West Lothian Council Lorna C. Webster 1 Chemical reactions revisited Read You already know that when some chemicals touch each other they can react to make new chemicals. This is called a chemical reaction. If a chemical reaction happens a new substance is always made and we might see: A change in colour - for example a rusting car A gas being made – for example a rotting egg A solid being made – for example milk turning sour Heat or light being given out or used up – for example any kind of burning eg. coal, wood, petrol, paper etc. Sometimes a solid is made when two clear solutions are mixed. This solid has a special name – it is called a precipitate. Your teacher may show you a video of chemical reactions (SS11) Write a heading and try the work below. 1. What is always made in a chemical reaction? 2. Give an example of a) a reaction where you might see a colour change. Lorna C. Webster 2 b) c) a reaction where you might notice a gas being made. a reaction where a solid forms from a liquid but not by freezing. d) a reaction that gives out heat. 3. What is the special name for a solid that is made when two solutions are mixed? 4. Copy the table below Substances added what I saw together Indigestion powder + vinegar Sulphuric acid + copper Sodium carbonate + cobalt chloride Copper sulphate + zinc Sulphuric acid + magnesium Barium chloride + sodium sulphate chemical reaction? Collect experiment card 1.20 and do the experiments. Fill in your table as you go along. Lorna C. Webster 3 Telling if a gas has been made Read It is sometimes difficult to tell if a gas has been made in a reaction but we know a gas has been made if: We see bubbles made in a solution. We can see it. We can smell it. We can use a test for it. Write a heading and try the work below. 1. Make a list of that ways that we can tell if a gas has been made in a reaction. 2. Copy the table below. What I heated what happened chemical reaction? Collect experiment card 1.21, do the experiments and fill in your table. NB Use pyrex test tubes for heating. 3. In one of your experiments the glowing splint relit. What does this tell you about the gas that was made? Lorna C. Webster 4 Telling if there is an energy change Read Sometimes the only way to tell if a chemical reaction has happened is if there is an energy change. We can use a thermometer to check if heat is being made or used up. Write a heading and try the work below. 1. Copy the table below and fill it in as you do experiment 1.22. What I added together what happened chemical reaction? 2. What type of energy has been made in these reactions? 3. Apart from the heat energy that is made, what other type of energy is made when substances burn? (hint: think about sitting in a room with no lights on but with a fire burning.) Everyday chemical reactions Read Lots of changes take place in the world around us but it is not always easy to decide whether these changes involve a chemical reaction or not. Think about freezing water. The water changes in to ice but the ice is still water but in the solid state. No new substance is formed so freezing is not a chemical reaction. Boiling water is also not a chemical reaction because the Lorna C. Webster 5 steam that is made is just water. No new substance has been made. Baking a cake, however, is a chemical reaction because the substances we add together like flour, butter, eggs, milk and sugar are changed into new substances. Write a heading and try the work below 1. Why is freezing or boiling water not a chmeical reaction? 2. Is melting ice a chemical reaction? Explain your answer. 3. Collect the sheet called “everyday chemical reactions?” and complete it before you stick it into your jotter. Lorna C. Webster 6 The speed of chemical reactions Read Some reactions go faster than others. An explosion is an extremely fast reaction, making toast is a reaction that happens in minutes while a car rusting or a body rotting will take years. Your teacher might demonstrate some reactions for you (demo 1.24). Write a heading and try the work below. 1. Copy the table below and complete it by ticking the correct boxes. Chemical reaction Reaction speed slow hydrogen exploding a car rusting a cake baking coal burning crude oil forming firing caps in a toy gun Lorna C. Webster 7 medium fast Particle size and the speed of reactions Read The speed of a reaction can be affected by using different sizes of particles. Your teacher will demonstrate some reactions for you (demo 1.25): Burning magnesium ribbon and magnesium powder. Burning and iron nail and iron powder. Burning normal sugar and icing sugar. Write a heading and try the work below. 1. Collect experiment card 1.26, do the experiment then answer the questions below. a) What did your see that told you a chemical reaction happened when you added the tablet to the acid? b) How did you know which reaction was the fastest? c) Make a list of two things you did to make sure the two experiments were fair. d) Copy and complete the sentence below. The __________ the particles the __________ the reaction. 2. Which will burn faster - small pieces of coal or large lumps of coal? 3. Which will burn faster - a wooden log or sawdust? 4. Which will cook faster - small potatoes or large potatoes? Lorna C. Webster 8 5. Dr Webster was running late and wanted her barbecue to light quickly. She had a choice between using charcoal lumps or broken pieces of charcoal she found at the bottom of an old bag of charcoal. Which would be the best to use and why? 6. Explain why it can be extremely dangerous to light a match in an icing sugar factory but not so dangerous in a sugar lump factory. Temperature and the speed of reactions Read The temperature of chemicals can affect how fast they will react together. Watch your teacher demonstrate how to do the next experiment before you start. measuring cylinder Hydrochloric acid beaker Sodium thiosulphate The time for the reaction can be measured by timing how long it takes for the cross to disappear. Lorna C. Webster 9 Collect experiment card 1.27 and do the experiment. Then write a heading and try the work below. 