Joint Stock Company
«Angarsk Catalysts and Organic Synthesis
Plant»
Angarsk, 2012
1
INFORMATION
JSC «Angarsk Catalysts and Organic Synthesis Plant»
JSC “Angarsk Catalysts and Organic Synthesis Plant” is an enterprise with 60year’s experience in catalysts manufacture. Over this period a wide range of products
was formed. There are catalysts, adsorbents, carriers, driers and zeolites, and organic
synthesis production as well.
JSC “Angarsk Catalysts and Organic Synthesis Plant” has a powerful base for
realization of research and experimental work in the field of processing and petrochemistry. The experimental of catalysts are preliminary tested at the plant micro-units and
checked in laboratory, that allows work on technology of their application more thoroughly and, to improve consumer properties and to increase the efficiency of their usage. The works on new high-performance catalysts development are realizing at JSC
“Angarsk Catalysts and Organic Synthesis Plant” right along.
The production of plant has recommended itself on refinery, chemical, nitric and
other factories of Russia, and foreign countries.
There are
-
JSC “Angarsk Petrochemical Company”
JSC “Angarsk Polymers Plant”
JSC “Gazprom Neftekhim Salavat”
JSC “Gazprom Neft Omsk Refinery”
JSC “Sintez Kauchuk”
JSC “RN-Komsomolsk-on-Amur Refinery”
JSC “Minudobreniya”
LLC “KINEF”
LLC “Purneftepererabotka”
“Azerbaijan State Oil Company (SOCAR), Heydar Aliev Baku Oil Refinary”
JSC “KuibyshevAzot”.
JSC “Angarsk Catalysts and Organic Synthesis Plant” renders service on support
in volume of a word practice:
- Realization of additional control of developers catalysts;
- Technological support at catalysts loading and until start-up;
- Realization of the fixed run with guaranteed parameters;
- Technical support of unit operation during a warranty period, including irregular
situations.
JSC “Angarsk Catalysts and Organic Synthesis Plant” is registered in the EastSiberian state inspection of assay supervision of Russian State assay office, as the legal
person who is carrying out operations with precious and jewels (the certificate №
0030000085).
2
CONTACT INFORMATION
JSC «Angarsk Catalysts and Organic Synthesis Plant»
Address: 665830, Russian Federation, Irkutsk region, Angarsk.
Sales Department: tel.: (3955) 578-953, 577-959, 576-831
Fax: (3955) 528-594, 527-545
E-mail: azkios@anhk.rosneft.ru web-site: http: //www.kataliz.ru
Office hours: from 8.30 a.m. to 17.15 p.m., lunch-hour: from 12.15 до 13.00 p.m.
(Time difference Moscow time +5 hours)
20-tonnes containers:
Batareynaya station, East Siberian Railway, code 932601
Railcars, 3-, 5-tonnes containers: Kitoy-Kombinatskaya station, East Siberian Railway,
code 932103, Plant code: 7491
General Director
Irina D. Reznichenko
577-932
Deputy General DirectorTechnical Director
Leonid G. Volchatov
576-097
Principal Deputy General DirectorFinancial Director
Olga I. Kudarenko
578-573
Deputy Technical Director –
Head of Research and Monitoring Centre
Alexander P. Bocharov 577-162
Deputy Technical Director –
Head of Production and Technical Department
Vladimir V. Anglyuster 578-730
Chief of Sales Department
Elena A. Kostina
578-953
Chief of Supply Department
Galina N. Denisenko
577-920
Head of Legal Department
Irena D. Kabakova
578-120
3
List of Content
Reforming catalysts
1.
2.
3.
4.
5.
6.
7.
RB-35YuKA (TC 2177-027-23092878-2003 with am.1)
RB-33U
(ТC 2177-005-23092878-2000 with am.1)
RB-44U
(TC 2177-023-23092878-2002 with am.1)
PR-81, PR-71 (TC 2177-040-46693103-2008 with am.1,2,3)
APM-99
(TC 2177-012-23092878-99 with am.1)
AP-56
(TC 2177-021-04610600-2000 with am. 1,2,3)
AP-64
(TC 2177-021-04610600-2000 with am. 1,2,3)
Isomerization catalysts
8. SI-1
9. SI-2
10.IP-82
11.IP-62М
12.KI-16М
(TC 2177-297-05742746-96 with am.1,2)
(TC 2177-009-04706192-00 with am.1, 2, 3)
(TC 2177-028-04610600-2004)
(TC 38.10173-88 with am. 1,2,3,4)
(TC 38.401923-92 with am.1-4)
Hydrogenation catalysts
13.APU
(TC 2172-013-94509069-2008)
14.APKB
(TC 2172-004-94509069-2006)
15.APKGS
(TC 2172-025-94509069-2008)
16.APKGU
(TC 2172-014-94509069-2008)
17.GIPH-108 (TC 6-02-672-84 with am.1-6)
18.PALLADIUM CHARCOAL (TC 6-09-5516-84 with am. 1-6)
19.PU-А
(TC 2172-055-46693103-2010)
20.PKA-25
(TC 2172-015-46693103-2005 with am.1-4)
21.PALLADIUM SIBUNITE (TC2172-041-46693103-2003)
22.PALLADIUM ON ACTIVE ALLUMINIUM OXIDE IN SULFURATED FORM
(TC 38.10249-92 with am.1)
23.A - EKG
(TC 2172-038-23351179-97)
24.NVS-A
(TC 2177-035-46693103-2007)
25.AP-15
(TC 2172-026-04610600-2003 with am.1)
26.AP-10
(TC 2172-026-04610600-2003 with am.1)
Hydrodealkilation catalysts
27.AGDA
(TC 2172-014-46693103-2005)
Hydrotreating catalysts
28.GO-38А
29.GO-15
30.AGKD-400
31.A-GPV
(TC 2177-047-46693103-2009 with am.1)
(TC 2172-005-47317879-2000 with am.1)
(TC 2177-020-46693103-2006 with am.1-4)
(TC 2177-018-46693103-2006)
Oxidation catalysts
32.КО-10
(TC 38.401920-05 with am.1)
Hydrocracking catalysts
33.SGK-1
34.SGK-5
35.GI-03М
36.GKM-21М
(TC 2177-338-05742746-99 with am.1)
(TC 2177-006-46693103-2004 with am.1)
(TC 38.401-58-392-2007)
(TC 2177-036-46693103-2007)
4
37.KDM-10
(TC 2172-268-05742746-94 with am.1)
Methanation catalyst
38.ANKM
(TC 2178-036-47317879-97 with am.1)
Conversion catalysts
39.GIAP-8
40.AKN-М
41.STK-05
42.GIAP-3-6N
(TC 113-03-382-86 with am. 1-7)
(TC 2171-025-46693103-2006 with am.1)
(TC 2171-017-46693103-2005)
(TC 113-03-313-85 with am. 1-4)
Adsorbents catalysts
43.МОА-98
44.А-09-МОА
45.PS-17
46.PS-17 М
47.AGS-60
48.PS-2003
49.AR-25
50.APS
(TC 2163-01-23092878-99 with am.1-3)
(TC 2163-048-46693103-2010 with am.1)
(TC 38.401-58-18-91 with am.1-3)
(TC 2177-037-46693103-2007 with am.1)
(TC 2163-004-23092878-99 with am. 1)
(СТО 46693103-ПК-011-2008)
(TC 2163-018-23092878-2000)
(TC 2178-007-46693103-2004 with am. 1,2,3)
Petrochemical catalysts
51.ZINC-CHROME-ALUMINA (TC 2172-039-46693103-2008 with am.1)
52.SMS-4
(TC 113-05-5504-78 with am.1-7)
53.PGB-А
(TC 2177-057-46693103-2010)
54.GKA-75
(TC 2174-030-04610600-2007)
55.А-601МТ IN REGENERATED FORM (TC 2172-038-46693103-2007)
56.APK-2А
(TC 2178-031-46693103-2006 with am. 1,2)
57.IKA-33-3
(TC 2174-054-46693103-2010 with am.1)
58.KDC-10
(TC 2173-050-46693103-2010)
Protective bed catalysts
59.FOR-1
60.FOR-2
(TC 2163-023-46693103-2006 with am.1,2)
(TC 2177-022-46693103-2006 with am.1,2)
Carriers
61.ACTIVE ALUMINIUM OXIDE – CARRIER FOR CATALYSTS
(TC 2163-025-04610600-2003 with am.1)
62.ACTIVE ALUMINIUM OXIDE – DEHUMIDIFIER
(TC 2163-023-04610600-2003)
Zeolites
63. ZEOLITE BETA (BEA) SODIUM AND AMMONIUM FORMS
(STO 46693103-ПК-015-2008)
64. ZEOLITE CVM (DK 04-21303-108-2007)
5
RB-35YuKA REFORMING CATALYST
ТC 2177-027-23092878-2003 with am.1
Catalysts RB-35YuKA is used in catalytic reforming process for the purpose of
gasoline components and C6-C8 aromatic hydrocarbons production. Range of application is reforming units with fixed-bed catalyst.
Polymetallic catalyst RB-35YuKA is revealed as balanced composition of platinum and rhenium and promoting agents that are uniformly distributed over the surface
of the carrier – active aluminum oxide.
Parameter
1 Catalyst components (on calcined basis at 850 oC), weight %:
− Platinum
− Rhenium
− Chlorine, within
− Ferrum, not more
− Sodium (on sodium oxide basis), not more
2 Packed density, g/cm³
3 Specific surface area, m²/g, not less
4 Strength factor (average), kg/mm, not less
5 Extrudates Diameter, mm
6 Mass fraction of particles less than 1 mm, %, not more
7 Mass fraction of extrudates longer than 15 mm, %, not more
8 Calcination losses at 850 ºС, wt %, not more
9 Catalytic properties:
− activity – aromatic hydrocarbons content in debutanized gasoline produced at 490 oC , wt %, not less
− selectivity – yield of debutanized gasoline with 65 wt % aromatic hydrocarbons content, wt %, not less
Values
0,33±0,02
0,33±0,03
1,0-1,5
0,01
0,01
0,75±0,05
200
1,5
1,5±0,2
0,5
1,0
3,0
70
84
6
RB-33U REFORMING CATALYST
TC 2177-005-23092878-2000 with am.1
RB-33U catalyst is destined for producing of the gasoline components and aromatic hydrocarbons by way of catalytic reforming process.
RB-33U polymetallic catalyst is balanced composition of uniformly distributed
over the active aluminum oxide surface platinum, rhenium and promoting agents.
We produce three grades (A, B and Sh) of RB-33U catalyst, witch are distinct
in using active aluminum oxide carrier.
