Metamorphism & Metamorphic Petrology M etamorphism may be defined as the response in solid rocks to pronounced changes in temperature, pressure and chemical environment, which takes place in general below the shells of weathering and cementation. By metamorphism, the constituent minerals of a rock are changed over to others which are more stable under the new conditions and these may arrange themselves with the production of structures which are likewise better suited to the new environment. AGENTS OF METAMORPHISM: Metamorphism is due to the co-operation of the three forces of temperature, pressure and chemically active fluids. As metamorphism takes place in depth, it follows that it depends upon increasing temperatures and pressures and the increased activity of fluids. The heat may be supplied from the general increase of temperature downward, or from magma. The pressure is due ultimately to gravity and may be resolved at any point into two kinds; hydrostatic or uniform pressure, which leads to change of volume, and directive or non-uniform pressure, or stress, which leads to change of shape or distortion. The environment of chemically active fluids is the most important factor in metamorphism as the reactions involved can only take place through partial or complete solution of the minerals. Water is undoubtedly the chief substance present in this way; but it may be reinforced locally by CO2, and by substances such as boric and hydrofluoric acids which emanate from igneous magmas. TYPES OF METAMORPHISM: Thermal Metamorphism(Heat predominant): IT is a general term including a variety of metamorphic processes, in all of which the temperature of heat factor dominated, pressure and fluids playing only secondary roles. A few types of thermal metamorphism are: Contact Metamorphism: It prevails in the immediate vicinity of magmatic injections, intrusions or flows and involves changes like recrystallisation of original minerals & the formation of new ones. Pyrometamorphism: This term is used for intense but essentially localised metamorphic changes brought about by high temperatures to which a given rock is subjected. It is illustrated by changes in a block of sedimentary rock that has incidentally fallen down in a body of flowing lava; the block may be so heated up that its original minerals are forced to recrystallise and rearrange themselves. Dynamic/Clastic Metamorphism(Directive pressure predominant): In this kind, the shearing stress is the dominant factor to bring about changes, which are mostly of mechanical nature. It http://continue.to/geonotes is also called kinetic metamorphism and is restricted to folded regions. When the pressure is due to the depth factor (i.e. hydrostatic type) the process of metamorphism is defined as load metamorphism. Dynamothermal Metamorphism(Directive pressure & heat predominant): It is the most important kind of metamorphism and includes the changes brought about in rocks under the combined effects of pressure, temperature and fluids. It is characteristic of intense folding and may include hundreds of kilometres of tectonic belts under its influence. Plutonic Metamorphism(Uniform pressure & heat predominant): Where the pressure of uniform nature (i.e. hydrostatic pressure at depths) and the very high temperatures are responsible for the bulk of the changes in a rock, the process is known as plutonic metamorphism. These conditions are available only at the lower levels in the earth’s crust and hence the process is characteristic of greater depths only. Metasomatism: It can be broadly defined as a type of thermal metamorphism in which fluids, liquids and gases, which are invariably at very high temperatures, attack the surrounding rocks and induce certain changes in them. Metasomatism is further distinguished into the following two types: Hydrothermal Metamorphism: When the rocks are attacked by chemically active solutions(aqueous or otherwise) Pneumatolytic Metamorphism: When the medium of attack is in the gaseous state or in vapours. The most important facts regarding metamorphic changes are: They take place essentially in the solid state The bulk composition of the rock undergoing metamorphism generally remains unaffected, except in some types, like metasomatism. If the temperature and pressure conditions change to such an extent that rocks become actually “molten” during the process, then it no longer remains a metamorphic change. The melt thus produced or “reborn” will crystallise under favourable conditions in a way similar to a magmatic melt, and hence will give rise to igneous rocks. This process of regeneration of a melt is termed anatexis or ultrametamorphism. METAMORPHIC ZONES & FACIES: ZONES: The degree or grade of metamorphism generally increases with depth for the simple reason that temperature and pressure factors become more powerful at deeper levels. This fact has given birth to the concept of metamorphic zones which signify the range of metamorphic effect at different depths below the surface. The three metamorphic