MATERIAL SAFETY DATA SHEET CHEMAT TECHNOLOGY, INC. 9036 Winnetka Avenue Northridge, CA 91324 (818) 727-9786, (818) 727-9477 FAX -----------------------------------------------IDENTIFICATION----------------------------------------------CHEMICAL NAME: Magnesium acetylacetonate dihydrate CATALOG NUMBER:M132 FORMULA: Mg(CH3COCHCOCH3)2.2H2O FORMULA WEIGHT: 222.53 (258.56) CAS #: 14024-56-7 CHEMICAL FAMILY: Metal acetylacetonate -------------------------------------HAZARDOUS INGREDIENTS--------------------------------------HAZARDOUS INGREDIENTS: % Title compound 100 ACGIH(TLV): No data OSHA/PEL: No data ------------------------------------------------PHYSICAL DATA----------------------------------------------APPEARANCE: Ivory white color crystals MELTING POINT: No data BOILING POINT: No data VAPOR PRESSURE: No data SPECIFIC GRAVITY: No data SOLUBILITY, WATER: 11g/l SOLUBILITY, TOLUENE: 0.1g/l SOLUBILITY, ETHANOL: 5g/l --------------------------------------------------FIRE HAZARD------------------------------------------------FLASH POINT: No data AUTOIGNITION TEMPERATURE:No data EXTINGUISHING MEDIA: Use only dry chemical, CO2. Liberates toxic gas under fire conditions. Do not use water. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (SCBA) and protective butyl rubber clothing to avoid skin and eye contact. UNUSUAL FIRE OR EXPLOSION HAZARDS: May generate toxic or irritating combustion products and magnesium oxide dust. -----------------------------------------------HEALTH HAZARD---------------------------------------------MODE OF ENTRY: INHALATION: Yes SKIN CONTACT: Yes EYE CONTACT: Yes INGESTION: Yes CARCINOGENCITY: NTP: Not known IARC: Not known OSHA: Not known 1 EFFECTS OF OVEREXPOSURE: INHALATION: Respiratory irritant. Inhalation or generated vapor may produce chemical pneumonitis, pulmonary edema and delayed scarring of the airway. SKIN CONTACT: Corrosive to skin. Toxic by skin absorption. Contact of this material with skin causes irritation and pain and may cause burn, necrosis and permanent injury. Product is readily absorbed through the skin and may cause nausea, headache and general discomfort. EYE CONTACT: Severe eye irritant. Contact of this material with eyes may cause severe irritation, burns, and pain. Burns of the eyes may cause blindness. Vapor generated from this material in air can cause lacrimation, conjunctivitis and corneal edema. INGESTION: Corrosive. Ingestion can cause severe damage to mouth and throat and may cause death unless treated promptly. EMERGENCY AND FIRST AID PROCEDURES: INHALATION: Remove the victim to fresh air and seek medical attention if coughing, shortness of breath or irritation persists. SKIN CONTACT: Wash the affected area with soap and water for at least 5 minutes. EYE CONTACT: Immediately flush eyes, including under eyelids, with large amounts of water for at least 15 minutes. Call a physician. INGESTION: Give the victim plenty of water and seek immediate medical attention. -----------------------------------------------REACTIVITY DATA-------------------------------------------STABILITY: Stable in normal conditions INCOMPATIBILITY: aldehydes, ketones, active hydrogen containing species, oxidizers, mineral, acids, bases, silicones, neoprene, paper and N-nitrosoamines. Many of them are known to be potent carcinogens and may be formed when the product is in contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations. HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2, magnesium oxide, and organic fumes HAZARDOUS POLYMERIZATION: None ---------------------------------ENVIRONMENTAL INFORMATION-------------------------------SPILL OR LEAKAGE PROCEDURES: Wearing full protective equipment, eliminate all sources of ignition. Cover spill with dry sand or vermiculite. Sweep up the mixture and dispose of properly. WASTE DISPOSAL: Consult state, local, or federal EPA regulations for proper disposal. ----------------------------------PROTECTION AND PRECAUTIONS-------------------------------VENTILATION REQUIREMENTS: Fume hood RESPIRATORY PROTECTION: NIOSH/MSHA approved respirator with an organic vapor cartridge. PROTECTIVE GLOVES: Rubber EYE/FACE PROTECTION: ANSI approved safety goggles HANDLING AND STORAGE: Handle and store the material under dry atmosphere. Keep away from heat. OTHER PRECAUTIONS:. Lab coat and apron, flame and chemical resistant coveralls, eyewash capable of sustained flushing, safety drench shower and hygienic facilities for washing. --------------------------------------------------------------------------------------------------------------------------The information herein is believed to be accurate and reliable as of the date compiled. However, Chemat Technology, Inc. makes no representation, warranty or guarantee of any kind with respect to the information on this data sheet or any use of the product based upon this information. DATE PREPARED: November 1997 2