Parameter
Grade А
Values
Grade B
Grade Sh
1 Catalyst components (on calcined basis at
850 oC), weight %:
− Platinum
0,30±0,02 0,30±0,02 0,30±0,02
− Rhenium
0,30±0,02 0,30±0,02 0,30±0,02
− Chlorine, within
1,3±0,2
1,3±0,2
1,3±0,2
− Ferrum, not more
0,01
0,02
0,02
− Sodium (on sodium oxide basis), not more
0,01
0,01
0,01
2 Packed density, g/cm³
0,73-0,83 0,67-0,73 0,70-0,80
3 Specific surface area, m²/g, not less
200
200
200
4 Strength factor, kg/mm, not less:
− average
1,2
1,2
3,3
− minimum
0,7
0,7
1,2
5 Extrudates Diameter, mm
1,4-1,8
1,2-1,6
1,6-2,0
6 Extrudates length, mm
5-10
5-10
7 Particles size distribution, wt %;
− particles less than 1 mm, wt %, not more
0,1
0,1
0,1
− particles with 3-10 mm of length, wt %,
not less
90,0
90,0
− extrudates longer than 10 mm, wt %, not
more
1,0
1,0
8 Calcination losses at 850 ºС, wt %, not
3,0
3,0
3,0
more
9 Catalytic properties:
− activity – aromatic hydrocarbons content
70
69
72
o
in debutanized gasoline produced at 490 C ,
wt %, not less
− selectivity – yield of debutanized gasoline
84
84
84
with 65 wt % aromatic hydrocarbons content,
wt %, not less
10 Period between regenerations, years
3-4
11 Performance period, years
7
7
RB-44U REFORMING CATALYST
TC 2177-023-23092878-2002 with am. 1
RB-44U catalyst is destined for producing of the gasoline components and aromatic hydrocarbons production by way of catalytic reforming process.
RB-44U polymetallic catalyst is balanced composition of uniformly distributed
over the active aluminum oxide surface platinum, rhenium and promoting agents.
We produce three grades (A, B and Sh) of RB-44U catalyst, witch are distinct
in using active aluminum oxide carrier.
Parameter
Grade А
1 Catalyst components (on calcined basis
at 850 oC), weight %:
− Platinum
0,25±0,02
− Rhenium
0,40±0,02
− Chlorine, within
1,0-1,5
− Ferrum, not more
0,01
− Sodium (on sodium oxide basis), not
0,01
more
2 Packed density, g/cm³
0,78±0,05
3 Specific surface area, m²/g, not less
200
4 Strength factor, kg/mm, not less:
− average
1,2
− minimum
0,6
5 Extrudates Diameter, mm
1,4-1,8
6 Extrudates length, mm
5-10
7 Particles size distribution, wt %;
− particles less than 1 mm, wt %, not more
0,1
− particles with 3-10 mm of length, wt %,
not less
90,0
− extrudates longer than 10 mm, wt %, not
more
1,0
8 Calcination losses at 850 ºС, wt %, not
3,0
more
9 Catalytic properties:
− activity – aromatic hydrocarbons content
in debutanized gasoline produced at 490 oC
70
, wt %, not less
− selectivity – yield of debutanized gasoline with 65 wt % aromatic hydrocarbons
84
content, wt %, not less
10 Period between regenerations, years
11 Performance period, years
Values
Grade B
Grade Sh
0,25±0,02
0,40±0,02
1,0-1,5
0,02
0,01
0,25±0,02
0,40±0,02
1,0-1,5
0,02
0,01
0,72±0,05
200
0,70-0,80
200
1,0
0,6
1,2-1,6
5-10
3,3
1,2
1,6-2,0
-
0,1
0,1
90,0
-
1,0
3,0
3,0
70
72
84
84
3-4
7
8
PR series REFORMING CATALYSTS
TC 2177-040-46693103-2008 with am. 1-3
Reforming catalysts PR series (PR-71, PR-81, PR-81F) are used for the producing of high-octane number gasoline components and aromatic hydrocarbons in
gasoline fractions catalytic reforming process.
The catalysts involves the rhenium promoted platinum, witch is uniformly distributed on the external and internal surfaces of active aluminium oxide granules
promoted with zirconium oxide (PR-71, PR-81 А, В and Sh grades) or with fluoride ion (PR-81F).
Parameter
1 Granules Diameter, mm*
2 Catalyst components (on
calcined basis at 850 oC),
weight %:
−
−
−
−
Platinum
Rhenium
Chlorine
Fluorine
3 Content of impurities (on
calcined basis at 850 oC),
weight,:
-Sodium oxide, not more
-Ferrum, not more
4 Calcination losses at 850 ºС,
wt %, not more
5 Strength factor, kg/mm, not
less:
− average
− minimum
6 Mechanical Strength: destructive force at crushing,
kg/mm, not less:
− average
− minimum
7 Mass fraction of particles
less than 1 mm, %, not more
8 Packed density, g/cm³
9 Specific surface area, m²/g,
not less
10 Catalytic properties:
− activity – aromatic hydrocarbons content in debutanized
gasoline produced at 490 oC ,
wt %, not less
− selectivity – yield of debu-
Values
PR-81
Grade А
PR-81
Grade В
PR-81
Grade С
PR-81
Grade F
PR-71
1,6±0,2
1,6±0,2
1,6±0,2
1,6±0,2
1,6±0,2
PR-81
Grade
Sh
1,8±0,2
0,25±0,02
0,30±0,02
1,0±0,3
-
0,25±0,02
0,40±0,02
1,0±0,3
-
0,300,02
1,0±0,3
-
0,35±0,02
0,30±0,05
0,250,02
0,300,02
1,0±0,3
-
0,250,02
0,300,02
1,0±0,3
-
0,02
0,02
0,02
0,02
0,02
0,02
0,02
0,02
0,02
0,02
0,02
0,02
4,0
4,0
4,0
7,0
4,0
4,0
1,2
0,6
1,2
0,6
1,2
0,6
1,2
0,6
1,2
0,6
-
-
-
-
-
-
230
120
0,1
0,75
200
0,1
0,75
200
0,1
0,75
220
0,1
0,75
200
0,1
0,75
220
0,1
0,75
200
72
72
70
70
72
72
9
tanized gasoline with 65 wt %
aromatic hydrocarbons content, wt %, not less
84
84
82
82
84
84
10
APM-99 REFORMING CATALYSTS
TC 2177-012-23092878-99 with am. 1
APM-99 catalyst is used for catalytic reforming process with a purpose of gasoline components producing.
APM-99 catalyst is modified gamma-aluminium oxide with uniformly dispersed over the surface platinum.
Parameter
1 Catalyst components, wt %
− Platinum
− Fluorine
2 Content of impurities, wt %, not more
− Sodium oxide
− Ferrum
3 Packed density, g/cm³
4 Strength factor (average), kg/mm, not less
5 Extrudates Diameter, mm
6 Calcination losses at 850 ºС, wt %, not more
7 Specific surface area, m²/g, not less
8 Total pore volume, cm³/g, not less
9 Mass fraction of particles less than 1 mm, %, not more
10 Catalytic properties:
− activity – motor octane number of debutanized gasoline, not
less
− selectivity – yield of debutanized gasoline with 79 motor octane
number, wt %, not less
Values
0,45±0,02
0,32±0,05
0,013
0,020
0,6-0,8
1,1
2,8±0,2
7,0
200
0,5
0,2
79
83,5
11
AP-56, AP-64
ALUMINA-PLATINUM REFORMING CATALYSTS
TC 2177-021-04610600-2000 with am.1,2,3
AP-56 и AP-64 catalyst are used for reforming of untreated gasoline.
The catalysts AP-56 and AP-64 consists of platinum uniformly distributed on
the external and internal surfaces of carrier extrudates (fluorinated and nonfluorinated active aluminium oxide).
In manufacturing process, the catalysts are sulfurizated with hydrogen sulfide.
Parameter
Values
АП-56
АП-64
1 Catalyst components (on calcined basis at 850 oC),
weight %:
− Platinum
0,55±0,03 0,62±0,02
− Chlorine
0,75±0,10
− Fluorine
0,32±0,05
− Ferrum, not more
0,020
0,017
− Sodium (on sodium oxide basis), not more
0,013
0,015
2 Packed density, g/cm³
0,70±0,10 0,70±0,10
3 Strength factor (average), kg/mm, not less
1,0
1,0
4 Extrudates Diameter, mm
2,8±0,2
2,8±0,2
5 Calcination losses at 850 ºС, wt %, not more
6,8
6,8
6 Specific surface area, m²/g, not less
195
195
7 Mass fraction of particles less than 1 mm, %, not
more
0,3
0,3
8 Total pore volume, cm³/g, not less
0,65
0,65
9 Catalytic properties:
− activity – motor octane number of debutanized gasoline, not less
79
86
− selectivity – yield of debutanized gasoline with 79
motor octane number for catalyst AP-56 and 86 motor
octane number for AP-64, %, on feed, not less
83
75
12
SI-1 and SI-2 LIGHT GASOLINE FRACTIONS
ISOMERIZATION CATALYSTS
SI-1 TC 2177-297-05742746-96 with am.1-2
SI-2 TC 2177-010-04706192-01
Catalysts SI-1 and SI-2 are destined for light gasoline fractions middletemperature isomerization.
SI-1 catalyst consists of platinum coated on zeolite-containing carrier.
SI-2 catalyst is sulphated zirconium oxide modified with aluminium oxide additive.
Parameter
Values
SI-1
SI-2
1 Catalyst components (on calcined basis at 850±10 oC),
weight %:
− Platinum
0,3±0,02
− Zirconium oxide
− Aluminium oxide
−
− Sulphate-ion
−
− Sodium oxide, not more
0,02
− Silicon oxide
40-58
− Ferrum, not more
0,08
2 Packed density (on calcined at 550 ±10 ºС catalyst),
g/cm³, not more
0,7
3 Strength factor (average), kg/mm, not less
1,0
4 Extrudates Diameter, mm
2,8±0,2
5 Calcination losses at 850±10 ºС, wt %, not more
4,0
6 Content of dust and chip (less than 1 mm),
wt %, not more
0,1
7 Total pore volume, cm³/g, not less
−
8 Specific surface area, m²/g, not less
−
9 Catalytic properties:
− аactivity – content of 2,2-dimethylbutane in С5+ catalyzate, wt %, not less:
− at 280 ºС
17
− at 220 ºС
−
− selectivity – content of hydrocarbons С5+ in catalyzate,
wt %, not less:
− at 260 ºС
97
− at 180 ºС
−
−
72-82
9-18
3-9
0,02
0,03
1,2
1,2
2,8±0,3
6,0
0,1
0,2
120
−
20
−
97
13
IP-62M and IP-82
ALUMINA-PLATINUM
HIGH-TEMPERATURE ISOMERIZATION CATALYSTS
IP-62M TC 38.10173-88 with am. 1-4
IP-82
TC 2177-028-04610600-2004
IP-62M catalyst is used for high-temperature isomerization process of npentane to iso-pentane and of non-treated and non-dried gasoline head fractions.
IP-82 catalyst is used for high-temperature isomerization process of n-pentane
and pentane-hexane fraction for the purpose of the feed for isoprene rubber and
gasoline component manufacturing.
IP-62M is platinum uniformly distributed on the external and internal surfaces
of fluorinated aluminium oxide extrudates.
IP-82 is platinum uniformly distributed on the external and internal surfaces of
sulfurized and fluorinated aluminium oxide extrudates.
