Name: __________________________ Date: ___________________________ Flynt - ___Period ___th Grade Science Introducing Colloids In 1860, the Scottish chemist Thomas Graham discovered that certain substances (e.g., glue, gelatin, or starch) could be separated from certain other substances (e.g., sugar or salt) by dialysis (the movement of fluids through a semi-permeable membrane). He gave the name colloid to substances that do not diffuse through a semi-permeable membrane (like parchment, cellophane, or cell walls) and the name crystalloid to those substances which do diffuse and which are therefore a true solution. The Greek word for glue is kola, leading Graham to choose the name “colloid” for these glue-like substances (kola also appears as a root in other words like "protocol" and "collagen"). While Graham followed the conventional practice for scientific nomenclature, it’s a shame that such a cool phenomenon should receive such a dull name! So what makes a colloid different from a solution or a suspension? Again, the differences here are not nearly as exciting as the substances themselves. Remember that colloids are mixtures of pure substances. Colloidal particles are larger than molecules in a solution, but too small to be observed directly with a microscope; however, their shape and size can be determined by electron microscopy. In a true solution, the particles of dissolved substance are of molecular size (tiny, tiny) and are thus smaller than colloidal particles; in fact, in a solution, the particles of solute and solvent are approximately the same size and in the same phase and all particles can diffuse across the semi-permeable membrane. In a coarse mixture (e.g., a suspension) the particles are much larger than colloidal particles and settle over time due to gravity. Although there are no precise boundaries of size between the particles in mixtures, colloids, or solutions, colloidal particles are usually on the order of 10-7 to 105 cm in size. Classification of Colloids One way of classifying colloids is to group them according to the phase (solid, liquid, or gas) of the dispersed substance and of the medium of dispersion. A gas may be dispersed in a liquid to form a foam (e.g., shaving lather or beaten egg white) or in a solid to form a solid foam (e.g., Styrofoam or marshmallow). A liquid may be dispersed in a gas to form an aerosol (e.g., fog or aerosol spray), in another liquid to form an emulsion (e.g., homogenized milk or mayonnaise), or in a solid to form a gel (e.g., jellies or cheese). A solid may be dispersed in a gas to form a solid aerosol (e.g., dust or smoke in air), in a liquid to form a sol (e.g., ink or muddy water), or in a solid to form a solid sol (e.g., certain alloys). Properties of Colloids One property of colloid systems that distinguishes them from true solutions is that colloidal particles scatter light. If a beam of light, such as that from a flashlight, passes through a colloid, the light is reflected (scattered) by the colloidal particles and the path of the light can therefore be observed. When a beam of light passes through a true solution (e.g., salt in water) there is so little scattering of the light that the path of the light cannot be seen and the small amount of scattered light cannot be detected except by very sensitive instruments. The scattering of light by colloids, known as the Tyndall effect, was first explained by the British physicist John Tyndall. When an ultramicroscope is used to examine a colloid, the colloidal particles appear as tiny points of light in constant motion; this motion, called Brownian movement, helps keep the particles in suspension. Absorption is another characteristic of colloids, since the finely divided colloidal particles have a large surface area exposed. The presence of colloidal particles has little effect on the colligative properties (boiling point, freezing point, etc.) of a solution. Thixotropy Thixotropy is a property exhibited by certain gels, specifically the semisolid, jelly-like colloids. A thixotropic gel appears to be solid and maintains a shape of its own until it is subjected to a shearing (lateral) force or some other disturbance, such as the violent shaking from an earthquake. It then acts as a sol (a semifluid colloid – basically a semi-liquid) and flows freely. To see “solid” ground suddenly start flowing like a liquid can be quite shocking, especially if the liquefaction occurs beneath buildings. Thixotropic behavior is reversible, and when allowed to stand undisturbed, the sol slowly reverts to a gel. Common thixotropic gels include oil well drilling mud, ketchup, silly putty, and certain clays. Quick clay (or quick sand), which is thixotropic, has caused landslides in permafrost regions such as Scandinavia and Canada. Summary: