Stain-Crete Black

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Material Safety Data Sheet
Increte Systems, Inc.
1611 Gunn Highway
Odessa, Florida 33556
(813)886-8811 Fax (813)886-0188
Emergency Only 1-800-424-9300 (CHEMTREC)
International
1-703-527-3887
Issue Date: 7/1/96 Rev.Date 7/1/00
Page 1 of 3
Section I – Identification
Product Name: Stain-Crete-Black
Classification:
Acidic solution of metal salts
D.O.T. Hazard Class:
Ingredient
Sodium Dichromate
Manganese Chloride
Hydrogen Chloride
Water
8, Corrosive Liquid, Acidic, Inorganic, N.O.S.,
(Contains Hydrochloric Acid), UN 3264, PG III
HMIS Rating
Health: 3
Flammability: 0
Reactivity: 1
Section II – Components
C.A.S.#
Wt.%
PEL
TLV
STEL
Notes
10588-01-9
10-20
.1 mg/m3
.05 mg/m3
See note 1.
7773-01-5
10-20
5 mg/m3
5 mg/m3
See note 1.
7647-01-0
3-5
5 ppm
5 ppm
See note 1.
7732-18-5
balance
not established
Note: Material is subject to SARA Title III, Section 313.
Section III – Physical Properties
Boiling Point: ~100 C (212 F)
Vapor Pressure: 17 mm Hg @ 68 F (20 C)
Melting Point: n.a.
Vapor Density: <1 Air = 1
Evaporation Rate: less than Butyl Acetate
Specific Gravity: 1.18-1.21
Water Solubility: 100%
Non-volatile: 20-30%
Physical Appearance: Dark brown or black solution, some sedimentation possible.
Flash Point: n.a.
Section IV – Fire and Explosion Hazard Data
Explosion Limits (LEL): n.a.
UEL: n.a.
Extinguishing Media: Not flammable, use extinguishing media appropriate for surroundings.
Hazardous Decomposition Products: Will give off corrosive HCl gas.
Firefighting Procedures: NIOSH/MSHA pressure-demand, self-contained breathing apparatus should be
used and full protective gear.
Special Fire & Explosion Hazards: Evolved HCl gas will react with metals to produce hydrogen gas,
which can react with air to form an explosive mixture.
Section V – Health Hazard Information
Primary Route(s) of Entry: Inhalation, skin contact, eye contact, and ingestion.
Suspect Carcinogens: Sodium dichromate (respiratory)
Effects of Acute Overexposure:
Eyes – Will cause burning, stinging, tearing, and redness. Can cause severe irritation and damage
to eyes with possible blindness if not treated immediately.
Skin – Exposure can cause irritation, redness, and burning. Chronic exposure can cause dermatitis.
Respiratory – Overexposure can cause difficulty with breathing and irritation of respiratory organs.
Prolonged or repeated exposure may cause ulceration and perforation of the nasal septum. Studies
indicate that long-term exposure to high levels of chromate mist is associated with increased levels
Stain-Crete Black MSDS, Page 2 of 3
of respiratory tract cancer in man, though no studies have indicated increased risk of lung cancer at
levels below the current TLV.
Ingestion – Burning of mouth and throat, nausea and gastro-intestinal irritation.
First Aid:
Eyes – Flush with large quantities of water immediately and get medical attention. Continue to flush
with water until a physician is available.
Skin – Remove contaminated clothing, flush exposed area with large amounts of water. If skin is
damaged or symptoms of irritation persist, seek medical attention.
Respiratory – Remove individual to fresh air immediately. Give oxygen for labored breathing. If
unconscious, begin artificial respiration. Seek medical attention.
Ingestion – DO NOT induce vomiting. Give individual several glasses of water or milk, keep
individual warm and quiet, and seek medical attention.
Section VI – Chemical Reactivity
Stability: Material is stable.
Hazardous Polymerization: Will not occur.
Incompatibility: Avoid metals, reducing agents, alkalis, oxidizers, and organic materials.
Conditions to Avoid: Excessive heat.
Hazardous Decomposition Products: Hydrogen chloride and chlorine fumes which may further react
with metals and other materials to produce explosive hydrogen gas or other toxic fumes.
Section VII – Spill Procedures
Small Spill: Neutralize with baking soda solution, absorb with inert material and discard.
Large Spill: Material will stain surrounding areas. Do not permit runoff. Neutralize unreacted acid with a
baking soda solution (when fizzing stops, neutralization is complete). Absorb with inert material or
use acid-resistant wet vacuum. Place contaminated materials in labeled containers and dispose.
Waste Disposal Method: Dispose of material in complaince with local, state and federal regulations.
Section VIII – Special Protection Information
Respiratory Protection: Wear approved acid-vapor respirator.
Ventilation: Use sufficient local exhaust as needed to maintain exposure below levels listed in Section II.
Gloves: Use acid-resistant gloves.
Eye Protection: Use splash-proof, chemical-resistant goggles.
Other Protective Equipment: Rubber boots and protective clothing are strongly advised. Emergency
eyewash, washing facilities and neutralizing solution should be available.
Section IX – Special Precautions
Handling and Storing: Store containers tightly sealed and upright in a cool, dry, well-ventilated area
away from combustible materials, heat, and incompatible materials. Protect containers from
damage. Do not reuse empty containers. Wash hands and exposed areas with soap and water.
Section X – Supplemental Information
The following materials are subject to the reporting requirement of SARA Title III, Section 313:
Sodium Dichromate (10588-01-9)
CERCLA Reportable Quantity = 10 lb
Hydrochloric Acid (7647-01-0)
CERCLA Reportable Quantity = 5000 lb
Manganese Chloride (7773-01-5)
Stain-Crete Black MSDS, Page 3 of 3
This information is provided in good faith and is correct to the best knowledge of Inco Chemical Company, Inc. Inco
Chemical Co., Inc. makes no representation as to its completeness or accuracy. Customers are encouraged to make
their own determination as to the suitability of this product for their purpose prior to use. Inco Chemical Co., Inc.
disclaims responsibility for damages of any kind resulting from the use of this information. No warranty of
merchantability, fitness for use, or any other warranty is expressed or is to be implied regarding the accuracy of these
data.
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