Historical Geology GEOL 1304 Exam I I. Introductory/Foundational Material “Geology” – from Greek “Geos” or “Gaia” = “mother earth”, & “Logos” = “the study of” A. Define GEOLOGY…the study of the planet Earth including: The materials of which it is made The processes that act on these materials The products formed The history of internal & surface features The history of the planet and how it formed The origin of life forms & how they change as the environment changes Geology is considered an “Eclectic” science, drawing upon information from: Chemistry Physics Astronomy Biology Mathematics Ecology Etc. B. Major Branches of Geology: Physical & Historical 1. Physical Geology – study of the physical and chemical aspects of the earth: Magma & lava chemistry & make-up Mineralogy - How minerals form Petrology - How rocks form Geomorphology - Formation of surface features: mountains, valleys, etc. Weathering and erosion of exposed rocks Vulcanology - Volcanoes Seismology- Earthquakes Glaciers Sedimentology - Deposition of sediments Oceanography- the chemical, physical, & biotic factors of the seas Etc. 2. Historical Geology – the study of the historical development of the earth and the evolution of life forms: Stratigraphy – science of rock strata (layers) aspects, interpretation, and mode of origin Paleontology – “Palaios” means “ancient”: the study of ancient life through the interpretation of fossils Paleoecology/Paleoclimatology – the study of how environments and climates have changed over time Geochronology – the science of dating rocks and events in the earth’s past Tectonics & Mountain Building Processes – the study of the movements of the earth’s crustal plates, and how these changes affect surface processes and Life. C. The Role of the Geologist: To understand and define: The structure and composition of the earth All facets of magma, lava, and volcanic activity Minerals and rock types Surface processes: rivers, streams, glaciers, etc. The earth’s past: both structure origin and life’s evolution with Paleontological investigations (studying fossil remains) Geologic features of other planets Also: To use information learned to find fossil fuels and ores To learn how to preserve the environment: erosion control, pollution control Geologic information ties in greatly with advances in technology D. The Development of “Scientific Thought”: Approximately 10,000 years ago, the development of agricultural practices and beginnings of the domestication of livestock set the stage for humans to become more “GREGARIOUS” (= living together in one or two semipermanent area) This gave rise to the development of villages-towns-cities in which people would share the workload, which increased the amount of personal “LEISURE TIME”. With this extra time came the development of aspects of what we refer to as “CIVILIZATION”. As increased technology developed in certain areas in the world, populations grew, increasing the sharing of the workload, increasing the leisure time, increasing the development of new ideas and technologies, etc. Ancient Grecian, Roman, and Egyptian cultures began to develop rudimentary sciences/technologies, but advances especially in mathematics sped up these changes. Contributions of Ancient Greeks such as Socrates (470 BC – 399 BC), Plato (427 BC – 347 BC), & Aristotle (384 BC – 322 BC) laid down the foundations of Philosophy, Mathematics, and Metaphysics. “Aristotelian Thought” centers on the metaphysical concept that reality (the earth) is surrounded by “spheres of the heavenly bodies” called “Celestial Spheres”. [This idea is thought to have arisen from the impression that the night sky gives an observer even today. It is the feeling of being inside an upside down bowl, or “half of a sphere” that makes up the night sky.] Since heavenly bodies were thought to be the only “true” reality, and the earth’s reality experienced by Aristotle was only a shadow of the “true Celestial Sphere Reality”, Aristotle proposed that there was no need to investigate the earth per se as to its make-up since it was only an illusion of sorts. Circular motion was considered to be restricted to the Celestial Spheres (due to the apparent “circular” motion of the night stars), and therefore impossible to exist on the surface of the earth. Any appearance of circular motion in everyday life was only an illusion according to Aristotle. The Celestial Spheres model of reality is one of the reasons that the “Ancients” (Greeks, Romans, & Egyptians) never formulated advanced studies of chemistry or earth sciences. Since the “lay persons” considered Aristotle somewhat infallible, this concept of Celestial Spheres was not challenged for almost 1200 years. As people ventured out to various parts of the world seeking trade, gold etc., certain new ideas arose to challenge Aristotelian thought. During the so-called “Dark Ages”, Marco Polo (1254 AD – 1324 AD) in his journeys brought back gunpowder from the east, and artillery (cannons and guns) soon developed in the west. As trajectory studies of cannon balls and other projectiles advanced, it was proven that circular motion does indeed exist on the earth. This was the first of many proofs that Aristotle’s Celestial Sphere concept was flawed. As Aristotelian thought gave way to a sophisticated “trial and error” learning process, modern scientific thought had its beginnings. With the rise of great scientific visionaries such as Nicolaus Copernicus (1473 – 1543), Johannes Kepler (1571 – 1630), and Galileo Galilei (1564 – 1642), the basics of planetary motion were developed that began to infringe on some of the statements made in the Bible. This caused the Catholic Church at the time to try to sequester scientific investigation. The “Age of Enlightenment” or “Aufklarung” around the beginning of the 17th century ushered in a rapid growth in the arts, sciences, and mathematics. Sir Isaac Newton (1642 – 1726) developed the Calculus that allowed a greater investigative power in mathematics. There are countless others, but by the mid 18th century scientists and researchers such as James Hutton, Charles Lyell, William Smith, Gottlob Werner, Cuvier, Alfred Wallace, Gregor Mendel, and Charles Darwin laid the foundations of modern geology. The development of the modern “Scientific Method” arose from the trials of these founding fathers of science. D. The Scientific Method: “A way of looking at and describing reality” 1. State the Problem - To solve any problem it must be clear as to what actually needs to be solved. 2. Construction of a Hypothesis - By studying the problem, an educated guess may be formed as to creating a model of investigation. 3. Experimentation, Testing, and Data Gathering – the experimental model is tested and records of the results are kept and compared. The results then may be published and sent worldwide for scrutiny by others. 