Energy and Mineral Resources 23 Energy and Mineral Resources begins with a discussion of renewable and nonrenewable resources. Coal, oil, and natural gas are examined in some detail followed by environmental effects of burning fossil fuels, oil sands and shales, and alternate energy sources. The relationship of mineral resources to igneous rocks, metamorphic rocks, and weathering are presented. The chapter closes with a brief look at nonmetallic mineral resources, including building materials and industrial minerals. Learning Objectives After reading, studying, and discussing the chapter, students should be able to: Distinguish between renewable and nonrenewable natural resources. Briefly discuss the various types of energy resources, including coal, oil, and natural gas. List and explain some of the environmental effects of burning fossil fuels. Discuss the potential of tar sands and oil shale as possible energy resources in the future. Briefly discuss the potential benefits and drawbacks to various alternate energy sources, including nuclear, solar, wind, hydroelectric, geothermal, and tidal energy. Explain the difference between mineral resources, mineral reserves, and mineral deposits. Briefly discuss the origin of mineral resources related to igneous processes. Explain the origin of mineral deposits unrelated to igneous processes, including metamorphic processes, weathering, and placer deposits. Discuss nonmetallic mineral resources, both building materials and industrial minerals. Chapter Outline___________________________________________________________________ I. Renewable and nonrenewable resources A. Renewable resources 1. Can be replenished over relatively short time spans 2. Examples a. Plants b. Animals for food c. Trees for lumber B. Nonrenewable resources 1. Significant deposits take millions of years to form 2. Examples a. Fuels (coal, oil, natural gas) b. Metals (iron, copper, uranium, gold) C. Some resources, such as groundwater, can go in either category depending on how they are used II. 191 Energy resources A. Coal 1. Formed mostly from plant material 2. Along with oil and natural gas, coal is commonly called a fossil fuel 3. The major fuel used in power plants to generate electricity 192 CHAPTER 23 4. Problems with coal use a. Environmental damage from mining b. Air pollution B. Oil and natural gas 1. Oil and natural gas, consisting of various hydrocarbon compounds, are found in similar environments 2. Derived from the remains of marine plants and animals 3. Formation is complex and not completely understood 4. A geologic environment that allows for economically significant amounts of oil and gas to accumulate underground is termed an oil trap a. Two basic conditions for an oil trap 1. Porous, permeable reservoir rock 2. Impermeable cap rock, such as shale b. Common oil and natural gas traps include 1. Anticlinal traps 2. Fault traps 3. Stratigraphic traps c. When the cap rock is punctured by drilling, the oil and natural gas, which are under pressure, migrate from the pore spaces of the reservoir rock to the drill hole C. Environmental effects of burning fossil fuels 1. Urban air pollution a. Air pollutants are airborne particles and gases that occur in concentrations that endanger the heath of organisms and disrupt the orderly functioning of the environment b. Two types of pollutants 1. Primary pollutants – emitted directly from identifiable sources 2. Secondary pollutants – formed when chemical reactions take place among primary pollutants 2. Carbon dioxide and global warming a. Burning fossil fuels produces carbon dioxide – one of the gases responsible for warming the lower atmosphere b. Greenhouse effect – the atmosphere is transparent to incoming short wavelength solar radiation. However, the outgoing long-wave radiation emitted by Earth is absorbed in the lower atmosphere, keeping the air near the ground warmer c. It appears that global temperatures have increased (global warming) due to a rising level of atmospheric carbon dioxide d. Possible consequences of global warming include 1. A probable rise in sea level 2. Shifts in the paths of large scale cyclonic storms 3. Stronger tropical storms 4. Increases in the frequency and intensity of heat waves and droughts D. Oil sands and oil shale 1. Oil sands a. Mixtures of clay and sand combined with water and bitumen (a viscous tar) b. Several substantial deposits around the world c. Obtaining oil from tar sands has significant environmental drawbacks 1. Substantial land disturbance Energy and Mineral Resources 2. Requires large quantities of water 3. Produces contaminated water and sediment 2. Oil shale a. Contains enormous amounts of untapped oil b. Currently, because of world markets and with current technologies, not worth mining E. Alternate energy sources 1. Nearly 90 percent of the world’s energy