MATERIAL SAFETY DATA SHEET
LONE STAR SPECIALTIES, LLC
SECTION I:
PRODUCT INFORMATION
PRODUCT NAME: WD 2000™
1993
IMO NUMBER: UN 1993
CHEMICAL NAME: Not Applicable
PRODUCT NUMBER: N/A
DOT NUMBER: UN
C.A.S. NUMBER: Not Available
MOLECULAR WEIGHT: Not Applicable
MANUFACTURERS NAME: Lone Star Specialties, LLC.
ADDRESS:
6412 U.S. Highway 259 South
Lone Star, Texas 75668
SYNONYMS: PSR / 07, Coal Tar Oils
CHEMICAL FORMULA: Not Applicable
PRODUCT USE: Pavement Maintenance
EMERGENCY TELEPHONE NUMBER: (800) 424-9300 CHEMTREC
HEALTH: 3
FLAMMABILITY: 2
REACTIVITY: 0
SUPPLIER INFORMATION: Lone Star Specialties, LLC.
HAZARD CODE: (0=NONE; 1=SLIGHT; 2=MODERATE; 3=SEVERE; 4=EXTREME)
SECTION II:
HAZARDOUS INGREDIENTS
EXPOSURE LIMITS
CONCENTRATIONS
HAZARDOUS
INGREDIENTS
Coal Tar Pitch
(Including Coal
Tar Pitch
Volatiles)
C.A.S.#
(%)
OSHA PEL
ACGIH TLV
<50.0
0.2 mg/m3
TWA as
volatiles
Mixed Xylenes
Light Aromatic
solvent Naphtha
(see Section IX)
1330-20-7
< 5.0
100 ppm TWA
0.2 mg/m3
TWA as
volatiles
100 ppm
STEL 150
64742-95-6
< 25.0
100 ppm TWA
25 ppm
Naphthalene
91-20-2
< 2.0
10 ppm TWA
10 ppm;STEL15
Anthracene
120-12-7
<..4
0.2mg/m3 TWA
0.2mg/m3 TWA
Biphonyl
92-52-4
< 0.1
0.2 ppm TWA
0.2 ppm TWA
Pyrene
Benz(a)anthracene
129-00-0
56-55-3
< 1.5
<0.2 0.4
0.2mg/m3
Not
Established
0.2 mg/m3
Not
Established
65996-93-2
1
LD 50 (ORAL)
/ LC 50
*=Mouse All
Other = Rat
6200mg/kg; Not
Available
4300
mg/kg;5000ppm/4hr
Not Available;
Not Available
490mg/kg;340
mg/m3/1 h
>17,000mg/kg:
N/A
1900 mg/kg; >200
mg/m3
2700 mg/kg;
170mg/m3
Not Available
MATERIAL SAFETY DATA SHEET
LONE STAR SPECIALTIES, LLC
SECTION III:
PHYSICAL DATA
PHYSICAL STATE: SOLID LIQUID X GAS
pH Not Available
VAPOR PRESSURE @ 20C: Not Available
ODOR & APPREARANCE: Black liquid with a coal tar odor. FREEZING POINT: Not Available
SPECIFIC GRAVITY: <1.12@ 25 C.
SOLUBILITY (WATER): Negligible
ODOR THRESHOLD: Not Available DENSITY: Not Available EVAPORATION RATE: Not Available
VAPOR DENSITY: Not Available
MELTING POINT: Not Available BOILING POINT: Not Available
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not Available
VOC Content: < 340 g/l or 2.8 lbs/gal
SECTION IV:
REACTIVITY DATA
PHYSICAL (REACTIVITY) HAZARD WARNING: Not Applicable
STABLE: Yes IF NO, UNDER WHICH CONDITIONS:
INCOMPATABILITIES: None Known
REACTIVE: No IF YES, UNDER WHICH CONDITIONS:
HAZARDOUS DECOMPOSITION PRODUCTS: Not Applicable
SECTION V:
FIRE AND EXPLOSION HAZARDS
PHYSICAL HAZARD WARNING: Combustible Liquid SENSITIVITY TO > STATIC DISCHARGE YES:
MECHANCIAL IMPACT: No
FLAMMABLE: Yes IF YES, WHICH CONDITIONS: Flame, Sparks
FLASHPOINT (METHOD): 128ºF.
FLAMMABLE LIMITS (% BY VOL.): UEL: Not Available
LEL: Not Available
AUTO IGNITION TEMPERATURE: Not Available
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MATERIAL SAFETY DATA SHEET
LONE STAR SPECIALTIES, LLC
HAZARD COMBUSTION PRODUCTS: Irritating and/or toxic fumes may be released if this material
is burned.
