Last update December 2015 Address: ICCOM-CNR Area di Ricerca di Firenze, room C163 Via Madonna del Piano 10 50019 Sesto Fiorentino (FI), Italy (EU) Italian citizen, male, married Email: l.gonsalvi@iccom.cnr.it www.iccom.cnr.it/gonsalvi/ Phone: +39 055 5225251 Fax: +39 055 5225203 Keywords: sustainable chemistry by catalysis (homogeneous catalysis: hydrogenation, oxidation, carbonylation, hydroformylation; heterogenised catalysts); synthesis and mechanisms (catalytic mechanisms; organometallic chemistry in water; white phosphorus coordination); catalysis for hydrogen production and storage (formic acid dehydrogenation; carbon dioxide hydrogenation). Education and Research Luca Gonsalvi Research Staff (permanent, collaboration Dr. Maurizio Peruzzini) Istituto di Chimica dei Composti Organometallici, Area di Ricerca CNR di Firenze (ICCOM-CNR), Sesto Fiorentino, Firenze, Italy, 2001-present Research Lines: (a) Hydrogen production and storage by HCOOH/CO2 catalytic dehydrogenation / hydrogenation cycle; (b) Synthesis of novel water soluble transition metal cyclopentadienyl complexes [(C5R5)MX(PTA)2] (R = H, Me; M = Ru, Re, Rh, Ir; X = H, halogen, solvent; PTA = 1,3,5-triaza-7-phosphaadamantane) and use as regioselective catalysts for hydrogenation of unsaturated substrates in aqueous biphasic conditions; (c) P4 chemical activation via mono- and bimetallic complexes; (d) water soluble organometallics as antimetastatic drugs. Postdoctoral Research Fellow (Supervisors Prof. Dr. Roger A. Sheldon, Dr. Isabel W. C. E. Arends) Delft University of Technology (TUD) and IOP Catalysis, The Netherlands, 1999-2001 Research Project: Catalytic oxidation of ethers and acetals to esters. Development and optimisation of highly selective oxidation protocols for the catalytic conversion of ethers and acetals to esters with high atom efficiency and low E-factor, using oxygen/air, hydrogen peroxide and other cheap oxidants (i.e. hypochlorite), under homogeneous, heterogeneous, biphasic conditions. Doctor of Philosophy – Organometallic Chemistry and Catalysis (Supervisors Dr. Anthony Haynes, Prof. Peter M. Maitlis FRS) University of Sheffield and BP Chemicals, United Kingdom, 1996-1999. Research Project: “Ligand Effects on Homogeneous Methanol Carbonylation”. Synthesis of chelated complexes [M(CO)I(LL)] (M = Rh, Ir; LL = PS, PP, PO, NN bidentate ligands) and kinetic studies of oxidative addition and migratory insertion in the reaction with MeI as models for stereoelectronic ligand effects in methanol carbonylation. Postgraduate Grant Holder (Supervisors Prof. Giovanni Predieri, Prof. Mirco Costa) Department of General and Inorganic Chemistry, University of Parma, Italy, 1994. Research Project: Study of catalytic properties of xerogel-bonded ruthenium clusters. Synthesis of organicallymodified materials by sol-gel process; binding of ruthenium clusters and application in alkyne hydrogenation and olefin hydroformylation processes. Laurea in Chimica (Supervisors Prof. Giovanni Predieri, Prof. Antonio Tiripicchio) University of Parma, Italy (M. Sc. Hons Chemistry, 5 years course, 12 months research project), 1987-1993. Research Project: “New hybrid inorganic-organic materials from sol-gel process. Applications in catalysis and precious metals recovery”. Synthesis of thiourea-modified silica by sol-gel process, binding of Rh(I) and Pd(II) and application in alkyne hydrogenation and olefin hydroformylation. Use of the materials as stationary phase for selective extraction of Pd(II), Rh(I), Ru(III), Ag(I), Pt(IV) from acidic aqueous solutions. Technical Skills Schlenk, vacuum and inert-atmosphere manipulation of moderate air, moisture sensitive organometallic and organic compounds. Liquid phase NMR including multi-nuclear, variable temperature, sapphire tube HP-NMR. Fischer-Porter apparatus and Parr autoclaves. Synthesis of heterogenised catalysts via LDH and modified silica. Fully conversed in GC, GC-MS, HPLC techniques and HP-IR, IR, UV-vis spectroscopy. Non-standard analytical techniques (SEM, XRF). Solvent and reagent purification, product isolation using vacuum distillation, crystallization or sublimation. Graphic design, molecular visualization (Chemdraw, Chem3D, ISIS Draw) Detailed knowledge and use of MS Office and other packages (PC and Macintosh). On-line multimedia presentations for progress report and meetings. ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 1 Last update December 2015 Bibliometric Data - (ISI Thomson WoS, 29/11/2015): results: 93; sum of times cited: 2230; citing articles: 1466; average citation per item: 23.98; h-index: 26. Researcher ID: D-8393-2011; ORCID ID: 0000-0002-5996-6307. Teaching and Supervisor Activity Tutor of more than 20 young researchers, postdoctoral, doctoral and graduate students, since 1999, including: Scientific supervision of 3 doctoral and 3 postdoctoral projects, ICCOM-CNR (2008-present); Scientific supervision of 2 postdoctoral projects (FP6 MC-RTN Aquachem), ICCOM-CNR, 2004-2007; Scientific supervision of 3 postdoctoral projects (FP5 MC-RTN Hydrochem), ICCOM-CNR, May 2003-2005; Full supervision of a IAESTE 3months stage undergraduate project, TUD, 2001; Co-supervision of a 3rd year undergraduate project, University of Sheffield, 1999; Three years demonstrating in inorganic chemistry undergraduate teaching laboratories, University of Sheffield, 1996-1999; Tutorship for General and Inorganic Chemistry undergraduate Chemistry students, University of Parma, 1992-1994. Co-supervision of undergraduate final year projects in Inorganic Chemistry, University of Parma, 1994; Demonstrating in inorganic and analytical chemistry undergraduate teaching laboratories, University of Parma, 1992-1994. Lectur course in Homogeneous Catalysis (postgraduate level), University of Florence, 2013. Management Activities - - Principal Investigator (PI) in WG2 of COST Action CM2405 CARISMA “Catalytic Routines for Small Molecules Activation” (2013-2017) National Coordinator for WP2 of CNR project EFOR “Progetti CNR per il Mezzogiorno” (2011-2015) ICCOM Research Unit Responsible: Chemical Hydrogen Storage and Production by Organic Hydrides (Formic acid and CO2 catalyzed activations) ICCOM Research Unit Responsible: Homogeneous Catalysis in Water and Biphasic Systems (Water-soluble ligands, organometallic complexes and application in catalytic hydrogenation and hydroformylation) Scientific Responsible for Strategic CNR Activity Module PM03.005.001 (Hydrogen production and Storage) and Curiosity-Driven CNR Activity DG.RSTL.020.004 (Valorisation of Inorganic Feedstocks) Partecipation to International (FP6 and FP7 MC Actions, COST, INTAS, EERA), National (PRIN), CNR (Premiale, Cluster, Mezzogiorno), Ministry for Environment (PIRODE), ECRF Foundation (Hydrolab, Hydrolab-2) and Region Tuscany (EBH2) Projects (2004-present). Scientific Responsible for bilateral CNR-CNRS Project (Italy-France) 2010-2012 Scientific Responsible for Joint Mobility Project Italy-USA 2008-2010 (joint reviewed), Ministry for Foreign Affairs. Scientific Secretary of COGICO-9, 9th Interdivisional Congress of Organometallic Chemistry, Florence 8-11/6/2010. Scientific Secretary of EWPC-6, 6th European Workshop on Phosphorus Chemistry, Florence 26-27/3/2009. Network Manager of Project AQUACHEM, Transition Metal Chemistry and Catalysis in Aqueous Media (FP6 RTN project n° MRTN-CT-2003-503864) 2004-2008. Other Activities - - Member elected of Scientific Committee of ICCOM (2009-2015). Peer-reviewer for Angew. Chem Int. Ed., Chem. Eur. J., ChemSusChem, Eur. J. Inorg. Chem., Beilstein J. Org. Chem. (Wiley) ; Chem. Rev., Organometallics, Inorg. Chem., ACS Catal., ACS Appl. Mat. & Interfaces (ACS); Coord. Chem. Rev., J. Organomet. Chem., Appl. Catal. A Gen., Appl. Catal. B Environm., Inorg. Chim. Acta, Inorg. Chem. Commun., Catal. Commun., J. Catal., Catal. Today, J. CO2 Utilization (Elsevier); Chem. Commun., Catal. Sci. Tech., Green Chem., New J. Chem. (RSC) Visiting Scientist : UNAM (Mexico), 2004 ; INEOS-RAS (Russia), 2006 ; CNRS-Université d’Artois (France), 2010-2011 ; LIKAT Rostock (Germany), 2011 ; EPFL Lausanne (Switzerland), 2013. Italian National Service, 12 months, 1995 Languages: English (fluent), Spanish (advanced), Dutch (basic), French (basic), Italian (native). Awards and Memberships Awards, Fellowships CNR Young Researchers Career Development Prize for 2005 University of Sheffield Turner Prize for best Chemistry PhD Thesis, 2000. Professional Affiliations Member, Royal Society of Chemistry (MRSC),1997-2005; CO2Chem Network, since 2014; EERA and EEC, since 2013. References Em. Prof. Dr. Roger A. Sheldon Laboratory for Biocatalysis and Organic Chemistry Delft University of Technology, Delft (NL) Email: R.A.Sheldon@tnw.tudelft.nl Em. Prof. Peter M. Maitlis FRS Department of Chemistry University of Sheffield, Sheffield (UK) E-mail: p.maitlis@sheffield.ac.uk ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 2 Last update December 2015 Publications – JCR Articles 1. Kalsin, A.M.; Peganova, T. A.; Novikov, V. V.; Peruzzini, M.; Gonsalvi, L. Cooperative effects of ruthenium micellar catalysts and added surfactants in transfer hydrogenation of ketones in water Catal. Sci. & Technol. 2015, 5, 4458 – 4465. [article] 2. Mellone, I.; Bertini, F.; Gonsalvi, L.; Guerriero, A.; Peruzzini, M. New wind in old sails: Novel Applications of Triphos-based Transition Metal Complexes as Homogeneous Catalysts for Small Molecules and Renewables Activation Chimia 2015, 69, 331-338. [article] 3. Sordakis, K.; Guerriero, A.; Bricout, H.; Peruzzini, M.; Dyson, P. J.; Monflier, E. Hapiot, F.; Gonsalvi, L.; Laurenczy, G. Homogenous catalytic hydrogenation of bicarbonate with water soluble biaryl phosphine ligands Inorg. Chim. Acta 2015, 431, 132-138. [article] 4. Jumde, V. R.; Gonsalvi, L.; Guerriero, A.; Peruzzini, M.; Taddei, M. A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process Eur. J. Org. Chem. 2015, 1829-1833 [article] 5. Bertini, F.; Mellone, I.; Ienco, A.; Peruzzini, M.; Gonsalvi, L. Iron(II) Complexes of the Linear rac-Tetraphos-1 Ligand as Efficient Homogeneous Catalysts for Sodium Bicarbonate Hydrogenation and Formic Acid Dehydrogenation ACS Catal. 