Parameter
Values
IP-62M
IP-82
1 Catalyst components (on calcined basis at 850±10
o
C), weight %:
− Platinum
0,50±0,05
− Fluorine
3,0-4,0
− Ferrum, не более
0,025
− Sodium (on sodium oxide basis), not more
0,015
2 Packed density, g/cm³, not more
0,60-0,70
3 Strength factor, kg/mm, not less:
− average
− minimum
4 Extrudates Diameter, mm
5 Mass fraction of particles less than 1 mm, %, not
more
6 Calcination losses at 850±10 ºС, wt %, not more
7 Catalytic properties, %, not less:
− conversion
− selectivity
0,45±0,03
3,5±0,5
0,03
0,025
не более
0,80
1,0
0,6
2,8±0,2
1,0±0,2
2,8±0,2
0,1
6,5
0,1
5,0
55
98
55
97
14
KI-16M CATALYST
TC 38.401923-92 with am.1-4
KI-16 M catalyst is designed for the technical xylene isomerization process.
The catalyst consists of active aluminium oxide and high-silica zeolite.
Parameter
1 Packed density (on calcined at 550 ºС basis), g/cm³, not more
2 Strength factor (average), kg/mm, not less
3 Extrudates Diameter, mm, within
4 Silicon oxide content (on calcined at 600 0С basis), wt %, not
less
5 Content of impurities (on calcined at 600 0С basis), wt %, not
more:
− Ferrum
− Sodium oxide
6 Calcination losses at 550 0С, wt %, not more
7 Content of dust and chip (less than 1 mm), wt %, not more
8 Isomerization activity at Т = 425 0С, V = 1 час−1:
− etylbenzene conversion, %, not less
− content in produced dimethylbenzene, wt %, not less:
− p-hylene
− о-hylene
− Content of co-products in catalizate, wt%, not more
Values
0,6
0,9
2,8-3,2
18,7
0,07
0,10
5,0
2,0
25
23
20
5
15
PALLADIUM ON CARBON CATALYS (АPU)
TC 2172-013-94509069-2008
APU catalyst is used for different organic compounds hydrogenation.
APU is AR-B grade activated carbon with dispersed on the surface active component palladium.
There are several grades of the catalyst with different palladium content.
Parameter
1 Appearance
Values
APU-0,25 APU-0,5 APU-0,8 APU-1,0 APU-1,5
Granules of cylindrical shape and charcoal gray black
coal
2 Extrudates size distribution,wt %:
− 2,8-5,0 mm, not less
90,0
− 1,0-2,8 mm
фиксируется
− less than1,0 mm, not
1,0
more
3 Packed density, g/dm³,
not more
610
4 Granules abrasive resistance, %, not less
70
5 Water content, wt %,
not more
2,5
6 Palladium on dry basis, wt %, within
0,20±0,02 0,50±0,0 0,8±0,1
1,0±0,2
3
1,5±0,2
16
APKB
PALLADIUM CATALYST
TC 2172-004-94509069-2006
APKB catalyst is used for treating of pyrolysis butadiene fraction from acetylenic compounds.
Катализатор АПКБ представляет собой алюмооксидный носитель,
на поверхности которого распределен металлический палладий.
Parameter
Values
APKB-0,3
1 Appearance
APKB-0,5
APKB-1
Extrudates (E) or spherical shape
granules (Sh) of deep-brown to
black color
2 content of particles less than 1 mm, wt
%, not more
0,3
3 Granules Diameter, mm, within
2,5±0,5
4 Packed density, kg/dm³, not more
0,9
5 Palladium (on calcinated at 850 ºС basis), wt %, within
0,30±0,03
6 Strength factor (average) for extrudates
(E grade), kg/mm, not less
1,2
7 Destructive force at crushing for spherical shape granules (Sh grade) , kg/cm2, not
less
40
8 Catalytic activity in reaction of phenylacetylene
hydrogenation,
not
less,
3
cm /minute.
2
0
9 Calcination losses at 850 С, wt %, not
more
9,0
0,3
2,5±0,5
0,9
0,3
2,5±0,5
0,9
0,50±0,05
1,00±0,10
1,2
1,2
40
-
2
2
9,0
9,0
17
APKGS
PALLADIUM CATALYST
TC 2172-025-94509069-2008
APKGS catalyst is designed for selective hydrogenation of acetylene and diene
components in liquid and gas pyrolysis fractions at EP-450,EP-300, EP-250, EP60industrial units.
Catalyst grade
APKGS-10Sh
APKGS-10E2
APKGS-20Sh
APKGS-10E1
APKGS-20E1
APKGS-20E2
Parameter
1 Appearance
Application
Ethane-ethylene and propane-propylene pyrolysis fractions selective hydrogenation.
Liquid pyrolysis fractions (pyrolysis condensate, benzene-toluene-xylene fractions) hydrostabilization
Values
10Sh 20Sh 10E1 20E1 10E2 20E2
spherical shape granules (Sh) or extrudates (E)
of light or deep-brown color
2 Extrudates size distribution,wt %:
− more than 8,0 mm, not more
0,5
− 1,0-2,5 mm, %, not more
15,0
− less than 1,0 mm, not more
0,3
3 Granules Diameter, mm,
−
within
4 Packed density, kg/dm³, not
more
0,9
5 Components (on calcinated
at 850 ºС basis), wt %:
− Palladium, within
0,10±
0,02
6 Mechanical strenght:
− Strength factor (average) for
extrudates (E grade), kg/mm,
not less
−
− Destructive force at crushing
for spherical shape granules
(Sh grade) , kg/cm2, not less
40
0
7 Calcination losses at 850 С,
wt %, not more
9,0
0,5
15,0
0,3
−
−
−
0,3
4,0±
0,5
−
−
0,3
4,0±
0,5
−
−
0,3
2,5±
0,5
−
−
0,3
2,5±
0,5
0,9
1,3
1,3
0,9
0,9
0,20±
0,02
0,10±
0,02
0,20±
0,02
0,10±
0,02
0,20±
0,02
−
1,8
1,8
0,9
0,9
40
−
−
−
−
9,0
5,0
5,0
9,0
9,0
18
APKGU
PALLADIUM CATALYST
TC 2172-014-94509069-2008
APKGU catalyst is designed for selective hydrogenation of acetylene and diene
components in gas pyrolysis fractions at EP-450, EP-300, EP-250, EP-60industrial
units.
There are four grades of APKGU catalyst.
Parameter
1 Appearance
Values
10Sh
3Sh
10E
3E
spherical shape granules (Sh) or extrudates (E) of light or deep-brown color
2 Extrudates size distribution,wt %:
− more than 8,0 mm, not more
0,5
0,5
−
−
− 1,0-2,5 mm, %, not more
15,0
15,0
−
−
− less than 1,0 mm, not more
0,3
0,3
0,3
0,3
3 Granules Diameter, mm, within
−
−
2,5±0,5 2,5±0,5
4 Packed density, kg/dm³, not more
0,9
0,9
0,95
0,95
5 Components (on calcinated at 850
ºС basis), wt %:
0,10±0,02 0,04±0,01 0,10±0,02 0,04±0,01
− Palladium, within
0,10±0,02 0,10±0,02 0,10±0,02 0,10±0,02
− Silver, within
6 Mechanical strength:
− Strength factor (average) for extrudates (E grade), kg/mm, not less
− Destructive force at crushing for
−
−
1,0
1,0
spherical shape granules (Sh grade) ,
kg/cm2, not less
40
40
−
−
0
7 Calcination losses at 850 С, wt %,
not more
9,0
9,0
9,0
9,0
19
GIPH-108
HYDROGENATION CATALYST
TC 6-02-672-84 with am.1-6
GIPH-108 catalyst is used for liquid-phase reduction of dimethylnitrosamine
(DMNA) to dimethylhidrazine (DMH) by continuous method.
GIPH-108 is AR-B type recuperated carbon with distributed in its surface metal
palladium.
Parameter
1 Appearance
2 Extrudates size distribution,wt %:
− 2,8-5,0 mm, not less
− 1,0-2,8 mm
3 Packed density, g/dm³, not more
4 Granules abrasive resistance, %, not less
5 Water content, wt %, not more
6 Palladium on dry basis, wt %, within
7 Catalytic activity as a reduction of dimethylnitrosamine to
dimethylhidrazine: average dimethylhidrazine yield (for last
48 hours) during 72-hours catalyst test in standard conditions,
%, not less
8 Activity as a time required for nitrobenzene reduction to 30
% conversion, minute, not less
Values
Granules of cylindrical shape,
charcoal grey or
black color
94,0
reported
61·10
7·10
2,5
1,8-2,0
85
4 ·10
20
PALLADIUM CHARCOAL
TC 6-09-5516-84 with am.1-6
«Palladium Charcoal» catalyst is used for different organic compounds hydrogenation.
«Palladium Charcoal» catalyst is AR-B, AGK-2 and improved quality AR-B
types recuperated carbon with distributed in its surface metal palladium.
Parameter
1 Appearance
2 Extrudates size distribution,wt %:
− 2,8-5,0 mm, not less
− 1,0-2,8 mm
− less than 1,0 mm, not more
3 Packed density, g/dm³, not more
4 Granules abrasive resistance, %, not less
5 Water content, wt %, not more
6 Palladium on dry basis, wt %, within
7 Activity as a time required for nitrobenzene reduction to 30
% conversion, minute, not less
Values
Granules of cylindrical shape,
charcoal grey or
black color
90
reported
1,0
520-600
7·10
1,0
1,8-2,0
4,5 ·10
21
PU-A
PALLADIUM ON CARBON CATALYST
TC 2172-055-46693103-2010
PU-A catalyst is used for different organic compounds hydrogenation.
PU-A catalyst is AR-B type recuperated carbon with distributed in its surface
metal palladium.
There are three grades of PU-A catalyst, which distinct by palladium content.
Parameter
1 Appearance
2 Extrudates size distribution,wt %:
− 2,8-5,0 mm, not less
− 1,0-2,8 mm
− less than 1,0 mm, not more
3 Packed density, g/dm³, not more
4 Granules abrasive resistance, %, not less
5 Water content, wt %, not more
6 Palladium on dry basis, wt %, within
7 Activity as a time required for nitrobenzene reduction to 30 % conversion, minute,
not less
Values
PU-A
PU-A
PU-A
- 2,0
- 1,5
- 1,0
Granules of cylindrical shape, charcoal grey or black color
1,8-2,0
90
reported
1,0
520 - 600
7*10
2,0
1,4 -1,6
0,9 – 1,1
4,5*10
------
-------
22
PКА-25
PALLADIUM CATALYST
TC 2172-015-46693103-2005 with am.1-4
PKA-25 catalyst is designed for selective hydrogenation of alkynes and alkadienes impurities in pyrolysis olefins fractions (PKA-25-1, PKA-25-3E and PKA-253Sh grades) and for nitrogen and hydrogen treating from (PKA-25-2, PKA-25-2U
grades).
PKA-25-1, PKA-25-2, PKA-25-2U and PKA-25-3E grades consists of palladium uniformly distributed on the external surface of active aluminium oxide extrudates.
