SUPER SIX Research Statements
Nano-Particle Enhanced Composites
This topic aims to increase performance of light weight materials, such as organic
matrix composites and associated technologies through nanoparticles-enhanced resins,
fibers, interfaces, and any combination therein. Improving functionality, such as tailoring
electrical, electromagnetic, thermal, or ballistic characteristics, brings a number of
challenging issues. These include surface modification of nano-fillers which allow for
good dispersion and optimal efficiency in forming polymers.
A fundamental
understanding of the interface between the nanomaterial and matrix is necessary to
design the architectures capable of meeting aerospace specifications. Example goals
include electromagnetic compatibility (EMC) design requirements for spacecraft that
require < 2.5 mohm for the primary and secondary DC current return, and a surface
resistivity of < 106 to 108 ohms/square for electrostatic discharge (ESD) control. An RF
shield is desired to reduce internally generated radiated emissions to greater than 60 dB
from 200 MHz to 18 GHz. Structural retrofits are needed for blast resistance with rapid,
large area application approaches (spray, roll-on) involving nanoparticle composites that
exceed present 300%-500% elongations with tensile strengths of 2 ksi -7 ksi. Finally,
ultra-light weight personnel or aircraft armor for extremity or high value assets protection
is desired to resist fracture at velocities in excess of 850 m/s.
Adaptive and Responsive Materials
Responsivity and Adaptivity embody the ability to respond to an external stimulus in
a controlled, reproducible and reversible manner enabling temporal modulation of
physical properties. These triggering stimuli may be intentionally applied, such as by a
current pulse to drive actuation, or associated with a threshold exceeded by the
operation environment, such as local damage or heat. Natural (biological) systems
provide vital inspiration, concepts and approaches.
In general, these novel characteristics result from a combination of the following
three features derived from the nanoscale: (a) the strong non-linear dependence of
material response on the length scale of morphological features, (b) a drastic reduction
in the “critical” flaw size corresponding to the dominant morphological features, and (c)
extremely large surface or interfacial area that may be engineered to provide
responsiveness.
Scientifically, increased ability to control nanoparticle interface and 3D assembly /
organization is vital to the realization of these characteristics. For example, in addition
achieving dispersion, nanoparticle functionalization must optimize energy flow between
the particle and matrix as well as possibly provide a means to modulate this interaction.
So-called “multi-ferroic” characteristics necessitate macroscopic morphologies that are
non-isotropic, and even non-centrosymmetric. Critical to forwarding this area is an
increased coupling between experimental and computational modeling that can handle
hierarchical structures as well as extensive time scales.
Applications range from the large scale, such as morphing aircraft skins and
deployable mechanisms for satellite arrays and antennas, to the small scale, such as
controlling surface texture to modulate aerodynamic flow. Furthermore, marriages of
materials and structural design that enable non-rigid robotics, such as those that mimic
octopi, provide key capabilities for search & rescue and special operations. Finally,
these “smart systems” are enabled by many types of “smart” / “self-sensing” materials,
including compliant electrodes, piezo-resistive elastomers, photo-triggered actuators,
etc.
Nano Energetics
Energetic materials are compounds that exothermically release energy at an
extremely rapid or controllable rate in deflagration, detonation, or thermitic reactions
upon an initiation stimulus or input. They are critical for many AF applications, including
munitions, air-breathing propulsion, and spacelift. Nanotechnology has the potential to
provide revolutionary capabilities by using the energetic nanostructure to control the
reaction energies, products, and rates. For example, reactive metal particles have
shown promise in changing the reaction rates for munitions applications while
nanoparticle-fuel additives could provide capabilities in thermal transport, signature
control, efficiency, and reaction rates. Nanostructured propellants have the potential to
improve the specific impulse and efficiency of spacelift engines with significant
advantages in performance, safety, cost, and structural properties. Coupling of nanoenergetic materials with MEMS devices for controllable energy release is also of
interest. Design and search for synthetic techniques must be enhanced by realistic
modeling at both atomic (reaction heats and activation barriers) and mesoscale (particle
shape, morphology, and stabilization). Also of interest is the development of specific
small-volume analytical techniques.
Power Generation and Storage
Hybrid Nanomaterials for Multifunctional Power Generation and Storage
Nanoscience and technology approaches are being pursued to advance a
number of power technologies, such as solar cells; superconducting generator
windings, permanent magnets for power generation and utilization, power conditioning
devices;
energy
storage
devices;
and
energy
harvesting
through
thermoelectric/thermionic and piezoelectric means. Nanostructured materials exhibit
unique optical, mechanical, thermal, magnetic and electrical properties.
Novel
combinations of these properties will lead to otherwise unachievable performance. For
instance, nanoscale defects embedded in superconducting materials work to maintain
high current densities that are normally compromised in the presence of high magnetic
fields. These nanoscale defects immobilize the vortices generated by the magnetic
fields, thus allowing the current to flow without resistance. Expected benefits from these
systems include higher power conversion efficiencies of solar cells, higher power and
energy densities of next-generation batteries, lighter-weight alternatives to high energy
density capacitor systems, more efficient fuel cell systems and “self-powered” loadbearing structures with integrated energy harvest/storage capabilities.
These
approaches will enable new capabilities for the Air Force and will provide reduced cost
and size of power conditioning devices; enhanced safety and improved reliability of
batteries for ground, air and space; compact power for high power applications; higher
power for satellites, and dramatic improvements in system-level efficiency.
Sensors
Electromagnetic sensors
This topic includes development of quantum engineered materials and devices
for high performance sensing and communication. Materials and structures are
required which can be exploited to produce uncooled sensors for diagnostic and
surveillance applications, especially in conformal and flexible platforms with device or
wafer-level encapsulation schemes.
This topic also includes nanosensors embedded into multi-functional systems
and the associated problems with interfacing such nanometer-scale sensors to the
outside world. For example, materials utilizing quantum effects from electrons confined
in 1, 2, or 3 dimensions on scales of 100 nm or less offer new capabilities in optical
detector design and performance. