AP Chemistry Memorization Quizzes AP Chemistry is a difficult course, most schools have students take it both fall and spring semesters. So, we will be starting at a disadvantage to some. AP Chemistry is not all about memorization; however, having these items memorized is essential for success in learning the concepts covered in the course. The quizzes will cover six areas of memorization: 1) Polyatomic Ions (including name, symbol and charge) 2) Variable valences for transition metals 3) Rules for naming acids 4) Rules for naming ionic compounds 5) The solubility rules 6) Determining oxidation numbers IF this seems like too much work for the next 15 weeks, please drop the course. Advanced Placement Chemistry is a college level course. You will need to be dedicated and work very hard if you are to be successful. Some 1) 2) 3) 4) things you may want to get to be successful in the class: In your textbook and look over chapters 1-7. Take notes. Pay attention in every class, and do your homework problems. Look on iFolder at the syllabus and other files (chapter Power Points are on here) Purchase your own copy of either 5 steps to a 5 on the AP: Chemistry or Cliffs AP Chemistry or Cliffs AP 5 Chemistry exams or The Princeton Review: Cracking the AP Chemistry exam. Rules for Naming and Acid When the name of the anion ends in –ide, the acid name begins with the prefix hydro-, the stem of the anion has the suffix –ic and it is followed by the word acid. -ide becomes hydro _____ic Acid Cl- is the Chloride ion so HCl = hydrochloric acid When the anion name ends in –ite, the acid name is the stem of the anion with the suffix –ous, followed by the word acid. -ite becomes ______ous Acid ClO2- is the Chlorite ion so HClO2 = Chlorous acid. When the anion name ends in –ate, the acid name is the stem of the anion with the suffix –ic, followed by the word acid. -ate becomes ______ic Acid ClO3- is the Chlorate ion so HClO3 = Chloric acid. Rules for Naming Ionic Compounds 1. Balance Charges (charges should equal zero) 2. Cation is always written first (in name and in formula) 3. Change the ending of the anion to -ide Solubility Rules 1. 2. 3. 4. 5. 6. All compounds containing alkali metal cations and the ammonium ion are soluble. All compounds containing NO3-, ClO4-, ClO3-, and C2H3O2- anions are soluble. All chlorides, bromides, and iodides are soluble except those containing Ag +, Pb2+, or Hg2+. All sulfates are soluble except those containing Hg2+, Pb2+, Sr2+, Ca2+, or Ba2+. All hydroxides are insoluble except compounds of the alkali metals, Ca 2+, Sr2+,and Ba2+. All compounds containing PO43-, S2-, CO32-, and SO32- ions are insoluble except those that also contain alkali metals or NH4+. Rules for Determining Oxidation Number Oxidation Number: A number assigned to an atom in a molecular compound or molecular ion that indicates the general distribution of electrons among the bonded atoms. 1. The oxidation number of any uncombined element is O. 2. The oxidation number of a monatomic ion equal the charge on the ion. 3. The more electronegative element in a binary compound is assigned the number equal to the 4. 5. 6. 7. 8. 9. charge it would have if it were an ion. The oxidation number of fluorine in a compound is always –1 Oxygen has an oxidation number of –2 unless it is combined with F, when it is +2, or it is in a peroxide, when it is –1. The oxidation state of hydrogen in most of its compounds is+1 unless it combined with a metal, in which case it is –1. In compounds, the elements of groups 1 and 2 as well as aluminum have oxidation number of +1, +2, and +3, respectively The sum of the oxidation numbers of all atoms in a neutral compound is O. The sum of the oxidation number of all atoms in a polyatomic ion equals the charge of the ion. Variable Valences For Transition Metals Name Chromium Cr +2 Stock Name Chromium (II) Mn +3 +2 Chromium (III) Manganese (II) Fe +3 +2 Manganese (III) Iron (II) Co +3 +2 Iron (III) Cobalt (II) Cu +3 +1 Cobalt (III) Copper (I) Pb +2 +2 Copper (II) Lead (II) Hg +4 +1 Lead (IV) Mercury (I) Sn +2 +2 Mercury (II) Tin (II) Au +4 +1 Tin (IV) Gold (I) Ag +3 +1 Gold (III) Silver Bi +2(rarely) +3 Silver (II) Bismuth (III) Sb +5 +3 Bismuth (V) Antimony (III) Cadmium Cd +5 +2 Antimony (V) Cadmium Zinc Zn +2 Zinc Manganese Iron Cobalt Copper Lead Mercury Tin Gold Silver Bismuth Antimony Symbol Charge Polyatmic Ions Name ammonium acetate bromate chlorate chlorite cyanide dihydrogen phosphate hypochlorite hydrogencarbonate(bicarbonate) hydrogen sulfate (bisulfate) hydrogen sulfite (bisulfite) hydroxide iodate nitrate nitrite perchlorate permanganate thiocyanate carbonate chromate dichromate oxalate selenate silicate sulfate sulfite phosphate phosphite Symbol NH4 C2H3O2 BrO3 ClO3 ClO2 CN H2PO4 ClO HCO3 HSO4 HSO3 OH IO3 NO3 NO2 ClO4 MnO4 SCN CO3 CrO4 Cr2O7 C2O4 SeO4 SiO3 SO4 SO3 PO4 PO3 Charge +1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -2 -2 -2 -2 -2 -2 -2 -2 -3 -3