgas. In view of the unique ecosystem of the Black Sea and its hydrological characteristics (lack of circulation of water masses, high level of hydrogen sulphide and low salinity), a large scale spill will be devastating for the frail ecological balance in the Black Sea. The results of the preliminary survey show that the present organization of the process of dealing with rubbish flows is satisfactory: The metal scrap is collected daily, stored and carried away for recycling; The wood garbage is collected daily and carried to a distribution point, where they are handled and after that used as burning wood; The oil products and fuel sludge are collected in a tanker at berth 20 and carried away for recycling. The recycled materials are stored and sold to licensed companies; The rest types of refuse are collected in special containers and carried periodically to the rubbish dumps in Bratovo or Marinka. 4. CONCLUSION The present review of the possibilities for spillage of oil and oil products in the area of the Port of Bourgas shows that the risk of accidents is not to be underestimated. The present organization (institutions bearing the responsibility) for the prevention and dealing with the results of spillage needs modernization. The equipment and manpower also need to be improved. Constant monitoring 132 for the presence of oil contamination needs to be ensured. The issue is important on an international scale and its significance is increasing because the Black Sea is a sea route for the transportation of large amounts of oil and oil products. The efforts of all Black Sea countries should be directed to the establishment of an international organization for dealing with oil spills because the consequences in this closed sea will be unpredictable. Metals Port of Burgas Terminals Directorate Workshops Technical Departments: Technological; Administrative and Social Collection separation and transportation of the difterent types of refuse: Burned for heating Rubber Dump site Construction materials Dump site Paper Luminiscent Light bulbs Communal economy Transport Workers Hospital Administration Wood Recycled Dump site Permanent storage Ashes Dump site Oil separator refuse Dump site Batteries Recycled Oil products (used oil) Recycled Domestic rubbish Dump site Hay Dump site Figure 10. Line diagram of the handling of refuse from the operations in the Port of Bourgas. 133 REFERENCES Bakan G., H.Buyukgungor, Maritime Pollution Bulletin, Vol 41, 16, pp 2443, 2000. MARPOL – 1973/1978. Official Site of PAA, Port administration Agency, BG. Oil Transportation by Tankers: An Analysis of Marine Pollution and Safety Measures. Congress of the United States office of Technology Assessment, July 1975. 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