2015, 5, 1254−1265 [article] 6. Potier, J.; Guerriero, A.; Menuel, S.; Monflier, E.; Peruzzini, M.; Hapiot, F.; Gonsalvi, L. Cyclodextrins as first and second sphere ligands for Rh(I) complexes of lower-rim PTA derivatives for use as catalysts in aqueous phase hydrogenation Catal. Commun. 2015, 63, 74-78 [article] 7. Talavera, M.; Bravo, J.; Gonsalvi, L.; Peruzzini, M.; Zuccaccia, C.; Bolaño, S. [IrCp*(NCMe)2(PPh2Me)][PF6]2 as Catalyst for the Meyer–Schuster Rearrangement of Aryl Propargylic Alcohols under Mild Conditions Eur. J. Inorg. Chem. 2014, 6268–6274 [article] 8. Guerriero, A.; Bricout, H.; Sordakis, K.; Peruzzini, M.; Monflier, E. Hapiot, F.; Laurenczy, G.; Gonsalvi, L. Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-biaryl Sulfonated Phosphines in Aqueous Solution ACS Catal. 2014, 4, 3002-3012 [article]. 9. Caporali, M.; Gonsalvi, L.; Mirabello, V.; Ienco, A.; Manca, G.; Zanobini, F.; Peruzzini, M. The bimetallic activation of white phosphorus by trans-[RhCl(CO)(dppm)]2 results in a tetrahedro-Rh2P2 moiety Eur. J. Inorg. Chem. 2014, 1652–1659 [article] 10. Kalsin, A.M.; Peganova, T. A.; Novikov, V. V.; Zhamoityna, A. I.; Gonsalvi, L.; Peruzzini, M. Transfer hydrogenation of ketones catalyzed by surface active ruthenium and rhodium complexes in water Chem. Eur. J. 2014, 20, 846 – 854 [article] 11. Tristany, M.; Laurent, R.; Dib, H.; Gonsalvi, L.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M. Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions Inorg. Chim. Acta 2014, 409,121–126 [article] 12. Manca, G.; Mellone, I.; Bertini, F.; Rosi, L.; Peruzzini, M.; Mellman, D.; Junge, H.; Beller, M.; Ienco, A.; Gonsalvi, L. Inner vs Outer-sphere Ru-catalyzed Formic Acid Dehydrogenation: A Computational Study Organometallics 2013, 32, 7053−7064 [article] 13. Mirabello, V.; Caporali, M.; Gonsalvi, L.; Manca, G.; Ienco, A.; Peruzzini, M. Stabilization of the triphosphallyl ligand 3-P3{P(O)H} at iridium via alkaline activation of P4 Chem. Asian J. 2013 8, 3177-3184 [article] 14. Caporali, M.; Guerriero, A.; Ienco, A.; Caporali, S.; Peruzzini, M.; Gonsalvi, L. ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 3 Last update December 2015 Water-soluble palladium nanoparticles stabilized by PTA and their application in biphasic catalytic hydrogenations at room temperature Chem. Cat. Chem. 2013, 5, 2517-2526 [article] 15. Gonsalvi, L.; Guerriero, A.; Hapiot, F.; Krogstad, D. A.; Monflier, E.; Reginato, G.; Peruzzini, M. Lower and Upper Rim-Modified PTA Derivatives: Coordination Chemistry and Applications in Catalytic Reactions in Water Pure Appl. Chem. 2013, 85, 385–396 [article] 16. Mellone, I.; Peruzzini, M.; Rosi, L.; Mellman, D.; Junge, H.; Beller, M.; Gonsalvi, L. Formic Acid Dehydrogenation Catalysed by Ruthenium Complexes bearing the Tripodal Ligands Triphos and NP3 Dalton Trans. 2013, 42, 2495-2501 [article] 17. Alidori, S.; Heift, D.; Santiso-Quinones, G.; Benkö, Z.; Grützmacher, H.; Caporali, M.; Gonsalvi, L.; Rossin, A.; Peruzzini, M. Synthesis and Characterisation of terminal [Re(XCO)(CO)2(triphos)] (X = N, P): Isocyanate versus Phosphaethynolate Complexes Chem. Eur. J. 2012, 18, 14805 – 14811 [article] 18. Barbaro, P.; Gonsalvi, L.; Guerriero, A.; Liguori, F. Facile heterogeneous catalytic hydrogenations of C=N and C=O bonds in neat water: anchoring of water-soluble metal complexes onto ion-exchange resins Green Chem. 2012, 14, 3211 - 3219 [article] 19. Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Gudat, D.; Frey, W.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M. Solution and Solid State Dynamics of Metal-Coordinated White Phosphorus Chem. Eur. J. 2012, 18, 11238–11250 [article] (issue 36 cover article) 20. Gonsalvi, L.; Peruzzini, M. Novel Synthetic Pathways for Bis(acyl)phosphine Oxide Photoinitiators Angew. Chem. Int. Ed.(Highlights) 2012, 51, 7895 – 7897 [article] 21. Servin, P.; Laurent, R.; Dib, H.; Gonsalvi, L.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M. Number of terminal groups versus generation of the dendrimer, which criteria influence the catalytic properties? Tetrahedron Lett. 2012, 53, 3876–3879 [article] 22. Caporali, M.; Gonsalvi, L.; Kagirov, R.; Mirabello, V.; Peruzzini, M.; Sinyashin, O.; Stoppioni, P.; Yakhvarov, D. The first water-soluble tetraphosphorus ruthenium complex. Synthesis, characterization and kinetic study of its hydrolysis J. Organomet.Chem. 2012, 714, 67-73 [article] 23. Coletti, C.; Gonsalvi, L.; Guerriero, A.; Marvelli, L.; Peruzzini, M.; Reginato, G., Re, N. Electron-Poor Rhenium Allenylidenes and Their Reactivity toward Phosphines: A Combined Experimental and Theoretical Study Organometallics 2012, 31, 57-69 [article] 24. Krogstad, D. A.; Guerriero, A.; Ienco, A.; Manca, G.; Peruzzini, M.; Reginato, G.; Gonsalvi, L. Imidazolyl PTA Derivatives as Water Soluble (P,N) Ligands for Ru-catalysed Hydrogenations Organometallics 2011, 30, 6292–6302 [article] 25. Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M. Dynamic Behaviour of Ru and Ru-Pt complexes containing tetrahedron-P4 Ligand Dalton Trans 2011, 40, 9668–9671 [article] 26. Six, N.; Guerriero, A.; Landy, D.; Peruzzini, M.; Gonsalvi, L.; Hapiot, F.; Monflier, E. Supramolecularly controlled surface activity of an amphiphilic ligand. Application to biphasic hydroformylation of higher olefins Catal. Sci. Technol. 2011, 1, 1347-1353 [article] (issue 8 cover article) 27. Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Rossin, A. Design And Synthesis Of Thiazole And Thiazolidine Metallosupramolecular Networks Phosphorus Sulfur Sil. Rel. El. 2011, 186, 1312-1315 [article] ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 4 Last update December 2015 28. Yakhvarov, D.; Caporali, M.; Gonsalvi, L.; Latypov, S.; Mirabello, V.; Rizvanov, I.; Sinyashin, O.; Stoppioni, P.; Peruzzini, M. Experimental evidence of phosphine oxide generation in solution and its trapping by ruthenium complexes Angew. Chem. Int. Ed. 2011, 50, 5370–5373 [article] 29. Guerriero, A.; Erlandsson, M.; Ienco, A.; Krogstad, D. A.; Peruzzini, M.; Reginato, G.; Gonsalvi, L. Iridium(I) Complexes of Upper Rim Functionalized PTA Derivatives. Synthesis, Characterization and Use in Catalytic Hydrogenations (PTA = 1,3,5-triaza-7-phosphaadamantane) Organometallics 2011, 30, 1874–1884 [article] 30. Levina, V. A.; Rossin, A.; Belkova, N. V.; Chierotti, M.; Epstein, L. M.; Filippov, O. A.; Gobetto, R.; Gonsalvi, L.; Lledos, A.; Shubina, E. S.; Zanobini, F.; Peruzzini, M. Acid–Base Interaction between Transition-Metal Hydrides: Dihydrogen Bonding and Dihydrogen Evolution Angew. Chem. Int. Ed. 2011, 50, 1367–1370 [article] 31. Rossin, A.; Di Credico, B.; Giambastiani, G.; Gonsalvi, L.; Peruzzini, M.; Reginato, G. Coordination Chemistry of Thiazole-Based Ligands: New Complexes Generating 3D Hydrogen-Bonded Architectures Eur. J. Inorg. Chem. 2011, 539-548 [article] 32. Reginato, G.; Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Rossin, A. Selective Synthesis of 2-Substituted 4-Carboxy Oxazoles, Thiazoles and Thiazolidines from Serine or Cysteine Amino Acids Tetrahedron 2011, 67, 267-274 [article] 33. Coletti, C.; Gonsalvi, L.; Guerriero, A.; Marvelli, L.; Peruzzini, M.; Reginato, G., Re, N. Reactivity of Rhenium Allenylidenes towards phosphines: a theoretical study Organometallics 2010, 29, 5982–5993 [article] 34. Kovacs, G.; Rossin, A.; Gonsalvi, L.; Lledos, A.; Peruzzini, M. Comparative DFT analysis of ligand and solvent effects on the mechanism of H2 activation in water mediated by half-sandwich complexes [Cp’Ru(PTA)2Cl] (Cp’ = C5H5, C5Me5; PTA = 1,3,5-triaza-7-phosphaadamantane) Organometallics 2010, 29, 5121–5131 [article] 35. Casini, A.; Edafe, F.; Erlandsson, M.; Gonsalvi, L.; Marrone, A.; Ciancetta, A.; Re, N.; Ienco, A.; Messori, L.; Peruzzini, M.; Dyson, P. J. Rationalization of the inhibition activity of structurally related organometallic compounds against drug target cathepsin B by DFT analysis Dalton Trans. 2010, 39, 5556–5563 [article] - selected as Hot Article May 2010 36. Rossin, A.; Gutsul, E. I.; Belkova, N. V.; Epstein, L. M.; Gonsalvi, L.; Lledós, A.; Lyssenko, K. A.; Peruzzini, M.; Shubina, E. S.; Zanobini, F. Mechanistic study of the protonation of [(k3-P,P,P-NP3)Ir(H)3] [NP3 = N(CH2CH2PPh2)3] by HBF4 and fluorinated alcohols through combined NMR, IR and DFT techniques Inorg. Chem. 2010, 49, 4343 - 4354 [article] 37. Caporali, M.; Gonsalvi, L.; Rossin, A.; Peruzzini, M. P4 activation by Late Transition Metal Complexes Chem. Rev. 2010, 110, 4178–4235 [article] 38. Ciancaleoni, G.; Bolaño, S.; Bravo, J.; Peruzzini, M.; Gonsalvi, L.; Macchioni, A. Counterion-dependent deuteration of pentamethylcyclopentadiene in water-soluble cationic Rh(III) complexes assisted by PTA Dalton Trans. 2010, 39, 3366 - 3368 [article] 39. Bolaño, S.; Plaza, M.; Bravo, J.; Castro, J.; Peruzzini, M.; Gonsalvi, L.; Ciancaleoni, G.; Macchioni, A. New Highly Water-Soluble Rhodium Complexes Bearing 1,3,5-Triaza-7-phosphaadamantane (PTA) and/or Tris(hydroxymethyl) phosphine (THP) Inorg. Chim. Acta 2010, 363, 509–516 [article] 40. Bravo, J.; Bolaño, S.; Gonsalvi, L.; Peruzzini, M. Coordination chemistry of 1,3,5-Triaza-7-phosphaadamantane (PTA) and derivatives. Part II. The quest for tailored ligands, complexes and related applications. Coord. Chem. Rev. 2010, 254, 555–607 [article] ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 5 Last update December 2015 41. Di Credico, B.; Fabrizi de Biani, F.; Gonsalvi, L.; Guerri, A.; Ienco, A.; Laschi, F.; Reginato, G.; Rossin, A.; Zanello, P.; Peruzzini, M. Cyclopentadienyl Ruthenium(II) Complexes with Bridging Alkynylphosphine Ligands. Chem. Eur. J. 2009, 15, 11985 – 11998 [article] 42. Rossin, A.; Caporali, M.; Gonsalvi, L.; Guerri, A.; Lledos, A.; Peruzzini, M.; Zanobini, F. Selective B-H vs. N-H bond activation in ammonia borane by [Ir(dppm)2][OTf] Eur. J. Inorg. Chem., 2009, 3055-3059 [article] 43. Servin, P.; Laurent, R.; Gonsalvi, L.; Tristany, M.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M. Grafting of water-soluble phosphines to dendrimers and their use in catalysis: positive dendritic effects in aqueous media Dalton Trans. 2009, 4432 - 4434 [article] 44. Legrand, F.-X.; Hapiot, F.; Tilloy, S.; Guerriero, A.; Peruzzini, M.; Gonsalvi, L.; Monflier, E. Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated -cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives Appl. Catal. A: Gen. 2009, 362, 62-66 [article] 45. Renfrew, A. K.; Phillips, A. D.; Egger, A.; Hartinger, C. G.; Bosquain, S. S.; Nazarov, A. A.; Keppler, B. K.; Gonsalvi, L.; Peruzzini, M.; Dyson, P. J. Influence of structural variation on the anticancer activity of RAPTA-type complexes: ptn versus pta Organometallics 2009, 28, 1165–1172 [article] 46. Caporali, M.; Barbaro, P.; Bolaño, S.; Gonsalvi, L.; Mañas Carpio, S.; Peruzzini, M. NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP){Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus Magn. Res. Chem. 2008, 46, S120-S125 [article] 47. Rossin, A; Ienco, A.; Costantino, F.; Montini, F.; Di Credico, B.; Caporali, M.; Gonsalvi, L; Fornasiero, P.; Peruzzini, M. Crystal-to-crystal phase transition and CO2 adsorption properties of polymeric magnesium formate Cryst. Growth Des. 2008, 8, 3302–3308 [article] 48. Caporali, M.; Bianchini, C.; Bolaño, S.; Bosquain, S. S.; Gonsalvi, L.; Oberhauser, W.; Rossin, A.; Peruzzini, M. Synthesis and characterisation of k1-P and k2-P,N palladium(II) complexes of the open cage water soluble aminophosphine PTN Inorg. Chim. Acta 2008, 361, 3017-3023 [article] 49. Bolaño, S.; Albinati, A.; Bravo, J.; Caporali, M.; Gonsalvi, L.; Male, L.; Rodriguez-Rocha, M.; Rossin, A.; Peruzzini, M. Synthesis and Reactivity of Rhodium(III) Pentamethylcyclopentadienyl Complexes of N–B–PTA(BH3). X-ray crystal structures of [Cp*RhCl2(N–B–PTA(BH3)] and [Cp*Rh{N–B–PTA(BH3)}(2-CH2=CHPh)] J. Organomet. Chem. 2008, 693, 2397–2406 [article] 50. Ciclosi, M.; Dinoi, C.; Gonsalvi, L.; Peruzzini, M.; Manoury, E.; Poli, R. Oxidation of thiophene derivatives with H2O2 in acetonitrile catalyzed by [Cp*2M2O5] (M = Mo, W): a kinetic study Organometallics 2008, 27, 2281–2286 [article] 51. Caporali, M.; Barbaro, P.; Gonsalvi, L.; Ienco, A.; Yakhvarov, D.; Peruzzini, M. Heterobimetallic cooperation mediates the transformation of white phosphorus into zwitterionic catenaphosphonium(+)diphosphenide(-) ligands Angew. Chem. Int. Ed. 2008, 47, 3766-3768 [article]; Angew. Chem. 2008, 120, 3826-3828 [article] 52. Yakhvarov, D.; Peruzzini, M.; Caporali, M.; Gonsalvi, L.; Midollini, S.; Orlandini, A.; Ganushevich, Y.; Sinyashin, O. Bimetallic activation of white phosphorus Phosph. Sulfur Sil. Rel. El. 2008, 183, 487–493 [article] 53. Bolaño, S.; Ciancaleoni, G.; Bravo, J.; Gonsalvi, L.; Macchioni, A.; Peruzzini, M. PGSE NMR studies on RAPTA derivatives: evidence for the formation of H-bonded dicationic species Organometallics 2008, 27, 1649-1652 [article] 54. Erlandsson, M.; Landaeta, V. R.; Gonsalvi, L.; Peruzzini, M.; Phillips, A. D.; Dyson, P.J.; Laurenczy, G. ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 6 Last update December 2015 Methylcyclopentadienyl iridium PTA complexes and their application in catalytic water phase carbon dioxide hydrogenation (PTA = 1,3,5-triaza-7-phosphaadamantane) Eur. J. Inorg. Chem. 2008, 620-627 [article] 55. Erlandsson, M.; Gonsalvi, L.; Ienco, A.; Peruzzini, M. Diastereomerically enriched analogues of the water soluble phosphine PTA. Synthesis of phenyl-(1,3,5-triaza-7phosphatricyclo [3.3.1.13,7]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)] Inorg. Chem. 2008, 47, 8-10 [article] 56. Bolaño, S.; Bravo, J.; Castro, J.; Rodriguez-Rocha, M.; Guedes da Silva, M. F. C.; Pombeiro, A. J. L.; Gonsalvi, L.; Peruzzini, M. Synthesis, reactivity, x-ray crystal structures and electrochemical behavior of tris(pyrazolyl)borate ruthenium(II) complexes of PTA (PTA = 1,3,5-triaza-7-phosphaadamantane) Eur. J. Inorg. Chem. 2007, 5523-5532 [article] 57. Bosquain, S. S.; Dorcier, A.; Dyson, P. J.; Erlandsson, M.; Gonsalvi, L.; Laurenczy, G.; Peruzzini, M. Aqueous phase carbon dioxide and bicarbonate hydrogenation catalysed by cyclopentadienyl ruthenium complexes Appl. Organomet. Chem. 2007, 21, 947-951 [article] 58. Ciardi, C.; Romerosa, A., Serrano-Ruiz, M.; Gonsalvi, L.; Peruzzini, M.; Reginato, G. Synthesis of New Enantiomerically Enriched -Hydroxy, -Amino Phosphines by Selective Transformation of Naturally Occurring Amino Acids J. Org. Chem. 2007, 72, 7787 - 7789 [article] 59. Rossin, A.; Gonsalvi, L.; Phillips, A. D.; Maresca, O.; Lledos, A.; Peruzzini, M. Water-assisted H-H bond splitting mediated by [CpRu(PTA)2Cl] (PTA=1,3,5-triaza-7-phosphaadamantane). A DFT analysis. Organometallics 2007, 26, 3289-3296 [article] 60. Best, J.; Wilson, J. M.; Adams, H.; Gonsalvi, L.; Peruzzini, M.; Haynes, A. Reactivity of Rh(I) iminophosphine carbonyl complexes with methyl iodide Organometallics 2007, 26, 1960-1965 [article] 61. Le Roux, E.; Malacea, R. ; Manoury, E. ; Poli, R. ; Gonsalvi, L. ; Peruzzini, M. Highly efficient asymmetric hydrogenation of alkyl aryl ketones catalyzed by iridium complexes with chiral planar ferrocenyl phosphino-thioether ligands Adv. Synth. Catal. 2007, 349, 309-313 [article] 62. Pelagatti, P.; Bacchi, A.; Balordi, M.; Caneschi, A.; Giannetto, M.; Pelizzi, C.; Gonsalvi, L.; Peruzzini, M.; Ugozzoli, F. Ligand driven geometry switch in octahedral and trigonal bipyramidal iron complexes containing (H)PNO and PNN ligands Eur. J. Inorg. Chem. 2007,162-171 [article] 63. Gutkin, V.; Gun, J.; Prikhodchenko, P. V.; Lev, O.; Gonsalvi, L.; Peruzzini, M.; Romerosa, A.; Campos Malpartida, T.; Lidrissi, C. Electrooxidation of ruthenium cyclopentadienyl PTA complexes in DMF: ESI-MS, cyclic voltammetry and on-line electrochemistry/ESI-MS studies J. Electrochem Soc. 2007, 154, F7-F15 [article] 64. Landaeta, V. R.; Gonsalvi, L.; Peruzzini, M. Ruthenium catalyzed selective oxidation of aryl thiophenes using hydrogen peroxide J. Mol. Catal. A: Chem. 2006, 257, 112-117 [article]. 65. Dorcier, A.; Ang, W. H.; Bolaño, S.; Gonsalvi, L.; Juillerat-Jeannerat, L.; Laurenczy, G.; Peruzzini, M.; Phillips, A. D.; Zanobini, F.; Dyson, P. J. In vitro evaluation of rhodium and osmium RAPTA analogues: the case for organometallic anticancer drugs not based on ruthenium Organometallics 2006, 25, 4090-4096 [article]. 66. Yakhvarov, D.; Barbaro, P.; Gonsalvi, L.; Mañas Carpio, S.; Midollini, S.; Orlandini, A.; Peruzzini, M.; Sinyashin, O.; Zanobini, F. A snapshot of P4 tetrahedron opening: Rh and Ir mediated bimetallic activation of white phosphorus ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 7 Last update December 2015 Angew. Chem. Int. Ed. 2006, 45, 4182-4185 [article]. Angew. Chem. 2006, 118, 4288-4291 67. Pelagatti, P.; Bacchi, A.; Balordi, M.; Bolaño, S.; Calbiani, F.; Elviri, L.; Gonsalvi, L.; Pelizzi, C.; Peruzzini, M.; Rogolino, D. Octahedral Ru(II) complexes with [PNO] hydrazonic ligands. Synthesis, structure, reactivity and catalytic activity in the addition of benzoic acid to alkynes Eur. J. Inorg. Chem. 2006, 2422-2436 [article] 68. Phillips, A. D.; Bolaño, S.; Bosquain, S. S.; Daran, J.-C.; Malacea, R.; Peruzzini, M.; Poli, R.; Gonsalvi, L. A new class of rhodium(I) k1-P and k2-P,N complexes with rigid PTN(R) ligands (PTN = 7-phospha-3-methyl 1,3,5-triazabicyclo[3.3.1]nonane) Organometallics 2006, 25, 2189-2200. [article] 69. Bolaño, S.; Albinati, A.; Bravo, J.; Gonsalvi, L.; Peruzzini, M. Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane) Inorg. Chem. Commun. 2006, 9, 360-363 [article]. 70. Bolaño, S.; Gonsalvi, L.; Barbaro, P.; Albinati, A.; Rizzato, S.; Gutsul, E.; Belkova, N.; Epstein, L.; Shubina, E.; Peruzzini, M. Synthesis, characterization, protonation studies and X-ray crystal structure of ReH5(PPh3)2(PTA) (PTA = 1,3,5triaza-7-phosphaadamantane) J. Organomet. Chem. 2006, 691, 629-637 [article] 71. Andrieu, J.; Camus, J.-M. ; Richard, P.; Poli, R.; Gonsalvi, L.; Vizza, F.; Peruzzini, M. Amino-phosphanes in RhI-Catalyzed Hydroformylation: Hemilabile Behavior of P,N Ligands under High CO Pressure and Catalytic Properties Eur. J. Inorg. Chem. 2006, 51-61 [article]. 72. Peruzzini, M.; Gonsalvi, L.; Romerosa, A. Coordination Chemistry and Functionalization of White Phosphorus via transition metal complexes Chem. Soc. Rev. 2005, 34, 1038 -1047 [article]. 73. Akbayeva, D. N.; Moneti, S.; Peruzzini, M.; Gonsalvi, L.; Ienco, A.; Vizza, F. On the Protonation of Ruthenium-PTA Complexes in Water. X-ray crystal structure of RuCl4(PTAH)2 4H2O (PTA = 1,3,5-triaza-7-phosphaadamantane) C. R. Chimie 2005, 8, 1491-1496. [article] 74. Lidrissi, C.; Romerosa, A.; Saoud, M.; Serrano-Ruiz, M.; Gonsalvi, L.; Peruzzini, M. Stable, water soluble PTA based Ru-Ag organometallic polymers Angew. Chem. Int. Ed. 2005, 44, 2568-2572. Angew. Chem. 2005, 117, 2624-2628 [article] 75. Mantovani, N.; Brugnati, M.; Gonsalvi, L.; Grigiotti, E.; Laschi, F.; Marvelli, L.; Peruzzini, M.; Reginato, G.; Rossi, R.; Zanello, P. Synthesis, characterization and electrochemical behavior of mono- and bimetallic Ru and Re allenylidenes bearing multiconjugated organic spacers Organometallics 2005, 24, 405-418. [article] 76. Bolaño, S.; Gonsalvi, L.; Zanobini, F.; Vizza, F.; Bertolasi, V.; Romerosa, A.; Peruzzini, M. Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of -unsaturated olefins. (PTA = 1,3,5-triaza-7-phosphaadamantane) J. Mol. Catal. A: Chem. 2004, 224, 61-70. [article] 77. Phillips, A. D.; Gonsalvi, L.; Romerosa, A.; Vizza, F.; Peruzzini, M. Coordination chemistry of 1,3,5-Triaza-7-phosphaadamantane (PTA). Transition metal complexes and related catalytic, medicinal and photo-luminescent applications Coord. Chem. Rev. 2004, 248, 955-993 [article] 78. Ciardi, C.; Reginato, G.; Gonsalvi, L.; de los Rios, I.; Romerosa, A.; Peruzzini, M. Ruthenium(II) -alkyne and vinylidene complexes derived from glycoynitols: new precursors for water soluble unsaturated carbenes Organometallics 2004, 23, 2020-2026. [article] 79. Baucherel, X.; Gonsalvi, L.; Arends, I. W. C. E.; Ellwood, S.; Sheldon, R. A. Aerobic oxidation of cycloalkanes, alcohols and ethylbenzene catalyzed by the novel carbon radical chain promoter NHS (N-hydroxy saccharin) ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 8 Last update December 2015 Adv. Synth. Catal. 2004, 346, 286-296. [article] 80. Gonsalvi, L.; Arends, I. W. C. E.; Moilanen, P.; Sheldon, R. A. The effect of pH control on the selective ruthenium-catalyzed oxidation of ethers and alcohols with sodium hypochlorite Adv. Synth. Catal. 2003, 345, 1321-1328. [article] 81. Bianchini, C.; Gonsalvi, L.; Oberhauser, W.; Seméril, D.; Brüggeller, P; Gutmann, R. Schulz-Flory oligomerisation of ethylene by the binuclear nickel(II) complex Ni2Cl4[cis, trans, cis-1,2,3,4-tetrakis(diphenylphosphino)cyclobutane] Dalton Trans. 2003, 3869 - 3875. [article] 82. Saoud, M.; Romerosa, A.; Mañas Carpio, S.; Gonsalvi, L.; Peruzzini, M. Ruthenium-catalysed selective transetherification of substituted vinyl ethers to acetals and aldehydes Eur. J. Inorg. Chem. 2003, 1614-1619. [article] 83. Gonsalvi, L.; Gaunt, J. A.; Adams, H.; Castro, A.; Sunley, G. J.; Haynes, A. Quantifying steric effects of -diimine ligands. Oxidative addition of MeI to Rh(I) and migratory insertion in Rh(III) complexes Organometallics 2003, 22, 1047-1054. [article] 84. Akbayeva, D. N.; Gonsalvi, L.; Oberhauser, W.; Peruzzini, M.; Vizza, F.; Brüggeller, P.; Romerosa, A.; Sava, G.; Bergamo, A. Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)Ru(PTA)2Cl] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane) Chem. Commun. 2003, 264-265. [article] 85. Gonsalvi, L.; Adams, H.; Sunley, G. J.; Ditzel E.; Haynes, A. Steric and electronic effects on the reactivity of Rh and Ir complexes containing P-S, P-P and P-O ligands; implications for the effects of chelate ligands in catalysis J. Am. Chem. Soc. 2002, 124, 13597-13612. [article] 86. Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A. Selective ruthenium-catalyzed oxidation of 1,2:4,5-di-O-isopropylidene--D-fructopyranose and other alcohols with NaOCl Org. Lett. 2002, 4, 1659-1561. [article] 87. Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A. Highly efficient use of NaOCl in the Ru-catalysed oxidation of aliphatic ethers to esters Chem. Commun. 2002, 202-203. Also quoted in Chem. Br. Perspectives, April 2002. [article] 88. Gonsalvi, L.; Adams, H.; Sunley, G. J.; Ditzel E.; Haynes, A. A Dramatic Steric Effect on the Rate of Migratory CO Insertion on Rhodium J. Am. Chem. Soc. 1999, 121, 11233-11234. [article] 89. Cauzzi, D.; Costa, M.; Gonsalvi, L.; Pellinghelli, M. A.; Predieri, G.; Tiripicchio A.; Zanoni, R. Anchoring rhodium(I) on thiourea-functionalized silica xerogels and silsesquioxanes. Part II. Matrix effects on the selectivity in the hydroformylation of styrene J. Organomet. Chem. 1997, 541, 377-389. [article] Publications – Non JCR Articles 1. Gonsalvi, L.; Peruzzini, M. 1,3,5-Triaza-7-Phosphaadamantane (Unique ID RN01186) Encyclopedia of Reagents for Organic Synthesis [Online], John Wiley & Sons Ltd., 2010 [article] Books as Editor 1. Phosphorus compounds: advanced tools in catalysis and material sciences (Eds M. Peruzzini, L. Gonsalvi), Catalysis by Metal Complexes series, Vol. 37, Springer (London) 1st Edition., 2011, ISBN: 978-90-481-3816-6 2. Proceedings of the 9th Interdivisional Congress of Organometallic Chemistry (COGICO-9), Florence 8-11 June 2010, (Eds B. Di Credico, L. Gonsalvi, G. Reginato), Tassinari (Firenze) 2010, ISBN: 9-788887-057539 ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 9 Last update December 2015 6th 3. Proceedings of the European Symposium on Phosphorus Chemistry (EWPC-6), Florence 26-27 March 2009, (Eds L. Gonsalvi, M. Caporali), Tassinari (Firenze) 2009, ISBN 9-788887-057492 4. Proceedings of the 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC-XII), Florence 18-22 July 2005, (Eds V. Dal Santo, G. Giambastiani, L. Gonsalvi, M. Guidotti), Tassinari (Firenze) 2005, ISBN 88-87057-34-6 Books as Chapter Author 1. Gonsalvi, L.; Bertini, F.; Guerriero, A.; Mellone, I. Chapter 14. “Hydrogen Activation in Water by Organometallic Complexes” in Organometallics and Related Molecules for Energy Conversion (Ed. W.-Y. Wong), Green Chemistry and Sustainable Technology series, pages 395-419, Springer (Heidelberg-Berlin) 1st Edition, 2015, ISBN: 978-3-662-46053-5 (Print) 978-3-66246054-2 (Online) [chapter] 2. Gonsalvi, L.; Guerriero, A.; Monflier, E.; Hapiot, F; Peruzzini, M. Role of Metals and Ligands in Organic Hydroformylation Top. Curr. Chem. 2013, 342, 1-47. In Taddei, M.; Mann, A. (Eds), Hydroformylation for Organic Syntheses, Springer Berlin Heidelberg , 1st Edition. ISSN: 978-3-642-45059-4 (Online) [chapter] 3. Gonsalvi, L.; Peruzzini, M. Chapter 7. “Aqueous Phase Reactions Catalysed by Transition Metal Complexes of 7-phospha-1,3,5triazaadamantane (PTA) and derivatives” in Phosphorus compounds: advanced tools in catalysis and material sciences (Eds M. Peruzzini, L. Gonsalvi), Catalysis by Metal Complexes series, Vol. 37, Springer (London) 1st Edition, 2011, ISBN: 978-90-481-3816-6 4. Caporali, M.; Gonsalvi, L.; Zanobini, F.; Peruzzini, M. Synthesis of the Water Soluble Bidentate (P,N) Ligand PTN(Me) [PTN(Me) = 7-Phospha-3-methyl-1,3,5triazabicyclo[3.3.1]nonane] Inorg. Synth. 2010, 35, 96-101. (Ed T. Rauchfuss), J. Wiley & Sons, ISBN: 978-0-471-68255-4. [book] 5. Bianchini, C.; Gonsalvi, L.; Peruzzini, M. Chapter 4 “Iridium-Catalyzed C=O Hydrogenation” in Iridium Complexes in Organic Synthesis, pages 55-106. Edited by L. Oro and C. Claver, Wiley-VCH, Weinheim, 2008 ISBN: 978-3-527-31996-1[book] 6. Peruzzini, M.; Bianchini, C.; Gonsalvi, L. Comprehensive Organometallic Chemistry III, chapter 7.04, pages 267-425 Edited by R. H. Crabtree and D. M. P. Mingos, Elsevier: Oxford 2007 ISBN: 008044590X [chapter] Patents 1. Sheldon, R. A.; Gonsalvi, L.; Arends, I. W. C. E.; Kühnle, A.; Jost, C.; Fries, G.; Neumann, M. Process for the oxidation of organic compounds, e.g. for production of esters from ethers, uses a liquid multiphase ruthenium catalyst system and an oxygen atom donor and is carried out using an aqueous phase of neutral or alkaline pH German Patent DE 10163579A1 (2003), to Degussa. [espacenet] Conferences 1. Gonsalvi, L.; Bertini, F.; Mellone, I.; Ienco, A.; Peruzzini, M. Efficient NaHCO3 Hydrogenation and HCOOH Dehydrogenation Catalyzed by Fe(II) Complexes Stabilized by a Linear Tetraphosphine Ligand CO2-FORUM, Large Volume CO2 Utilization : Enabling Technologies for Energy and Resource Efficiency Lyon, France, 25-26 September 2014. 2. Gonsalvi, L.; Guerriero, A.; Peruzzini, M. Amphiphilic Aminophosphines as Stabilizing Ligands for Homogeneous and Heterogeneous Catalytic Processes in Water QIES 2014 – Conferencia Plenaria de Quimica Inorganica de la Real Sociedad Española de Quimica Almeria, Spain, 15-18 June 2014. Keynote Invited Lecture C2. 3. Bertini, F.; Mellone, I.; Ienco, A.; Peruzzini, M.; Gonsalvi, L. ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 10 Last update December 2015 Hydrogen Storage and Release by NaHCO3 Hydrogenation and HCOOH Dehydrogenation Catalyzed by Fe(II) Complexes of the Linear Tetraphos-1Ligand ICPC-2014 - 20th International Conference on Phosphorus Chemistry Dublin, Ireland, 28 June - 2 July 2014. Book of Abstracts, P65. 4. Caporali, M.; Mirabello, V.; Gonsalvi, L.; Gudat, D.; Frey, W.; Gallo, V.; Latronico, M.; Mastrorilli, P.; Peruzzini, M. A Dynamic NMR Study in Solution and in Solid State of Metal-Coordinated White Phosphorus ICPC-2014 - 20th International Conference on Phosphorus Chemistry Dublin, Ireland, 28 June - 2 July 2014. Book of Abstracts, . 5. Guerriero, A.; Gonsalvi, L.; Peruzzini, M. Ru, Ir and Rh-catalysed processes in Water and Biphasic Media using Amphiphilic Aminophosphines Homogeneous Catalysis for Sustainable Development – GDRI, 7th Annual Meeting Paris, France, 16-17 June 2014. 6. Guerriero, A.; Sordakis, K.; Peruzzini, M.; Monflier, E.; Bricout, H.; Hapiot, F.; Laurenczy, G.; Gonsalvi, L. Selective HCOOH dehydrogenation for hydrogen production in water catalyzed by Ru-sulfonated phosphines 1st CARISMA Meeting - Catalytic Routines for Small Molecules Activation (COST Action CM1205) Venice, Italy, 5-7 May 2014. Book of Abstracts, Oral Communication O39. 8. Sordakis, K.; Guerriero, A.; Peruzzini, M.; Monflier, E.; Bricout, H.; Hapiot, F.; Laurenczy, G.; Gonsalvi, L. Homogenous catalytic hydrogenation of CO2 in basic media with new water soluble phosphine ligands 1st CARISMA Meeting - Catalytic Routines for Small Molecules Activation (COST Action CM1205). Venice, Italy, 5-7 May 2014. Book of Abstracts, Poster communication P26. 8. Mellone, I.; Mellmann, D.; Bertini, F.; Gilbert-Wilson, R.J.; Field, L.D.; Junge, H.; Beller, M.; Peruzzini, M.; Gonsalvi L. Hydrogen Storage and Release by HCOOH Dehydrogenation and NaHCO3 Hydrogenation Catalyzed by Ru(II) Complexes Bearing Bulky Polydentate Phosphines IGCS-2. Second International Green Symposium & Advanced School on Green Chemistry Rennes, France, 02-04 April 2014. Book of Abstracts, OC7. 9. Caporali, M.; Guerriero, A.; Ienco, A.; Caporali, S.; Peruzzini, M.; Gonsalvi, L. Water-Soluble Palladium Nanoparticles Stabilized by Aminophosphine Ligands 11th EWPC – European Workshop on Phosphorus Chemistry Sofia, Bulgaria, 11-16 March 2014. 