PKA-253Sh grades catalyst is palladium uniformly distributed on the external
surface of active aluminium oxide spherical granules.
Parameter
PKA25-1
PKA25-2
Values
PKA- PKA25-2U 25-3E
1 Catalyst components
(on calcined basis at 850oC), wt %:
- Palladium, within
0,25±0,03 0,25±0,03 1,0±0,1 1,5±0,1
- Ferrum, not more
0,02
------------- Sodium (on sodium oxide basis), not
----more
0,13
--------2 Palladium distribution depth from external surface into the interior of extrudates, mm, not more
0,2
------------3 Packed density, g/cm³, not more
0,8
0,9
0,9
0,9
4 Strength factor (average), kg/mm, not
less
- average
1,3
1,2
1,2
---- minimum
0,6
0,7
0,7
---5 Mechanical strength, MPa, not less
---------4,0
6* Extrudates diameter, mm, within
2,8±0,2
2,5±0,5
4,0±0,5 4,0±0,5
7 Mass fraction of particles less than 1 mm, 0,1
0,3
0,3
0,3
%, not more
8 Calcination losses at 850 0С, wt %, not
more
9,0
9,0
9,0
9,0
9 Catalytic activity:
– 35 cm3 hydrogen adsorption time at 0,1
cm3 phenylacetylene hydrogenation,
10
------10
minute, not more
– rate of phenylacetylene hydrogena3
------3
3
tion, cm /min, not less
* ― Production of the other sized catalysts is assumed.
PKA25-3Sh
1,5±0,1
--------
----0,9
------2,5
4,0±0,5
0,3
9,0
10
3
23
«PALLADIUM SIBUNITE» CATALYST
TC 2172-041-46693103-2009
«Palladium Sibunite» catalyst is used for the plant oils and distilled soap-stocks
fatty acids hydrogenation process to stearine acid.
Catalyst consists of spherical carbonaceous granules with palladium uniformly
distributed on the external surface.
Parameter
1. Water content at 100 – 1100С, wt %, not more
2. Extrudates size distribution,wt %:
− 3,6-5,0 mm, not more
− less than 1,0 mm, not more
3. Packed density (on dried basis), kg/dm³, within
4. Palladium on dry basis, wt %, within
5. Palladium dispersity on dry basis, not less
Values
3,0
90
1
600 – 750
1,0 ± 0,1
0,30
24
PALLADIUM ON ACTIVE ALUMINIUM OXIDE IN SULFURATED FORM
TC 38.10249-92
«Palladium on active aluminium oxide in sulfurated form» is designet for selective hydrogenation of diene and alkenylaromatics hydrocarbons of liquid pyrolysis
fractions, witch are steaming away at 200oC.
Catalyst consists of palladium uniformly distributed on the external and internal
surfaces of active aluminium oxide extrudates.
Parameter
1 Catalyst components (on calcined basis at 850oC), wt %:
- Palladium, within
- Sulphur, within
- Ferrum, not more
- Sodium (on sodium oxide basis), not more
2 Packed density (on calcined at 550 ºС catalyst), kg/dm³, not more
3 Strength factor, kg/mm, not less
- average
- minimum
4 Extrudates Diameter, mm, within
5 Dust content, wt %, not more
6 Calcination losses at 850 0С, wt %, not more
Values
0,50±0,05
0,15±0,05
0,02
0,03
0,8
1,0
0,5
2,8±0,2
0,1
9,0
25
A-EKG
CATALYST
TC 2172-038-23351179-97
A-EKG catalyst is used for hydrogenation of carbonylic compounds to alcohols: 2-ethylhexanal to 2-ethylhexanol, crotonic aldehyde to n-butanol, and butyl
ethers of synthetic fatty acids to C5-C12 aliphatic alcohols.
A-EKG catalyst consists of copper, zinc and aluminium oxides and promoting
agents and comes in two types: in tablet shape (T type) or in extrudate shape (F
type). There are two grades of A-EKG catalyst depending on active component
composition: A-EKG-1 (copper-zinc compound) and A-EKG-2 (cupric chromate).
Parameter
Values
A-EKG-1
Т
F
1 Granules size, mm, within:
− diameter
− height
2 Packed density, kg/dm³, within
3 Mechanical strength - Destructive
force at crushing:
− on generatrix, MPa, not less
− on edge, MPa, not less
4 Calcination losses at 900 0С, wt
%, not more
5 Catalyst components, wt %:
− Copper on CuO basis, not less
− Zinc on ZnO basis, within
− Chrome on Cr2O3 basis, not more
6 Catalytic activity:
− conversion during ethyl acetate
hydrogenation , %, not less
− conversion during butyl acetate
hydrogenation , %, not less
A-EKG-2
Т
F
5,0±0,5
5,0±0,5
1,2-1,6
5,0±2,0
4,0-15,0
1,2-1,4
5,0±0,5
5,0±0,5
1,2-1,6
5,0±2,0
4,0-15,0
1,2-1,4
4,0
16
2,0
−
4,0
16
2,0
−
15,0
30,0
15,0
15,0
40
30-32
−
40
30-32
−
50
25-30
20
50
25-30
20
45
45
45
45
35
35
35
35
26
NVS-A CATALYST NICKEL-WOLFRAM SULPHIDE WITH
ALUMINIUM OXIDE ADDITION
TC 2177-035-46693103-2007
NVS-A catalyst is used in hydrogenation of petroleum sulfur feed stock process
with the purpose of special type fuels producing.
NVS-A catalyst is of large tablet shape of black color. The catalyst consists of
nickel and wolfram sulphides and active aluminium oxide.
Parameter
1
−
−

2
3
4
5
6
−
−
7
Catalyst components, wt %:
Nickel, within
Wolfram on WO3 basis, within
Sulphur, within
NiS/WS2 molar ratio, within
Water content, wt %, not more
Packed density, kg/dm³, not more
Mechanical strength, kg/cm2, not less
Tablet size, mm, within:
diameter
height
Activity  benzol to cyclohexane coversion degree, %, not less
Values
15,5-16,5
30,0-33,0
17,0-18,5
1,9-2,4 : 1,0
3,0
1,7
250
10 ± 1
10 ± 1
65
27
AP-10 and AP-15 ALUMINA-PLATINUM SELECTIVE HYDROGENATION CATALYSTS
TC 2172-026-04610600-2003
AP-10 and AP-15 catalysts are designed for selective hydrogenation of unsaturated compounds in catalytic reforming products.
AP-10 and AP-15 are platinum sulphide uniformly distributed on the external
and internal surfaces of active aluminium oxide extrudates.
Parameter
1 Catalyst components (on calcined basis at 850±10
o
C), weight %:
− Platinum
− Ferrum, not more
− Sodium on sodium oxide basis, not more
2 Packed density (on calcined at 550±10 ºС catalyst),
g/cm³, within
3 Strength factor, kg/mm, not less
- average
- minimum
4 Extrudates Diameter, mm, within
5 Mass fraction of particles less than 1 mm, %, not
more
6 Calcination losses at 850±10 0С, wt %, not more
7 Catalytic properties:
− activity – hydrogenated catalyzate bromine number,
g Br/100cm3 of product, not more
− selectivity – absolute difference between aromatics
content in feed and in product, %, not more
Values
AP-10
AP-15
0,10±0,01
0,017
0,020
0,15±0,01
0,017
0,020
0,70±0,10
0,70±0,10
0,97
0,55
2,8±0,2
0,97
0,55
2,8±0,2
0,1
7,0
0,1
7,0
0,08
0,08
2,0
2,0
28
AGDA
ANGARSK CATALYST
TC 2172-014-46693103-2005
AGDA catalyst is used for hydrodealkilation process of toluene and pyrolysis
condensate fraction at pressure 5,0-6,0 MPa and temperature 600-640 oC with the
purpose of benzene producing.
AGDA catalyst is modification of alumina-chrome catalyst promoted with
structure-directing and anti-coke additives.
Depending on composition and operational characteristics there are two grades
of catalyst: AGDA-1 and AGDA-2.
Parameter
1 Catalyst components (on calcined at 650 ºС basis), wt %:
− Cr2O3
− B2O3
− Na2O
2 Packed density, g/cm³, not less
3 Specific surface area, m²/g, not less
4 Average Strength factor (knife 0,1 mm), kg/mm, not less
5 Extrudates Diameter, mm, within
6 Mass fraction of particles less than 1 mm, %, not more
7 Calcination losses at 650 0С, wt %, not more
8 catalytic properties with toluene:
− content of benzene in catalyzate, wt %, not less
− activity – benzene yield per passed-through toluene, wt %,
not less
− selectivity – benzene yield per converted toluene, wt %, not
less
9 Catalytic properties with real feed (hydrotreated benzenetoluene-xylene fraction):
− conversion of alkylaromatic compounds, %, not less
− conversion of non-aromatic compounds, %, not less
− conversion of organosufur compounds, %, not less
10 Resistance to coke formation – carbon content in dead catalyst, wt %, not more
Values
AGDA-1 AGDA-2
12±2
1,5-3,0
0,7-1,5
0,8
100
2,0
3,0±0,2
1
4
18±2
1,5-3,0
0,7-1,5
0,8
100
2,0
3,0±0,2
1
4
60
70
55
97
60
97
65
90
80
75
93
80
2
2
29
GO-38A CATALYST
TC 2177-047-46693103-2009 with am.1
GO-38A catalyst is used for oil fractions and feed stocks for white oils hydrotreating process.
GO-38A catalyst is an alumina-nickel-molybdenum system.
Parameter
Catalyst components (on calcined at 650 ºС basis), wt %:
molybdenum trioxide (MoO3), within
nickel oxide (NiO), within
sodium oxide (Na2O), not more
ferrous oxide (Fe2O3), not more
Packed density (on calcined at 550 ºС catalyst), g/cm³, not less
Extrudates Diameter, mm, within
Strength factor (average), kg/mm, not less
Calcination losses at 650 0С, wt %, not more
1
−
−
−
−
2
3
4
5
6 Mass fraction of particles less than 1 mm, %, not more
Values
18,0-21,0
7,0-9,0
0,4
0,2
0,8
2,5-3,5
0,8
5,0
1,0
GO-38A catalyst provides 96%-reduction of oil distillate sulfur content down to
0,01-0,02 %-remaining content and to 0,08-0,10 % in residual oils.
Catalyst may be used for wax concentrates hydrotreating and reduces sulfur and
nitrogen levels to 97-98%.
30
GO-15
CATALYST
TC 2172-005-47317879-2000 with am.1
GO-15 catalyst is designed for distillate and aromatic including pyrolysis condensate benzene-toluene-xylene hydrotreating and for aromatics aftertreatment
from sulfur compounds.
The catalyst is an alumina-(nickel)cobalt-molybdenum system. There are three
grades depending on nickel and cobalt content: GO-15N, GO-15NK and GO-15K.