needs are derived from nonrenewable fossil fuels 2. Possible alternate energy sources a. Nuclear energy 1. Energy from nuclear fission 2. Primary fuel is Uranium235 3. Obstacles to development a. Cost to build nuclear facilities b. Possibility of serious accidents b. Solar energy – the direct use of the Sun’s rays 1. Passive solar collectors – e.g., south-facing windows 2. Active solar collectors – e.g., roof-mounted devices that collect heat or rooftop photovoltaic systems c. Wind energy – an almost free, nonpolluting source of energy that has been used for centuries d. Hydroelectric power 1. Power generated by falling water 2. Limited by the availability of appropriate sites 3. Recently, pumped water storage systems have come into use e. Geothermal energy 1. Tapping natural underground reservoirs of steam and hot water f. 193 2. Favorable geologic factors include a. A potent source of heat b. Large and porous reservoirs with channels connected to the heat source c. A cap of low permeability rocks Tidal power 1. Harnessed by constructing a dam across the mouth of a bay or an estuary having a large tidal range 2. Not feasible along most of the world’s coasts III. Mineral Resources A. The endowment of useful minerals ultimately available commercially 1. Mineral resources include a. Reserves – already identified deposits from which minerals can be extracted profitably b. As well as known deposits that are not economically or technologically recoverable 2. Ore – refers to useful metallic minerals that can be mined at a profit and in common usage to some nonmetallic minerals such as fluorite and sulfur 3. To be considered of value, an element must be concentrated above the level of its average crustal abundance B. Mineral resources and igneous processes 1. Some of the most important accumulations of metals are produced by igneous processes that concentrate the desirable materials 2. Processes include a. Magmatic segregation 194 CHAPTER 23 1. Heavy minerals that crystallize early tend to settle to the lower portion of the magma chamber 2. In the late stages of cooling granitic magmas, the residual melt may become enriched in rare elements and heavy metals b. Diamonds 1. Originate at great depths 2. Once crystals form, they are carried upward toward the surface 3. Crystals are disseminated in ultramafic rock called kimberlite c. Hydrothermal solutions 1. Among the best known and important ore deposits a. Gold deposits of the Homestake mine in South Dakota b. Lead, zinc, and silver ores near Coeur d’Alene, Idaho 2. Majority originate from hot, metal rich fluids that are remnants of late-stage magmatic processes 3. Move along fractures, cools, and precipitates the metallic ions to produce vein deposits 4. Disseminated deposits, rather than being concentrated in narrow veins, are distributed throughout an entire rock mass C. Mineral resources and metamorphic rocks 1. Many of the most important metamorphic ore deposits are produced by contact metamorphism a. Sphalerite (zinc) b. Galena (lead) c. Chalcopyrite (copper) 2. Regional metamorphism can also generate useful deposits a. Talc b. Graphite D. Weathering and ore deposits 1. Secondary enrichment – concentrating metals into economically valuable concentrations a. By downward-percolating water removing undesirable materials b. By carrying desirable elements to lower zones and concentrating them 2. Bauxite a. Principal ore of aluminum b. Forms in rainy tropical climates from chemical weathering and the removal of undesirable elements by leaching 3. Other deposits, such as many copper and silver deposits, result when weathering concentrates metals that are deposited through a low-grade primary ore E. Placer deposits 1. Placers – deposits formed when heavy metals are mechanically concentrated by currents 2. Involve heavy and durable minerals 3. Examples include a. Gold b. Platinum c. Diamonds F. Nonmetallic mineral resources 1. Use of the word “mineral” is very broad 2. Two common groups a. Building materials Energy and Mineral Resources 1. 2. 3. Natural aggregate (crushed stone, sand, and gravel) Gypsum (plaster and wallboard) Clay (tile, bricks, and cement) 195 b. Industrial minerals 1. Fertilizers 2. Sulfur 3. Salt Answers to the Review Questions 1. The difference between renewable and nonrenewable resources is really a function of the time scale involved. On a geological time scale, one could argue that even metallic mineral deposits are renewable because they are currently forming at many locations on the ocean floor. The typical economist’s or corporate executive’s time scale may be a few years to a few decades. In recent years, environmental concerns have forced resource planners to consider time scales of hundreds and even thousands of years. The idea is simply that a renewable resource, like hydroelectric power from a dam, will be there year after year (as long as the rains come and the reservoir does not break or fill with sediments). Nonrenewable resources such as petroleum, copper, coal, and groundwater (in dry land areas) were formed in the geologic past and are not presently being replenished at even a tiny fraction of the rate at which they are being used. Nonrenewable resources can be extracted for a finite length of time after which the resource is exhausted or operating costs are too high to justify continuing production. 