4. Development of a Theory (Factual Level of Science) If an experimental model tends to be correct after extensive testing and review time and again; it may then be considered a Theory. The Theory of Gravity, the Theory of Light Refraction, Atomic Structure Theory, etc. are all considered to be scientific facts. A fact in science is only considered to be true until it is disproved sometimes in the future. It makes no sense to say that Evolution if not to be believed because that it is “only a theory”. It is “only a theory” that gravity or light behave the way they do. To the Lay Person, theory means a lack of knowledge. This is not the case in science. Theory in science is considered “FACT”. Most religious dogmas, whether they are Judeo-Christian, Buddhist, Hindu, etc., are based upon some form of religious writings: the Bible, Torah, Koran, etc. Religious writings provide a “Fact Level” for describing reality and it is accepted as true because of its Divine nature. Creationist scientists then try to find data to support “religious facts” in the writings. This is tantamount to working the scientific method backwards. Founders of Historical Geology Leonardo Da Vinci – (1452 – 1519) - He is attributed with: the first recorded reference to “fossils” actually being the remains of once living organisms. He also claimed that when the remains of sea creatures are found on mountain tops that it shows the impermanence of oceans as well as mountains. Prior to and during his claims, there were wide ranging explanations for seashells on mountains; from being left by the Deluge, to fossils having placed on mountains to by Satan to sway the non-faithful into believing heresy. Nicolaus Steno – (1638 – 1687) – Niels Stensen was a Danish physician to the Grand Duke of Tuscany who after settling down in Tuscany, Italy, “latinized” his name to Nicolaus Steno. He did not have much work to do, as attending the medical needs of the Duke took very little time. During his frequent walks and hiking excursions, he began to notice certain patterns and repetitions in some of the rock outcrops he passed. After considerable pondering, he developed what have come to be known as “Steno’s Three Principles of Geology”: i. ii. iii. Principle of Superposition – In any sequence of undisturbed strata, the oldest layer is at the bottom and the successively higher layers are successfully younger. (“Undisturbed” refers to them not having been compressed to the point that older material is folded on top of the younger material. Principle of Original Horizontality – Steno claimed that “Most sediment must have been deposited in layers that were nearly horizontal and parallel to the earth’ surface on which they were accumulating. (Exceptions Steno did not know about: 1. The terminal ends of river deltas show a near vertical deposition as deposits are dropped into deeper water. 2. “Crossbedding” of strata in riverbeds (“Fluvial”=”water carried” cross-bedding showing embrication of grains due to the more consistent flow of water) and sand dunes (“Aeolian” = “wind carried” cross-bedding showing non-embricated, scattering of the grains). Principle of Lateral Continuity – As originally deposited, strata either extend in all directions until they: 1. “thin” to a feather edge at the margin of a depositional basin; 2. end abruptly against some barrier to deposition (i.e. mountain range); 3. or grade laterally into a different kind of sediment (i.e. the marine lithofacies) Steno’s Principles form the foundational principles of the branch of geology called Stratigraphy – the study of layered sedimentary rocks, including texture, composition, arrangement, and correlation from place to place. Steno’s Principles were lost for a while after his death, but were “rediscovered” and put to use by late 17th and early 18th century European scientists. These contributors to geology are referred to as the “Interpreters of Geologic Successions”. Interpreters of Geologic Successions John Strachey – (1671 – 1743) First recorded use of Steno’s Principles to successfully and repeatedly find coal bearing strata in England. Giovanni Arduino – (1714 – 1795) [and others] First to classify mountains as to rock type found there. He defined “Primary” mountains as those of a crystalline nature (later known as Igneous & Metamorphic) and “Secondary” Mountains as those of layered, wellconsolidated, fossiliferous rocks (later known as Sedimentary). Abraham Gottlob Werner – (1750 – 1817) A keen mineralogist, but better remembered for his views on geology: He insisted that all rocks of the earth were deposited or precipitated from a great ocean that once enveloped the entire planet in a concept known as “Neptunism” after the Roman god of the Sea. The major criticism is where did this large body of water go? When it was proven by the French geologist, J. F. D’Aubisson de Voisins (1769 – 1832) that basaltic layers in Werner’s sequences were created by volcanic activity, this formed an opposing view of “Neptunism” (“rocks formed in water”) called “Plutonism” (rocks formed in fire” after the Roman god of the Underworld – Pluto) James Hutton – (1726 – 1797) One of the earliest “Plutonist” whose staunch opposition of Neptunism, and astute observations of the earth led to the concept of “Uniformitarianism”. This concept states that: the earth is an ever-changing, dynamic system, whereby mountains rise up and are eroded down volcanoes erupt and the igneous rocks formed weather to other sedimentary rocks rivers change their courses depending upon the ever-changing terrain seas inundate the lowlands, only to recede or to evaporate, leaving behind series of sediments rivers can eventually cut through mountains and erode them into particles carried off to the sea etc. “These physical and chemical processes that alter and change the earth’s surface today also went on in the geologic past” Hutton published his concepts and findings in a famous 1875 book entitled Theory of the Earth. This book became the standard for geologic study even into the early 20th century. James Hutton is considered to be the “Father of Modern Geology” …“The past history of our globe must be explained by what can be seen to be happening now.” Charles Lyell – (1797 – 1875) – As a student and proponent of Hutton, he was an early advocate of Uniformitarianism, and was against Neptunism. In the early 1800’s, he published a book entitled Principles of Geology in which he added his observations to those of Hutton. His additions were: The Principle of Cross-cutting Relationships – “An igneous intrusion, a break, or a fault cutting across preexisting strata, must be younger than the strata it cuts across”. In other words, something must first be in existence prior to anything happening to it, making the “something” necessarily older than the “happening”. The Principle of Inclusions – “Fragments of rocks within larger rock masses are older than the rocks they are contained within”. For example, an arkose sandstone (chiefly composed of quartz particles) layer may be 200 million years old. Since the quartz grains were originally formed in igneous rocks that were eventually eroded into sediments, which were carried off by the elements, to eventually settle in a basin of deposition (such as a seafloor), the