1 Chemical reactions revisited Read You already know that when some chemicals touch each other they can react to make new chemicals. This is called a chemical reaction. If a chemical reaction happens a new substance is always made and we might see: A change in colour - for example a rusting car A gas being made – for example a rotting egg A solid being made – for example milk turning sour Heat or light being given out or used up – for example any kind of burning eg. coal, wood, petrol, paper etc. Sometimes a solid is made when two clear solutions are mixed. This solid has a special name – it is called a precipitate. Your teacher may show you a video of chemical reactions (SS11) Write a heading and try the work below. 1. In a chemical reaction a n___ s___________ is always made. 2 2. Give an example of a) a reaction where you might see a colour change is ___________________________ b) a reaction where you might notice a gas being made is ___________________________ c) a reaction where a solid forms from a liquid but not by freezing is _____________________________. d) a reaction that gives out heat is _______________ _____________. 3. The special name for a solid that is made when two solutions are mixed is a P___________ 4. Complete the table below while doing experiment 1.20 Substances added what I saw together Indigestion powder + vinegar Sulphuric acid + copper Sodium carbonate + cobalt chloride Copper sulphate + zinc Sulphuric acid + magnesium Barium chloride + sodium sulphate 3 chemical reaction? (Y/N) Telling if a gas has been made Read It is sometimes difficult to tell if a gas has been made in a reaction but we know a gas has been made if: We see bubbles made in a solution. We can see it. We can smell it. We can use a test for it. Try the work below. 1. Make a list of the 4 ways that we can tell if a gas has been made in a reaction. (i) (ii) (iii) (iv) ____________________________ ____________________________ ____________________________ ____________________________ 2. Collect experiment card 1.21, do the experiments and fill in 4 your table. NB Use pyrex test tubes for heating. What I heated what happened chemical reaction? 3.In one of the experiments the glowing splint relit. This tells me that the gas made was oxygen/nitrogen. Telling if there is an energy change Read Sometimes the only way to tell if a chemical reaction has happened is if there is an energy change. We can use a thermometer to check if heat is being made or used up. Write a heading and try the work below. 1. Look at the table below and fill it in as you do experiment 1.22. What I added together what happened chemical reaction? 2. The type of energy made in these reactions was _________. 3. Apart from the heat energy that is made, the other type of energy made when substances burn is __________? (hint: 5 think about sitting in a room with no lights on but with a fire burning.) Everyday chemical reactions Read Lots of changes take place in the world around us but it is not always easy to decide whether these changes involve a chemical reaction or not. Think about freezing water. The water changes in to ice but the ice is still water but in the solid state. No new substance is formed so freezing is not a chemical reaction. Boiling water is also not a chemical reaction because the steam that is made is just water. No new substance has been made. Baking a cake, however, is a chemical reaction because the substances we add together like flour, butter, eggs, milk and sugar are changed into new substances. Write a heading and try the work below 1. Freezing or boiling water not are not chemical reactions because __________________________________. 2. Is Melting ice a chemical reaction? Yes/No. 3. Collect the sheet called “everyday chemical reactions?” and complete it before you stick it into your jotter. 6 The speed of chemical reactions Read Some reactions go faster than others. An explosion is an extremely fast reaction, making toast is a reaction that happens in minutes while a car rusting or a body rotting will take years. Your teacher might demonstrate some reactions for you (demo 1.24). Try the work below. 1. Complete the table below by ticking the correct boxes. Chemical reaction Reaction speed slow medium fast hydrogen exploding a car rusting a cake baking coal burning crude oil forming firing caps in a toy gun Particle size and the speed of reactions 7 Read The speed of a reaction can be affected by using different sizes of particles. Your teacher will demonstrate some reactions for you (demo 1.25): Burning magnesium ribbon and magnesium powder. Burning and iron nail and iron powder. Burning normal sugar and icing sugar. Try the work below. 1. Collect experiment card 1.26, do the experiment then answer the questions below. a) When I added the tablet to the acid I knew a reaction had occurred because b _______ were formed. b) I knew which reaction was the fastest because ___________________________. c) Two things I did to make sure the two experiments were fair were _________________________________ _________________________________________ d) Copy and complete the sentence below. The __________ the particles the __________ the reaction. 2. Which will burn faster - small pieces of coal or large lumps of coal?________________________ 3. Which will burn faster - a wooden log or sawdust? ______________________ 8 4. Which will cook faster - small potatoes or large potatoes? __________________________________ 5. Dr Webster was running late and wanted her barbecue to light quickly. She had a choice between using charcoal lumps or broken pieces of charcoal she found at the bottom of an old bag of charcoal. Which would be the best to use and why? ____________________________ ______________________________________________ ______________________________________________ 6. It can be extremely dangerous to light a match in an icing sugar factory but not so dangerous in a sugar lump factory because the smaller icing sugar particles react faster/slower than the larger sugar lumps. Temperature and the speed of reactions Read The temperature of chemicals can affect how fast they will react together. Watch your teacher demonstrate how to do the next experiment before you start. measuring cylinder Hydrochloric acid beaker The time for the reaction can be measured timing how long Sodium by thiosulphate it takes for the cross to disappear. 9 Collect experiment card 1.27 and do the experiment. Then write a heading and try the work below. 1. The aim of the experiment (what were you trying to find out) was___________________________________________ 2. I measured the time for the reaction by using a _________. 3. I changed the temperatures by _____________________. 4. Complete he table below with your results. time for the cross to dissapear(sec) Temperature(C) 5. In conclusion I can say the higher/lower the temperature the faster the reaction. 6. The three things I did to make sure that the three experiments you did were fair were (i) (ii) (iii) 7. Complete the sentence below. The ________ the temperature the __________ the reaction. 8. Food rot faster in a fridge/freezer. 9. Plants grow faster in a greenhouse /outside. 10.Explain your answer to question 9. _______________________________________________ 10 11. Sarah carried out an experiment to compare the speed of the reaction of a metal with some acid. Her results are shown in the table below. Temperature(C) time for all of the metal to be used up (sec) 0 78 20 45 40 23 60 10 Copy and complete the sentences below As the temperature increases, the time for the metal to be used up _________________. As the temperature increases the reaction gets ____________________. 11 Concentration Read Before we learn about how concentration can change the speed of reactions we need to understand what the concentration of a solution is. The concentration of a solution tells us about how much solid has been dissolved in water. The amount of the solid is measured is not measured in weight but it is measured in units called moles. Just like time is measured in units called minutes, concentration is measured in units called moles per litre. If one mole of salt is dissolved in one litre of water we say it has a concentration of 1 mole per litre. One mole of salt Salt solution, concentration = 1 mole per litre One litre of water If two moles of salt is dissolved in one litre of water we say it has a concentration of 2 moles per litre. 12 The more salt dissolved in the water the greater the concentration of the solution. The concentration of all solutions can be measured in moles per litre eg the acid you used in the last experiment had a concentration of 1 mole per litre. A solution that has a concentration of 2 moles per litre is more concentrated that a solution that has a concentration of 1 mole per litre. To turn a concentrated solution into a dilute one we can add water. Write a heading and try the following work in your jotter. 1. The concentration of a solution tell us how much _______ has been dissolved. 2. Concentration measured in m______ p___ l________. 3. Describe how you would make a salt solution that has a concentration of 2 moles per litre. You may use a diagram if you wish. 4. Copy and complete the sentence below. The more salt dissolved in the water the _________________ the concentration. 5. Which solution is the most concentrated? (circle the answer) A 1 mole per litre B 3 moles per litre 13 6. Which solution is the most dilute? (circle the answer) A 4 moles per litre B 2 moles per litre 7. You would add ________ to a concentrated acid if you wanted to dilute it. 8. When water is added to an acid the concentration of the acid will be higher/lower. Concentration and the speed of reactions Read The concentration of a solution can change the speed of a reaction. Collect the experiment card called PPA 2, do the experiment and write any results as notes into your jotter. Then Write a heading and try the work below. 1. The aim of the experiment (what were you trying to find out) was ________________________________________ 2. I knew when all of the magnesium had reacted because ___________________________. 3. The concentration of acid was changed by adding w______. 4. My conclusion (what I found out) was ______________________________________________ ______________________________________________ 5. Two things I did to make sure that the three experiments you did were fair were ______________________________________________ ______________________________________________ 6. John did this experiment but each time he dropped the magnesium in it floated and was not all covered by the acid. This meant that reaction time was faster/slower because all of the metal was not covered. 14 7. Copy and complete the sentence below. The ________ the concentration the __________ the reaction. Your teacher may ask you to complete a PPA assessment sheet now. Continue your work by trying the questions below 1. A pupil did three experiments in different concentrations of acid –(A)1 mole per litre acid, –(B)2 moles per litre acid and– (C) 3 moles per litre acid. a) Reaction ___ would be fastest 2. This is due to ______________________________________________ ______________________________________________ 3. Look atthe diagrams below which show an experiment with an acid and zinc metal and answer the questions on the next page. B A 1 mole per litre acid 10C zinc powder 1 mole per litre acid 10C zinc lump 15 C 1 mole per litre acid 20C zinc powder a) The two experiments you would set up to compare the effect of particle size on the speed of a reaction are __ & __. b) The two experiments you would set up to compare the effect of temperature on the speed of a reaction are __ & __. c) Which reaction would be faster - B or C? This is due to _________________________________________. Catalysts Read Another way to speed up a chemical reaction is to use a chemical called a catalyst. A catalyst speeds up a reaction but is not used up so it can be used over and over again. Your teacher may demonstrate (demo 1.29) a reaction where a catalyst can be used to speed up a reaction to make oxygen. Glowing splint Glowing splint Hydrogen peroxide Hydrogen peroxide + catalyst 16 Try the work below 1. The name of a chemical that can be used to speed up a chemical reaction is a ________________. 2. It possible to use a catalyst more than once because catalysts are n__ u_____ up. 3. Draw a diagram of the demonstration that you saw and add bubbles where you say them. 4. In the experiment without the catalyst the glowing splint did/did not relight. 