Compound Writing Review Worth 20 Test Points. Assignment: Where necessary, put in the symbol, the oxidation number/charge, the subscripts, and the name. For every multiple of 7, you must calculate the molar mass of the compound. You must be able to know the names of an element given its symbol. This includes the first 18, all of the alkaline metals, alkaline earths, and the halogens. This also includes Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Ag, Cd, Sn, Pt, Au, Hg, Pb, and U. Naming Rule 1: The first element in a compound, the cation (the positive one), keeps its name. Elements that have negative oxidation numbers/charges have names that end in “ide” when they are in compounds. They are Carbide, Nitride, Oxide, Fluoride, Phosphide, Sulfide, Chloride, Selenide, Bromide, Telluride, Iodide, and Astatide. This rule ALWAYS applies. Naming Rule 2: Metals with more than one positive oxidation number/charge will have the positive oxidation number/charge given to you. In the name you must add a roman numeral equal to the oxidation number/charge. For example Co3+. In a compound with Sulfur, Co2S3, its name is Cobalt III Sulfide. Naming Rule 3: Non-metals that can have positive oxidation numbers/charges will have the positive oxidation number/charge given to you. In the name you must add prefixes equal to the subscripts. For example S6+. In a compound with Fluorine, SF6, its name is Sulfur Hexafluoride. The first element never uses the prefix mono and carbon never uses a prefix in these kinds of compounds. Hydrogens added to common polyatomic ions have the charge of +1 and reduce the negative charge of the ions as follows: H1+ and CO32– = HCO31– Hydrogen Carbonate. H1+ and PO43– = HPO42– Hydrogen Phosphate. 2 H1+ and PO43– = H2PO41– Dihydrogen Phosphate. H1+ and SO42– = HSO41– Hydrogen Sulfate. You need to memorize the polyatomic ions in the chart below, the names, the symbols, and the charge. Ion Name Ammonium Hydronium Symbol NH41+ H3O+1 Ion Name Chromium III Iron III Lead III Symbol Cr3+ Fe3+ Pb3+ Ion Name Acetate Chlorite Cyanide Dihydrogen Phosphate Hydrogen Carbonate 1+ Copper I Cu Silver Mercury I Ag1+ Hg22+ Lead IV Tin IV Pb4+ Sn4+ Cadium II Cd2+ Fluoride F1– Chromium II Cr2+ Chloride Cl1– Cobalt II Copper II Iron II Lead II Co2+ Cu2+ Fe2+ Pb2+ Bromide Iodide Br I–1 1– Oxide O2– Bromate Chlorate (Bicarbonate) Hydrogen Sulfate (Bisulfate) Hydroxide Hypochlorite Nitrate Nitrite Symbol CH3COO1– C2H3O21– BrO31– ClO31– Symbol CO32– CrO42– Cr2O72– HPO42– ClO21– CN1– H2PO41– Ion Name Carbonate Chromate Dichromate Hydrogen Phosphate Oxalate Peroxide Sulfate HCO31– Sulfite SO32– Phosphate Arsenate PO43– AsO43– C2O42– O22– SO42– HSO41– OH1– ClO1– NO31– NO21– Manganese II Mercury II Nickel II Tin II Zinc II Mn2+ Hg2+ Ni2+ Sn2+ Zn2+ Sulfide S2– Nitride Phosphide N3– P3– Carbide C4– ClO41– Permanganate MnO41– Perchlorate I. For numbers 1-160, use either the given oxidation number/charge or use the table of group numbers and oxidation numbers to assemble the molecule with subscripts. If the atom does not have an oxidation number, you need to give it an oxidation number based on the table below. Name the compound. For every 7th problem (bold faced and underlined) calculate the molar mass. II. For numbers 161-256, change the names into symbols. Put in oxidation numbers or charges (polyatomic ions have charges) and assemble the molecule with subscripts. For every 7th problem (bold faced and underlined) calculate the molar mass. 1 2 13 14 15 16 17 18 1+ 2+ 3+ 4+ 2+ 33+ 5+ 22+ 4+ 6+ 11+ 3+ 5+ 7+ 0 Group Oxidation # Li Sn4+ Ba Al Ti4+ NH4+ Fe3+ Pb2+ ClO3–1 S AsO43– SO32– N Br 1 9 17 25 2 10 18 26 3 11 19 27 4 12 20 5 13 6 21 28 BrO3– ClO2–1 O 33 41 34 49 50 Fe2+ Ag+ Be Pb4+ Na Ni3+ Sn2+ Co3+ 3+ P N3+ P5+ C2+ 43 51 42 57 NO3 CO3 35 58 –1 2– 59 –1 2– ClO–1 7 SO42– 29 22 30 15 23 31 8 16 24 32 CH3COO-1 PO43– P Cr2O72– 36 44 52 37 45 53 38 46 54 39 47 55 40 48 60 61 62 63 PO43– 64 C2O42– ClO3–1 SO4 14 2– 56 O22– OH CO3 65 66 67 68 69 70 71 72 73 81 89 74 82 90 75 83 76 77 84 92 79 87 95 80 88 96 C2H3O2–1 CrO42– 98 91 NO2–1 85 93 78 86 94 HPO42– OH–1 CN–1 ClO4–1 MnO4–1 99 100 101 102 103 104 107 115 108 116 109 117 110 118 111 112 113 106 114 119 120 121 122 123 124 125 127 128 F Cl S Te N I 129 137 130 138 131 139 132 Se 133 126 Br 140 141 134 142 135 143 136 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 97 105 Cobalt III Silver (+1) Antimony (+5) Sulfur (+4) Potassium Nickel II Tin IV Chromium VI Barium Iron II Gallium Zinc (+2) Nitrite Chromate Arsenate Chlorite Iodide Hydrogen Carbonate Cyanide HypoChlorite 161 169 162 170 163 171 164 172 165 166 173 174 167 175 168 176 177 185 178 186 179 180 187 188 181 189 182 190 183 191 184 192 Acetate Hydroxide Dihydrogen Phosphate Sulfide Phosphate Perchlorate Permanganate 193 194 202 196 204 197 205 198 206 199 207 200 201 195 203 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 Chlorate Carbonate Oxide Sulfate Phosphate Nitrate Peroxide 225 Chloride 226 227 228 229 230 231 232 233 241 234 242 235 236 243 244 237 245 238 246 239 247 240 248 249 250 251 252 253 254 255 256 Oxalate 208