zones are: Epizone: It is the near-surface zone and is characterised by a low temperature, generally less than 300°C, and strong shear stress. Rocks are therefore deformed chiefly under the http://continue.to/geonotes influence of dynamic metamorphism. The common rocks resulting in this zone are slates and mica schists. Mesozone: It is the middle zone in which temperature becomes rather moderate (300°C-500°C) and the pressure factor is of shear as well as hydrostatic character. Dynamothermal metamorphism is typical of this zone and schists(like the biotite-garnet schist) are the chief rocks developed. Ketazone: It is a zone of high temperature (500°C-800°C) and hydrostatic stress. Plutonic metamorphism dominates this zone with the formation of a variety of gneisses. FACIES: It has been found possible to classify metamorphic rocks on the basis of the metamorphic environment through which these rocks have passed. The concept of metamorphic facies simplifies the classification of these rocks in that it eliminates the necessity of knowing the nature of the parent rock and original characters. Eskola has recognised eight different metamorphic facies: Sanidine facies Green-schist facies Epidote-Amphibolite facies Amphibolite facies Pyroxene-hornfels facies Granulite facies Glaucophane schist facies Eclogite facies Metamorphic rocks exhibit mineralogical composition The composition of the The type and degree of a great variation in their which is defined in most cases by: parent rock metamorphism undergone by the rock. Many rocks consist of reconstituted minerals of the parent rock; for example, marbles are made up from reconstituted calcite of limestone, quartzites of reconstituted quartz of sandstones and so on. It must be made clear here that metamorphic minerals are produced primarily under the influence of metamorphic agents, namely temperature and pressure, and hence they must be stable under new conditions imposed on these rocks. Those minerals which are produced in metamorphic rocks chiefly under the influence of the stress factor are known as stress minerals. They are characterised by flaky, platy or lamellar structures. Dynamothermal metamorphism chiefly results in stress minerals which include kyanite, staurolite, amphiboles, muscovite, chlorite etc. Such minerals are characteristically stable under conditions of high stress. The other group of minerals include those that are primarily formed under the influence of the temperature factor. These anti-stress minerals are generally equidimensional in character and are the product of plutonic metamorphism. Examples are sillimanite, olivine, cordierite, pyroxenes etc. Anti-stress minerals are unstable under high stress conditions. http://continue.to/geonotes TEXTURES OF METAMORPHIC ROCKS: The textures of metamorphic rocks can be broadly classified as: Crystalloblastic Palimpsest or Relict Crystalloblastic Textures: These include all those types that have been newly imposed upon the rock during the process of metamorphism and are, therefore, essentially a product of metamorphism. Among the crystalloblastic textures, the porphyroblastic and granoblastic types are the most common. In the first case, the fine-grained ground mass of the rock shows, embedded in it, idioblastic crystals (crystals with perfect outlines) of stronger minerals. In the granoblastic texture, the rock is composed of equidimensional grains of hard minerals. Palimpsest/Relict Textures: These comprise the textures which were present in the original rock and which have resisted the effects of metamorphism and thus are retained by the rock. Palimpsest textures are generally described by using the word “blasto” as prefix to the original texture that has been retained by the rock. Thus, if an igneous rock with porphyritic texture undergoes metamorphism whereby its mineral composition is changed but the same texture is retained in the new rock, the texture of the rock will now be described as blastoporphyritic. CARBONATE ROCKS: Metamorphism of limestone and other carbonate rocks is of considerable interest and importance. When pure limestone recrystallises without any mineral formation but with definite change in grain size, the resulting rock is crystalline and is commonly known as marble. When the limestone is impure, simple recrystallisation is substituted by the formation of new minerals. New minerals that are formed depend upon the nature of the impurities as well as on the temperature and pressure conditions. When silica is the sole impurity a mineral wollastonite results, whereas the presence of alumina and magnesia leads to the formation of anorthite and amphiboles respectively. When the limestone is dolomitic in composition, metamorphic changes show great variation and many new minerals like periclase, forsterite, spinel, diopside etc. may be formed, depending on whether the dolomite is pure of whether impurities like silica and alumina are also present in it. IMPORTANT METAMORPHIC ROCKS SLATE: Slate is a fine-grained metamorphic rock characterised