TCE Contamination and Cleanup Curriculum Investigating Contaminants Written by Christopher Martin Edits By: Stephanie Nardei Time: Preparation Time: Materials: 1 class period Provide copies of the chemicals identified and the epidemiologic studies sections of the Love Canal report. Internet access Abstract When considering waste management, it is important to understand nature and threats posed by each chemical. Students will investigate Trichloroethylene (TCE) and chemicals found in Love Canal. Chemicals from landfill sites pose the greatest threat to the environment when they enter the water supply. Students will apply their knowledge of chemistry and search the EPA website for contaminants in drinking water. Objectives Students will be able to: 1. Draw chemical structures 2. Understand need for safe disposal of waste chemicals National Science Education Standards: The designed world B. Materials and manufacturing Waste management includes considerations of quantity, safety, degradability, and cost. It requires social and technological innovations, because waste-disposal problems are political and economic as well as technical. Arizona Science Standards: Strand 1: Inquiry Process Concept 3: Analysis, Conclusions, and Refinements. Evaluate experimental design, analyze data to explain results and propose further investigations. Design models. Teacher Background Conversion of units, research of EPA guidelines for safe levels of contaminants and demonstration of chemical geometry will enable students to understand dangers industrial chemical waste can pose. Refer to the resources below for valuable background information. Related and Resource Websites Conversion of Units http://www.chemie.fu-berlin.de/chemistry/general/units_en.html Online Conversion.com http://www.onlineconversion.com/ EPA Drinking Water Containments http://www.epa.gov/safewater/contaminants/index.html Love Canal: A Special Report to the Governor & Legislature: April 1981 http://www.health.state.ny.us/nysdoh/lcanal/lcreport.htm TCE Contamination and Cleanup Curriculum Trichloroethylene in Wikipedia http://en.wikipedia.org/wiki/Trichloroethylene ADSTR on Trichloroethylene http://www.atsdr.cdc.gov/tfacts19.html Water in the Tucson Area: Seeking Sustainability http://cals.arizona.edu/AZWATER/publications/sustainability/report_html/chap6_01.html The TCE Blog http://www.tceblog.com/posts/1150060057.shtml Arizona Daily Star on TCE in Tucson http://www.azstarnet.com/allheadlines/139787 Activity 1. Distribute copies of “chemicals identified” section from the Love Canal report. To understand contamination levels, it will be helpful to convert to mg/l or milligrams/liter. Explain 1 µg/l (microgram/liter) = 0.001 mg/l. 2. Read the love canal report section “Epidemiological studies” http://www.health.state.ny.us/environmental/investigations/love_canal/lcreport.htm#epide miologic (from above Related and Resource websites) and health threats found among the population at Love Canal). 3. Using the worksheet, students record information using the “chemicals identified” report section and EPA website http://www.epa.gov/safewater/contaminants/index.html 4. Students interpret the information and answer the questions: Are levels of chemicals found in the water at Love Canal hazardous to life? Based on the chemical analysis, what illnesses will people at Love Canal suffer from? Found at Love Canal (water) mg/l Benzene Carbon Tetrachloride Chlorobenzene Chloroform Dichlorobenzene Dichloroethane Tetrachloroethylene Trichlorobenzene Trichloroethylene Toluene Dioxin (TCDD) Health risks EPA standards for drinking water mg/l Structural Formula Hazardous to Humans? TCE Contamination and Cleanup Curriculum Extension Trichloroethylene has been found in the ground water in Tucson, Arizona at levels of 26 parts per billion. This is 0.026 mg/L. Fortunately, the water is being treated and the TCE is removed. However, prior to 1980 people were unaware of this contaminant in their drinking water. What health affects was associated with this level of contamination? Embedded Assessment Successful completion of the chart and interpretation will demonstrate the student’s ability to understand the need for safe disposal of industrial waste.