2. At the beginning of the 19th century, the world population had barely reached one billion; the population has grown rapidly over the past 200 years, reaching two billion in 1930 and four billion in 1975. It could easily reach seven billion during the first decade of the 21st century. In the near future, such a rapid growth rate will result in lower living standards for most people because of increasingly harsh environmental pressures on terrestrial and marine habitats, and intensified competition for living space and natural resources. 3. More than 70 percent of domestically produced coal is burned in electrical power-generating plants in the United States and abroad. Coal is an important U.S. export commodity. It fueled the industrial revolution and was the dominant home-heating and railroad fuel until the late 1940s. The “dawn” of the petroleum age early in this century portended an end to coal’s reign as the fossil fuel of choice, but rising electricity consumption, huge domestic reserves, and problems with nuclear power have assured that coal will retain a substantial role in domestic energy production in the foreseeable future. Coals are generally ranked as lignite (brown coal), bituminous (soft coal), and anthracite (hard coal), with lignite having the lowest carbon content and anthracite having the highest. Lignites provide the lowest number of heat calories per unit weight. Bituminous coals rich in hot-burning, hydrocarbon compounds may generate more heat energy than some anthracites of higher carbon contents. Coal-fired electrical generation plants can use any rank of coal; steady, reliable supplies and low fuel transportation costs are essential. Transporting fuel to the plant site is far more expensive, on an energy unit per mile basis, than “sending” electricity to distant consumers over high voltage transmission lines. 196 CHAPTER 23 Thus most new coal-fired plants are sited at or relatively close to mines and utilize low-cost, fuel transportation technologies (pipeline slurries, unit trains, etc.). 4. Oil traps are confined porous and permeable zones, usually in sedimentary rocks, that trap and retain the constituents of crude oil in open pores, cracks, and cavities. All traps have porosity (open space) and impermeable cover rocks that prevent the petroleum from leaking upward. 5. The pore spaces in oil sands and sandstones are saturated with highly viscous crude oil (bitumen). Compared with high quality “light, sweet” crude, bitumen is more expensive to refine and produces lower percentages of high value products such as gasoline and heating oil. Surface mining and waste disposal present many serious environmental problems. At best, bitumen comprises only about 20 percent by volume of the in situ oil sands. The huge tonnages mined to feed a large refinery result in large volumes of processed sand and other wastes. Surface mining and waste disposal facilities disrupt the landscape and destroy habitat, and toxic substances may seriously threaten aquatic communities, birds, other organisms, and air quality. 6. Domestic oil shale reserves are mainly in northeastern Utah, southwestern Wyoming, and northwestern Colorado. The oil shale accumulated as fine-grained, mostly chemical sediments in ancient lakes that covered the area during Eocene time. Shale oil is very expensive to produce; presently it cannot compete cost wise with other fuels such as petroleum and coal, and large-scale mining and shale oil production would generate severe regional environmental impacts. For example, readily leached chemical constituents in the massive tonnages of processed waste would seriously threaten water quality in the Colorado River. 7. The main fuel for most nuclear power plants is uranium enriched in the fissionable isotope U-235; this isotope comprises only 0.7 percent of natural uranium. Fissionable, manmade plutonium can also be used as reactor fuel. Both materials are produced in government-owned facilities, many of which were formerly associated with production of weapons-grade, enriched uranium and plutonium. 