age of the individual grains that comprise the arkose sandstone must necessarily be older than the sandstone in its entirety. From the Uniformitarianism views of both Hutton and Lyell, very thick strata of sediments would take a very long time to accumulate. …Therefore, the age of the earth is many times greater than the few thousands (10,000 years or so) of years as proposed by the major religious writings: namely the Bible. Uniformitarianism was considered to be an assault upon religious doctrine and was thought of as heresy by many at that time. William “Strata” Smith – (1769 – 1839) He was an English land surveyor whose contributions include: Making the first known Geologic Map of England and Wales in 1815, showing outcrops of various strata (most of which is correct even today). Being able to use geologic principles to predict subsurface strata, especially coal. Made extensive studies of fossil assemblages and used geologic principles to formulate Correlation Techniques to find continuances of eroded layers. Using his findings, he developed the “Principle of Biologic Succession”. The Principle of Biologic Succession states: “…Life of each age in the earth’s history is unique for that particular period.” This can be understood if you think of all of the 40 million or so life forms alive today: elephants, red fish, banana trees, humans, mushrooms, amoebas, etc. If you go back in geologic time, say, 2 million years ago, most of these life forms were probably in existence, along with a few that have since become extinct. So, if you examine strata of that time, it would probably have an assortment of fossils that reflect the life forms of that time. If you go back 400 million years, probably very few of the life forms in existence today would have been in existence, but a great many organisms [that have subsequently become extinct] would be represented in the strata of that time preserved in the Fossil Record. Therefore, Smith is saying that each time frame has its own array of life forms that “represent” that time frame in the geologic record. Baron Georges Leopold Cuvier – (1769 – 1832) AND Alexander Brongniart – (1770 – 1847) – Both Cuvier and Brongniart were French scientists: Cuvier, an anatomist, and Brongniart, a naturalist and mineralogist. They were close associates that also worked with and contributed to aspects of “Biologic Succession”, and studied fossil sequences in various strata. They are best known for the formulation of the “anti-uniforminitarianism” view called “Catastrophism”. Their explanation of why there were fossil seashells on mountain tops, or why there would an abrupt end to a certain fossil life forms existence is because of a religious concept called “Deus Irae”, which is Latin for the “Wrath of God”. Cuvier and Brongniart felt that the [sometimes “violent”] upheavals of mountain ranges, or the twisting of solid rock layers, or thick layers of salt deposits within rock sequences were evidence of God’s Wrath unleashed upon the earth as punishment of sinners or the cleansing of evil by such acts as the Noachian Deluge. At this time of the mid to late 1800’s, geologists could subscribe to one of two main camps of thought: 1. Hutton’s Uniformitarianism, or, 2. Cuvier’s Catastrophism During meetings of the Royal Academy of Science in London, it is written that many violent fistfights erupted during the debates between these two concepts by the proponents of each side. As geologic techniques developed further toward the end of the 19 th century that showed the the earth was indeed millions of years older that the Biblical account, Catastrophism faded out of popularity, being replaced by Uniformitarianism based geology. “Creationist Science” of today can be said to be an offshoot of Catastrophism in many ways. Gregor Mendel – (1822 – 1884) – He was an Austrian Monk schooled as a mathematician, particularly in the field of statistics. When he had the time, he enjoyed gardening, especially the raising of sweet pea plants. Over time, he began to notice and record differences that arose within the population of plants, especially from certain crosses he would make. He realized that if Tall Plants were crossed with Dwarf Plants that the offspring generation would all be Tall. If he crossed Dwarf plants with Dwarf plants they would all be Dwarf. When he crossed Tall Hybrid plants, the results showed that both Tall and Dwarf plants would be present in the next generation. Mendel discovered means by which he could statistically predict the next generation. Because of his findings, Mendel is considered the “Father of Genetics”. Alfred Russel Wallace – (1823 – 1913) He worked in the Philippines and parts of Indonesia describing the inter-relationships of organisms and their environments. He noted that physical characteristics of organisms changed in response to environmental changes. His work is very similar to Darwin’s concept of Natural Selection. Charles Darwin – (1809 – 1882) He began his education in the field of religion, and later in medicine, never completing either. With his strong interest in all life forms, his father procured a position on the H.M.S. Beagle that was a research vessel. The 5-year journey was primarily a mapping mission, but sample collections of life forms were also taken at all ports. Darwin signed on really as the unpaid assistant to the Captain and 1st Mate. Darwin kept journals of all things encountered, as well as the environmental conditions in which they were found.. Whenever they would go into port, Darwin would start collecting specimens of insects, plants birds, etc. Upon analyzing his journals, he concluded it was the environment that determined which characteristic trait of an organism’s population would be expressed: hence, he developed the Concept of Natural Selection and Survival of the Fittest. Thomas Morgan Hunt – Around 1910, he was first to describe the “chromosome” as the means in which genetic information is passed from one generation to the next. He also coined the term “gene” being the discrete unit of a chromosome that controls traits. He is considered the person that discovered the mechanical transfer of genetic inheritance in dividing cells. James Watson and Francis Crick – They discovered the complex shape and function of deoxyribonucleic acid (DNA) and their research provided the basis of genetics on the molecular level. ++++++++++++++++++++++++++++++++++++++++++++++++++++ Planetary Beginnings – Big Bang, etc…. The History of the Universe, Solar System, & Planets Be familiar with the Big Bang and the development/formation of the earth Universe beginnings – the “Big Bang”. Description of the Big Bang: Metaphysical event creating “reality” occurring around 10-15 Billion Years Ago. In a space smaller than an atom, both space and time were set at zero…There is NO BEFORE BIG BANG! This is because that both space and time are unalterably linked to form a space-time continuum as per Einstein’s Theory of Relativity…Without 3diminsional space there can be no time Evidences of the “BIG BANG” – First – The “Doppler Shift” indicates that the universe is expanding… Galaxies are moving away from each other Secondly – the universe is permeated by a “background radiation” of 2.7 degrees above absolute zero (00 Kelvin)…almost no molecular movement at all! Subatomic particles collide, increasing their mass, that increases their gravitational attraction , that causes larger particles to form from the fusion of smaller ones. The first element, hydrogen, formed. As more hydrogen formed, it began to coalesce forming the first stars. As these stars “ran out” of hydrogen, other elements formed. These early stars eventually exploded (supernova) spreading the 92 naturally occurring elements in nebulae (clouds of stardust). These clouds coalesced into other stars (i.e. the sun) with the outer clumps of matter forming the planetesimals that would eventually form the planets. Age of the universe = 8 – 10 BYA Age of the Sun = 5BYA Age of the Earth = 4.6 BYA Structure of the Modern Earth and Tectonics I. The Earth consists of three concentric layers: 1. the core 2. the mantle 3. the crust They are formed as a result of: density differences between the layers variations in composition differences in temperature and pressure II. The Characteristics of the Core: The Core is thought to be composed of iron with some nickel. It is spherical in shape with its outer surface lying 2900 km below the outer surface of the earth. The total diameter of the core is 3470 km. It has an average density of about 10 to 13 grams/cm3 and comprises 16% of the earth’s volume. Seismic Tomography data (studying the earth’s interior indirectly by studying the behavior of earthquake waves) indicate that the core has a small Solid Inner Region (1220 km in diameter) surrounded by an apparently Liquid Outer Region (2250 km thick). III. The Characteristics of the Mantle: The Mantle surrounds the core and comprises about 83%of the earth’s volume. It is less dense than the core with an average density of approximately 3.3 – 5.7 grams/cm3. It is composed largely of Peridotite, a dark, dense, igneous rock containing high amounts of iron and magnesium. The Mantle can be divided into three regions: 1. The Lower Mantle – This is solid and comprises most of the volume of the earth’s interior. 2. The Upper Mantle – This consists of the Asthenosphere and the overlying solid mantle rocks up to the base of the crust. The asthenosphere surrounds the lower mantle and has the same peridotite composition. It behaves plastically and slowly flows. Partial melting within the asthenosphere generates Magma, molten rock material, some of which rises to the surface because it is less dense than the material from which it was derived. 3. The Lithosphere – This is the solid portion of the upper mantle and the overlying crust. The lithosphere is broken into numerous pieces called Plates that move over the asthenosphere as the result of underlying Convection Cells (or Mantle Plumes generated from heat). IV. The Characteristics of the Crust: The Crust is the outermost layer of the earth. It consists of two types of rock materials: 1. Continental Crust – (20 – 90 km thick) this material comprises most of the continental plates. It has a density of 2.7 grams/cm3 and is rich in silica and aluminum. This type of rock material is referred to as being “Sialic” or “Felsic”. 2. Oceanic Crust – (5 – 10 km thick) has a density of 3.0 grams/cm3 and is largely comprised of the igneous rock Basalt, which is rich in iron and magnesium. This type of rock material as referred to as being “Mafic” or “Basaltic”. V. The Refinement of the Earth’s Crust The early outer crust of the earth was a mixture of sialic and mafic material. The following processes occurred to separate the sialic materials from the mafic. This allowed for the formation of the continents that are mostly sialic (less dense granitic materials) in composition, from the denser, more mafic materials that today compose the oceanic crust. A. Separation of Mafic Materials from Sialic 1. Partial Melting – This is the process whereby hot mantle plumes rising up from the upper mantle heats (“partially melts”) the overlying mixture of mafics and sialics. This causes the denser mafic materials to separate downward, leaving the less dense sialic materials above…. Think of the early crust as being a block of wax (representing the less dense sialic material) with marbles (representing the denser mafic material) suspended in it. If this mixture of wax and marble is placed into a pan and heated up, the marbles (mafics) will sink to the bottom, leaving the wax (sialics) on top. 2. Fractional Crystallization – Mafic materials, being high in iron and magnesium, will crystallize at a higher temperature than sialic material, that is high in silica and aluminum. If the entire mixture of mafic and sialic material is heated to the point of melting and then allowed to cool, the mafic minerals will crystallize first, and being denser than the sialic material, will separate downwards in the melt from the still molten sialic materials on top…. Think of this as being similar to placing a cup of lead B-B’s (representing the mafic materials) and a cup of plastic B-B’s (representing the sialic materials) randomly in a vessel. Lead has a melting temperature of around 8000 F and plastic’s melting temperature, let’s say, is about 2000 – 3000F dependant upon the type of plastic. If the vessel is heated, as the temperature reaches the 3000F mark, the plastic B-B’s would become liquid, but the lead B-B’s would remain solid. As the temperature surpasses 8000F, all of the B-B’s would be molten. Now allow the vessel to cool. As the temperature drops below 8000F, the lead will begin to solidify (or crystallize first) but the plastic would remain molten. Since lead has a greater density, it would move downward in the vessel. As the temperature drops below 2000F, the plastic would begin to solidify on top of the lead, completing the separation. B. Formation of Continental (Sialic) Plates: Continental Accretion As more crustal movement occurred, as the less dense sialic material was pushed against the denser mafic materials, the denser mafic material would become subducted or pushed downwards, underneath the sialic materials, thereby melting as it was subducted, the hot magma rising upwards through the sialic materials forming island arcs (“clumps” of sialic material). The formation of the island arcs perpetuated the refining processes of partial melting and fractional crystallization. As the less dense sialic “clumps” formed on the earth’s surface, spreading centers (divergent “cracks” in the earth’s surface) pushed the sialic materials together forming larger masses of sialic “chunks” in a process known as Continental Accretion. This caused a fusion of the early sialic materials into Sialic or Granitic Continental Plates. This also accounts for the composition of the continental plates as being High Grade Metamorphic Terranes (metamorphic rocks are formed under intense heat and pressure, the conditions during continental accretion). Tectonic