1. What was the aim of the experiment (what were you trying to find out)? 2. How did you measure the time for the reaction? 3. Draw a diagram of the experiment. 4. How did you change the temperatures? 5. Design a table for your results with two headings. 6. What is your conclusion (what did you find out)? 7. Make a list of at three things you did to make sure that the three experiments you did were fair. 8. Copy and complete the sentence below. The ________ the temperature the __________ the reaction. 9. Where would food rot faster - in a fridge or in a freezer? 10.Where do plants grow faster - in a greenhouse or outside? 11. Explain your answer to question 2. 12.Sarah carried out an Temperature(C) time for all of experiment to compare the metal to be the speed of the reaction used up (sec) 0 78 of a metal with some 20 45 acid. Her results are 40 23 shown in the table below. 60 10 a) Copy the table of results into your jotter. b) Copy and complete the sentences below As the temperature increases, the time for the metal to be used up _________________. As the temperature increases the reaction gets ____________________. Lorna C. Webster 10 Concentration Read Before we learn about how concentration can change the speed of reactions we need to understand what the concentration of a solution is. The concentration of a solution tells us about how much solid has been dissolved in water. The amount of the solid is measured is not measured in weight but it is measured in units called moles. Just like time is measured in units called minutes, concentration is measured in units called moles per litre. If one mole of salt is dissolved in one litre of water we say it has a concentration of 1 mole per litre. One mole of salt Salt solution, concentration = 1 mole per litre One litre of water If two moles of salt is dissolved in one litre of water we say it has a concentration of 2 moles per litre. Lorna C. Webster 11 The more salt dissolved in the water the greater the concentration of the solution. The concentration of all solutions can be measured in moles per litre eg the acid you used in the last experiment had a concentration of 1 mole per litre. A solution that has a concentration of 2 moles per litre is more concentrated that a solution that has a concentration of 1 mole per litre. To turn a concentrated solution into a dilute one we can add water. Write a heading and try the following work in your jotter. 1. What does the concentration of a solution tell us? 2. What units is concentration measured in? 3. Describe how you would make a salt solution that has a concentration of 2 moles per litre. You may use a diagram if you wish. 4. Copy and complete the sentence below. The more salt dissolved in the water the _________________ the concentration. 5. Which solution is the most concentrated? A 1 mole per litre B 3 moles per litre 6. Which solution is the most dilute? A 4 moles per litre B 2 moles per litre Lorna C. Webster 12 7. What would you add to a concentrated acid if you wanted to dilute it? 8. If water is added to an acid will the concentration of the acid be higher or lower? Concentration and the speed of reactions Read The concentration of a solution can change the speed of a reaction. Collect the experiment card called PPA 2, do the experiment and write any results as notes into your jotter. Then Write a heading and try the work below. 1. What was the aim of the experiment (what were you trying to find out)? 2. How did you know when all of the magnesium had reacted? 3. How was the concentration of acid changed? 4. Design a table for your results with two headings. 5. What is your conclusion (what did you find out)? 6. Make a list of at two things you did to make sure that the three experiments you did were fair. 7. John did this experiment but each time he dropped the magnesium in it floated and was not all covered by the acid. What would this do to the time for the reaction to happen? 8. Copy and complete the sentence below. The ________ the concentration the __________ the reaction. Your teacher may ask you to complete a PPA assessment sheet now. Lorna C. Webster 13 Continue your work by trying the questions below 1. A pupil did three experiments in different concentrations of acid - 1 mole per litre acid, 2 moles per litre acid and 3 moles per litre acid. a) which reaction would be fastest b) explain you answer to question 1a 2. Copy the diagrams below which show an experiment with an acid and zinc metal. B A 1 mole per litre acid 10C zinc powder 1 mole per litre acid 10C zinc lump C 1 mole per litre acid 20C zinc powder a) Which two experiments would you set up to compare the effect of particle size on the speed of a reaction? b) Which two experiments would you set up to compare the effect of temperature on the speed of a reaction? c) Which reaction would be faster - B or C? Explain your answer. Lorna C. Webster 14 Catalysts Read Another way to speed up a chemical reaction is to use a chemical called a catalyst. A catalyst speeds up a reaction but is not used up so it can be used over and over again. Your teacher may demonstrate (demo 1.29) a reaction where a catalyst can be used to speed up a reaction to make oxygen. Glowing splint Glowing splint Hydrogen peroxide Hydrogen peroxide + catalyst Write a heading and try the work below 1. What is the name of a chemical that can be used to speed up a chemical reaction? 