Parameter
Greenish
color
Values
GOGO-15К
15NK
From blush to grey
color
13,0-16,0
3,5-4,5
−
13,0-16,0
1,5-0,2
1,5-2,0
13,0-16,0
−
3,0-4,0
0,08
0,20
0,70-0,90
1,5-2,5
0,08
0,20
0,70-0,90
1,5-2,5
0,08
0,20
0,70-0,90
1,5-2,5
1,3
5,0
1,3
5,0
1,3
5,0
1,0
1,0
1,0
93
94
94
GO-15N
1 Appearance
2 Catalyst components (on calcined at 550 ºС
basis), wt %:
− molybdenum trioxide (MoO3), within
− nickel oxide (NiO), within
− cobalt oxide (CoO), within
3 Content of impurities (on calcined at 550 ºС
basis), wt %, not more:
− sodium oxide (Na2O)
− ferrous oxide (Fe2O3)
4 Packed density, g/cm³, within
5 Extrudates Diameter, mm, within
6 Average Strength factor (knife 0,1 mm),
kg/mm, not less
7 Calcination losses at 650 0С, wt %, not more
8 Dust and fines (particles less than 1,0 mm), wt
%, not more
9 Catalytic activity:
− diesel fuel desufurization degree at t=380 ºС,
pressure 2,0 MPa, LHSV 6 h-1, %, not less
31
AGKD-400
CATALYST
TC 2177-020-46693103-2006 with am.1- 4
AGKD-400 catalyst of AN, BN, AK and BK grades in oxide form and ASN,
ASK, BSN and BSK grades in sulfurized form is used for hydroforming:
– pyrolysis condensate benzene-toluene-xylene fraction and high-sulfur gasolines (AN, АК, ASN and ASK grades);
– diesel fuel and и vacuum gasoil (BK, BN, BSN and BSK grades).
The catalyst is an alumina-nickel-molybdenum or alumina-cobalt-molybdenum
system in oxide or sulfurized form and is produced in form of aetrudates.
Parameter
1 Catalyst components (on
calcined at 600 ºС basis), wt%,
not less:
− molybdenum oxide (MoO3)
− nickel oxide (NiO)
− cobalt oxide (CoO)
− sulphur1)
− phosphorus oxide (Р2O5),
2 Sodium oxide (Na2O) concentration (on calcined at 600
0
С basis), wt %, not more
3 Packed density, g/cm³, within
4 2) Extrudates Diameter, mm,
within
5 Strength factor (average),
kg/mm, not less
6 Calcination losses at 600
0
С, wt %, not more
71) Water content, wt %, not
more
8 Activity in vacuum gasoil
hydroterating at t=370 0С,
pressure 5,0 MPa and LHSV
1,0 h-1:
– residual sulfur concentration
in hydrogenizate, wt %, not
more
9 Activity in pyrolysis condensate benzene-toluene-xylene
fraction hydroterating at t=350
0
С, pressure 5,0 MPa and
LHSV 1,5 h-1:
Values
АГКД-400
Sulfurized form
ASK
BSN
AN
AGKD-400
Oxide form
AK
BN
BK
ASN
10,0
2,5
−
−
3,0
10,0
−
2,5
−
3,0
10,5
2,8
−
−
3,0
10,0
−
2,5
−
3,0
10,0
2,5
−
3,5
3,0
0,08
0,60,8
1,32,0
0,08
0,60,8
1,32,0
0,08
0,60,8
1,32,0
2,0
2,0
2,0
2,0
2,0
2,0
2,0
2,0
5,0
5,0
5,0
5,0
−
−
−
−
−
−
−
−
3,0
3,0
3,0
3,0
−
−
0,25
0,25
−
−
0,25
0,25
10,0
−
2,5
3,5
3,0
10,5
2,8
−
3,5
3,0
0,08
0,08
0,08
0,08
0,6-0,8 0,6-0,8 0,6-0,8 0,6-0,8
1,3-2,0 1,3-2,0 1,3-2,0 1,3-2,0
BSK
10,0
−
2,5
3,5
3,0
0,08
0,60,8
1,32,0
32
Parameter
− residual sulfur concentration
in hydrogenizate, wt %, not
more
− iodine number of hydrogenizate, g J2/100cm3 of product,
not more
10 Desulphurization degree of
diesel fuel at t=3600С, pressure
4,0 MPa and LHSV 3 h-1,
not less
Values
AN
AGKD-400
Oxide form
AK
BN
5∙
10−5
5∙
10−5
2
96
АГКД-400
Sulfurized form
ASK
BSN
BK
ASN
BSK
−
−
5∙
10−5
5∙
10−5
−
−
2
−
−
2
2
−
−
96
−
−
96
96
−
−
33
A-GPV
CATALYST
ТУ 2177-018-46693103-2006
A-GPV catalyst is used for prehydrotreating of feedstocks for hydrogen production. The primary purpose of catalyst is hydrogenation of an organosulfur compounds contained in natural and refinery gases at the units for production of hydrogen, synthesis gas and ammonia.
A-GPV catalyst is the system of nickel, molybdenum and aluminium oxides.
Parameter
1 Catalyst components (on calcined at 600 ºС basis), wt%:
− molybdenum trioxide (MoO3), not less
− nickel oxide (NiO), not less:
2 Sodium oxide (Na2O) concentration (on calcined at 600 0С basis),
wt %, not more
3 Packed density, g/cm³, not less
4 Extrudates Diameter, mm, within
5 Calcination losses at 600 0С, wt %, not more
6 Strength factor (average), kg/mm, not less
7 Mass fraction of particles less than 1 mm, %, not more
8 Activity in hydrodesulphurization process:
− Concentration of mercaptans in catalizate, wt %
Values
7,0
2,0
0,1
0,7
2,0-3,5
5
1,8
2,0
Absence
.
34
KO-10
OXIDATION CATALYST
TC 38.401920-05 with am.1
KO-10 catalyst is designed for oxidation of CO to CO2 in catalytic cracking
unit’s regeneration off-gases.
KO-10 catalyst is microspheric aluminium oxide with planned porous structure
and contains platinum micro-additives.
KO-10 catalyst is used as individual additive to cracking catalyst at FCC catalytic cracking units.
1
2
3
4
5
Parameter
Packed density, g/cm³, not less
Calcination losses at 850 0С, wt %, not more
Mass fraction of particles 0,03 mm and more, %, not less
Platinum (on calcined at 850 ºС basis), wt %, within
Wear resistance, %, not less
Values
0,9
10,0
80
0,03-0,05
90
35
SGK-1 and SGK-5 CATALYSTS
SGK-1 TC 2177-338-05742746-99 with am. 1
SGK-5 TC 2177-006-46693103-2004 with am. 1
SGK-1 and SGK-5 catalysts are designed for processes of petroleum fractions
n-paraffins hydrocarbons selective hydrocracking and hydrodewaxing of oil fractions with a purpose to produce low-pour-point dielectric oils, hydraulic oils, mineral oils and other low-pour-point petroleum products.
SGK-5 catalyst has improved hydrogenation properties and is used for simultaneous secondary oil distillates hydrodewaxing and hydrotreating to produce lowpour-point dielectric oils.
SGK-1 and SGK-5 are granules made of high-silica pentasil-group zeolite, aluminium oxide and hydrogenating components.
Parameter
1 Catalyst components (on calcined at 550 ºС basis),
wt%:
− molybdenum trioxide (MoO3), within
− nickel oxide (NiO), within
− aluminium oxide (Al2O3), not more
− sodium oxide (Na2O), not more
2 Packed density, g/cm³, not more
3 Granules Diameter, mm, within
4 Calcination losses, wt %, not more:
− at 650 ºС
− at 550 ºС
5 Strength factor (average), kg/mm, not less
6 Fraction, wt %:
− less than 2,5 mm, not more
− less than 1,6 mm, not more
7 Activity – dielectric base oil pour point, ºС, not higher
Values
SGK-1
SGK-5
5,0-8,0
−
45
0,10
0,8
3-4
10-12
5-6
−
0,2
0,8-0,9
2,5-3,5
8,0
−
1,0
−
8
0,8
4
−
− 48
−
2,5
− 45
36
GI-03M
CATALYST
TC 38.401-58-392-2007
GI-03M catalyst is used for diesel fractions and oil distillates hydrogenation
process with purpose to produce low-velocity base oils for hydraulic liquids.
GI-03M catalyst is platinum uniformly distributed on external and internal surfaces of siliferous alumina support.
Catalyst is made in sulfurized form.
Parameter
1 Catalyst components (on calcined at 850 ºС basis), wt%:
− silicon oxide, within
− platinum, within
2 Detrimental impurities (on calcined at 850 ºС basis), wt%, not
more:
− sodium oxide (Na2O)
− ferrous oxide (Fe2O3)
3 Packed density, g/cm³, within
4 Splitting Strength factor, kg/mm, not less
5 Granules Diameter, mm, within
6 Calcination losses at 850 0С, wt %, not more
7 Dust and fines (particles less than 1,0 mm), wt %, not more
8 Catalytic activity:
8.1 hydrogenating activity
− sulphonated compounds in fraction EBP 210 ºС-cut, wt %, not
more
8.2 cracking activity:
− 210 ºС IBP-cut, vol %, not more
Values
6-12
0,48-0,52
0,1
0,08
0,50-0,65
1,0
2,0-3,0
8,5
2,0
4
5
37
GKM-21M
CATALYST
TC 2177-036-46693103-2007
GKM-21catalyst is designed for hydrocracking of heavy sulfur and nitrogenrich feed to produce insulating oils.
GKM-21catalyst consists of molubdenum, nickel, aluminium and silicon
oxides.
Parameter
1 Catalyst components (on calcined at 600 ºС basis), wt%, within:
− molybdenum trioxide (MoO3)
− nickel oxide (NiO)
 silicon oxide (SiО2)
2 Detrimental impurities wt%, not more:
− sodium oxide (Na2O)
− ferrous oxide (Fe2O3)
3 Packed density, g/cm³, within
4 Granules Diameter, mm, within
5 Calcination losses at 600 0С, wt %, not more
6 Strength factor, kg/mm, not less
7 Mass fraction of particles less than 1,6 mm, %, not more
8 Activity: quality data of fraction 280 0С EBP-cut separated from
hydrogenizate produced at Т=390 0С, Р=23 MPa:
8.1 Density at 20 0С, g/cm3, not more
8.2 Refraction index at 20 0С, not more
8.3 Carbon in aromatic rings, %, not more
Values
30-42
15-21
5,0-10,0
0,15
0,2
0,7-1,1
2,0-4,0
10
1,0
7,0
0,845
1,4650
2
38
KDM-10
CATALYST
TC 2172-268-05742746-94 with am. 1
KDM-10 catalyst is used for petroleum fractions hydrofining and hydrodewaxing processes.
KDM-10 catalyst is a granules made of high-silica pentasil-group zeolite, aluminium oxide and hydrogenating components.