10. Mellone I.; Manca G.; Ienco A.; Peruzzini M.; Rosi L.; Mellmann D.; Junge, H.; Beller, M.; Gonsalvi, L. A Combined VT-NMR and DFT Computational Studies on Ru-catalyzed Formic Acid Dehydrogenation XLI CONGRESSO NAZIONALE CHIMICA INORGANICA della Societa’ Chimica Italiana Parma, Italy, 03-06 September 2013. Book of Abstracts, P45. 11. Peruzzini, M.; Gonsalvi, L.; Guerriero, Hapiot, F.; Krogstad, D.; Monflier, E. Sustainable chemistry with water soluble phosphines: the enlightening story of PTA as an environmental friendly ligand IUPAC 44th World Chemistry Congress Istanbul, Turkey, 11-16 August 2013. 12. Caporali, M.; Mirabello, V.; Raltchev, K.; Gonsalvi, L.; Oberhauser, W.; Karaghiosoff, K.; Peruzzini, M. A new method for the preparation of fluorophosphines mediated by ruthenium complex European Workshop on Phosphorus Chemistry (10th EWPC) Regensburg, Germany, 18-20 March 2013. 13. Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Gudat, D.; Frey, W.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M. Solution And Solid State NMR Study On Metal-Coordinated White Phosphorus XLI NATIONAL CONGRESS ON MAGNETIC RESONANCE Pisa, Italy, 17-19 September 2012. Book of Abstracts, p. 35 14. Mellone, I.; Rosi, L.; Peruzzini, M.; Gonsalvi, L. Selective formic acid dehydrogenation catalysed by ruthenium complexes bearing multidentate ligands XL CONGRESSO NAZIONALE DI CHIMICA INORGANICA Sestri Levante, Italy, 09-13 September 2012. Book of Abstracts, P37, p. 129 ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 11 Last update December 2015 15. Peruzzini, M.; Mirabello, C.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Gudat, D.; Frey, W.; Ienco, A.; Latronico, M.; Mastrorilli, P. Solution and Solid State Dynamics of Metal-Coordinated White Phosphorus 40th INTERNATIONAL CONFERENCE ON COORDINATION CHEMISTRY (ICCC-40) Valencia, Spain, 09-13 September 2012. Book of abstracts, p C354, MS.C3.P.473 16. Reginato, G.; Gonsalvi, L.; Peruzzini, M.; Guerriero, A.; Krogstad, D.A.; Mordini, A. Functionalization of PTA: A Class of Water Soluble Neutral Phosphines for Use in Aqueous Phase Catalysis INTERNATIONAL CONFERENCE OF CATALYSIS IN ORGANIC SYNTHESIS (ICCOS-2012) Moscow, Russia, 05-10 September 2012. Poster P119 17. Kalsin, A.M.; Peganova, T.A.; Gonsalvi, L.; Peruzzini, M. Transfer Hydrogenation of Ketones in Water Catalyzed by Ruthenium and Rhodium Surface Active Complexes INTERNATIONAL CONFERENCE OF CATALYSIS IN ORGANIC SYNTHESIS (ICCOS-2012) Moscow, Russia, 05-10 September 2012. Poster P119 18. L. Gonsalvi, A. Guerriero, F. Hapiot, E. Monflier, M. Peruzzini, N. Six Biphasic Hydroformylation Of Higher Olefins Via A Thermoregulated Process Involving Cyclodextrins and Amphiphilic Water-Soluble Phosphines 25th INTERNATIONAL CONFERENCE ON ORGANOMETALLIC CHEMISTRY (ICOMC-25) Lisbon, Portugal, 03-07 September 2012. Poster PB.85. CD-Abstract, S8.2 19. Peruzzini, M.; Gonsalvi, L.; Guerriero, A.; Krogstad, D. A. Recent Advances in 1,3,5-Triaza-7-Phosphaadamantane (PTA) Organometallic Chemistry and Catalysis 25th INTERNATIONAL CONFERENCE ON ORGANOMETALLIC CHEMISTRY (ICOMC-25) Lisbon, Portugal, 03-07 September 2012. Invited Session Lecture. CD-Abstract, S8.2 20. Caporali, M.; Mirabello, V.; Gonsalvi, L.; Peruzzini, M.; Seniori Costantini, S.; Bazzicalupi, C.; Stoppioni, P. Exploring the reactivity of white phosphorus in water 19th INTERNATIONAL CONFERENCE ON PHOSPHORUS CHEMISTRY - ICPC 2012 Rotterdam, The Netherlands, 08-12 July 2012. Oral Communication. CD-Abstract, O18 21. Peruzzini, M.; Gonsalvi, L.; Guerriero, A.; Hapiot, F.; Monflier, E. Organometallic chemistry and catalysis with water soluble phosphines: the enlightening story of PTA 15th INTERNATIONAL CONGRESS ON CATALYSIS 2012 – 15 ICC Munich, Germany, 01-06 July 2012. Session Lecture 22. Mellone, I.; Rosi, L.; Gonsalvi, L.; Peruzzini, M. Selective formic acid dehydrogenation catalysed by ruthenium complexes bearing multidentate ligands COGICO-10 - 10° CONGRESSO DEL GRUPPO INTERDIVISIONALE DI CHIMICA ORGANOMETALLICA Padova, Italy, 05-08 June 2012. Book of Abstracts, P21, p. 79 23. Guerriero, A.; Casini, A.; Ciancetta, A.; Edafe, F.; Gonsalvi, L.; Ienco, A.; Messori, L.; Peruzzini, M.; Re, N.; Reginato, G.; Dyson, P. J. RAPTA-type organometallic compounds and their inhibition activity against the drug target cathepsin B COGICO-10 - 10° CONGRESSO DEL GRUPPO INTERDIVISIONALE DI CHIMICA ORGANOMETALLICA Padova, Italy, 05-08 June 2012. Book of Abstracts, P15, p. 73 24. Gonsalvi, L.; Guerriero, A.; Hapiot, F.; Krogstad, D. A.; Monflier, E.; Peruzzini, M.; Reginato, G.; Six, N. Keep it simple: tailored functionalizations of a versatile phosphine for use in aqueous phase catalysis COGICO-10 - 10° CONGRESSO DEL GRUPPO INTERDIVISIONALE DI CHIMICA ORGANOMETALLICA Padova, Italy, 05-08 June 2012. Book of Abstracts, KN6, p. 30. Key Note Lecture (invited) 25. Caporali, M.; Mirabello, V.; Gonsalvi, L.; Peruzzini, M.; Seniori Costantini, S.; Bazzicalupi, C.; Stoppioni, P. Ruthenium-mediated activation and functionalization of P4 carried out in water PRIN 2009 - SPRING Meeting 2012 - “Designing metal containing molecular fragments for advanced chemical applications”- II RIUNIONE SCIENTIFICA 2012 Bertinoro, Italy, 13-15 May 2012. Book of Abstracts, s.n., Oral Communication 26. Peruzzini, M.; Guerriero, A.; Gonsalvi, L.; Hapiot, F.; Krogstad, D.; Monflier, E. Organometallic chemistry with water soluble phosphines: the instructive case of PTA 12TH EURASIA CONFERENCE ON CHEMICAL SCIENCES (Euasc2s-12) Corfu, Greece, 16-21 April 2012, Oral presentation OP1 27. Caporali, M.; Bazzicalupi, C.; Gonsalvi, L.; Seniori Costantini, S.; Peruzzini, M.; Stoppioni, P. ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 12 Last update December 2015 Activation of White Phosphorus Mediated by a Ruthenium Complex Bearing Highly Basic Phosphines 9th European Workshop on Phosphorus Chemistry (EWPC-9) Rennes, France, 22-23 March 2012. Book of abstracts, p 51, P10 28. Peruzzini, M.; Guerriero, A.; Gonsalvi, L.; Hapiot, F.; Krogstad, D.; Monflier, E. Water soluble complexes and their application in catalysis International Green Catalysis Symposium & Advanced Spring School On Green Catalysis Rennes, France, 07-09 March 2012. Invited Session Lecture. Book of abstracts, IL14 29. Guerriero, A.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Krogstad, D. A.; Six, N.; Hapiot, F.; Monflier, E. Novel functionalized PTA ligands, their coordination complexes and use in catalysis XXIV National Congress of the Italian Chemical Society Lecce, Italy, 11-16 September 2011 30. Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M. 1D and 2D 31P NMR spectroscopy as diagnostic tool to assess chemical exchange around P4 moieties XXIV National Congress of the Italian Chemical Society Lecce, Italy, 11-16 September 2011 31. Caporali, M.; Yakhvarov, D.; Gonsalvi, L.; Mirabello, V.; Latypov, S.; Rizvanov, I.; Sinyashin, O.; Stoppioni, P.; Peruzzini, M. From P4 to H3P(O): Unprecedented Process Feasible Via Electrochemistry XXIV National Congress of the Italian Chemical Society Lecce, Italy, 11-16 September 2011 32. Levina, V.A.; Rossin, A.; Belkova, N.V.; Chierotti, M.R.; Gobetto, R.; Gonsalvi, L.; Shubina, E.S.; Peruzzini, M. Acid–Base Interaction between Transition-Metal Hydrides: Dihydrogen Bonding and Dihydrogen Evolution XXIV National Congress of the Italian Chemical Society Lecce, Italy, 11-16 September 2011 33. Caporali, M.; Yakhvarov, D.; Gonsalvi, L.; Latypov, S.; Mirabello, V.; Rizvanov, I.; Sinyashin, O.; Stoppioni, P.; Peruzzini, M. First experimental evidence of generation and trapping of H3P(O) in solution 8th European Symposium of Phosphorus Chemistry (EWPC-8) Muenster, Germany, 28-29 March 2011 34. Evangelisti, C.; Karaghiosoff, K.; Peruzzini, M.; Caporali, M.; Gonsalvi, L.; Lein, M.; Schwerdtfeger, P. Quantum Chemical Study on the reactivity of complexes of White Phosphorus 8th European Symposium of Phosphorus Chemistry (EWPC-8) Muenster, Germany, 28-29 March 2011 35. Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M. Pendulum and Planetary Motion around tetrahedron-P4 8th European Symposium of Phosphorus Chemistry (EWPC-8) Muenster, Germany, 28-29 March 2011 36. Shubina, E.; Gutsul E., Tsupreva, V.; Belkova, N.; Filippov, O.; Gonsalvi L., Peruzzini M., Rossin A., Zanobini, F. Tetrahydroborate metal complexes and dihydrogen bonding EUROBORON-5, European Conferences on Boron Chemistry Edinburgh, Scotland, 29 August – 2 September 2010 37. Caporali, M.; Gonsalvi, L.; Ienco, A.; Yakhvarov, D.; Peruzzini, M. New hydroxyphosphoryl ligand, P3POH, derived from white phosphorus ICPC 18, International Conference on Phosphorus Chemistry Wrocław, Poland, 11-15 July 2010. (oral communication) 38. Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Rossin, A. Synthesis of Novel Molecular and Polymeric Organometallic Architectures: towards New Materials XXXVIII Congresso Nazionale della Divisione di Chimica Inorganica della Società Chimica Italiana Trieste, Italy, 13-16 September 2010. 39. Guerriero, A.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Krogstad, D.A. Upper rim derivatives of the water-soluble phosphine PTA via selective lithiation reactions 9th International Symposium on Carbanion Chemistry Firenze, Italy, 20-24 July 2010. ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 13 Last update December 2015 40. Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Rossin, A. Design and Synthesis of Thiazole and Thiazolidine Metallo-Supramolucular Networks ISOCS-24 International Symposium on the Organic Chemistry of Sulfur Firenze, Italy, 25-30 July 2010. (oral communication) 41. Tiozzo, C.; Gonsalvi, L.; Manoury, E.; Peruzzini, M.; Poli, R. Water Soluble Planar Chiral Ferrocenyl Phosphines COGICO 2010, 9th Italian Congress of Organometallic Chemistry Firenze, Italy, 8-11 June 2010. 