by a perfect cleavage. The slaty cleavage is due to parallel arrangement of platy or flaky minerals, under the influence of metamorphism. http://continue.to/geonotes ORIGIN: Slate is a product of low-grade regional metamorphism on argillaceous rocks like shale. When slate is subjected to further action of dynamothermal metamorphism, recrystallisation may lead to the development, in number and size, of the micas. Such metamorphic rocks with conspicuous mica layers and slaty appearance are termed phyllites, which on further metamorphism change to crystalline schists. SCHIST: Schists are microscopically crystalline, metamorphic rocks characterised by a schistose structure. The constituent flaky and platy minerals are mostly arranged in irregularly parallel layers of bands. ORIGIN: Schists are generally the products of dynamothermal metamorphism of argillaceous rocks like shales. GNEISS: Gneiss is a megascopically crystalline metamorphic rock, characterised by segregation of constituent minerals into layers or bands of contrasting colour, texture and composition. ORIGIN: Gneisses are generally the produce of advanced stages of regional metamorphism of a variety of parent rocks, chief among them which are sandstone, conglomerates and granitic rocks. QUARTZITE: Quartzite is a fine-grained metamorphic rock composed of intersutured grains of quartz. The name orthoquartzite is used for a sedimentary rock of similar composition with siliceous cement. Metamorphic quartzite is a granular rock characterised by a tendency of fracturing through the grains under heavy loads. ORIGIN: Quartzite results from the recrystallisation of sandstone under the influence of contact and dynamic metamorphism. PHYLLITE: It is mostly a fine0grained metamorphic rock and represents an intermediate stage in the metamorphism from slate to schist. The individual minerals are not recognised by the unaided eye, bu8t the presence of muscovite is easily indicated by the shining cleavage surface. The rock shows a foliated structure. ORIGIN: Phyllites are formed as a result of dynamothermal metamorphism of argillaceous rocks like shales. HORNFELS: It is a term applied to a group of metamorphic roc developed commonly in contact zones of igneous intrusions characterised by fine to medium grained textures and a maculose structure. ORIGIN: They are formed from fine-grained argillaceous rocks like shales. MARBLE: It is essentially a metamorphic rock, composed chiefly of recrystallised calcite. It is characterised by a granulose structure, but the grain size shows extreme variations, from finely saccharoidal to highly coarse. They may often show banded structure. http://continue.to/geonotes ORIGIN: They result from the recrystallisation of limestones or dolomites under the influence of contact and regional metamorphism. Slate Texture Very finegrained, individual minerals are not recognised by the unaided eye. Structure Foliated structure; shows perfect slaty cleavage. Composition Minerals recognised only under microscope and include chiefly species of clay groups. Phyllite Fine-grained, individual minerals are not recognised by the unaided eye, but mica flaked are definitely better developed in number and size. Foliated structure, better than slates; cleavage may be poor. Mostly the same as for slate, but mica increased in number and size, and give a shiny appearance to cleavage surface. Schist Megascopically crystalline, components are well arranged and easily recognisable. Highly foliated; rock shows schistose structure, in which platy/flaky minerals show irregularly parallel arrangement. Micaceous minerals dominate; porphyroblasts of some hard minerals present; chiefly muscovite, chlorite, sericite, garnet and tourmaline. The following rocks are generally classed as of doubtful origin: Migmatites: There are essentially mixed roc that consist of intimately associated members of igneous(granitic) rocks, and metamorphic(gneisses, schists, etc.) divisions. A streaky or banded appearance is typical of all, and the bands may be of alternating igneous and metamorphic minerals. Eclogites: These are rocks of uncertain origin containing garnets, grass-green pyroxene, omphacite and plagioclase feldspar. Charnockites: These are hypersthene-bearing granitic rocks that are generally garnetiferous. http://continue.to/geonotes TYPE OF METAMORPHISM METAMORPHIC FACIES Regional (includes dynamothermal & plutonic) Green schistose Epidoteamphibolitic Amphibolitic Granulitic Contact metamorphic proper Contact metasomatism Dynamic/ Cataclastic Eclogite Hornfelses METAMORPHIC ROCKS FORMED ACCOERDING TO PARENT ROCKS Clay and Carbonate Basic and Feldspar magmatic greywackes and marls Clay, Calcareous Chlorite schist, schist and talc phyllite schist, hornblende, serpentine Crystalline Marble Amphibolite schist, quartz Gneiss Marble Amphibolite Granulite and migmatite Hornfels, quartzite Marble Skarn Granulite Eclogite Amphibolitic and pyroxene hornfels Serpentine - Gneisses - Tectonic breccia, cataclast, mylonite http://continue.to/geonotes