8. In its early day, nuclear energy was greatly oversold to the public as the wave of the future. Virtually all costs associated with research, development, and U-235 enrichment were borne by the government and the U.S. taxpayer. Reactor manufacturers and utility companies widely touted the low cost of nuclear electricity and the unlimited supply of uranium for fission reactors and next generation of breeder reactors. Environmental problems and accident risk, so prominent today, were quietly overlooked. Incidents such as the Three Mile Island (Pennsylvania) accident and the Chernobyl (Ukraine) disaster heightened public fears and concerns over nuclear plant safety and ignited a spirited public debate over the future of nuclear electricity in the United States. Blanket assurances from government officials and company executives no longer soothed a worried, cynical public. Two major problems have effectively stopped growth of fission-generated electricity in the United States. Capital costs of new generating facilities have escalated rapidly and the major issue of radioactive waste disposal has yet to be satisfactorily addressed. Historically, capital costs for new, electric power-generating plants were recouped after the plant was operating. Utility rate payers are not happy with the prospect of bankrolling escalating construction costs of very expensive, new plants long before any electricity is produced. New plants sited in dangerous areas Energy and Mineral Resources 197 (earthquake prone, for example) faced huge cost overruns to comply with safety requirements; others built in heavily populated areas were completed but never operated because nearby areas could not be evacuated quickly enough should a serious accident ever threaten the plant. Massive public borrowing and overspending on new nuclear plants, based on overly optimistic projections of future electricity usage, led to the largest municipal bond default in history by the state of Washington. Safe storage and disposal of spent reactor fuel and other radioactive wastes is a very complex and difficult technological problem and has become a volatile, highly contentious, public policy issue as well. The waste remains dangerous for such long time spans that simple, out-of-sight, out-of-mind, disposal concepts are inappropriate and dangerous; long term, isolated storage and constant monitoring are better options. Nuclear energy does have an advantage over conventional fossil fuels in that it does not emit carbon dioxide – the greenhouse gas that contributes significantly to global warming. By contrast, the generation of electricity from fossil fuels produces large quantities of carbon dioxide. 9. Sunlight falling on photovoltaic cells generates electricity directly. Cell efficiencies have been slowly rising in recent years and costs have declined steadily. However, per kilowatt costs are still higher than for conventional power plants, thus photovoltaic cells are used mainly in small, low demand devices such as handheld calculators, or in remote locations where electricity from power grids is not readily available. At larger-scale, solar generating facilities, the Sun’s rays are collected and focused to heat and vaporize water or some low boiling point fluid. The heated vapor is then passed through turbines, generating electricity in the same manner as in a conventional power plant. 10. All reservoirs eventually fill with sediment. A small dam across a steep-walled mountain canyon may fill in a decade or two. Very large reservoirs such as Lake Powell (behind the Glen Canyon dam on the Colorado River) may last for 300 years or more. By the time that half the original reservoir volume is filled with sediment, much of the dam’s hydroelectric generation capacity has already been lost, and turbid, sediment-laden water is more likely to reach intake penstocks, resulting in excessive wear on turbines and increased maintenance costs. Thus a dam’s useful lifetime is over long before the pool completely fills with sediment. In addition, a dam may deteriorate badly or pose a serious safety hazard for other reasons long before its useful lifetime for power generation is over. 11. Generating electricity from tidal changes would be reliable, predictable, and relatively non-polluting. However, coastal areas with consistently large daily tidal variations are sparse; in areas with lower tidal ranges, the output of electricity per unit volume of flowing water would be very low because of the small elevation difference between the reservoir and exit pools. Even in favorable areas, large volume reservoir pools would be needed, raising construction costs and increasing adverse environmental effects. High upfront capital costs and adverse environmental impacts mean that electricity from tides will probably never contribute substantially to the world’s energy production. 12. Both terms refer to potential value that might be derived in the future from a nonrenewable resource such as a copper deposit or petroleum accumulation. Reserve refers to the volume or tonnage of material that can be extracted profitably in the near future (next few years or decades) based on the current value of the product (today’s price of copper or petroleum) and the current or projected costs of producing the product. 