42. Mirabello, V.; Gonsalvi, L.; Caporali, M.; Ienco, A.; Peruzzini, M.; Gallo, V.; Latronico, M.; Mastrorilli, P. Ligand Effects on the Planetary Motion of Ru(II) Diphosphine Centres around White Phosphorus COGICO 2010, 9th Italian Congress of Organometallic Chemistry Firenze, Italy, 8-11 June 2010. 43. Guerriero, A.; Gonsalvi, L.; Krogstad, D. A.; Peruzzini, M.; Reginato, G. Iridium(I) and Ruthenium(Ii) Complexes of “Upper Rim” Functionalised PTA Ligands as Catalysts for Hydrogenations in Water and Biphasic Media COGICO 2010, 9th Italian Congress of Organometallic Chemistry Firenze, Italy, 8-11 June 2010. 44. Caporali, M.; Gonsalvi, L.; Ienco, A.; Mirabello, V.; Peruzzini, M. White Phosphorus Activation Mediated by A-Frame Type Complex trans-[Rh(CO)(Cl)(dppm)]2 COGICO 2010, 9th Italian Congress of Organometallic Chemistry Firenze, Italy, 8-11 June 2010. 45. Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Rossin, A. Novel Metal-Organic Coordination Architectures with Heterocyclic Ligands COGICO 2010, 9th Italian Congress of Organometallic Chemistry Firenze, Italy, 8-11 June 2010. (oral communication) 46. Guerriero, A.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Krogstad, D. A. New “upper rim” derivatives of PTA, coordination chemistry and applications in catalytic hydrogenations and hydroformilations in water XV Edizione della Scuola Nazionale di Chimica Organometallica per dottorandi Bertinoro, Italy, 23-27 May 2010 (oral communication). 47. Mirabello, V.; Gonsalvi, L.; Caporali, M.; Ienco, A.; Peruzzini, M.; Gallo, V.; Latronico, M.; Mastrorilli, P. Dynamic Behaviour of a Ruthena-P4 complex and its Platinum adduct. First evidence for a Planetary Motion around coordinated P4 7th European Symposium of Phosphorus Chemistry (EWPC-7) Budapest, Hungary, 25-26 March 2010 48. Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Rossin, A. Hydrogen storage: dove mettere l’idrogeno Energethica, 5° Salone dell'Energia Rinnovabile e Sostenibile Genova, Italy, 4-6 March 2010. 49. Rossin, A.; Gonsalvi, L.; Guerriero, A.; Tiozzo, C.; Reginato, G.; Erlandsson, M.; Peruzzini, M. The quest for advanced tailoring of water soluble phosphines. Upper rim functionalisation of PTA and applications in catalytic hydrogenation reactions Chemistry Of Organolement Compounds:Results And Prospects Moscow, Russian Federation, 28/09-02/10-2009. 50. Peruzzini, M.; Caporali, M.; Gonsalvi, L.; Ienco, A.; Mirabello, V.; Yakhvarov, D. “New Insights into the Coordination Chemistry of White Phosphorus with late Transition Metals” 2do Simposio Latinoamericano de Química de Coordinación y Organometálica (Silqom 2009) Maracaibo, Venezuela, 25/29-10-2009. 51. Landaeta, V.; Guarate, C.; Peruzzini, M.; Gonsalvi, L. Synthesys and NMR Behavior of Iridium-PTA Hydrides Potentially Soluble in Water 2do Simposio Latinoamericano de Química de Coordinación y Organometálica (Silqom 2009) Maracaibo, Venezuela, 25/29-10-2009. ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 14 Last update December 2015 52. Mallqui Ayala, M.; Romerosa, A.; Serrano Ruiz, M.; Peruzzini, M.; Gonsalvi, L. Synthesys of Gels Using Water Soluble Cp(CONHCMe3)2 Containing Allenylidene Ruthenium Complexes 12th EUROPEAN STUDENT CONFERENCE (ESC 2009 – European Colloid And Interfase Society) Almeria, Spain, 15/18-07-2009. Book of Abstracts, p 42. 53. Guerriero, A.; Reginato, G.; Peruzzini, M.; Gonsalvi, L. Upper rim functionalisation of the water soluble phosphine PTA and use of the related Ru and Ir complexes in catalytic hydrogenations 7th INTERNATIONAL SCHOOL OF ORGANOMETALLIC CHEMISTRY (ISOC-7) Camerino, Italy, 05/09-09-2009. Book of Abstracts, P49. 54. Mirabello, V.; Caporali, M.; Gonsalvi, L.; Ienco, A.; Peruzzini, M. Reactivity of White Phosphorus with Mononuclear Ruthenium Complexes 7th INTERNATIONAL SCHOOL OF ORGANOMETALLIC CHEMISTRY (ISOC-7) Camerino, Italy, 05/09-09-2009. Book of Abstracts, P68. 55. Di Credico, B.; Gonsalvi, L.; Reginato, G.; Rossin, A.; Peruzzini, M. Metal-Organic Coordination Architectures with Thiazole- and Oxazole-Spaced Carboxylates XXIII CONGRESSO NAZIONALE DELLA SOCIETÁ CHIMICA ITALIANA Sorrento, Napoli, 05/10-07-2009. Atti del Congresso. Abstract INO-PO-18, p. 257. 56. Caporali, M.; Ienco, A.; Gonsalvi, L.; Peruzzini, M. New insights into the activation of white phosphorus XXIII CONGRESSO NAZIONALE DELLA SOCIETÁ CHIMICA ITALIANA Sorrento, Napoli, 05/10-07-2009. Atti del Congresso. Abstract INO-OR-3, p. 245. 57. Di Credico, B.; Fabrizi De Biani, F.; Gonsalvi, L.; Guerri, A.; Ienco, A.; Laschi, F.; Peruzzini, M.; Reginato, G.; Rossin, A.; Zanello, P. Nuovi complessi macrociclici di Rutenio(II) con leganti alchinilfosfinici TUMA 2009. XXVIII Congresso Interregionale delle Sezioni Toscana Umbria Marche Abruzzo della Società Chimica Italiana Tirrenia, Pisa, 20/22-09-2009. Atti del Congresso. Abstract CO37. 58. Mirabello, V.; Caporali, M.; Gonsalvi, L.; Peruzzini, M. Reactivity of White Phosphorus with Mononuclear Complexes of Ruthenium FIGIPAS 10th, The 10th International Meeting in Inorganic Chemistry Palermo, Italy, 1-4 July 2009 59. Malacea, R.; Routaboul, L.; Vincendeau, S.; Poli, R.; Daran, J.-C.; Manoury, E.; Le Roux, E.; Gonsalvi, L.; Peruzzini, M.; Hayes, J. M.; Ujaque, G.; Lledos, A. New Planar Chiral Ferrocenyl P,S Ligands for Asymmetric Catalysis FIGIPAS 10th, The 10th International Meeting in Inorganic Chemistry Palermo, Italy, 1-4 July 2009 60. Rossin, A.; Giambastiani, G.; Giannasi, A.; Gonsalvi, L.; Ienco, A.; Peruzzini, M; Ulivi, L.; Ziparo, C.; Zoppi, M. Phase transitions and H2 uptake by H[Mg(HCOO)3] NHMe2 MOFCAT2009 Workshop, MOFs on the Road to Applications Oslo, Norway, 17-19 June 2009 61. Rodriguez-Rocha, M.; Bolaño Garcia, S.; Bravo Bernardez, J.; Castro Fojo, J.; Gonsalvi, L.; Peruzzini, M. Reactivity of [TpRuCl(PTA)(PPh3)] with Alkynes and Propargylic Alcohols 6th European Symposium of Phosphorus Chemistry (EWPC-6) Firenze, Italy, 26-27 March 2009 62. Yakhvarov, D. G.; Peruzzini, M.; Gonsalvi, L.; Caporali, M.; Ganushevich, Y.; Morozov, V.; Sinyashin, O. Electrochemical Properties of Co, Rh And Ir Complexes bearing Oligophosphorus Ligands 6th European Symposium of Phosphorus Chemistry (EWPC-6) Firenze, Italy, 26-27 March 2009 63. Caporali, M.; Barbaro, P.; Gonsalvi, L.; Ienco, A.; Zanobini, F.; Peruzzini, M.; Yakhvarov, D. G. Zwitterionic Catena-Phosphonium(+)Diphosphenide(-) Ligands from Stepwise Activation of White Phosphorus 6th European Symposium of Phosphorus Chemistry (EWPC-6) Firenze, Italy, 26-27 March 2009 ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 15 Last update December 2015 64. Rossin, A.; Costantino, F.; Di Credico, B.; Fornasiero, P.; Gonsalvi, L.; Ienco, A.; Montini, T.; Peruzzini, M. Phase transitions and CO2 adsorption of polymeric magnesium formate MOF08, 1st International Conference on Metal-Organic Frameworks and Open Framework Compounds Augsburg, Germany, 8-10 October 2008 65. Gonsalvi, L.; Peruzzini, M. How to teach an old dog new tricks: the renaissance of the water soluble phosphine PTA (1,3,5-triaza-7phosphaadamantane) and its analogues (oral communication) ISHC XVI, 16th International Symposium on Homogeneous Catalysis Florence, Italy, 7-11 July 2008 66. Guerriero, A.; Erlandsson, M.; Ienco, A.; Reginato, G.; Peruzzini, M.; Gonsalvi, L. Synthesis of diastereomerically enriched analogues of the water soluble phosphine PTA and use in catalytic hydrogenations ISHC XVI, 16th International Symposium on Homogeneous Catalysis Florence, Italy, 7-11 July 2008 67. Urbina-Blanco, C. A.; Landaeta, V. R.; Erlandsson, M.; Peruzzini, M.; Gonsalvi, L. Indenyl iridium(iii) complexes bearing the water soluble phosphine PTA phosphaadamantane) ISHC XVI, 16th International Symposium on Homogeneous Catalysis Florence, Italy, 7-11 July 2008 (PTA = 1,3,5-triaza-7- 68. Rossin, A.; Kovacs, G.; Lledos, A.; Gonsalvi, L.; Peruzzini, M. Homolytic Vs. Heterolytic Water-Assisted Dihydrogen Splitting By Ru(II)-PTA Complexes: A DFT Analysis of the reaction mechanism (PTA = 1,3,5-Triaza-7-Phosphaadamantane) ISHC XVI, 16th International Symposium on Homogeneous Catalysis Florence, Italy, 7-11 July 2008 69. Malacea, R.; Routaboul, L.; Vincendeau, S.; Poli, R.; Daran, J.-C.; Manoury, E.; Le Roux, E.; Gonsalvi, L.; Peruzzini, M.; Hayes, J. M.; Ujaque, G.; Lledos, A. Asymmetric Hydrogenation of ketones catalyzed by Iridium complexes of Ferrocenyl P,S ligands ISHC XVI, 16th International Symposium on Homogeneous Catalysis Florence, Italy, 7-11 July 2008 70. Di Credico, B.; Fabrizi de Biani, F.; Gonsalvi, L.;Guerri, A.; Ienco, A.; Laschi, F.; Peruzzini, M.; Reginato, G.; Rossin, A.; Zanello, P. Reactivity studies of cyclopentadienyl ruthenium(II) complexes towards alkynylphosphine ligands COGICO 2008, 8th Italian Congress of Organometallic Chemistry Perugia, Italy, 25-28 June 2008 71. Guerriero, A.; Coletti, C.; Gonsalvi, L.; Marvelli, L.; Re, N.; Reginato, G.; Peruzzini, M. NMR and DFT studies on the nucleophilic addition of phosphines to C(gamma)-activated rhenium allenylidenes COGICO 2008, 8h Italian Congress of Organometallic Chemistry Perugia, Italy, 25-28 June 2008 72. Coletti, C.; Guerriero, A.; Gonsalvi, L.; Marvelli, L.; Re, N.; Peruzzini, M. A DFT study on the electronic structure of rhenium allenylidenes and their reactivity towards phosphines COGICO 2008, 8th Italian Congress of Organometallic Chemistry Perugia, Italy, 25-28 June 2008 73. Rossin, A.; Gonsalvi, L.; Kovacs, G.; Lledos, A.; Peruzzini, M. A combined experimental and DFT approach to the analysis of dihydrogen activation By by water-soluble ruthenium complexes COGICO 2008, 8th Italian Congress of Organometallic Chemistry Perugia, Italy, 25-28 June 2008 74. Dinoi, C.; Ciclosi, M.; Vincendeau, S.; Poli, R.; Gonsalvi, L.; Peruzzini, M. Efficient oxidation of thiophene derivatives catalyzed by organomolybdenum and tungsten oxido complexes 235th ACS National Meeting, Cotton Memorial Symposium New Orleans, LA, 6-10 April 2008. 