Plate boundaries: I. Constructive – “Divergent” creating new earth surface a. M.O.R – “mid-oceanic ridge”, the spreading centers on the ocean floors especially the “mid – Atlantic ridge” b. Continental Rifts – i.e. the Great Rift Valley of eastern Africa II. Destructive – “Convergent” – destroying earth’s surface a. Continental/Continental – two or more continental plates converging as in India – Asia forming the Himalayan Mountains b. Continental/Oceanic – oceanic mafic plate is thrust under the sialic continental plate in a process of “subduction” as in the Pacific Rim or “ring of fire” c. Oceanic/Oceanic – two mafic oceanic plates thrust together whereby one dives deeply below and melts. The rising magma can form volcanic islands. III. Shear or Transform – Two plates “slide” past one another as in the San Andreas Fault. There is no up or down movement, only lateral movement. ++++++++++++++++++++++++++++++++++++++++++++++++++++ Geochronology – Dating the Earth There are two main methods used in dating rocks: I. Absolute Dating - Utilizing the rate of decay of radioactive isotopes to determine exact age of when the rock formed. II. Relative Dating - Rock layers are placed in their proper order or sequence of events. The ages of the layers are found ONLY relative to each other. In order to become proficient in relative dating techniques, you must be familiar with the following principles and terms. Relative Dating Terminology Law of Superposition - Geologic Principle stating that in an undisturbed sequence of strata, the youngest is on top and the oldest is on the bottom. Principle of Original Horizontality - The layers of sediments are generally deposited in a nearly horizontal position. Principle of Crosscutting Relationships - Principle stating that an intrusion or fault that cuts across a sequence of strata is always younger than the strata it cuts. Principle of Inclusions - Principle stating that any fragments or particles of country rock in an igneous intrusive body is always older than the intrusion itself. Also, any sedimentary rock is made of substances (i.e. particles) that are older than that sedimentary rock. Unconformities - Periods of no deposition and represent a gap in time in the geologic record. These appear as erosional surfaces in a sequence of strata. Types of Unconformities: i. Angular Unconformity - Strata below the unconformity are folded or tilted before being eroded. ii. Disconformity - A type of unconformity where there is an erosional surface between two groups of sedimentary strata. iii. Nonconformity - An erosional surface between igneous/metamorphic layers and sedimentary layers. There is a lithologic change across the unconformity. Radiometric or Absolute Dating There are 92 naturally occurring elements in nature. All matter is made up of chemical elements, with each being composed of extremely small particles called atoms. The nucleus of an atom is comprised of positively charged particles called protons, neutrally charged particles called neutrons, with negatively charged particles, called electrons encircling the nucleus in energy levels or electron shells. The number of protons in the nucleus of any atom of an element is the atomic number of that particular element. That is the basis of the numbering of the elements on the Periodic Table of Elements. For instance, the element Hydrogen has one proton in its nucleus. Therefore it has an atomic number of 1; Helium has two protons in its nucleus, and therefore has an atomic number of 2; Uranium has 92 protons in its nucleus and therefore has an atomic number of 92. The atomic number of an element defines that element. If an element looses a proton by some means, it is no longer that element. Conversely, if an element gains a proton by some means, it is no longer that element. Neutrons in the nucleus of an atom do not affect its charge (since neutrons are neutrally charged), but neutrons do affect the atomic mass of the element. The atomic mass of an element is the combined number of protons and neutrons in the nucleus. Not all atoms of the same element have the same number of neutrons in their nuclei. These variable forms of the same element are called isotopes. For instance, hydrogen has an atomic number of one: one proton and one electron. If a neutron is added to the nucleus of hydrogen, it still has the same atomic number, but you have increased its atomic mass, forming the isotope of hydrogen called deuterium. If another neutron is added to the nucleus it becomes the isotope of Hydrogen called tritium. All three, Hydrogen, Deuterium, and Tritium all have an atomic number of one (one proton in the nucleus), but they are all different isotopes of the same element. If you could continue to add neutrons to the nucleus of an atom, a point would be reached that the nucleus would become very unstable. Because of our reality being “ruled” by the processes of entropy (whereby everything “wants” to be at its lowest point of equilibrium, or its lowest “rest” state), atoms with unstable nuclei (those with high neutron to proton ratios) begin to emit particles, which we refer to as radioactivity. Radioactive decay is the process whereby an unstable atomic nucleus is spontaneously transformed into an atomic nucleus of a different element. There are three basic types of radioactive decay: Alpha Decay Beta Decay Electron Capture Decay Alpha decay occurs when 2 protons and two neutrons are emitted from the nucleus, resulting in a loss of 2 atomic numbers and 4 atomic mass numbers. Beta decay occurs when a neutron in the nucleus emits a fast-moving electron, changing that neutron to a proton and consequently increasing the atomic number by 1, with no resultant atomic mass number change. Electron capture decay comes about by a proton in a nucleus capturing an electron from an electron shell and thereby converting into a neutron, resulting in the loss of one atomic number, but not changing the atomic mass number. Some elements undergo only one step to convert from an unstable nucleus to a stable one. Others require several conversions until a stable state is achieved. For example, the element rubidium 87 decays to strontium 87 by a single beta emission, and potassium 40 decays to argon 40 by a single electron capture. Uranium 235 decays to lead 207 by seven alpha steps and six beta steps. Uranium 238 decays to lead 206 by eight alpha and six beta steps. The half-life of a radioactive element is the time it takes for one-half of the atoms of the original unstable parent element to decay into atoms of a new, stable daughter element. The daughter element is the stable element that an unstable element decays or changes into. The half-life of radioactive elements is constant and can be measured. Each different unstable radioactive element has a different half-life that can range from less than a billionth of a second to 49 billion years. All igneous rocks contain radioactive isotopes. Whenever they solidify (or cool) the radioactive parent isotope begins to decay into the stable daughter element. So, whenever