GA 3. Louisiana Tech University, Chemistry 100. POGIL(Process Oriented Guided Inquiry Learning) exercise on Chapter 2. Atoms and Elements Why? Why our planet is made up of some 92 stable elements? Why only 25 or so out of those 92 are found in living things? How the structure of atoms making up these elements does plays a major role in determining their chemistry? Why is it important to understand the structure of atoms to explain chemistry? How did the efforts of many scientists over a period of time have contributed to unraveling the structure of atoms. How does the atomic structure explain the concepts relating to nuclear atom, atomic number which defines each element, isotopes an element that have different atomic masses, and average atomic weight? How does the periodic table of elements summarize and provide comprehensive data on the chemical elements including structure, chemical and physical properties, element names and symbols? Why is it important to know how to extract the information from the periodic table in applying chemical knowledge and solving problems? Learning Objectives Atomic Structure and Subatomic Particles 1. Describe radioactivity, electrons, nuclear atom, nucleus, protons, neutrons and the general structure of the atom (Sections 2.1 - 2.2). 1. Describe how early experiments (Thomson's cathode ray tube experiments and Millikan's oil drop experiments) lead to the discovery of the electron, its mass, and its charge (Section 2.1, pages 43-44). The Nuclear Atom 1. Describe how Rutherford’s experiment leads to the concept of a nuclear atom and atomic number. (Section 2.2, pages 45-46). Atomic Numbers and Mass Numbers 1. Explain isotopes and isotopic symbols with atomic number and mass number for an element. (Section 2.5, page 54) 2. Define isotope and given the atomic number and number of neutrons for a specific isotope (Section 2.5, page 55). 3. Compare mass and charges of electron, proton and neutron (Section 2.5, page 57) 4. Count number of neutrons, protons given an isotopic name or symbol (Section 2.5, page 57). The periodic Table 1. Describe the use of periodic table: periods, groups, families, metals, non-metals, metalloids, main group elements, transition metals, actinides, lanthanides (section 2.9, pages 64-69) 2. Compare the relative abundances of elements in the periodic table that are found in biological systems. Success Criteria Understand how atomic structure was discovered, differences between subatomic particles (electron, proton and neutron), concept of nuclear atom, atomic number, mass number, and the importance of periodic classification elements. Resources Chemistry: The Molecular Science 3rd Edition, John W. Moore, Conrad L. Stanitski and Peter C. Jurs. Prerequisites High school chemistry: Definition of matter, Scientific method, Dalton’s Atomic theory, and atomic symbols. Components of atoms: nucleus (proton and neutrons) and electrons. Three states of matter, hierarchy of matter, and separation of mixtures. New Concepts Atomic Structure and Subatomic Particles Radioactivity: Henri Becquerel discovered the decay of unstable elements (E.g. uranium) to stable elements emitting , , and radiation. Radiation Mass radiation -particles: particles Electrons Charge High energy electro magnetic radiation (EMR) 1.674928716 x 10-24 g 9.10938188 x 10-28 g 4.0087 amu Positive (2 x 1.602176462 x 10-19 C) 0.000549 amu Negative (1.602176462 x 10-19 C) Half-life: Radioactive decay proceeds according to a principal called the half-life. The half-life (t½) is the amount of time necessary for ½ of the radioactive material to decay. This is useful in measuring the age of rocks and ancient artifacts. J.J.Thomson's cathode ray tube experiments led to the discovery of electron. Robert Millikan's oil drop experiments measured the charge of electrons. Earnest Rutherford’s experiment leads to the concept of a nuclear atom, atomic number, and how subatomic particles (nucleus, electrons, protons, neutrons) are arranged in the atom. Subatomic Particle Proton Neutron Electrons Mass 1.67262158 x 10-24 g Charge Positive (1.602176462 x 10-19 C) 1.0073 amu 1.674928716 x 10-24 g 1.0087 amu Neutral 9.10938188 x 10-28 g Negative (1.602176462 x 10-19 C) 0.000549 amu Atomic number (Z): Number of protons in a nucleus of an atom is called atomic number (Z), Z is characteristic to an element. Mass Numbers (A): Number of neutrons and protons together in a nucleus of an atom is called mass number (A). Isotopes: Atoms of the same element with different masses or different number of neutrons in the nucleus. E.g. 1H (hydrogen with one proton and one electron)and 2H (deuterium with one proton, one neutron and one electron). Isotopic Symbols A 12 X Z E.g carbon-12: C 6 The periodic Table Dmitrii Mendeleev summarized all comprehensive data on chemical elements including mass, structure, chemical and physical properties, element names and symbols in a table named periodic table baseh on increasing atomic mass. Modern periodic table is based on atomic number and consists of, groups, families, metals, non-metals, metalloids, main group elements, transition metals, actinides, and lanthanides. Key Questions (relatively simple to answer using the Focus Information) 1) What is radioactive decay? 2) What are following radiation? a) b) c) 3) Which of the following radiation, and is most harmful? 4) How did Thompson know that every element has electrons? 5) How did Thompson know that an electron has a negative charge? 6) In the Millikan’s oil drop experiment, how did he remove electrons from atoms? 7) In the Millikan’s oil drop experiment, where did some of the electrons removed from atoms ended up? 8) In the Millikan’s oil drop experiment, why was some oil drops had multiples (1,2,3 of −1.60 x 10-19 ) of charges? 9) In the Rutherford’s experiment, what caused a few α’s were deflected through large angles and some came almost straight back! 10) What subatomic particles take up the most space in the atom? 11) Which particle has lager mass? Proton or neutron. What maybe the reason? 12) How many times a proton weighs compared to an electron? 13) What are isotopes? 14) How many isotopes the elemental hydrogen, has? Give their symbols. Are they all these isotopes stable? 15) Naturally occurring carbon had two stable isotopes (carbon-12 and carbon 13) and an unstable isotope, carbon -14. Write isotopic symbols for a) carbon-12 b) carbon-13 c) carbon-14: b) How many protons, neutrons and electrons are in the carbon-12 isotope? 16) What group or family following elements belong to: a) Na b) Ca c) Cl d) He 17) List two elements in each of the following: a) Main group elements b) Transition elements c) Lanthanides d) Actinides 18) Identify following elements as either metals, non-metals, metalloids, noble gases, transition metals, actinides or, and lanthanides. a) Si b) Ca c) Cl d) Eu e) Pu f) Ni g) Ar 19) Which of the following are main group elements? a) Si b) Ca c) Cl d) Eu e) Pu f) Ni Exercises (Applying concepts) g) Ar 20) How long will take for carbon -14 to decay from 16 g to 2 g if the half life of carbon 14 is 5730 years. 21) Thomson calculated the mass/charge (m/e) ratio for an e- to be = −5.60 x 10-9 g/C. and then Millikan found the charge on an e- to be −1.60 x 10-19 C. What is the mass on an electron? 22) How many electrons, protons and neutrons a 24 Mg2+ isotope have? 23) Order of elements in the modern periodic table is arranged according to atomic number. In his periodic table, Mendeleev used atomic weights not atomic number. a) In the periodic table what elements should have been swapped if Mendeleev was to following order of increasing atomic masses strictly? b) In the periodic table, Why is atomic masses approximately correlated with atomic number? c) What is most directly involved in chemical reactivity: nucleus or the outermost electrons? d) Why do the elements in a group of the periodic table have similar chemical properties