2. Why is it possible to use a catalyst more than once? 3. Copy a diagram of the demonstration that you saw and add bubbles where you say them. 4. What happened to the glowing splint in the experiment without the catalyst? Lorna C. Webster 15 5. What happened to the glowing splint in the experiment with the catalyst? 6. What does this tell you about the name of the gas that is made in the reaction? 7. Which reaction made the gas the fastest? 8. Your teacher used 1g of catalyst in the second experiment. a) How much catalyst would there be after all of the solution had reacted? b) How could you separate the catalyst from the solution to use it again? 9. Copy the sentences below. Use of catalysts Catalysts are often used in motor car exhaust systems. The part of the exhaust that contains the catalyst is called a catalytic convertor. The catalytic convertor changes harmful and poisonous gases into safer ones that can go out into the air. Lorna C. Webster 16 Enzymes Read An enzyme is the scientific word for a catalyst that is found in living things. Enzymes have many important uses in industry: Your teacher may show you a vidoe about enzymes (SS16) Enzymes can help make jeans look faded. Enzymes can be used to remove stains. Enzymes can be used to make foods eg bread, beer, cheese and fruit juice. Write a heading and try the work below 1. What is the special name for a catalyst that can be found in living things? 2. List some uses of enzymes in industry. You are now going to do an experiment using an enzyme called pectinase to make apple juice. Lorna C. Webster 17 Collect experiment card 1.30 and follow the instructions on the sheet. Then continue with the work below. 1. What was the only difference between your two experiments? 2. Make a list of two factors you had to make sure you kept the same to keep the experiment fair. 3. Copy the diagram from the instruction card 1.30 part 7 and label it with the following labels: apple sauce + pectinase filter funnel apple sauce + water filter paper clamp stand measuring cylinder 4. Draw a line on the measuring cylinders in your diagram to show how much juice was in each cylinder? 5. What is the process called that you used to separate the juice from the solid apples? 6. Which experiment produced the most juice? 7. We did the same experiment last year but we used apples that had been cut up into quarters. What effect do you think this would have on the speed that we collected the juice? 8. Why do you think factories that make fruit juice buy pectinase? Lorna C. Webster 18 9. Read the passage below Cellulose is the name of an enzyme that is used to make jeans look more faded. Yeast contains an enzyme called zymase which changes sugars into alcohol for drinks. Protease is the name of an enzyme that is added to detergent powders to assist the removal of stains from clothes. To make meat more tender an enzyme called papain is added. The enzyme called pectinase is used to make fruit juices. Miss a line and then split the information in the passage into two lists. Give each list a heading and then draw in lines to turn your headings and lists into a table. Lorna C. Webster 19 10. Use the information in the passage below to copy and complete the flow diagram. protein s Key = chemical = enzyme The proteins in the food we eat contain large molecules and before we can make use of them, we must break them down into much smaller molecules called amino acids. The breakdown starts in the stomach where the enzymes, pepsin and trypsin convert the proteins into peptides. The peptides move into the small intestine and using enzymes called peptidases break down into small amino acids. Lorna C. Webster 20 Word equations Read A word equation is a short way to write down what happens in a chemical reaction. There is set of rules for writing equations. 1. Draw an arrow in the middle of a line. 2. Write the names of the chemicals we start with on the left of the arrow separated by + signs. 3. Write the names of the chemicals that are made on the right of the arrow separated by + signs. Look at the example below. When methane reacts with oxygen the new substances that are made are water and carbon dioxide. The word equation for this reaction will be: Methane + oxygen water + carbon dioxide It is better to write the names of chemicals on two lines like carbon dioxide in the example above) to make sure that the chemicals are on the correct sides of the arrow. The chemicals we start with are called reactants (methan and oxygen). The chemicals we make are called products (water and carbon dioxide) Lorna C. Webster 21 Write a heading and try the work below. 1. What is a word equation? 2. What side of the arrow do the reactants go on? 3. What side of the arrow do the products go on? 4. The sentences below tell you about some chemical reactions. Copy each sentence and underneath it write a word equation for the reaction. a) When calcium reacts with oxygen a new substance called calcium oxide is made. b) When copper reacts with chlorine a new substance called copper chloride is formed. c) When iron reacts with fluorine a new substance called iron fluoride is made. d) Magnesium chloride is made when magnesium reacts with chlorine. e) Sodium bromide is made when sodium reacts with bromine. f) When aluminium is added to hydrochloric acid two new substances are made. The new substance are called aluminium chloride and hydrogen. g) Sodium hydroxide and hydrogen are made if sodium is added to water. h) Petrol burns in oxygen to make carbon dioxide and water. i) Sugar burns in oxygen to give carbon dioxide and water. Lorna C. Webster 22 j) If mercury oxide is heated it can be turned into mercury and oxygen. 5. Copy and complete the table below to show the reactants and the products for each of the reactions you did for question 1. The first one has been done for you. reaction a reactants calcium and oxygen b c d e f g h i j Lorna C. Webster 23 products calcium oxide