an igneous rock of unknown age is found, a field sample of it is taken, and the sample is analyzed as to which radioactive isotope is present in abundance. When that is determined, a survey of the daughter element that particular radioactive element decays into is made from the sample in question. This creates a percentage of radioactive parent isotope to the stable daughter isotope present in what is called the parent/daughter ratio for that particular rock. The half-life (a measurement of time) for that particular radioactive element found in abundance in the field specimen is easily found in physics and chemistry reference books. So, knowing the percentage of the radioactive parent to the stable daughter element present in the sample of igneous rock of unknown age, and knowing the half-life for the radioactive isotope in question, the actual age of the igneous rock can be deduced. Usually, only igneous rocks can be dated using the following procedures. For metamorphic rocks, only the age of the actual metamorphism can be determined. In rare instances, some sedimentary rocks containing Glauconite (a green-colored, radioactive potassium mineral found in some sedimentary deposits) can give information on the age of deposition of the sedimentary beds. All igneous rocks can be dated using radiometric techniques. Absolute dating techniques involve the measurement of the breaking down of certain radioactive elemental compounds in the rock that have occurred over time. The rate of decay is known for these radioactive elements from laboratory experimentation. If a geologist finds an igneous rock layer in the field and needs to know the exact age of the rock, a sample is taken from the outcrop. This sample is then sent to a laboratory that specializes in radiometric dating techniques. There the rock is ground into a very fine powder. This powder is then analyzed as to which radioactive isotopes are present in the rock. This lab must be equipped with an apparatus called a mass spectrometer. This analytical device allows the geologist to project purified samples of the rock in question into a strong, fluctuating magnetic field that has sensors that can detect the presence of different elements that have different atomic masses. It works similarly to the following scenario. If you turned on a strong fan and stood in front of the fan with a feather in one hand and a lead ball in the other, and simultaneously let go of both, what would happen? The feather would go shooting off because of its low weight (low mass) and the lead ball would fall to the ground because of its high weight (high mass). It’s the same principle whenever the atoms of different masses are projected through the magnetic field of the mass spectrometer: the “lighter” elements “fall” through the magnetic field differently than the “heavier” elements, there fore hitting the sensors at different areas and different rates. This is how the parent daughter ratio is determined in an unknown sample. To fully understand this technique, one must be familiar the following terms: Isotope - Varieties of the same element that have different mass numbers. Their nuclei contain the same number of protons but different numbers of neutrons. Parent Isotope - the full amount of isotope in the newly formed igneous rock. Daughter Isotope - (what the parent isotope will eventually turn into) the amount of altered parent isotope over time. Half-life - The time it takes for one-half of the atoms of a radioactive substance (Parent Material) to decay into another element (Daughter Material). For example, Uranium 238 (Parent) decays to Lead 206 (Daughter). The rate of decay is known for many of the naturally occurring radioactive elements. So, if the rate of decay is known, and the ratio of parent material to daughter material is measured in a rock, then the age of the formation of the rock can be found. Mass Spectrometer – the laboratory device used in determining the relative amounts of Parent and Daughter isotopes. Sample problems of Radiometric Dating Techniques 1.) In the geologic past, a rock formed from cooling magma, containing 1 gram of radioactive Uranium 238 and no Lead 206. Many years later a geologist who wants to find the exact age of this rock collects a sample. If the half-life for U238 is 4.5 billion years and after analysis the Uranium 238 to Lead 206 ratio (parent/daughter ratio) was 1:1 (50% U & 50% Pb), how old is the rock? 2.) A rock specimen was found that had a ratio of Potassium-40 to Argon-40, which was 1:7 (1 part Potassium-40 to 7 parts of Argon-40). Potassium-40 has a half-life of 1.3 billion years. How old is the rock? 3.) A geologist collects a piece of a meteorite rock in the field and wants to know the exact age of the rock. After close examination of the specimen, it was discovered that the specimen contains sufficient amounts of the potassium 40 to warrant using the K40 – Ar40 test. Knowing that the halflife of K40 is 1.3 billion years and that there was a ratio of 1 part K40 to 3 parts Ar40, how old is the rock? 4.) If a rock contained a parent/daughter ratio of “parent element X” to “daughter element Y” of 3:1, and the known age of the rock is 500 million years, what is the half-life of “element X” Sediments and Sedimentary Rocks Most fossils are found in sedimentary rocks. This is because the organic remains of organisms are usually destroyed by the high temperatures associated with igneous activity or the processes of metamorphism. The type of sedimentary rock formed in an area reflects the environment in which it was deposited. The term used by geologist to describe this aspect of sedimentary beds is “facies”. Much can be learned about the ancient environments of the earth by studying various characteristics of sedimentary rocks. All rocks form initially with the solidification of molten magma or lava. These newly formed igneous rocks are subsequently subjected to the surface processes of weathering and erosion (the destructive actions of running water, wind, glaciers, etc.) These rock fragments eventually settle out somewhere to form “sediments”. These sediments can become compacted to form sedimentary rocks. If these “new” sedimentary rocks are subjected to enough heat and pressure, they may become changed into “metamorphic” rocks. If the sedimentary rocks are completely melted by geologic processes, they revert back into a type of igneous rock upon cooling. I. The Rock Cycle: The rock cycle is the conversion of one rock type into another by melting, pressure deformation, and weathering and erosion. All rocks are initially igneous (The word “Igneous” means “born of fire”). II. Rock Types: Igneous rocks make up 90% by volume of the earth's crust. Igneous rocks are formed directly from molten material having its origin in the interior of the earth. As this molten material cools in some areas, it solidifies and hardens to become rock. Intrusive igneous rock forms below the surface of the earth. Extrusive igneous rocks form from molten material that has been forced out onto the surface of the