Parameter
1 Packed density, g/cm³, not less
2 Granules Diameter, mm, within
3 Strength factor (average), kg/mm, not less
4 Catalyst components, wt:
− molybdenum trioxide (MoO3), not less
− sodium oxide (Na2O), not more
5 Calcination losses at 650 0С, wt %, not more
6 Mass fraction of particles less than 1 mm, %, not more
7 Activity:
relative activity is determined by pour point during dewaxing of desired cut from second vacuum hydrocracking, oC, not more
Values
0,55
3-4
1,2
5,0
0,1
8,0
2,5
− 48
39
ANKM
METHANATION CATALYST
TC 2178-036-47317879-97 with am.1
ANKM catalyst is used for gas treating (hydrogen, nitrogen) from carbon oxides and oxygen.
Grade
ANKM-1Т
ANKM-1E
АТО-2
ANKM-1P
Characteristics
Tablets of cylindrical shape
and charcoal gray to black
color.
Consists of nickel and aluminum oxides.
Exstrudates of charcoal gray
to black color
Consists of nickel and aluminum oxides.
Tablets of cylindrical shape
and charcoal gray to black
color.
Alumina-chrome-nickel system
Granules of charcoal gray to
black color with yellowish
tinge
Satutrated with nickel salt and
promoters
Application
Works at pressure 2,0-30,0 MPa, temperature range 180-450оС,
LHSV range 3000-20000 h-1 and 0,3-1,3 vol. % CO and CO2
concentration in initial gas. Designed to produce ammonia and
hydrogen.
Works at pressure 2,0-30,0 MPa, temperature range 180-450оС,
LHSV range 3000-20000 h-1 and 0,3-2,5 vol. % CO and CO2
concentration in initial gas.
Works at pressure 0,1-30,0 MPa, temperature range 180-450оС,
LHSV range 5000-20000 h-1 and 2,0 vol. % CO and CO2 concentration in initial gas.
Works at pressure 2,0-30,0 MPa, temperature range 180-450оС,
LHSV range 3000-20000 h-1 and 0,3-3,0 vol. % CO and CO2
concentration in initial gas
Parameter
1 Granules size, mm, within:
− diameter
− height
2 Packed density, g/cm³, within
3 Mechanical strength
- Destructive force at crushing along
generatrix, MPa, not less
− Strength factor (average), kg/mm,
not less
4 Calcination losses at 800 0С, wt
%, not more
5 Catalyst components (on calcined
at 800 ºС basis), wt%, within:
− NiO, not less
− Al2O3, not less
 Cr2O3, not less
6 Dust and fines (particles less than
2,5 mm), wt %, not more
Values
ANKM-1Т
ANKM-1E
АТО-2
ANKM-1P
4,0-6,0
4,0-6,0
1,0-1,3
3,0-4,0
4,0-7,0
0,8-1,0
4,0-6,0
4,0-6,0
1,1-1,4
3,0-5,0
не норм.
0,8-1,1
2,0
−
3,5
−
−
20
1,0
15
−
18
1,1
10
34,0-38,0
48,0
−
34,0-38,0
48,0
−
35,0-41,0
45,0
9-15
20,0-25,0
60,0
−
3
3
3
3
40
GIAP-8
NICKEL CATALYST FOR HYDROCARBON GASES
CONVERSION
GIAP-8 TC 113-03-382-86 with am. 1-7
GIAP-8T TC 113-03-27-74-89
GIAP-8 and GIAP-8T catalysts are used for steam, steam-carbon-dioxide and
steam-and-air conversion of hydrocarbon gases with purpose to technical hydrogen
and other technical gases manufacturing.
GIAP-8T catalyst possesses of improved strength and thermal stability and
therefore it is recommended fore charging into “hot” converters areas, where there
are higher thermal stresses.
Parameter
1 Appearance
2 Packed density, kg/dm³, within
3 Granules size, mm:
− external diameter, within
− internal diameter, not less
4 Mechanical strength
- Destructive force at crushing on
edge, MPa, not less:
− GIAP-8
− GIAP-8T
5 Thermal stability: Number of
thermal cycles from 1200 oC to granules blackening in the air without
granules destruction, not less:
− GIAP-8
− GIAP-8T
6 Nickel, wt %
7 Activity: methane residual volume
concentration after natural gas conversion with water steam at
steam:gas ratio=2:1 and LHSV=6000
h-1, %, not more:
at temperature:
− 500 ºС
− 800 ºС
8 Sulfur content (on SO3 basis), wt
%, not more
Values
C-15
C-20
R-15
R-20
Porous granules of grey or light-grey color
cylinders
rings
1,0-1,3
0,9-1,2
1,0-1,3
0,8-1,1
15,0±1,0
−
20,0±1,0
−
15,0±1,0
3,0
20,0±1,0
4,0
18
23
18
22
16
21
15
20
20
20
6,0-10,0
20
20
6,0-10,0
20
20
6,0-10,0
15
20
6,0-10,0
35,0
1,0
35,0
1,0
35,0
1,0
35,0
1,0
0,005
0,005
0,005
0,005
41
AKN-M
CATALYST
TC 2171-025-46693103-2006 with am.1
AKN-M catalyst is used for refinery off-gases and naphta steam conversion at
pressure to 4,0 MPa to produce of technical hydrogen and synthesis gas for alcohols and ammonia manufacturing.
AKN-M catalyst is promoted nickel oxide dispersed on corundum support.
AKN-M catalyst is produced in shape of cylinders, riffled rings and rings.
Parameter
1 Appearance
2 Granules size *, mm:
− external diameter, within
− external diameter maximum, within
− external diameter minimum, within
− internal diameter, within
− height, within
3 Packed density, kg/dm³, not more
4 Fines and defected granules, wt %, not more
5 Mechanical strength:
5.1 Destructive force at crushing on edge, MPa,
not less:
− average
− minimum
5.2 Destructive force at crushing along generatrix, MPa,
− average, not less **
6 Nickel (on NiO basis), wt %, not less
7 Activity: methane residual volume concentration after natural gas conversion with water
steam at steam:gas ratio=2:1, LHSV=6000 h-1,
and 800 oC, %, not more
8 Thermal stability: Number of thermal cycles
from 1200 oC to granules blackening (in 40 s) in
the air without granules destruction, not less
9 Sulfur content (on SO3 basis), wt %, not more
10 Calcination losses at 800 0С, wt %, not more
C
Cylinders
Values
R
Ring
18,0±2,0
−
−
−
18,0±2,0
1,4
5
18,0±2,0
−
−
4,0
18,0±2,0
1,2
5
−
17,0±2,0
15,0±2,0
4,0
18,0±2,0
1,2
5
18
8
18
8
16
8
5
6,0
5
6,0
5
6,0
RK
Riffled
ring
No norms,
determination is obligatory
20
0,005
5
20
0,005
5
20
0,005
5
* - In coordination with user manufacturing of other standard sized catalysts is assumed;
** - Parameter is not objectionable and serves for fact data taking.
42
STK-05
GATALYST
TC 2171-017-46693103-2005
STK-05 catalyst is designed for carbon monoxide medium-temperature steam
conversion in processes of ammonia and hydrogen production as well as for carbon
monoxide and organic impurities removal from off-gases.
Parameter
Values
STK-05-1
Т
F
1 Appearance
STK-05-3
Т
F
Cylindrical tablets (Т) or extrudates
(F) of deep brown to black color
2 Granules size, mm within, :
− diameter
5,0±0,5
− height
5,0±0,5
3 Packed density, kg/dm³, not more
1,6
4 Mechanical strength:
- Destructive force at crushing along generatrix, MPa, not less
3,0
5 Catalyst components, wt%:
− Ferrum (on Fe2O3 basis), not less
80
− Chrome (on Cr2O3 basis), not less
7,0
–
 Copper (on CuO basis), within
6 Sulfur content, wt %, not more
0,04
o
7 Activity: velocity constant at 350 C,
cm3/g·s, not less
1,2
5,0±0,5
–
1,4
5,0±0,5
5,0±0,5
1,6
5,0±0,5
–
1,4
2,5
3,0
2,5
80
7,0
–
0,04
80
7,5
2,5±0,5
0,04
80
7,5
2,5±0,5
0,04
1,3
1,6
1,8
43
GIAP-3-6N
NICKEL CATALYST FOR GASEOUS HYDROCARBONS CONVERSION
TC 113-03-313-85 with am.1-4
GIAP-3-6N catalyst is used for synthes-gas production to use in ammonia and
methanol production in process of methane steam-air conversion in secondary
mine converters under the pressure until 40 atm.
Parameter
1 Appearance
2 Packed density, g/cm³, within
3 Deformed granules, wt %, not more
4 Fines, wt %, not more
5 Granules size, mm, within, :
− external diameter
− internal diameter
− height
6 Mechanical strength - Destructive force at crushing along generatrix, MPa, not less:
− average
− minimum
7 Thermal stability: Number of thermal cycles from
1200 oC to room temperature in the air without granules destruction, not less
8 Nickel (on NiO basis), wt %, within
9 Activity: methane residual volume concentration
after natural gas conversion with water steam at
steam:gas ratio=2:1 and LHSV=6000 h-1, %, not
more, at temperature:
− 500 ºС
− 800 ºС
10 Sulfur content (on SO3 basis), wt %, not more
Values
К-15
C-11
C-15
Rings
Cylinders
Granules of grey or light-grey
color
1,4±0,1
1,6±0,1
1,6±0,1
4,0
4,0
4,0
0,7
0,7
0,7
15,0±1,0
4,0±1,0
15,0±1,0
11,0±1,0
−
11,0±1,0
15,0±1,0
−
15,0±1,0
4,0
2,0
4,0
2,0
5,0
2,5
4
7,5±1,5
19
7,5±1,5
15
7,5±1,5
38,5
1,5
0,005
38,5
1,5
0,005
38,5
1,5
0,005
44
MOA-98
CHLORINE SELECTIVE ADSORBENT
TC 2163-01-23092878-99 with am.1-3
MOA-98 adsorbent is used for deep reforming gas streams treating from hydrogen chloride and drying allowing reducing corrosion and preventing ammonium
chloride deposit formation.
Adsorbent can be used for gas and liquid fluids treating and drying in other processes such as isomerization, polymerization, reforming, etc.
MOA-98 adsorbent is active aluminium oxide promoted with calcium oxide.
Parameter
1 Appearance
2 Diameter, mm, within:
− Spherical granules
− Extrudates
3 Packed density (on calcined at 550oC basis), g/cm³,
within
4 Calcination losses at 850 0С, wt %, not more
5 Strength factor (average), kg/mm, not less
- Chipping strength factor, kg/mm, not less
- Destructive force at crushing, MPa, not less
6 Specific surface area, m²/g, not less
7 Water resistance, %, not less
8 Static activity: adsorption of water vapors at air temperature (20±3) ºС, grams of water per 100 g of adsorbent
- at relative humidly 10%, not less
- at relative humidly 60%, not less
9 Dynamic chlorine-retaining capacity before chlorine
appearing at test method conditions, %, not less
10 Calcium, wt %, within
11 Total pore volume, cm3/g, not less
Values
МОА-98Sh
МОА-98E
Spherical
Extrudates
granules
4-7
−
−
3-4
0,7±0,1
8
0,7±0,1
8
−
3,0
190
98
1,0
−
190
−
3,0
9,0
3,0
9,0
3,5
1-6
0,4
3,5
1-6
0,4
45
A-09-MOA
ADSORBENT FOR TREATING OF REFORMING
UNITS HYDROGEN-BEARING GAS
TC 2163-048-46693103-2010 with am. 1
A-09-MOA adsorbent is designed for hydrogen-bearing or inactive gases treating from hydrogen sulfide, hydrogen chloride and acid impurities.
