INVESTIGATING WHICH REACTANT IS IN EXCESS Limiting Reagent Lab When a reaction occurs, an equation for the reaction can be written to indicate the chemical changes that are taking place. For example, you learned in a previous experiment that zinc reacts exothermically with hydrochloric acid to produce zinc chloride and hydrogen gas. Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g) + energy The balance equation indicates that on a microscopic level one atom of Zn reacts with two molecules of HCl to produce one molecule of ZnCl2 and one molecule of H2. This also means that one mole of Zn reacts with two moles of HCl to produce one mole of ZnCl2 and one mole of H2. When these two reactants are combined, the reaction will continue to occur until one reactant is used up. At this time the other reactant also may be used up. If not, the reactant that remains is said to be in EXCESS, because more of that reactant was present than the amount required to react. In this experiment, you will measure the amount of each reactant carefully and predict which reactant will be in excess. OBJECTIVES 1. to make careful measurements of the amounts of each reactant 2. to calculate the number of moles of each reactant 3. to predict which reactant is in excess 4. to relate macroscopic observations to microscopic events 5. to use drawings to relate microscopic events, to write chemical equations that represent those microscopic events MATERIALS APPARATUS test tube (18 x 150-mm) beaker (150-mL) balance forceps safety goggles lab aprons REAGENTS zinc pieces 3M HCl 1 PROCEDURE – Part 1 1. Put on your laboratory apron and safety goggles. 2. Determine the mass of a clean, dry 18- x 150-mm test tube and record your data on the Report Sheet. 3. Add one piece of zinc to the test tube and determine the mass of the test tube and zinc. Record your data on the Report Sheet. CAUTION: Hydrochloric acid is corrosive to skin, eyes, and clothing. When handling hydrochloric acid, wear safety goggles and lab apron. Wash spills and splashes off your skin and clothing immediately using plenty of water. Call your teacher. 4. Add between 5 and 20 mL of 3M HCl to the test tube and record the volume on the Report Sheet. 5. Record your observations on the Report Sheet. 6. Make a drawing of the test tube and its contents on the Report Sheet and label all the substances present. 7. Store the test tube in a beaker so it remains upright. 8. Before you leave the laboratory, wash your hands thoroughly with soap and water. PROCEDURE – Part 2 (the following day) 1. Put on your lab apron and safety goggles. 2. Observe your test tube and contents. Make a drawing of the test tube and label the contents. POST LAB DISCUSSION If you correctly predicted that zinc would be in excess, then there should be some solid zinc remaining in your test tube. If you correctly predicted there would be HCl in excess, then there should be no zinc remaining in the test tube. CALCULATIONS 1. Write a balanced chemical reaction in symbol form and use (s), (aq), (g), and (l), where appropriate to designate the state of each reactant or product. (include the heat term) 2. Calculate the mass of Zn added to the test tube. 3. Calculate the moles of Zn added to the test tube. 4. Calculate the volume of HCl added to the test tube. 5. Calculate the moles of HCl added to the test tube. 6. Based upon your macroscopic observations of the test tube and contents, tell which reactant was in excess. Explain your decision. 7. Predict, using mole relationships which reactant will be in excess. Show your DA work. 8. Do your macroscopic observations and your calculations confirm one another? Explain. 2