NCEA Level 1 Chemistry (90648) 2010 — page 1 of 4 Assessment Schedule – 2010 Chemistry: Describe properties and reactions of carbon and its compounds (90648) Evidence Statement Q Evidence Achievement ONE (a) Sugars such as glucose (also fructose and sucrose) are converted into energy, ethanol and carbon dioxide. Yeasts perform the fermentation process under anaerobic conditions (without oxygen). THREE of: Identifies the reactants (sugar and yeast) for the fermentation process or identifies the requirements (anaerobic) for the fermentation process. Glucose ethanol + carbon dioxide gas + energy C6H12O6 2C2H5OH + 2CO2 + energy (c)(i) (ii) ethanoic acid (or acetic acid) Methanol reacts with oxygen in both types of combustion. Complete combustion requires plenty of oxygen, producing carbon dioxide and water. Incomplete combustion occurs when there is insufficient oxygen present for complete combustion to occur, and produces carbon (or soot) / carbon monoxide and water. CH3OH + 3 O2 CO2 + 2H2O 2 Or 2CH3OH + 3O2 2CO2 + 4H2O (iii) Achievement with Excellence Identifies the reactants OR requirements for the fermentation process. Identifies the reactants AND requirements for the fermentation process. AND AND Both structural formulae correctly drawn. Both structural formulae correctly drawn. AND EITHER AND Links both complete and incomplete combustion reactions to the products formed AND writes a balanced equation for the complete combustion of methanol. Links both complete and incomplete combustion reactions to the products formed AND writes a balanced equation for the complete combustion of methanol. OR AND Explains ONE way carbon dioxide impacts on the environment. Eg: increased levels of CO2 trap heat causing the greenhouse effect which has led to global warming. Discusses TWO ways carbon dioxide impacts on the environment. Eg: increased levels of CO2 trap heat causing the greenhouse effect which has led to global warming and has caused sea levels to rise with melting ice caps. Draws the structural formula for ethanol. (b)(i) (ii) Achievement with Merit The part carbon dioxide plays in environmental processes. Photosynthesis Green plants convert carbon dioxide and water into food compounds, such as glucose, and oxygen. This process is called photosynthesis. The food and oxygen made are used by all living things for respiration. Influence of carbon dioxide on alkalinity Carbon dioxide can change the pH of water. Carbon dioxide dissolves slightly in water to form a weak acid called carbonic acid-CO2 + H2O H2CO3 Identifies and draws the structural formula for ethanoic acid. Identifies requirements for each type of combustion. Identifies complete and incomplete combustion products. Writes a balanced equation for the complete combustion of methanol Identifies an effect that CO2 has on the environment. NCEA Level 1 Chemistry (90648) 2009 – page 2 of 4 pH can drop from 7 to 5.5 In the atmosphere Greenhouse gases absorb some of the heat from the sun and trap it so that the earth is warmed up. This process is commonly known as the greenhouse effect. Carbon dioxide is a major greenhouse gas. Increasing amounts of this have added to the greenhouse effect and is known as global warming. This may cause increases in storm activity, melting of polar ice caps, which will cause flooding of the continents etc. Complete combustion CO and C soot from incomplete combustion have detrimental health effects on humans (CO poisoning/haemoglobin and asthma from soot). CO2 is not as toxic and more energy efficient. NCEA Level 1 Chemistry (90648) 2009 – page 3 of 4 TWO (a) Structures: TWO of: EITHER: Structure of diamond is drawn or described. Structure of graphite is drawn or described. Diamonds are made up of atoms covalently bonded in a 3-dimensional structure. Unlike graphite, diamond has no weak intermolecular forces that are easily broken. ONE relevant property of each of diamond and graphite is identified. Links the relevant properties (hard / strong) of diamond to its structure and use in microbearings Demonstrates an understanding of how the structure of diamond determines the properties (hard / strong won’t break) that make it useful in micro-bearings. OR Links the relevant properties (layers slide/weak forces) of graphite to its structure and use as a lubricant. Graphite is made up of layers of covalently bonded carbon atoms. The layers are held together by weak intermolecular forces. (b) Diamonds are made up of atoms covalently bonded in a 3-dimensional structure to form a giant network. Unlike graphite, diamond has no weak intermolecular forces that are easily broken. Since the covalent bonds are very strong and take a lot of energy to break. This means that diamonds are extremely hard and durable so can be used in microbearings even as very small balls. They work in the same way that steel ball bearings work by reducing the friction that occurs between moving parts and preventing them from getting damaged. Graphite is made up of layers of covalently bonded carbon atoms which form a giant network. The layers are held together by weak intermolecular forces. These are easily broken when pressure is applied or as parts move over each other and reform when the movement stops. This allows graphite to be used as a dry lubricant that reduces friction between moving parts. (Note: If state weak forces due to delocalised electrons merit only) AND Demonstrates an understanding of how the structure of graphite determines the properties (layers slide / weak intermolecular forces) that make it a good lubricant. (Note: Covalent networks need only to be mentioned for one but can be implied for the other, eg layers.) NCEA Level 1 Chemistry (90648) 2009 – page 4 of 4 THREE Carbon dioxide dissolves in water in small amounts making the water slightly acidic as it forms carbonic acid, H2CO3. The pH of Lake Nyos will be less than 7. CO2 is less soluble at higher temps and as the lake is volcanic it may have heated up and therefore more gas was released. CO2 is a colourless odourless gas. When it was released from the lake, the people and animals living nearby would not have been able to see or smell it so wouldn’t know they were in danger. The gas is also more dense than air so would have stayed close to the ground, and flowed down the sides of the volcano, depriving people and animals of air so they would have died from suffocation / asphyxiation. Because carbon dioxide displaces oxygen, it is a health risk since we need oxygen to live. CO2 is an asphyxiant. It can cause headaches, drowsiness and loss of ability to maintain concentration. Describes TWO different properties of carbon dioxide gas. Eg, acidic or dense or colourless or odourless or slightly soluble. OR Describes ONE property and a symptom CO2 can cause in people. Eg, asphyxiant / death. Links TWO properties of carbon dioxide to an effect from the Case Study. Eg acidic when dissolved so lowers lake pH warmer water, more CO2 released as less soluble dense so flowed down mountain displacing oxygen odourless or colourless so wasn’t noticed. Discusses TWO effects of CO2 in the Case Study in terms of the relevant properties. Eg: acidic when dissolved so lowers lake pH as forms carbonic acid dense so flowed down mountain and displaced oxygen and caused suffocation odourless or colourless so wasn’t noticed so people couldn’t avoid it. OR AND Links ONE property of carbon dioxide to an effect from the Case Study. AND Discusses why carbon dioxide has a dangerous impact on human (or animal) health. Eg, asphyxiant / death. Explains why carbon dioxide has a dangerous impact on human (or animal) health. Eg, asphyxiant / death. Judgement Statement Achievement Achievement with Merit Achievement with Excellence 2A 2M 2E