Depending on application, there are two grades of A-09-MOA adsorbent: А-09МОА-1 and А-09-МОА-2
А-09-МОА-1 grade adsorbent is used for hydrogen-bearing or inactive gases
treating from hydrogen chloride and its partial drying allowing reducing corrosion
and preventing ammonium chloride deposit formation.
А-09-МОА-2 grade adsorbent is used for drying and advanced treating of recycling hydrogen-bearing gas or reforming inactive gas from chlorine and sulfur as
well as for gas and liquid fluids treating and drying in other processes.
Parameter
1 Appearance
2 (1) Extrudates diameter, mm, within:
3 Packed density (on calcined at 550oC basis),
g/cm³, within
4 Calcination losses at 850 0С, wt %, not more
5 Average chipping strength factor, kg/mm, not less
6 Specific surface area, m²/g, not less
7 Water resistance, %, not less
8 Static activity: adsorption of water vapors at air
temperature (20±3) ºС, grams of water per 100 g of
adsorbent
- at relative humidly 10%, not less
- at relative humidly 60%, not less
- at relative humidly from 90 to 100 %, not less
9 Calcium oxide, wt %, within
10 Total pore volume, cm3/g, not less
11 Mass fraction of particles less than 1 mm, %,
not more
12 Static chlorine-retaining capacity, %, not less
13 Dynamic chlorine-retaining capacity, %, not less
Values
А-09-МОА-1 А-09-МОА-2
Extrudates
Extrudates
3,5±0,5
4,0±0,5
0,7±0,1
0,7±0,1
8
1,0
190
98
10
0,9
98
3,0
9,0
3-9
0,4
1,0
9,0
16,0
30,0
0,5
1,0
8,0
4,0
-----
Remark:
1) - In coordination with user manufacturing of other standard sized catalysts is assumed
46
PS-17
CATALYST for SULFUR OXIDES REMOVAL from
REGENERATION GASES
TC 38.401-58-18-91 with am. 1-3
PS-17 catalyst is used for regeneration off-gases treating from sulfur oxides and
it is used as individual additive to cracking catalyst at FCC catalytic cracking units.
PS-17 catalyst is aluminium oxide with definite pore structure.
Parameter
1 Packed density, g/cm³, not less
2 Calcination losses at 850 0С, wt %, not more
3 Size distribution: content of fraction 0,03 mm and more, wt %,
not less
4 Wear resistance, %, not less
5 Specific surface area, m²/g, not less
Values
0,9
15,0
80
90
100
47
PS-17M
CATALYST
TC 2177-037-46693103-2007 with am.1
PS-17M catalyst is designed for binding of sulfur oxides in regeneration gases.
PS-17M catalyst is used as individual additive to cracking catalyst at FCC catalytic cracking units.
PS-17 catalyst is aluminium oxide with definite pore structure promoted with
alcaly-earth-metals oxides.
Parameter
1 Packed density, g/cm³, not less
2 Size distribution: content of fraction 0,03 mm and more, wt %, not
less
3 Wear resistance, %, not less
4 Specific surface area, m²/g, not less
5 Calcination losses at 850 0С, wt %, not more
Values
0,9
80
92
70
10
48
AGS-60
ADSORBENT for DEEP DESULFURIZATION of
REFORMING FEED
TC 2163-004-23092878-99 with am. 1
AGS-60 adsorbent is designed for adsorptive catalytic removal of organosulfur
impurities (mercaptans, sulfides, disulfides, etc.) and hydrogen sulfide from reforming feed – it means gasoline fraction in mixture with hydrogen-rich gas –as
well as for deep hydrogen sulfide and organosulfur compounds removal from hydrogen-rich gases.
AGS-60 adsorbent is produced in form of cylindrical brown or gray extrudates
and consists of manganese and aluminium oxides.
Parameter
Sulfur-retaining capacity, %, not less
Manganese content, wt %, within
Packed density, g/cm³, not less
Average strength factor, kg/mm, within
1
2
3
4
5 Extrudates diameter, mm, within
6 Content of fraction less than 1 mm, wt %, not less
7 Specific surface area, m²/g, not less
Values
22
60±10
1,0
1,0±0,2
2,1±0,2
0,5
50
49
PS-2003 SOx
ADSORBENT
SТО 46693103-ПК-011-2008
PS-2003 adsorbent is designed for SOx removal from calcination off-gases.
PS-2003 adsorbent is an aluminium oxide modified with calcium oxide.
Parameter
1 Appearance
2 Extrudates diameter, mm, within
3 Packed density (on calcined at 550 oC), g/dm³, not less
4 Calcination losses at 850 0С, wt %, not more
5 Average strength factor, kg/mm, within
6 Total pore volume, cm3/g, not less
7 Water resistance, %, not less
8 Static activity: adsorption of water vapors at air temperature
(20±3) ºС, grams of water per 100 g of adsorbent
- at relative humidly 10%, not less
- at relative humidly 60%, not less
9 Calcium content, wt %, within
Values
Extrudates
5-6
0,9
12
1,0
0,4
98
1,0
10,0
15
PS-2003 adsorbent is used in JSC “Angarsk Catalysts and Organic Synthesis
Plant” for treating gases from sulfur oxides.
50
AR-25
ADSORBENT – CATLYTIC REFORMING DRIER
TC 2163-018-23092878-2000
AR-25 adsorbent is destined for drying and aftertreating recycling reforming
hydrogen-rich or inactive gases from chlorine and sulfur as well as for drying and
treating gas and liquid fluids in other processes.
AR-25 adsorbent is a combination of aluminium oxide with zeolite.
Parameter
1 Granules shape
2 Granules diameter, mm, within
3 Packed density, g/cm³, not less
4 Strength factor, kg/mm, within
5 Calcination losses at 850 0С, wt %, not more
6 Total pore volume, cm3/g, not less
7 Static activity: adsorption of water vapors at air temperature
(20±3) ºС, grams of water per 100 g of adsorbent
- at relative humidly 10%, not less
- at relative humidly 60%, not less
- at relative humidly from 90 to 100 %, not less
8 Water resistance, %, not less
9 Content of fraction less than 1 mm, wt %, not less
Values
cylinders
2-5
0,6
0,9
10
0,5
9,0
16,0
30
98
0,5
51
APS
CATALYST
TC 2178-007-46693103-2004 with am.1-3
APS catalyst is designed for removal of hydrogen sulfide and mercaptans from
gaseous and liquid hydrocarbons.
APS-T grade zinc catalyst is produced in form of tablets based on activated zinc
oxide and used for hydrogen sulfide adsorption at II-stage of desulfurization.
APS-F grade zinc-copper catalyst is designed for hydrogen sulfide adsorption
and organosulfur compounds of petroleum gases, refinery off-gases and natural
gases advanced conversion as well as sulfur-containing compounds removal from
gaseous and liquid hydrocarbons.
APS-M grade zinc catalyst is used for recycling reforming and isomerization
hydrogen-rich gases treating from hydrogen sulfide.
Parameter
1 Granules shape
2* Granules size, mm:
− diameter
− height
3 Catalyst components (on calcined at 800 ºС basis), wt%, not less:
− zinc oxide (ZnO)
− copper oxide (CuO)
4 Packed density, g/cm³, within
5 Calcination losses at 800 0С, wt %, not more
6 Mechanical strength - destructive force at crushing along generatrix, MPa, not less:
7 Strength factor, kg/mm, not less
8 Sulfur-retaining capacity –
sulfur content in sulfurized catalyst after saturation
with hydrogen sulfide at temperature:
− 300 0С, wt %, not less
− 400 0С, wt %, not less
9 Specific surface area, m²/g, not less
APS-F
Extrudates
Values
APS-T
Tablets
APS-M
Extrudates
6,0-7,0
−
4,0-7,0
3,0-6,0
3,0-4,0
−
80
10,0
1,5-1,8
12
90
−
1,5-1,8
10
35
−
0,6-0,9
8
1,5
−
3,0
−
−
0,9
23
−
−
−
180
25
−
* - In coordination with user manufacturing of other standard sized catalysts is assumed
52
ALUMINA-ZINC-CHROME CATALYST
TC 2172-039-46693103-2008 with am.1
Alumina-zinc-chrome catalyst is used for reducing of buthyl aldehydes contained in cobaltized product of propylene hydroformylation as well as synthetic fatty acids methyl ethers to alcohols.
1
−
−
−
2
3
4
−
−
5
6
7
Parameter
Catalyst components (on dried at 100-110 ºС basis), wt%:
chrome (on CrO3 basis), not less
zinc (on ZnO basis), not less
aluminum (on Al2O3 basis), not more
Water removed at 100-110 oC, wt %, not more
Packed density, g/dm³, not more
Granules size, mm:
diameter
lenght
Strength factor, kg/mm, not less
Particles less than 3,6 mm, wt %, not more
Activity determined as butyl aldehydes conversion, wt%, not less
Values
32
54
4
0,8
1,2
4-5
4-6
1,0
5
85
53
SMS-4
ZINC-CHROME CATALYST
for METHANOL SYNTHESIS
TC 113-05-5504-78 with am. 1-7
SMS-4 catalyst is designed for industrial methyl alcohol production from hydrogen and carbon monoxide.
SMS-4 catalyst is produced in regenerated and non-regenerated grades in form
of cylindrical tablets.
Parameter
1 Zinc content in dry product (on ZnO basis), wt %
2 Hexavalent chrome content in dry product (on Cr2O3 basis), wt %
3 Trivalent chrome content in dry product (on Cr2O3 basis),
wt %
4 Ferrum content on Fe2O3 basis, wt %, not more
5 Acid insoluble residue content, wt %, max
6 Tablets size, mm
− diameter
− height
− diameter
− height
− diameter
− height
− diameter
− height
7 Packed density, g/dm³, not more
8 Mechanical strength - destructive force at crushing along
generatrix, MPa, not less
− average
− minimum
9 Activity:
cm3 of raw methanol/cm3 of catalyst per hour, not less
− at methanol content in raw methanol, wt %, not less
Values
Regenerated
Nonregenerated
65-68
No norms
55-58
34±1
31±1
не норм.
0,04
3,0
0,02
−
9,0±0,3
7,8±0,8
9,0±0,3
4,9±0,5
6,9±0,2
5,9±0,6
5,0±0,2
4,9±0,5
2,0
9,0±0,3
8,0±0,8
9,0±0,3
5,0±0,5
7,0±0,2
6,0±0,6
5,0±0,2
5,0±0,5
2,0
4,0
2,0
2,0
1,0
6,5
95
6,3
95
54
PGB-A
CATALYST
TC 2177-315-05742746-97
PGB-A catalyst is used for olefin-rich refinery off-gases as well as low octane
directly distilled or gas condensate gasoline fractions to high-octane motor gasoline blendstock conversion.
