MATERİAL SAFETY DATA SHEET
40406
1.1.Product Identifier
Product name: 40406
SECTİON 1:Identification of the substance/mixture and of the company
Company:
404 Kimya San. Ve Tic. A Ş
Address:
Merkez Mh. Akçe Sokak
Güzle İş Merkezi No:3 Kat: 1
Çekmeköy
İstanbul / TURKİYE
Web:
www.404.com.tr
Telephone:
+90 216 642 92 71
Fax:
+90 216 642 92 75
E-mail:
info@404.com.tr
SECTİON 2:Hazards identification
2.1.Classification of the substanca or mixture
2.1.1Classification
19999/45/EC
Main Hazards
Xi; R36/37/38
Irritating to eyes, respiratory system and skin.
SECTİON 3: Composition /Information on ingredients
3.1 Mixtures
67/548EEC / 1999/45/EC
Chemical name
Index no.
CAS no.
EINCS no.
REACH
Conc(&w/w)
Classification
Registration
Number
Ethyl-2-cyanoacrylate
607-236-00-9
7085-85-0
230-391-5
80-90%
Xi;R36/37/38
(ethyl cyanoacrylate)
1,4-dihydroxbenzene
604-005-00-4
123-31-9
204-617-8
0-0.1%
Carc. Cat 3;R40 Muta Cat 3;R68
Xn;R22 Xi;R41 R43 N;r50
SECTİON 4: First aid measures
4.1.Description of the first aid measures
Inhlation :
IMove the exposed person to fresh air. Seek medical attention if irritation or symptoms persist
Eye contact : Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical
attention. Seek medical attention if irritation or symptoms persist
Skin contact : Wash off immediately with plenty of soap and water.seek medical attention.Seek medical
attention if irritation or symptoms persist
ingestion:
DO NOT INDUCE VOMITING.If ingested,induce vomiting,but only under medical
supervision.see medical attention.
SECTİON 5: Firefighting measures
5.1.Extinguishing media:
Use extinguishing media appropriate to the surrounding fire conditions.
5.2.Special hazards arising from the substance or mixture:
Burning produces irritating, toxic and obnoxious fumes. Vapour may travel
considerable distance to source of ignitionand flash back.
5.3.Advice for firefighters:
Wear suitable respiratory equipment when necessary.
SECTİON 6: Accidental release measures
6.1.Personal precautions, protective equipmentand emergency procedures:
Evacuate personnel to a safe area. Keep personnel away from spill.
6.2.Envirolmental precautions:
Do not allow product to enter drains. Do not flush into surface water.
Prevent further spillage if safe.
6.3.Methods and material for containmentand cleaning up:
Absorb with inert, absorbent material. Sweep up. Transfer to suitable,
labelled containers for disposal.
SECTİON 7:Handling and storage
7.1.Precautions for safehandling:
Adopt best Manual Handling considerations when handling, carrying and
dispensing.Avoid contact with eyes and skin. Ensure adequate ventilation
of the working area Do not breathe gas/fumes/vapour/spray.Do not
eat,drink or smoke in areas where this product is used or stored. Do not
emptyinto drains. Open container carefully
7.2.Conditions for safe storage,including any incompatibilities:
Store in correctly labelled containers.Avoid contact
with: Oxidising agents. Avoid contact with: Direct
sunlight. Keep containers tightly closed Keep in a
cool, dry, well ventilated area
SECTİON 8:Exposure controls/personalprotection
8.1.Control parameters
8.1.1.Exposure limit values
1,4-dihydroxbenzene
Ethyl-2-cyanoacrylate
WEL 8-hr limit ppm:-
WEL 8-hr limit mg/m3: 0,5
WEL 15 min limit ppm: -
WEL 15 min limit mg/m3: -
WEL 8-hr limit ppm: -
WEL 8-hr limit mg/m3: -
WEL 15 min limit ppm: 0,3
WEL 15 min limit mg/m3: 1,5
8.2.Exposure controls
8.2.1.Appropriate engineering
controls
Ensure adequate ventilation of the working area
8.2.2.Individual protection measures Adopt best Manual Handling considerations when handling,
carrying and dispensing.Product clothing from contact with the
product.
Eye /face protection
Avoid contact with eyes. In case of splashing, wear:. Approved
safety goggles.
Skin protection/
Hand protection
Respiratory protection
Occupationel exposure
Butyl rubber gloves.Wash hands after handling the product.