MEANS OF EXTINCTION: Water fog, foam, carbon dioxide, dry chemical
UNUSUAL FIRE/EXPLOSION HAZARDS: Product will degas (generates flammable gas) when
heated. Closed containers may explode when exposed to extreme heat. Vapors are heavier than air may
travel along the ground, pit or sewer line to some distant source of ignition and flash back.
SPECIAL FIRE FIGHTING PROCEDURES: Wear complete fire service protective equipment,
including full-face MSHA/NIOSH approved self-contained breathing apparatus. Use water to cool fire
exposed container/structure/protect personnel. Toxic vapors may be given off in a fire.
SECTION VI:
TOXICOLOGICAL PROPERTIES
HEALTH HAZARD WARNINGS: Carcinogen, Irritant, Sensitizer
ROUTES OF ENTRY > SKIN CONTACT: X
SKIN ABSORPTION: X EYE CONTACT: X
INHALATION: X INGESTION: X
EFFECTS OF ACUTE EXPOSURE: Coal tar pitch vapors are irritating to the skin, eyes, and
respiratory tract. Direct skin contact with high vapor concentrations may cause burning and itching,
changes in pigmentation, and skin eruptions. Direct contact with the product may cause inflammation,
discomfort, conjunctivitis, and possible abrasion. In general, acute oral toxicity is assumed to be
moderate, but ingestion is not likely to be a primary route of exposure. Symptoms of systemic poisoning
after ingestion of other coal tar products include salivation, vomiting, respiratory difficulties, dizziness,
and headache, loss of papillary reflexes, cyanosis, hypothermia, and mild convulsions. It is assumed that
ingestion of this product would produce similar symptoms. The presence of solvents in this material may
lead to central nervous system effects with symptoms similar to those caused by systemic poisoning after
ingestion of coal tar. Symptoms include gastrointestinal irritation, nauseas, vomiting, and diarrhea.
IRRITANCY OF PRODUCT:
photosensitization
Minor skin irritant, SENSITIZATION TO PRODUCT: Causes
EFFECTS OF CHRONIC EXPOSURE: High vapor concentrations or chronic exposure to levels
above the TLV may lead to systemic symptoms (See acute oral toxicity symptoms). Prolonged or
repeated contact may lead to dermatitis and with poor hygienic practices, to skin cancer.
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MATERIAL SAFETY DATA SHEET
LONE STAR SPECIALTIES, LLC
CARCINOGEN: X REPRODUCTIVE EFFECTS :} BRIEF DESCRIPTION: Prolonged or repeated
contact, along with poor hygienic practices, may lead to cancer.
TERATOGENICITY: MUTAGENICITY
SYNERGISTIC MATERIALS: None Known
MEDICAL CONDITIONS AGGRAVATED: Persons with pre-existing skin disorders may be at
increased risk from overexposure. Exposure to vapors may aggravate pre-existing lung conditions.
SECTION VII:
FIRST AID MEASURES
SKIN: Wash exposed area twice with waterless hand cleaner, soap and water, or a mild detergent. Do
not use solvents on skin as they may promote absorption of this material. The exposed area should be
examined by medical personnel if irritation or pain persists after washing.
EYE: Flush eyes immediately with large amount of water for at least 15 minutes, occasionally lifting the
eyelids. GET MEDICAL ATTENTION.
INHALATION (BREATHING): Remove from exposure area to fresh air immediately. If breathing
has stopped, give artificial respiration. Keep affected person warm and rest. Give oxygen if respiration is
shallow. GET MEDICAL ATTENTION.
INGESTION: (SWALLOWING) if conscious, DO NOT induce vomiting, Give oxygen if respiration is
shallow. GET MEDICAL ATTENTION. Do not give anything by mouth to an unconscious person.
DECONTAMINTATION PROCEDURES: Use emergency shower if available. Remove all
contaminated clothing to prevent further absorption. Wash all clothing and exposed areas of the body
twice with soap and water. Leather shoes that have been saturated should be discarded.
SECTION VIII:
PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT: GLOVES (Impervious Rubber), FOOTWEAR: (Impervious Boots)
EYES: Chemical goggles or face shield where necessary.
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CLOTHING: (Impervious Suits)
MATERIAL SAFETY DATA SHEET
LONE STAR SPECIALTIES, LLC
RESPIRATOR: NIOSH approved half-face piece or full-face piece filter/chemical cartridge respirator
or full-face continuous flow, positive pressure air supplied respirator as necessary for protection from coal
tar pitch volatiles.