earth (i.e. volcanoes). Sedimentary rocks form from the accumulation of eroded debris of other rocks or chemically from elements in seawater. Sedimentary rocks make up 75% of all of the rocks exposed at the earth's surface and are where most all fossilized remains are found. This makes sedimentary rocks useful in interpreting the earth's geologic history. Metamorphic rocks are formed from pre-existing rocks that have been altered as the result of intense heat and pressure. Metamorphism increases the “crystallinity“ and hardness of the rock; sandstone changes to quartzite; shale changes to slate, and limestone changes to marble. III. Types of Sedimentary Rocks: Since the facies of sedimentary beds tells the geologists so much information about the geologic past (paleoenvironments, paleoclimates, and past life forms), sedimentary rocks are emphasized in Historical Geology. There are 2 basic groups of sedimentary rocks: 1. Chemical Precipitates from the evaporation of seawater, or from the concentration of ions in water. These include rocks such as limestone and various salts such as Halite (NaCl), Sylvite (KCl), Gypsum (CaSO4), etc. The salts usually indicate periods of massive evaporation of aqueous environments. 2. Clastic Sedimentary Rocks are formed from the accumulation of debris from the weathering and erosion of other rocks. The 4 stages of the formation of clastic sedimentary rocks (“clastic” means "broken") are described on the following pages. IV. The Four Steps for Formation of Sedimentary Rocks: 1. Physical and Chemical Weathering of the “Parent Rock” (the source rock from which the clastic material is being derived). Physical weathering includes the breaking apart of the parent rock by freezing and thawing, wind erosion, etc. Chemical weathering includes dissolution of the parent rock by chemicals in the water (i.e. acid rain). 2. Transportation is the stage where the clastics are "moved"(“transported”) from the source area by water, wind, gravity, or ice. The terrain determines the area of transportation. The distance the particles are moved depends on the amount of energy operating in the environment. It would take more energy to move a boulder than a grain of sand. The larger the sediment size, the more energy is needed to move it. High- energy environments would include white water mountain streams that are capable of moving almost all sizes of particles. Low-energy environments include lagoons, lakes, deltas, swamps, etc., that are capable of moving only the smaller particles. 3. Deposition is the stage where the sediment is deposited in a particular geographic environment, which constitutes the sedimentary environment. As in transportation, the area of deposition is also determined by terrain. For example, large rocks formed on a mountain range would be carried down the steep gradient and deposited at the base of the mountain if the energy of the stream carrying them decreased when it reached the base of the mountain. Since the stream no longer has the high energy from the gradient, the large rocks are deposited in a manner indicative of a mountain stream environment. Sedimentary rocks can be interpreted to find out the environment in which they formed. Sedimentary Environments can be divided into several categories: Shoreline and Coastal Environments “Fluvial” or Stream, River, and Delta Environments Alluvial Fans or deposits at the bases of mountains “Aeolian” or “wind-borne” deposits There are numerous other sedimentary environments that your instructor will inform you of at the appropriate time 4. Compaction is the final stage in the formation of a sedimentary rock. At this stage the sediments are compacted due to the weight of the overburden (overlying sediments) and can be eventually “lithified” (turned to stone) as the particles are cemented together with substances such as Calcite (CaCO3), Silica (SiO2), or forms of Iron Oxide (i.e. Fe2O3), among other compounds.. V. Properties of Clastic Sediments: These include certain characteristics of the sedimentary rock that give specific information about the environment of deposition. These include particle size, degree of roundness, degree of sorting, and color. 1. Particle Size: Clastic sediments are found in various sizes ranging from <1/256 mm to >256 mm. Refer to Figure 1. The Wentworth Scale of Particle Sizes. The name of a particular sediment size is based on its particle size rather than its chemical composition. For example, "sand" refers to particles having a size range between 0.125mm – 0.5mm. There can be quartz sand such as that found along the Gulf Coast or there may be feldspar sands, gypsum sands, etc. Remember that sediment size indicates the amount of energy operating in the depositional environment and is therefore a useful clue in determining what the sedimentary environment was. Boulders represent a high- energy environment such as a river channel while clays represent a low energy environment such as a floodplain or swamp. The Wentworth Scale of Particle Sizes that is a list of sediment particle sizes and the names used to describe them: The Wentworth Scale of Particle Sizes (modified) Particle Name Approximate Particle Diameter in millimeters Boulders greater than 256 mm Cobbles 64 to 256 mm Pebbles 2 to 64 mm Sand 1/16 to 2 mm Silt 1/256 to 1/16 mm Clay less than 1/256 mm 2. Roundness: This is simply how “round” (or smooth) the particles in the rock are. Particles in rocks that are angular, irregular in shape, and have sharp edges are called “poorly rounded”. Particles that are smooth and have no edges are called “well rounded”. The degree of roundness indicates either the amount of agitation the particles were subjected to before deposition, or the length of time it took to transport the particle. “Well rounded” particles indicate that the particles were subjected to a high amount of saltation (bouncing along as they were transported) or being transported for a very long distance such as from the center of a continent to its shoreline. Both of these factors indicate how much the rock particle was hit by other fragments or was saltated along the route of transportation. “Poorly rounded” sediments indicate either a low amount of agitation, or a short distance of transportation from the time the particle weathered or broke away from their parent rocks. A high-energy environment, which allows for a long period of exposure to weathering, such as a beach or in a stream, is condusive to the formation to the formation of “well-rounded” sediments. On the other hand, a high-energy depositional environment that does not allow a long period of exposure to agitation, such as an alluvial fan, prevents the sediments from becoming “well-rounded” 3. Sorting: refers to rock fragments separated according to particle size. “poorly sorted” sediment would contain particles of varying size. This usually represents a rapid deposition as the result of a rapid decrease in the energy of an environment. Poorly sorted sediments are many times found in alluvial fans at the base of a mountain. This results in a "dumping effect" of sediments at the base of the mountain (high- energy to low- energy). “Well Sorted” sediment contains material that is made up primarily of all the same sized particles. This indicates that the rate of deposition is slow enough to allow the materials to be separated. Of course, the energy of the environment must be sufficient to accomplish this. Beaches, such as those along the Texas coast, allow sorting to occur. The high energy from the waves combined with a proper depositional rate provides excellent conditions for sorting of the sediments. Sediment is said to be "Mature" if it is well rounded and well sorted. Poorly sorted and poorly rounded sediment is said to be "Immature". 