Chapter 4 Problem Set. 2. You have a Fahrenheit thermometer in your left hand and a celcius thermometer in your right hand. Both thermometers show the same reading in degrees. What is the temperature? Answer: Relevant formulas: Tc = 5/9 (Tf – 32) Tf = 9/5*Tc + 32 You can use either formula and plug in Tc for Tf or vice versa. Using the first formula and substituting Tc for Tf: Tc = 5/9 (Tc – 32) Tc = 0.55*Tc – 17.8 .44*Tc = -17.6 Tc = -40.0C Using the second formula and substituting Tf for Tc: Tf = 9/5*Tf + 32 Tf = 1.8*Tf + 32 -.8Tf = 32 Tf = -40F 8. How much heat must be added to 1.5 kg of aluminum to raise its temperature from 20C to 200C? Relevant formula: Q = mcT [Heat transferred = (mass) X (specific heat) X (temperature change)]. We are given the mass of aluminum (1.5 kg), the temperature change (200C - 20C = 180C) and we can look up the specific heat of aluminum from Table 4-1 on pg 110 (0.92 kJ/kgC). Substituting into the formula: Q = mcT = (1.5 kg) X (0.92 kJ/kgC) X (180C) = 248.4 kJ = 2.48 X 105 J (joules) 12. A 2.0-kg brass monkey has a volume of 240 cm3. What is the density of the brass? Relevant formula: d = m/V (density = mass/volume) We are given the mass of the brass monkey (2.0 kg = 2,000 g) and we are given the volume of the brass monkey (240 cm3 ). Density is usually expressed as Kg/m3 or g/cm3. Since we’ve already changed kilograms into grams: d = m/V = (2000 g)/(240 cm3) = 8.33 g/cm3 24. The propellant gas that remains in an empty can of spray paint is at atmospheric pressure. If such a can at 20C is thrown into a fire and is heated to 600C, how many times atmospheric pressure is the new pressure inside the can? (The higher pressure may burst the can, which is why such cans should not be thrown into a fire.) The relevant formula here is: (p1V1)/T1 = (p2V2)/T2 (pressure1 X volume1)/temperature1 = (pressure2 X volume2)/temperature2 We are given pressure 1 (atmospheric pressure [1 atm]), temperature 1 (20C) and temperature 2 (600C). We also know that the volumes are equal in this case (the volume of the can. First, we can eliminate the volume factor from the equation. p1/T1 = p2/T2 We just need to rearrange the formula to solve for the new pressure. p2 = (p1/T1) X T2 = [(1 atm)/20C] X 600C = 30 atm 30. A total of 500 kJ of heat is added to 1 kg of water at 20C. What is the final temperature of the water? If it is 100C, how much steam, if any is produced? Relevant formulas: Q = mcT (heat added = mass X specific heat X temperature change) And Hv = heat of vaporization ( = amount of energy needed to convert 1 kilogram of a substance from a liquid into a vapor [ ie: water into steam]) We are given the overall amount of energy input (500 kJ), the mass of water (1 kg) and the change in temperature (100C - 20C = 80C). First we solve for the amount of energy needed to raise 1 kg of water by 80C: Q = mcT = 1 kg X 4.2 kJ/kgC X 80C = 336 kJ To find out how much energy we have left over, we subtract the energy required to raise the 1-kg of water from 20C to 100C (336 kJ) from our total energy input (500 kJ): Energy remaining = 500 kJ – 336 kJ = 164 kJ Hv for water is 2260 kJ/kg. To find the amount of water converted into steam, we set the total energy equal to the heat of vaporization X the mass of water that gets converted to steam. Energy = Hv X m Rearranging to solve for the mass of water converted to steam: m = Energy/Hv = (164 kJ)/(2260 kJ/kg) = 0.0726 kg = 72.6 g of water converted to steam 38. An engine that operates at the maximum efficiency possible takes in 1.0 MJ (megajoules = 106 joules) of heat at 327C and exhausts waste heat at 127C. How much work does it perform? From pg 137 we get the relevant formulas: Maximum efficiency = (work output)/(energy input) = Eff(max) And Eff(max) = 1 – Tcold/Thot We are given the energy input (1.0 MJ), the Tcold (127C = 400K), and the Thot (327C = 600K). Substituting in and solving for Eff(max): Eff(max) = 1 – Tcold/Thot = 1 - 400K/600K = 1 - .667 = 0.333 Now, rearranging the first formula to solve for the work output: Work output = Eff(max) X (energy input) = 0.333 X 1.0 X 106 J = 333,000 J or 333 kJ