75. Caporali, M.; Bianchini, C.; Gonsalvi, L.; Oberhauser, W.; Peruzzini, M. Synthesis and characterisation of Rh(I), Ru(II) and Pd(II) complexes of the open cage water soluble aminophosphine PTN ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 16 Last update December 2015 5th European Workshop on Phosphorus Chemistry Regensburg, Germany, 10-11 March 2008. 76. Gonsalvi, L.; Peruzzini, M. Aqueous phase catalysis, organometallic reactivity and much more: the renaissance of the water soluble monodentate phosphine PTA CIAM Workshop – Catalysis in Aqueous Media (Plenary Lecture) Toulouse, France, 30 November-1 December 2007 77. Erlandsson, M.; Landaeta, V. R.; Bosquain, S. S.; Dorcier, A.; Phillips, A. D.; Dyson, P.J.; Laurenczy, G.; Gonsalvi, L.; Peruzzini, M. Comparative studies for the catalytic wate pahse carbon dioxide hydrogenation using iridium and ruthenium PTA complexes (PTA=1,3,5-triaza-7-phospha-adamantane) CIAM Workshop – Catalysis in Aqueous Media Toulouse, France, 30 November-1 December 2007 78. Servin, P.; Laurent, R.; Gonsalvi, L.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M. PTA ligands as end groups of water-soluble phosphorus dendimers. Use of their Ru(II) complexes as catalysts CIAM Workshop – Catalysis in Aqueous Media Toulouse, France, 30 November-1 December 2007 79. Mallqui Ayala, I. M.; Gonsalvi, L.; Peruzzini, M.; Romerosa, A.; Serrano-Ruiz, M. Catalytic hydrogenations in water phase using ruthenium(II) complexes bearing sulfonated phosphines and diamines CIAM Workshop – Catalysis in Aqueous Media Toulouse, France, 30 November-1 December 2007 80. Landaeta, V. R.; Erlandsson, M.; Vasquez-Perez, M. E.; Urbina-Blanco, C. A.; Phillips, A. D.; Gonsalvi, L.; Peruzzini, M. Synthesis and characterisation of novel iridium complexes with water-soluble phosphine ligands CIAM Workshop – Catalysis in Aqueous Media Toulouse, France, 30 November-1 December 2007 81. Caporali, M.; Gonsalvi, L.; Ienco, A.; Peruzzini, M.; Yakhvarov, D. G. Double activation of white phosphorus mediated by diphosphine complexes of Group 8 metals and Pt(0) moieties 6th ISOC International School of Organometallic Chemistry Camerino, Italy, 8-12 September 2007 82. Bosquain, S. S.; Dorcier, A.; Dyson, P. J.; Erlandsson, M.; Gonsalvi, L.; Laurenczy, G.; Peruzzini, M. Aqueous phase carbon dioxide and bicarbonate hydrogenation catalysed by cyclopentadienyl ruthenium complexes 6th ISOC International School of Organometallic Chemistry Camerino, Italy, 8-12 September 2007 83. Mallqui Ayala, I. M.; Serrano Ruiz, M.; Romerosa, A.; Gonsalvi, L.; Peruzzini, M. Synthesis and reactivity of water soluble allenylidene ruthenium complexes bearing Cp(CONC(CH3)3)2 ligand and PPh3, PTA, mPTA and TPPMS 6th ISOC International School of Organometallic Chemistry Camerino, Italy, 8-12 September 2007 84. Servin, P.; Tristany, M.; Laurent, R.; Caminade, A.-M.; Majoral, J.-P.; Gonsalvi, L.; Peruzzini, M. Ru(II) catalysis in the presence of water with a PTA dendritic ligand 5th IDS – International Dendrimer Symposium Toulouse, France, 28 August – 1 September 2007 85. Malacea, R.; Routaboul, L. ; Vincendeau, S.; Poli, R.; Daran, J.-C; Manoury, E. ; Le Roux E., Gonsalvi L., Peruzzini M.; Hayes, J. M.; Ujaque, G.; Lledos, A. Asymmetric Hydrogenation Of Ketones Catalysed By Iridium Complexes of Planar Chiral Phosphane Thioether Ligands 2nd German-French Congress in Organic Chemistry and Biomolecular Chemistry Calvi, France, 30 June - 5 July 2007 86. Dinoi, C.; Gonsalvi, L.; Peruzzini, M.; Poli, R. Binuclear Cyclopentadienyl Oxo Molybdenum and Tungsten Complexes as Catalysts for Aryl Thiophenes Oxidation using H2O2 ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 17 Last update December 2015 3rd International Conference on Green and Sustainable Chemistry Delft, The Netherlands, 1-5 July 2007 87. Peruzzini, M.; Akbayeva, D. N.; Barbaro, P.; Caporali, M.; Di Vaira, M.; Gonsalvi, L.; Midollini, S.; Sinyashin, O.; Seniori Costantini, S.; Stoppioni, P.; Yakhvarov, D. New Pathways in metal-mediated P4 activation 9th FIGIPAS Meeting in Inorganic Chemistry Vienna, Austria, 4-7 July 2007 88. Mallqui Ayala, I. M.; Gonsalvi, L.; Peruzzini, M.; Romerosa, A.; Serrano Ruiz, M. Water phase catalytic hydrogenations with ruthenium(II) complexes bearing sulfonated phosphines and diamines 9th FIGIPAS Meeting in Inorganic Chemistry Vienna, Austria, 4-7 July 2007 89. Servin, P.; Tristany, M.; Laurent, R.; Caminade, A.-M.; Majoral, J.-P.; Gonsalvi, L.; Peruzzini, M. Water soluble dendritic catalysts 9th FIGIPAS Meeting in Inorganic Chemistry Vienna, Austria, 4-7 July 2007 90. Yakhvarov, D. V.; Peruzzini, M.; Caporali, M.; Barbaro, P.; Gonsalvi, L.; Midollini, S.; Orlandini, A.; Zanobini, F.; Ganushevich, Y.; Sinyashin, O. Bimetallic Activation of White Phosphorus 17th International Conference on Phosphorus Chemistry (ICPC-17) Xiamen, China, 15-19 April 2007 91. Rossin A., Gutsul E., Peruzzini M., Gonsalvi L., Reginato G., Giambastiani G., Bianchini C. Hydrogen storage with MOFs and transition metal borohydride complexes IDECAT Workshop “Catalysis for Sustainable Energy Production” Sesto Fiorentino, Italy, 29 November – 1 December 2006 92. Peruzzini M., Gonsalvi L., Romerosa A. Water-soluble complexes stabilized by 1,3,5-triaza-7-phosphaadamatane and its derivatives The Fourth Italian-Korean Joint Meeting On Inorganic Chemistry (Kimic Iv) Malcesine, Verona, Italy, 2-6 October 2006. Book of Abstracts, p 26 93. Reginato G., Ciardi C., Peruzzini M., Gonsalvi L., Romerosa A. Sintesi di Nuove g-Ammino b-Idrossifosfine Chirali per Elaborazione di Amminoacidi Naturali XXII CONGRESSO NAZIONALE DELLA SOCIETA’ CHIMICA ITALIANA Firenze, Italy, 10-15 September 2006. Atti del Congresso. Abstract ORG-P95, p. 377 94. Rossin, A.; Gonsalvi, L.; Peruzzini, M.; Phillips, A. D.; Lledos, A. Water-assisted dihydrogen activation in Ruthenium PTA complexes: a DFT study (PTA=1,3,5-triaza-7-phosphaadamantane) XXII CONGRESSO NAZIONALE DELLA SOCIETA’ CHIMICA ITALIANA Firenze, Italy, 10-15 September 2006 95. Manoury E., Malacea R., Routaboul L., Vincentedeau S., Poli R., Daran J.-C., Turrin C. O., Majoral J.-P-, Caminade, A.-M., Dunne J. P., Withwood A. C., Godard C., Duckett S. B., Le Roux E., Gonsalvi L., Peruzzini M. New Chiral Ferrocenyl Phosphane-Thioether Ligands: Coordination amd Asymmetric Catalysis EXPERIMENT & THEORY IN TRANSTION METAL CHEMISTRY: A MEETING POINT (E&Ttmc) Bellaterra, Spain, 27-29 September 2006. Book of Abstracts, Poster 30, p 64 96. Malacea R., Manoury E., Daran J.-C., Poli R., Le Roux E., Gonsalvi L., Peruzzini M.. Coordination Chemistry of Chiral Planar Ferrocenyl Phosphine-Thioether. Application in Hydrogenation of Ketones EXPERIMENT & THEORY IN TRANSTION METAL CHEMISTRY: A MEETING POINT (E&Ttmc) Bellaterra, Spain, 27-29 September 2006. Book of Abstracts, OD.3, p 19 97. Rossin A., Gonsalvi L., Peruzzini M., Phillips A. D., Lledos A., Maresca O. H2 activation mediated by Ru(II) PTA water-soluble complexes: how the water solvent takes an active part in the process (PTA = 1,3,5-triaza-7-phosphaadamatane EXPERIMENT & THEORY IN TRANSTION METAL CHEMISTRY: A MEETING POINT (E&Ttmc) Bellaterra, Spain, 27-29 September 2006. Book of Abstracts, OC.6, p 16 98. Malacea R., E. Le Roux, Manoury E., Poli R., Gonsalvi L., Peruzzini M. ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 18 Last update December 2015 Asymmetric Hydrogenation Of Ketones Catalysed By Chiral Planar Phosphine Thioether Iridium Complexes VII Conference on Mechanisms of Catalytic Reactions St. Petersburg, Russia, July 3-8, 2006 99. Malacea, R.; Routaboul, L. ; Vincendeau, S.; Poli, R.; Daran, J.-C; Manoury, E. ; Dunne, J. P.; Withwood A. C.; Godard, C.; Duckett, S. B.; Le Roux, E.; Gonsalvi , L.; Peruzzini, M. New chiral ferrocenyl P,S ligands for asymmetric catalysis XXIInd ICOMC, 22nd International Conference on Organometallic Chemistry Zaragoza, Spain, 23-28 July 2006 100. Rossin, A.; Gonsalvi, L.; Peruzzini, M.; Phillips, A. D.; Lledos, A., Maresca, O.. The active role of the water solvent in the dihydrogen activation in Ru(II) water soluble complexes bearing PTA ligands: a DFT analysis (PTA=1,3,5-triaza-7-phospha-adamantane) XXIInd ICOMC, 22nd International Conference on Organometallic Chemistry Zaragoza, Spain, 23-28 July 2006 101. Albinati, A.; Bolaño, S.; Bravo, J.; García-Fontán, S.; Gonsalvi, L.; Male, L.; Peruzzini, M.; Rodríguez-Rocha, M. Synthesis, characterization and reactivity of [RhCp*(H)2{PTA(N-BH3)}] XXIInd ICOMC, 22nd International Conference on Organometallic Chemistry Zaragoza, Spain, 23-28 July 2006 102. Mallqui, M.; Serrano-Ruiz, M.; Romerosa, A.; Gonsalvi, L.; Peruzzini, M. Aquosoluble ruthenium complexes with the Cp(CONC(CH3)3)2 ligand and PPh3, PTA, mPTA and TPPMS XXIInd ICOMC, 22nd International Conference on Organometallic Chemistry Zaragoza, Spain, 23-28 July 2006 103. Malacea, R.; Manoury, E.; Daran, J.-C; Poli, R.; Le Roux, E.; Gonsalvi , L.; Peruzzini, M. Coordination chemistry of chiral planar ferrocenyl phosphine-thioether. Applications in hydrogenation of ketones COGICO 2006, 7th Italian Congress of Organometallic Chemistry Parma, Italy, 9-12 July 2006 104. Barbaro, P.; Gonsalvi, L.; Mañas Carpio, S.; Midollini, S.; Orlandini, A.; Sinyashin, O.; Yakhvarov, D.; Zanobini, F.; Peruzzini, M. Opening of the P4-tetrahedron caught into action: experimental evidence for bimetallic activation of white phosphorus COGICO 2006, 7th Italian Congress of Organometallic Chemistry Parma, Italy, 9-12 July 2006 105. Bolaño, S.; Bosquain, S. S.; Phillips, A. D.; Peruzzini, M.; Romerosa, A.; Gonsalvi, L. A multi-faceted water soluble phosphine: coordination chemistry, organometallic reactivity and catalytic applications of PTA-based transition metal complexes COGICO 2006, 7th Italian Congress of Organometallic Chemistry Parma, Italy, 9-12 July 2006 106. Ciardi, C.