5. In the experiment with the catalyst the glowing splint did/did not relight. 6. This tell you that the name of the gas that is made in the reaction is o_________. 7. The reaction which made the gas the fastest was the one with/without the catalyst. 8. Your teacher used 1g of catalyst in the second experiment. a) How much catalyst would there be after all of the solution had reacted? __________________ b) To separate the catalyst from the solution to use it again you would f_________ it. 17 9. Copy the sentences below. Use of catalysts Catalysts are often used in motor car exhaust systems. The part of the exhaust that contains the catalyst is called a catalytic convertor. The catalytic convertor changes harmful and poisonous gases into safer ones that can go out into the air. 18 Enzymes Read An enzyme is the scientific word for a catalyst that is found in living things. Enzymes have many important uses in industry: Your teacher may show you a vidoe about enzymes (SS16) Enzymes can help make jeans look faded. Enzymes can be used to remove stains. Enzymes can be used to make foods eg bread, beer, cheese and fruit juice. Write a heading and try the work below 1. What is the special name for a catalyst that can be found in living things? 2. List some uses of enzymes in industry. 19 You are now going to do an experiment using an enzyme called pectinase to make apple juice. Collect experiment card 1.30 and follow the instructions on the sheet. Then continue with the work below. 1. The only difference between your two experiments was _______________________________ _______________________________ 2. Two factors you had to make sure you kept the same to keep the experiment fair were using the same a__________ of apple sauce and same v_________ of liquid. 3. Copy the diagram from the instruction card 1.30 part 7 and label it with the following labels: apple sauce + pectinase filter funnel filter paper measuring cylinder apple sauce + water clamp stand 4. Draw a line on the measuring cylinders in your diagram to show how much juice was in each cylinder? 20 5. The process that I used to separate the juice from the solid apples was called ________________________________. 6. The experiment which produced the most juice was _____________________________________________. 7. We did the same experiment last year but we used apples that had been cut up into quarters. This meant that the speed that we collected the juice was faster/slower. 8. Factories that make fruit juice buy pectinase because _________________________________________. 9. Read the passage below Cellulose is the name of an enzyme that is used to make jeans look more faded. Yeast contains an enzyme called zymase which changes sugars into alcohol for drinks. Protease is the name of an enzyme that is added to detergent powders to assist the removal of stains from clothes. To make meat more tender an enzyme called papain is added. The enzyme called pectinase is used to make fruit juices. 21 Now complete the table using the information. Name of Enzyme Use of Enzyme 22 10. Use the information in the passage below to complete the flow diagram. protein s Key = chemical = enzyme The proteins in the food we eat contain large molecules and before we can make use of them, we must break them down into much smaller molecules called amino acids. The breakdown starts in the stomach where the enzymes, pepsin and trypsin convert the proteins into peptides. The peptides move into the small intestine and using enzymes called peptidases break down into small amino acids. 23 Word equations Read A word equation is a short way to write down what happens in a chemical reaction. There is set of rules for writing equations. 1. Draw an arrow in the middle of a line. 2. Write the names of the chemicals we start with on the left of the arrow separated by + signs. 3. Write the names of the chemicals that are made on the right of the arrow separated by + signs. Look at the example below. When methane reacts with oxygen the new substances that are made are water and carbon dioxide. The word equation for this reaction will be: Methane + oxygen water + carbon dioxide It is better to write the names of chemicals on two lines like carbon dioxide in the example above) to make sure that the chemicals are on the correct sides of the arrow. The chemicals we start with are called reactants (methan and oxygen). The chemicals we make are called products (water and carbon dioxide) 24 Write a heading and try the work below. 1. A word equation is a short way to ___________________________________________ 2. The reactants go on on the ________ of the arrow. 3. The products go on the __________ of the arrow. 4. The sentences below tell you about some chemical reactions. Underneath each sentence write a word equation for the reaction. a) When calcium reacts with oxygen a new substance called calcium oxide is made. ____________________________________________ b) When copper reacts with chlorine a new substance called copper chloride is formed. _____________________________________________ c) When iron reacts with fluorine a new substance called iron fluoride is made. _____________________________________________ d) Magnesium chloride is made when magnesium reacts with chlorine. _____________________________________________ e) Sodium bromide is made when sodium reacts with bromine. ______________________________________________ f) When aluminium is added to hydrochloric acid two new substances are made. The new substance are called aluminium chloride and hydrogen. _______________________________________________ g) Sodium hydroxide and hydrogen are made if sodium is added to water. _______________________________________________ h) Petrol burns in oxygen to make carbon dioxide and water. 25 i) Sugar burns in oxygen to give carbon dioxide and water. _______________________________________________ j) If mercury oxide is heated it can be turned into mercury and oxygen. _______________________________________________ 5. Complete the table below to show the reactants and the products for each of the reactions you did for question 1. The first one has been done for you. reaction a reactants calcium and oxygen b c d e f g h i j 26 products calcium oxide