OTHER: Not applicable
PERSONAL HYGIENE PRACTICES: Contact lenses should not be worn when handling this
material. Do not smoke or eat in areas where this material is handled. Wash hands thoroughly before
eating or smoking. A complete soap and water shower should be taken at the end of each work day.
Contaminated work clothes should not be reworn until cleaned.
ENGINEERING CONTROLS: All operations should be conducted in well-ventilated conditions.
Local exhaust ventilation should be provided.
LEAK AND SPILL PROCEDURE: Remove all ignition sources. Ventilate area of spill or leak.
Release of solid material can be handled in the same manner as a coal spill. If hot liquid is spilled,
contain with suitable absorbent material (e.g. sand, earth, etc.) allow cooling, collecting material, and then
dispose of properly. Wear protective equipment during clean-up. After collection of material, flush area
with water.
WASTE DISPOSAL METHOD: Dispose of the material in accordance with standard practice for
disposal of potentially hazardous materials as required by applicable federal, state and local laws. Wear
protective equipment as necessary.
HANDLING PROCEDURES AND EQUIPMENT: Wear protective equipment when performing
maintenance on contaminated equipment. Protect containers against physical damage.
STORAGE REQUIREMENTS: Outside or detached storage is preferable. Inside storage should be in
standard flammable liquids storage room or cabinet if material is flammable or combustible.
SPECIAL SHIPPING INFORMATION: DOT DESCRIPTION:
BULK SHIPMENTS – Flammable Liquid, n.o.s., (Contains Coal Tar Pitch 50%), 3, UN 1993, PG III,
RQ (Benz (a) Anthracene).
NON BULK - Flammable Liquid, n.o.s., (Contains Coal Tar Pitch 50%), 3, UN 1993, PG III.
IMO: Flammable Liquid, n.o.s., 3.3, UN 1993, PG III, (Contains Coal Tar Pitch 50%), if in bulk, add
RQ, (Benz (a) Anthracene).
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MATERIAL SAFETY DATA SHEET
LONE STAR SPECIALTIES, LLC
SECTION IX:
ADDITIONAL COMMENTS
This product contains substances known by the State of California to cause cancer. Light Aromatic
Solvent Naphtha contains the following hazardous ingredients:
LD 50(ORAL) /
COMPOUND
CAS#
OSHA PEL
ACGIG TLV
LC50 (RAT)
1,2,45000 mg/kg;
Trimethylbenzene
95-63-6
25 ppm TWA
25 ppm TWA
18g/m ¾ hr.
100ppm; STEL4300 mg/kg; 5000
Mixed Xylenes
1330-20-7
100 ppm TWA
150 ppm
ppm / 4 hr.
50 ppm TWA
50 ppm TWA
1400 mg/kg;
Cumene
98-82-8
(Skin)
(Skin)
>8000ppm / 4 hr.
Hazardous Materials Guidebook Number: 128 (FMS # 3-07 Mfag# None)
SECTION 313 SUPPLIER NOTIFICATION > This product contains the following toxic chemicals
subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right to
Know Act of 1986 and of 40 CFR 372:
C.A.S. #
91-20-2
120-12-7
92-52-4
132-64-9
12-00-0
91-22-5
1330-20-7
95-63-6
98-82-8
CHEMICAL NAME
Naphthalene
Anthracene
Biphenyl
Dibenzofuren
Pyrene
Quinoline
Xylene
1, 2, 4-Trimethylbenzene
Cumene
%BY WEIGHT
< 2.0
< 0.4
< 0.1
< 5.0
< 1.5
0.5
< 10.0
< 8.0
< 0.5
Based upon the criteria set forth in Section 34 through 36 of the Controlled Products Regulation of
Canada, this product is classified as: Class D, Division 2, Subdivision A: Very Toxic Material
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MATERIAL SAFETY DATA SHEET
LONE STAR SPECIALTIES, LLC
PRECAUTIONARY STATEMENT: Personnel should avoid inhalation of vapors and personal
contact with compound. Do not get the compound in the eyes or skin. When handling, this compound
must be kept away from all sources of ignition. Have a respirator available. May be harmful if
swallowed or inhaled in large amounts. Please note that the information contained herein is furnished
without warranty of any kind. Users should consider these data only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of
information from all sources to assure proper use and disposal of these materials and the safety and health
of employees and customers.
SECTION X:
PREPARATION INFORMATION
Prepared By: Chris O. Smith
Phone Number: (800) – 256 - 2032
Date: January 15, 2010
Updated: May 1, 2011 added VOC content information Section III
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