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Romerosa, A.; Serrano, M. Synthesis of New Chiral Water Soluble Phosphines from Naturally Occurring Amino Acids OMCOS 13 – IUPAC Symposium on Organometallic Chemistry directed towards Organic Synthesis Geneva, Switzerland, 17-21 July 2005 107. Bosquain, S. S.; Bolaño, S.; Phillips, A. D.; Gonsalvi, L.; Peruzzini, M. Rh(I)-PTN Based Catalysts for Olefin Hydroformylation and Hydrogen Transfer Reactions ISHHC XII, 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis Firenze, Italy, 18-22 July 2005 108. Landaeta, V.; Gonsalvi, L.; Peruzzini, M. Ruthenium – Catalyzed Selective Oxidation of Aryl Thiophenes Using H2O2 ISHXC XII, 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis Firenze, Italy, 18-22 July 2005 109. Laurenczy, G.; Dorcier, A.; Dyson, P. J.; Bosquain, S.; Peruzzini, M.; Gonsalvi, L. Catalytic CO2 Reduction in Aqueous Solution Using CpRu(PTA)2Cl and Cp*Ru(PTA)2Cl Precursors ISHHC XII, 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis Firenze, Italy, 18-22 July 2005 ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 19 Last update December 2015 110. Bacchi, A.; Balordi, M.; Bolaño, S.; Calbiani, F.; Carcelli, M.; Elviri, L.; Gonsalvi, L. ; Pelagatti, P.; Pelizzi, C.; Peruzzini, M.; Rogolino, D. Synthesis, Characterization and Catalytic Behaviour of Ruthenium(Ii) Complexes with PNO Tridentate Ligands ISHHC XII, 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis Firenze, Italy, 18-22 July 2005 111. Romerosa, A.; Campos, T.; Lidrissi, C. Saoud, M.; Serrano, M.; Gonsalvi, L.; Bolaño, S.;Peruzzini, M. New water soluble vinylidene and allenylidene ruthenium complexes containing hydrosoluble phosphines and cyclopentadiene derivatives Green Solvents for Synthesis Bruchsal, Germany, 3-6 October 2004 112. Peruzzini, M.; Bolaño Garcia, S.; Bosquain, S; Campos, T.; Gonsalvi, L.; Lidrissi, C.; Mañas Carpio, S.; Phillips, A. D; Romerosa, A.; Saoud, M.; Serrano Ruiz, M. Nuovi complessi metallici idrosolubili stabilizzati dalla fosfina PTA (PTA = 1,3,5-triaza-7-fosfaadamantano) XXXII Congresso Nazionale della Divisione di Chimica Inorganica Roma, Italy, 20-24 September 2004 113. Phillips, A. D.; Ienco, A.; Gonsalvi, L.; Peruzzini, M.; Mealli, C. Understanding the molecular properties in hetero-substituted phosphaadamantanes EuroConference on New Theoretical and Spectroscopical Approaches to Inorganic Chemistry Problems San Feliu de Guixols, Spain, 4-9 September 2004 114. Bolaño, S.; Gonsalvi, L.; Zanobini, F.; Vizza, F.; Bertolasi, V.; Romerosa, A.; Peruzzini, M. Regioselective hydrogenation of benzylidene acetone and cinnamaldehyde catalysed by water soluble ruthenium complexes Summer School on Green Chemistry – 7th Edition Venezia, Italy, 5-11 September 2004 115. Poli, R.; Phillips, A. D.; Gonsalvi, L.; Malacea, R.; Daran, J.-C.; Peruzzini, M. A new class of rhodium-P,N complexes derived from cage-type phosphabicyclo[3.3.1]-nonane ligands for use in hydroformylation catalysis III Euchem Conference on Nitrogen Ligands in Organometallic Chemistry and Homogeneous Catalysis Camerino, Italy, 8-12 September 2004 116. Ortiz-Frade, L. A.; Ruiz-Ramirez, L.; Moreno-Esparza, R.; Gonsalvi, L.; Masi, D.; Peruzzini, M.; Zanobini, F.; Vizza, F. Reactivity study in solution of a New Ru(II) Compound Containing the Ligand 1,8-bis(2-Pyridyl)-3,6-dithiaoctane (pdto) and triphenylphosphine. Electrochemical & structural study of the dimeric product [Ru(pdto)Cl]2 XXXVI ICCC, 36th International Conference on Coordination Chemistry Merida, Mexico, 18-23 July 2004 117. Gonsalvi, L.; Phillips, A. D.; Maresca, O.; Lledos, A.; Peruzzini, M. Stable water soluble Cp and Cp* Ru hydrides. HP-NMR, DFT studies and catalytic tests for the selective hydrogenation of activated olefins ISHC XIV, 14th International Symposium on Homogeneous Catalysis Munich, Germany, 5-9 July 2004 118. Gonsalvi, L.; Reginato, G.; Mantovani, N.; Marvelli, L.; Rossi, R.; Grigiotti, E.; Zanello, P.; Peruzzini, M. Multiconjugated carbon-carbon chains based on bimetallic allenylidene units MOLMAT 2004, International Symposium on Molecular Materials and Organometallics Rennes, France, 12-14 May 2004 119. Phillips, A. D.; Gonsalvi, L.; Romerosa, A.; Vizza, F.; Peruzzini, M. Novel water soluble Ru-PTA complexes: recent advances in catalytic and biological applications RSC Dalton Discussion 6, Organometallic Chemistry and Catalysis York, UK, 9-11 September 2003 120. Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A. Simple yet efficient optimisation of ruthenium catalysed oxidations with NaOCl via pH control ISHC XIII, 13th International Symposium on Homogeneous Catalysis Tarragona, Spain, 3-7 September 2002 121. Gaunt, J.; Gonsalvi, L.; Sunley, G.; Cavallo, L.; Haynes, A. Ligand effects on organometallic reactivity ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 20 Last update December 2015 XXth ICOMC, 20th International Conference on Organometallic Chemistry Corfu, Greece, 7-12 July 2002 122. Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A. Green catalytic -oxidation of ethers to esters (oral communication) NCCC II, Second Netherlands Catalysis and Chemistry Conference Noordwijkerhout, The Netherlands, 5-7 March 2001 123. Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A. A Clean Catalytic Process for the Oxidation of Ethers and Acetals to Esters via O2 ISHC XII, 12th International Symposium on Homogeneous Catalysis Stockholm, Sweden, 27 August - 1 September 2000 124. Gaunt, J.; Haynes, A.; Gonsalvi, L.; Sunley, G. Stereoelectronic Effects on the Rate of Migratory CO Insertion in Rhodium catalysed Methanol Carbonylation ISHC XII, 12th International Symposium on Homogeneous Catalysis Stockholm, Sweden, 27 August - 1 September 2000 125. Gonsalvi, L.; Haynes, A.; Adams, H.; Maitlis, P. M. Ligand Effects on Rhodium and Iridium Catalysed Methanol Carbonylation XVIIIth ICOMC, 18th International Conference on Organometallic Chemistry Munich, Germany, 16-21 August 1998 126. Gonsalvi, L.; Adams, H.; Haynes, A. Ligand Effects on Homogeneous Rhodium-Catalysed Methanol Carbonylation ISHC XI, 11th International Symposium on Homogeneous Catalysis St Andrews, Scotland, UK, 12-17 July 1998 127. Haynes, A.; Gonsalvi, L.; Evans, D.; Sunley, G. J. Oxidative Addition of Methyl Iodide to [RhI(CO){Ph2PCH2P(S)Ph2}] ECTOC-3, Electronic Conference on Trends in Organometallic Chemistry Web conference, 30 June-31 July 1997 128. Cauzzi, D.; Costa, M.; Predieri, G.; Gonsalvi, L.; Tiripicchio, A.; Zanoni, R. Metal Catalysts anchored to hybrid organic-inorganic sol-gel materials CO.GI.C.O. 94, 2nd Italian Congress of Organometallics, Marina di Ascea (Italy), 18-21 September 1994 Lectures - invited 1. Gonsalvi, L.; Guerriero, A.; Peruzzini, M. Amphiphilic Aminophosphines as Stabilizing Ligands for Homogeneous and Heterogeneous Catalytic Processes in Water QIES 2014 – Conferencia Plenaria de Quimica Inorganica de la Real Sociedad Española de Quimica Almeria, Spain, 15-18 June 2014. Keynote Invited Lecture C2. 2. Gonsalvi, L.; Guerriero, A.; Hapiot, F.; Krogstad, D. A.; Monflier, E.; Peruzzini, M.; Reginato, G.; Six, N. Keep it simple: tailored functionalizations of a versatile phosphine for use in aqueous phase catalysis COGICO-10 - 10° CONGRESSO DEL GRUPPO INTERDIVISIONALE DI CHIMICA ORGANOMETALLICA Padova, Italy, 05-08 June 2012. Book of Abstracts, KN6, p. 30. Key Note Lecture (invited) 2. Aqueous phase catalysis, organometallic reactivity and much more: the renaissance of the water soluble monodentate phosphine PTA CIAM (Catalysis in Aqueous Media) Workshop, CNRS-LCC, Toulouse, France, 30 November 2007 (Plenary Lecture) 3. A multi-faceted water soluble phosphine: coordination chemistry, organometallic reactivity and catalytic applications of PTA-based transition metal complexes INEOS Seminar, Russian Academy of Sciences, Moscow, Russia, 12 September 2006 4. Aqueous phase hydrogenations catalysed by water soluble half sandwich ruthenium hydrides. Synthesis, catalytic tests and mechanism. Sustainable / Green Chemistry and Chemical Technology Workshop, Venice, Italy, 20-21 February 2004 ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 21 Last update December 2015 5. Aqueous hydride Chemistry: hydrosoluble ligands and complexes for selective hydrogenations Ciclo de Conferencias Semanales, Universidad Nacional Autonoma de Mexico, Mexico, 20 January 2004 6. Advances in Rhodium Catalysed Methanol Carbonylation Ciclo de Conferencias Semanales, Universidad Nacional Autonoma de Mexico, Mexico, 20 January 2004 7. Liquid Phase Organic Oxidations for Fine Chemicals. An example of process optimisation. Inorganic Chemistry Seminar, University of Parma, Italy, 20 December 2002. 8. Advances in Rhodium Catalysed Methanol Carbonylation Inorganic Chemistry Seminar, University of Parma, Italy, 13 December 2002. 9. Modelling Ligand Effects in Catalytic Methanol Carbonylation Inorganic Chemistry Seminar, University of Parma, Italy, 8 November 2000. Present and Past Collaborations Dr. Thibault Cantat and Dr Guillaume Lefevre, CEA Paris Saclay, France; Prof. Karl Kirchner, Vienna University of Technology, Austria; Dr. Henrik Junge and Prof Matthias Beller, Leibnitz Institute for Catalysis, Rostock, Germany; Prof. Frederic Hapiot and Prof Eric Monflier, Université Lille Nord UCCS-UdA, Lens, France; Prof Paul Dyson and Prof Gabor Laurenczy, EPFL Lausanne, Switzerland; Prof Hansjörg Grützmacher, ETH Zurich, Switzerland; Dr. Donald A. Krogstad, Concordia College at Moorhead, USA; Prof. Rinaldo Poli, CNRS LCC Toulouse, France; Dr Paolo Pelagatti, University of Parma, Italy; Dr Willem Schipper, Thermphos Int. BV, Vlissingen, The Netherlands; Prof. Dr. J-G. de Vries, DSM Life Sciences, Geleen, The Netherlands; Dr. Anthony Haynes, University of Sheffield, UK and Dr G. J. Sunley, BP Chemicals, Hull, UK. ATTENTION: this document is property of the author and cannot be downloaded, used or printed without the author’s permission. 22