PGB-A catalyst consists of granules made of high-silica pentasil-group zeolite
and aluminium oxide promoted with several kinds of promoters including zinc.
Parameter
1 Catalyst components (on calcined at 550 ºС basis), wt%:
− silicon dioxide
− zinc oxide
− sodium oxide, not more
2 Calcination losses at 650 0С, wt %, not more
3 Packed density, kg/m³, not less
4 Chipping Strength factor, kg/mm, not less
5 Granules diameter, mm
6 Dust and crumb content, wt %, not more
7 Catalytic properties:
- activity – content of aromatic hydrocarbons in stable catalyzate
produced at 400 oC, %, not less
- selectivity – yield of the stable catalyzate at 400 oC, %, not less
Values
55-65
1,5-3,0
0,15
6,0
600
1,0
2,0-5,0
0,5
20
75
55
GKA-75
CATALYST
TC 2174-030-04610600-2007
GKA-75 catalyst is used for alcohols amination process
GKA-75 catalyst is light-yellow extrudates made of active aluminium oxide
with addition of kaolin.
Parameter
1 Catalyst components (on calcined at 650 ºС basis), wt%, not
more:
− Ferrum oxide
− Sodium oxide
− sulfat-ion
2 Calcination losses at 650 0С, wt %, not more
3 Packed density (on calcined at 650 ºС basis), g/cm³, not more
4 Extrudates passed trough the sieve with 8 mm-diameter holes, wt
%, not more
5 Mechanical strength, kg/cm2, not less
− average
− minimum
6 Extrudetes size, mm:
− diameter
− lenght
7 Catalytic properties:
activity − acetic acid conversion, %, not less
Values
0,3
0,1
0,1
6,0
0,9
2,5
45
25
8-10
9-11
90,0
56
A-601MT
CATALYST in REGENERATED FORM
TC 2172-038-46693103-2007
A-601MT catalyst in regenerated form is designed for butyl aldehydes hydrogenation to butyl alcohols.
A-601MT catalyst consists of copper, zinc, chrome oxides and promoters.
Parameter
1 Appearance
2 Granules size, mm:
− diameter, within
− height, within
3 Catalyst components (on dried at 110 ºС basis), wt %:
− zinc oxide ZnO, not less
− copper oxide CuO, within
− chrome oxide Cr2O3, within
4 Packed density, kg/dm³, within
5 Mechanical strength
- destructive force at crushing along generatrix, MPa, not less
6 Particles less than 2,5 mm, wt %, not more
7 Water removed at 100-110 oC, wt %, not more
8 Activity - butyl aldehydes conversion, wt %, not less
Values
tablets
5,0±0,5
5,0±1,0
50,0
10,0-14,0
19,0-25,0
1,2-1,8
2,4
5
5,0
97
57
APK-2A
CATALYST
TC 2178-031-46693103-2006 with am.1-2
APK-2A catalyst is used for nitric acid manufacturing off-gases treating from
nitrogen oxides.
The process is providing at gas mixture temperature 400-750 oC,
LHSV=22000 h-1 and CH4/O2 ratio = 0,55 ÷ 0,6.
Parameter
1 Appearance
2 Granules size, mm, within:
− diameter
− height
3 Palladium content (on dry basis), wt %, within
4 Packed density, kg/dm³, within
5 Content of fines and defected granules, wt %, not more
6 Mechanical strength
- destructive force at crushing along generatrix, kg/cm2,
not less:
− average
− minimum
7 Specific surface area, m²/g, not less
8 Water content, wt %, not more
9 Activity:
− impurities volume concentration in treated gas, %, not
more:
− NO + NO2
− СО
at temperatures 540-5900С
Values
Granules of от yellowish-brown to
dark-brown color
12±1
12±1
1,8-2,0
1,0-1,3
7
35
20
4
3,0
0,005
0,30
58
IKA-33-3
ALKYLATION CATALYST
TC 2174-054-46693103-2010 with am.1
IKA-33-3 catalyst is designed for phenyl-amine catalytic alkylation with methanol for methyl-aniline production.
IKA-33-3 catalyst is made of capper and aluminum oxides.
Parameter
1 Appearance
1* Granules size, mm, within:
− diameter
− height
2 CuO content (on calcined at 800 oC basis), wt %,
within
3 Packed density, kg/dm³, within
4 Mechanical strength
- destructive force at crushing along generatrix, MPa,
not less:
5 Particles less than 2,5 mm, wt %, not more
6 Water content, wt %, not more
8 Specific surface area, m²/g, within
Values
Grade
Grade
А
Б
Tablets
5,0±0,5
3,0±0,5
5,0±1,0
3,0±0,5
40-44
0,6-1,0
2,5-3,5
2
5
100-180
59
KDC-10
CATALYST
TC 2173-050-46693103-2010
KDC-10 catalyst is designed for following processes:
- дегидрирования вторичных циклических спиртов;
- second cyclic alcohols dehydrogenation;
- butyrates decomposition.
The promoted with calcium oxide special activated zinc oxide and calcium carbonate are included into the catalyst composition.
There are three grades of KDC-10 catalyst depending on composition (KDC10-1, KDC-10-2, KDC-10-3).
Parameter
1 Appearance
2 * Granules size, mm, within:
− diameter
− height
3 Catalyst components (on calcined at 800 ºС basis), wt %, not
less:
− zinc oxide ZnO
− calcium oxide CaO
4 Packed density, kg/dm³, within
5 Calcination losses at 800 0С, wt
%, not more
6 Mechanical strength
- destructive force at crushing
along generatrix, MPa, not less:
7 Specific surface area, m²/g, not
less
8 Catalytic properties in dehydrogenation of cyclohexanol to cyclohexanon process, not less:
- activity
- selectivity
Values
KDC-10-1
KDC-10-2
KDC-10-3
Tablets of cylindrical shape
5,0±0,5
5,0±0,5
10,0±1,0
10,0±1,0
10,0±1,0
10,0±1,0
90,0
---1,2-1,8
80,0
10,0
1,2-1,8
70,0
20,0
1,2-1,8
10,0
15,0
20,0
2,0
2,5
2,5
25
20
20
75
98
77
98,5
80
98,5
* - In coordination with user manufacturing of other standard sized catalysts is assumed
60
PROTECTIVE BED CATALYSTS
FOR-1 FORECONTACT
TC 2163-023-46693103-2006 with am.1, 2
FOR-2 FORECONTACT
TC 2177-022-46693103-2006 with am.1, 2
FOR-1 and FOR-2 forecontacts are used as a protective catalyst beds in different units of petroleum processing and petrochemical plants.
Depending on granules shape there are two grades of FOR-1 and FOR-2 forecontacts: rings (K grade) or riffled rings (RK grade).
FOR-1 and FOR-2 forecontacts are made of aluminium oxide.
Hydrogenating components – molybdenum and nickel oxides are dispersed
over external and internal surfaces of aluminium oxide granules of FOR-2.
Parameter
Values
К
FOR-1
1 Appearance
2 Granules size *, mm:
− external diameter, within
− external diameter maximum, within
− external diameter minimum, within
− internal diameter, not less
− height, within
3 Packed density, kg/dm³, within
4 Mechanical strength
- destructive force at crushing on edge, MPa,
not less:
5 Content of fines and defected granules, wt %,
not more
6 Catalyst components (on calcined at 800 ºС basis),
wt %, not less:
− molybdenum trioxide (MoO3), not less
− nickel oxide NiO, not less
7 Calcination losses at 550 0С, wt %, not more
RK
FOR-2
Rings
FOR-1
FOR-2
Riffled rings
16-20
−
−
4
16-20
1,7
16-20
−
−
4
16-20
1,7
−
15-19
13-17
4
16-20
1,2
−
15-19
13-17
4
16-20
1,2
10
12
12
12
5
5
5
5
−
−
−
3
1,5
3
−
−
−
3
1,5
3
61
ACTIVE ALUMINIUM OXIDE – CARRIER FOR CATALYSTS
TC 2163-004-04610600-2003 with am.1
Active aluminium oxide is used as a carrier for different catalysts and prodused
in fluorinated and non-fluorinated types.
Active aluminium oxide is extrudates of cylindrical shape.
1
−
−
−
Parameter
Impurities content, wt %:
ferrum, not more
sodium (on sodium oxide basis), not more
fluorine:
Values
0,020
0,025
марка А-64
марка А-56
марка И-62
2
3
4
5
6
7
8
Packed density, g/cm³, not more
Strength factor (average), kg/mm, not less
*Extrudates diameter, mm
Particles les than 1 mm, wt %, no more
Calcination losses at 850±10 0С, wt %, not more
Specific surface area, m²/g, not less
Total pore volume, cm3/g, no less
absence
0,32±0,05
3,5±0,5
0,80
1,05
2,8±0,2*
0,3
5,0
195
0,68
* - In coordination with user manufacturing of other standard sized exrudates is assumed
62
ACTIVE ALUMINIUM OXIDE – GASES DRIER
TC 2163-023-04610600-2003
Active aluminium oxide is used as gases drier.
Active aluminium oxide is extrudates of cylindrical shape of white, cream and
pink colors.
Parameter
1 Impurities content, wt %:
− ferrum, not more
− sodium (on sodium oxide basis), not more
− sulfur (on SO2 basis), not more
2 Packed density, g/cm³, not more
3 Strength factor, kg/mm, not less
− average
− minimum
4 Extrudates diameter, mm
5 Particles les than 1 mm, wt %, no more
6 Calcination losses at 850 0С, wt %, not more
7 Specific surface area, m²/g, not less
8 Total pore volume, cm3/g, no less
9 Static activity: adsorption of water vapors at air temperature
(20-25) ºС, grams of water per 100 g of adsorbent
- at relative humidly 10%, not less
- at relative humidly 60%, not less
Values
0,14
0,10
1,5
0,80
1,0
0,5
4,5±0,5
0,3
5,0
190
0,65
3,0
9,0
63
Beta (BEA) ZEOLITE (SODIUM and AMMONIUM FORMS)
STO 46693103-ПК-015-2008
Zeolite Beta is used for isomerization catalyst producing.
Parameter
1 Components (on calcined at 650 oC basis), wt %:
− sodium oxide, not more
− ferrum, not more
− aluminium oxide, not less
− silicon oxide, not less
2 SiO2/Al2O3 molar ratio, not less
3 Calcination losses at 650 0С, wt %, not more
4 Crystallinity, %, not less
Values
Ammonium
Sodium form
form
0,2
0,12
5,0
85
20
65
85
2,0
0,12
5,0
85
20
65
85
64
ZEOLITE CVM in AMMONIUM FORME
DK 04-21303-108-2007
Zeolite CVM is analog of zeolite ZSM-5
Parameter
Values
ZSM-5
1 Components (on calcined at 650 oC basis), wt %:
− sodium oxide, not more
− aluminium oxide, not more
2 Calcination losses at 650 0С, wt %, not more
3 Crystallinity, %, not less
0,14
6
55
85
65