Supplementary Information Uniformly Connected Conductive Networks on Cellulose Nanofiber Paper for Transparent Paper Electronics Hirotaka Koga,* Masaya Nogi,* Natsuki Komoda, Thi Thi Nge, Tohru Sugahara and Katsuaki Suganuma *Corresponding author: H. Koga, M. Nogi The Institute of Scientific and Industrial Research, Osaka University 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan Phone: +81-6-6879-8521, Fax: +81-6-6879-8522 E-mail address: hkoga@eco.sanken.osaka-u.ac.jp; nogi@eco.sanken.osaka-u.ac.jp 1 100 Transmittance (%) Nanopaper 80 60 AgNW@nanopaper 40 20 0 200 300 400 500 600 700 800 Wavelength (nm) Figure S1 Specular transmittance as a function of wavelength for original nanopaper (solid line) and AgNW@nanopaper prepared by filtration coating (dotted line). Sheet resistance of the AgNW@nanopaper was 12 Ω sq.–1. 2 Transmittance (%) 100 AgNW [This work] ITO [1] Cu/Ti [2] CVD-grown Graphene [3] Reduced graphene oxide [4] CVD-grown SWNT [5] DWNT [6] SWNT [7] CuNW [8] PEDOT/PSS [9] 90 80 70 60 101 102 103 Sheet resistance (Ω sq-1) Figure S2 Transmittance versus sheet resistance for the state-of-the-art transparent conductive films. The AgNW@nanopaper prepared in this study offered sheet resistance of 12 Ω sq.–1 with optical transparency of 88% (red circle). This transparent conductive performance was superior to those of ITO prepared by sputtering (black circle, 50–300 Ω sq.–1, 90% [1]), Cu/Ti prepared by sputtering (black triangle, 16 Ω sq.–1, 86% [2]), CVD-grown graphene (blue circle, 30 Ω sq.–1, 90% [3]), reduced graphene oxide (blue triangle, 800 Ω sq.–1, 82% [4]), CVD-grown singlewalled carbon nanotube (SWNT) (green circle, 50 Ω sq.–1, 70% [5]), double-walled carbon nanotube (DWNT) prepared by dip coating (green triangle, 100 Ω sq.–1, 90% [6]), SWNT prepared by bar coating and photonic curing (green square, 68 Ω sq.–1, 89% [7]), CuNW prepared by bar coating (pink circle, 186 Ω sq.–1, 90% [8]), poly(3,4- ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT/PSS) prepared by spin coating (gray circle, 176 Ω sq.–1, 88% [9]). 3 References 1. Hu, L., Kim, H. S., Lee, J. -Y., Peumans, P., Cui, Y. Scalable coating and properties of transparent, flexible, silver nanowire electrodes. ACS Nano 4, 2955–2963 (2010). 2. Ghosh, D. S., Chen, T. L., Pruneri V. Ultrathin Cu-Ti bilayer transparent conductors with enhanced figure-of-merit and stability. Appl. Phys. Lett. 96, 091106 (2010). 3. Bae, S., Kim, H., Lee, Y., Xu, X., Park, J.-S., Zheng, Y., Balakrishnan, J., Lei, T., Kim, H. R., Song, Y. I., Kim, Y.-J., Kim, K. S., Özyilmaz, B., Ahn, J.-H., Hong, B. H., Iijima, S. Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nature Nanotech. 4, 574–578 (2010). 4. Wu, J., Agrawal, M., Becerril, H. A., Bao, Z., Liu, Z., Chen, Y., Peumans, P. Organic lightemitting diodes on solution-processed graphene transparent electrodes. ACS Nano 4, 43–48 (2009). 5. Ma, W., Song, L., Yang, R., Zhang, T., Zhao, Y., Sun, L., Ren, Y., Liu, D., Liu, L., Shen, J., Zhang, Z., Xiang, Y., Zhou, W., Xie, S. Directly synthesized strong, highly conducting, transparent single-walled carbon nanotube films. Nano Lett., 7, 2307–2311 (2007). 6. Mirri, F., Ma, A. W. K., Hsu, T. T., Behabtu, N., Eichmann, S. L., Young, C. C., Tsentalovich, D. E., Pasquali, M. High-performance carbon nanotube transparent conductive films by scalable dip coating. ACS Nano 6, 9737–9744 (2012). 7. Kim, Y., Chikamatsu, M., Azumi, R., Saito, T., Minami, N. Industrially feasible approach to transparent, flexible, and conductive carbon nanotube films: cellulose-assisted film deposition followed by solution and photonic processing. Appl. Phys. Express 6, 025101 (2013). 4 8. Rathmell, A. R., Wiley, B. J. The synthesis and coating of long, thin copper nanowires to make flexible, transparent conducting films on plastic substrates. Adv. Mater. 23, 4798–4803 (2011). 9. Kim, Y. H., Sachse, C., Machala, M. L., May, C., Müller-Meskamp, L., Leo, K. Highly conductive PEDOT:PSS electrodes with optimized solvent and thermal post-treatment for ITOfree organic solar cells. Adv. Funct. Mater. 11, 1076–1081 (2011). 5