Chapter 15 answer keys packet Page 1 notes Page 2 notes Page 3 WS Intro to Solutions 1. solute-smaller portion solvent-larger portion 2. 5 mL alcohol in 95 mL water solvent 5mL water solute in 95 mL solvent 3. increase temp causes increase in solubility of solid increase temp cause increase in KE to break crystal lattice and make part of solution 4. saturated solution can’t hold any more solute at the given temperature. Unsaturated can hold more 5. 1. make a saturated solution. 2. increase heat 3. add more solute 4. allow to cool undisturbed 6. solubility-amount of solute that can be held in a set amount of solvent at a certain temperature g solute/100 g of water at a certain temp 7. one of the particles on the bottom dissolves and one of the particles that is dissolved sinks back down 8. salvation is the chemical reaction between a solute and a solvent and causes dissociation and a solution to be formed. 9. unlimited ability to mix with one another. 10. try to dissolve more solute. If all you add settles to the bottom, it was saturated. 11. Try to add more solute. If any that you add dissolves, it was unsaturated. 12. Try to add more solute. If more than you added drops to the bottom, it is supersaturated. 13. CaCl2 (s) ---- Ca+2 (aq) + 2 Cl- (aq) SnF2 (s) ---- Sn+2 (aq) + 2 F- (aq)_ Al2 S3 (s) ---- 2Al+3 (aq) + 3 S-2 (aq)_ Page 4 Continued 14. homo, homo, hetero, homo, hetero, hetero, homo, homo, hetero, hetero, hetero, homo, homo, homo 15. solute=sugar solvent tea solute= silver solvent= gold solute= zinc, tin, copper solvent=iron solute=oxygen, argon, carbon dioxide solvent=nitrogen solute= chocolate syrup solvent = milk solute= coke syrup and carbon dioxide solvent= water Page 5 WS Solubility Curves 1 1. 54-55 degrees Celcius 2. NH3 and Ce2(SO4)3 3. KNO3 steepest slope 4. NaCl least steep slope 5. 130 g 6. at 70 = 130 g at 50 = 80 g 130 - 80 = 50 g 7. at 50 = 49 g at 70 = 59 g 59 - 49 = 10 g 8. KI 9. Ce2(SO4)3 10. at 90 = 70 g 70g/100g water = x/1000g water x = 700 g 11. at 40 = 104 g 104g/100g water = x/250g water x = 260 g 12. supersaturated at 50, it should hold 80 g. since it is holding 100 g, it is holding excess. It is supersaturated. Page 6 Graph Potassium Nitrate 1. 2. 3. 4. 5. 6. 7. decrease 65 g to 69 g 171 g supersaturated supersaturated 27 to 30g 5g Page 7 Graph Lab Solubility of Solutes 1. 2. 3. 4. 5. 20 degrees celcius 135 g supersaturated 117g -88g = 29g 45 g KCl/x g KCl = 100 g water/250 g water Li2CO3 Page 8 and 9 notes Page 10 notes Page 11 Notes Page 12 Molarity Ws 1. 13.1 g 2. .337 M 3. .128 L 4. .400 moles 5. 3.89 M 6. 342 g/mol = 112.5 g KCl 7. 4.52 x 1023 molecules 8. 4.29 M Page 13 WS Molarity and Molality -1 1. 100. mol NaCl 2. 2100 g NaCl 3. 100. mol CaCl2 _ 4. 4000 g CaCl2 5. .115 m 6. .3333 m 7. .07000m 8. .4667 m Page 14 Continued 9. 8.07 x 1025 FU 10. 1.23 x 1026 FU 11. .225 M 12. .01540 M 13. .169 m 14. 6.67 x 10-4 m 15. 3.23 g 16. 1.86 m 17. 1.41 M Page 15 notes Page 16 WS Net Ionic Equations 1 1. a. 3CuSO4 (aq) + 2FeCl3(aq) ---- 3CuCl2(aq) + Fe2(SO4)3 (aq) b. 3Cu+2(aq) + 3SO4-2(aq) + 2Fe+3(aq) +6Cl-1(aq) ---- 3Cu+2(aq) + 6Cl-1(aq) + 2Fe+3(aq) + 3SO4-2(aq) c. NR 2. a. FeSO4 (aq) + (NH4 )2S(aq) ---- FeS(S) + (NH4)SO4 (aq) b. Fe+2(aq) + SO4-2(aq) + 2 NH4+(aq) + S-2(aq) ---- FeS(S) + 2 NH4+(aq) + SO4-2(aq) c. Fe+2(aq) + S-2(aq) ---- FeS(S) 3. a. K2CO3 (aq) + Sr (NO3)2(aq) ---- 2KNO3(aq) + SrCO3 (s) + b. 2K (aq) + CO3-2(aq) + Sr+2(aq) + 2NO3-1(aq) ---- 2K+(aq) + 2NO3-1(aq) + SrCO3(s) c. CO3-2(aq) + Sr+2(aq) ---- SrCO3(s) 4. a. NaI (aq) + AgNO3(aq) ---- AgI(s) + NaNO3 (aq) b. Na+(aq) + I-1(aq) + Ag+1(aq) + NO3-1(aq) ----- 2AgI(s) + Na+1(aq) + -1 NO3 (aq) c. Ag+1(aq) + I-1(aq) ---- AgI(s) 5. a. Al2 (SO4)3 (aq) + 3CaCl2 (aq) ---- 2AlCl3 (aq) + 3CaSO4 (s) +3 b. 2Al (aq) + 3SO4-2(aq) + 3Ca+2(aq) + 6Cl-1(aq) ---- 2Al+3(aq) + 6Cl-1(aq) + 3CaSO4 (s) c. 3SO4-2(aq) + 3Ca+2(aq) ---- 3CaSO4 (s) page 17 chart page 18 notes page 19 notes page 20 WS Boiling Point Elevation and Freezing Point Depression -1 1. -1.86 0C 2. -1.86 0C 3. -1.86 0C 4. 100.13 0C 5. 100.39 0C page 21WS Boiling Point Elevation and Freezing Point Depression -1 continued 6. 100.71 0C 7. -3.65 0C 8. 1.9 moles 9. .897 mol 10. 72.1 g Page 22 WS Colligative Properties 1. 100.575 0C 2. 101.323 0C 3. -7.19 0C 4. 101.10 0C 5. -3.94 0C 6. -3.72 0C 7. 75.22 g/mol Page 23 Colligative properties of solutions 1. 2000g 2. 625 g 3. .00666 m 4. -.545 0C 5. -.465 0C 6. .23 m 7. .215 m 8. 172 g