Do not breathe gas/fumes/vapour/spray.In case of hypersensitivity
of therespirotorytract (e.g. asthmatics andthosewho suffer from
chronic bronchitis).It is unadvisableto work withthe product.Wear
suitable respiratory equipment.Suitble half mask respirator with
filter P2(EN 143).
Keep away from food, drink and animal feedingstuffs
controls
SECTİON 9:Physical and chemical properties
9.1.Information on basic physical and chemical properties
State:Liquid
Colour:Green
Odour:Characteristic
Flash point:>125
Viscosity :10-30mPa.s
Boiling point:>150
SECTİON 10:Stability and reactivity
10.2.Chemical stability
Stable under normal conditions. May polymerize
10.3.Possibility of hazardous reactions
Reacts violently with water.Strong bases.Amines. Oxidising agent.
10.4.Conditionsto avoid:
Heat. Direct sunlight.Moisture.Alkalis.
10.6.Hazardous decompositionproducts
Burning produces irritating, toxic and obnoxious fumes. Carbon oxides.
Nitrogen oxides.
SECTİON 11:Toxicological information
11.1. . Information on toxicological effects
Acute toxicity:
Skin corrosion/irritation
May cause allergic reactions in susceptible people.May cause irritation to
skin, eyes and mucous membranes.
Exposure above the recommended occupational exposure limit (OEL) may
cause adverse health effects.Inhalation may cause coughing,tightness of
the chest and irritation of the respiratory system.
Respiratory or skin
Sensitisation:
May cause sensitisation by inhalation skin contact
Germ cell mutagenicity
Reproductive toxcity
No mutagenic effects reported
No carcinogenic effects reported
No teratogenic effects reported
Repeated or prolonged
May cause allergic reactions in susceptible people.
Carcinogenicity
exposure
SECTİON 12:Ecological information
12.1.Toxicity
No data is available on this product
12.2.Persistence and degradability More than % 90 biodegradable
12.3.Bioaccumulative potential
No data is available on this product
12.4.Mobilityin soil
No data is available on this product
SECTİON 13:Disposal considerations
General information
Disposal methods
Dispose of in compliance with all local and national regulations. Do
not allow product to enter drains.
Dispose of in compliance with all local and national regulations
Dispsal of packaging
Empty containers can be sent to landfill after cleaning, if in
compliance with local and national regulations.Once the product
residues adhering to the walls of the containers have been rendered
harmless,the product and hazard labels must be invalidated.
SECTİON 14: Transport information
Hazard pictograms
14.1.UN number :
UN3334
14.2.UN roper shipping name
Proper shipping name:
AVIATION REGULATED LIQUID,N.O.S
14.3.Transport hazard class(es)
14.4.Packing group
ADR/RID
9
IMDG
9
Subsidiary risk
-
IATA
9
Subsidiary risk
-
-
14.5.Environmental hazards
Environmental hazards:
yes
Marine pollutant::
yes
Further information:
The product is not classifed as dangerous for carriage
ADR/RID
Hazard ID:
-
EmS code:
-
IMDG
IATA
Packing instruction(cargo)
906
Maximum quantity
220L
Packing instruction(passenger)
906
Maximum quantity
100L
SECTİON 15:Regulatory information
Labelling
Symbols
Xi: Irritant
Risk phrases
Safety phrases
R36/37/38 - Irritating to eyes, respiratory system and skin
S2-Keep out of the children
S24/25-Avoid contact with skin
S26-In case of contact with eyes,rinse immediately with plenty of water and seek
medical advice
Do not breathe vapour.
SECTİON 16:Other information
Other information
Revision
This document differs from the previous version in the following
areas
9 - 9.1. information on basic physical and chemical propertie
9 - 9.2. other infor
Text of risk phrases in section 3.
R22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin.
R36/38 - Irritating to eyes and skin.
R40-Limited evidence of a carcinogenic effect
R41 - Risk of serious damage to eyes
R43 - May cause sensitisation by skin contact.
R50 - Very toxic to aquatic organisms.
R68-Possible risk of irreversibleeffects.
Further information:
The information supplied in this Safety Data Sheet is designed only as guidance for
the safe use, storage and handling of the product. This information is correct to the
best of our knowledge and
belief at the date of publication however no guarantee
is made to its accuracy. This information relates only to the specific material
designated and may not be valid for such material used in combination with any
other materials or in any other process
.