198 CHAPTER 23 Resource is a more general term that describes concentrations or accumulations of valuable materials, such as copper or petroleum, which for various reasons (economic, environmental, political, etc.) are not being exploited but which could be utilized at some time in the future. 13. This could readily happen if the price of the metal were to rise, production costs were to drop, or new tonnages of higher grade material were discovered in the deposit; thus the desired product could then be produced at a profit. Changes in environmental and political factors could also effect a change from mineral deposit to ore deposit. Ore deposit has the same meaning as reserve, and mineral deposit has the same meaning as resource (Review Question 14). 14. Hydrothermal solutions associated with igneous intrusions can deposit metals (copper, lead, zinc, silver, etc.) as sulfide minerals in veins (long, open fractures); as small, disseminated grains; and as clusters of grains in small cracks. Hydrothermal springs issuing from the ocean floor can produce mounds and pinnacles of metal-rich sulfides around the spring vent. When buried by lava flows or sedimentary layers, these deposits form part of a stratigraphic section that represents an ocean floor environment. Because metal sulfide minerals dominate these deposits, they are called massive sulfides. 15. Cooling igneous intrusions provide heat to drive extensive hydrothermal circulation through the intrusive rock and surrounding wall rocks. These hydrothermal solutions dissolve metals and transport them to depositional sites in fissures and open cracks, in other channels for fluid movement, and in fractured, or chemically reactive, wall rocks. Hydrothermally deposited, magnetite-rich, iron ores and veins containing copper, lead, zinc, and silver minerals can form in the contact metamorphic zone around a pluton. 16. The primary aluminum ore is bauxite, a complex mixture of various aluminum oxides and hydroxides. Bauxite is a lateritic soil formed by intense, chemical weathering under moist, tropical conditions. Bauxite accumulates where the parental bedrock material is rich in aluminum and low in iron; the intense, chemical leaching removes silica and leaves only the highly insoluble, aluminum and iron oxides behind in the surficial weathered zone. 17. Most copper deposits contain pyrite (FeS2) and copper sulfides or copper-iron sulfides as primary minerals. Exposed to weathering, sulfide minerals decompose quickly. Iron oxides are insoluble and remain behind in the outcrop; the copper dissolves in the strongly acidic water (a solution of sulfuric acid) generated by the decomposing pyrite and is carried downward to be precipitated as copper sulfides below the zone of oxidation. Thus strong limonitic or hematitic (iron oxide) staining at the surface may indicate secondary enrichment of an underlying, primary deposit at depth. 18. Relatively higher density, chemically resistant minerals such as native gold, diamonds, rutile, and cassiterite (tin oxide) are mined from placers. Placer deposits are mainly sand and gravel deposited in swiftly flowing streams or along beaches with strong wave action and current activity. The dense mineral grains are concentrated (left behind) as the smaller grains of the less dense minerals are carried elsewhere. 19. Nonmetallic resources, such as building materials and fertilizers, are consumed in all parts of the world at far higher rates than are metallic resources. Sand and gravel, including crushed stone, are utilized in much Energy and Mineral Resources 199 larger amounts on a per capita basis than is iron, the most widely used metal. Increased use of glasses, plastics, ceramics, and new, high-tech materials will undoubtedly limit future demand for most metals. 20. The two groups are industrial minerals (defined according to their major uses), and materials used in construction and building. The latter group is most widely distributed and includes sand and gravel, limestone (used to make Portland cement and agricultural lime), gypsum (used in plaster and wallboard), and building stone; industrial minerals include quartz (glass manufacture), sulfur (for making sulfuric acid), phosphate rock (fertilizer manufacture), rutile (used to manufacture white paint pigment), and hard minerals (diamond, corundum, garnet) used to manufacture abrasives. Resources such as petroleum and coal are considered as a separate fuels (energy) group. Lecture outline, art-only, and animation PowerPoint presentations for each chapter of Earth, 9e are available on the Instructor’s Resource Center CD (0131566911). 200 NOTES: CHAPTER 23