4. Color: The color of sediment can provide useful information about a sedimentary environment. In general, colors of sedimentary rocks can be interpreted in the following manner: a.) Red, yellow, brown - oxidation conditions, probably marine in origin. b.) Black, gray, greenish-gray - reducing conditions, probably marine except for floodplains and swamps. c.) Light gray or white - little iron present, either marine or nonmarine; other characteristics of the rock must be considered such as the presence of fossils, the type of fossils, whether or not there is cross-bedding, etc. VI. Chemical Precipitates: Chemically formed sediments are produced under various conditions, but generally speaking, when seawater becomes saturated with chemicals, they will precipitate out of solution. This is similar to when a lot of sugar is added to hot tea and then it is allowed to cool. Some of the sugar will "crystallize" or settle out of solution because the tea was "saturated" with sugar and it could not stay dissolved. Precipitates usually form only in low energy environments such as lagoons or deep-sea environments. Chemical Precipitates would not be found in high- energy environments. Limestone and Dolostone – These “carbonate rocks result from the concentration and precipitation of Ca+, Mg+, and CO3- ions in the sea. Limestone - Ca CO3 (primarily calcite)- forms offshore from the precipitation of calcium and carbonate ions that have been dissolved off of the continents. Limestones may also be formed from the accumulation of microscopic calcareous tests (shells) of planktonic (or other aquatic level) micro-organisms. Dolostone - Ca,Mg (CO3)2 (primarily dolomite)- forms in a similar manner, but contains magnesium as well as calcium. Dolostone may start off as limestone and later is subjected to groundwater replacing Ca+ with Mg+. Or, some dolostones indicate having formed the calcium/magnesium carbonate all at once. “Bioclastic sediments” are formed by living organisms. Many aquatic marine organisms produce shells or other protective coverings by secreting calcium carbonate (limestone) or calcium magnesium carbonate (dolomite). When these organisms die, their shells accumulate along the sea floor forming layers of broken shell fragments. Such material is biochemically produced and is ultimately broken by water action They are then referred to as "bioclastic sediments". The sedimentary rock coquina is a good example of a bioclastic deposit. The availability of nutrients decreases the further from the shore therefore most marine organisms live in the coastal, shallow water areas. As the distance from shore increases, generally the number of marine organisms decreases. The facies of bioclastic sediments such as coquina usually indicates a beachfront. “Organic Rocks” form as the result of organics (such as vegetative matter) accumulating in low energy, reducing, anaerobic environments such as swamps. The material does not rot quickly and the volatiles are driven off leaving behind the carbon. A good example of an organic rock is coal. The first stage is called peat. As the peat gets compressed over time, it becomes lignite coal. As lignite becomes compressed, it becomes bituminous coal. As bituminous coal becomes compressed, it forms the metamorphic rock anthracite, the final stage of coal. Other types of organic rocks may form from accumulations of dead organisms (such as fish) in low energy lagoons. VII. Bedding or Layering of Sedimentary Materials: Sedimentary rocks are deposited in layers known as "beds". The type of bedding will vary depending on the environment of deposition. Under normal conditions, beds are deposited in horizontal layers with the bedding planes (the line of contact between the beds) parallel to one another. "Cross-bedding" occurs when the surface of deposition is inclined (i.e. a delta) or a current is present (i.e. a stream). This type of bedding is called "cross-bedding" and is indicative of these environments. The types of currents that form cross-bedding strata are: a. Aeolian - wind action b. Fluvial - river and stream action c. Marine in Origin - current action Types of cross-bedding include planar - the bedding planes separating the cross-bedded units are parallel, wedged - the bedding planes are at an angle to one another and form a wedge; and trough - the bedding planes separating the cross-bedded units are curved. Thick planar or wedged cross-bedding always indicates an aeolian (wind) deposit such as a sand dune in the desert. Thin planar or wedged units may be aeolian, fluvial, or marine. Because of this, other characteristics such as color must be used to determine the environment of deposition. Many times paleocurrents of water (and sometimes wind) can be traced by the ripple marks left in some sedimentary rocks indicating ancient river channels or beachfronts. Mud cracks can also be preserved indicating ancient low energy mud flats. Another type of bedding is known as graded bedding. This is where there is a gradation in the size of particles within a unit of deposition. Larger particles are found on bottom with successively smaller sediments on top. This type of bedding is formed by "turbidity currents", which are the sudden flows of material down the continental slopes. This causes the finer particles to be suspended in the water while the larger particles fall out and are deposited on the bottom with smaller and finer sediment on top. This results in a "gradation" in particle size. The facies of graded bedding is deep water marine. VIII. The Marine Lithofacies: This refers to the depositional sequence found in a cross section of a shore to deep- water environment. The usual sequences of rock types are: 1. Sandstone formed on beach areas 2. Siltstone formed near-shore 3. Claystone/Shale formed further out 4. Limestone formed even further out in deeper waters A schematic of the typical marine lithofacies is as follows: The Marine Lithofacies Transgression: - the advancement of the sea onto the land because of a worldwide increase in sea level or a subsidence of the landmass. Regression: - the retreat of the sea from the land due to a worldwide drop in sea level or the uplift of the land. Transgressional and Regressional sequences of strata can be used to interpret and retrace ancient coastlines. Transgressional Sequence Regressional Sequence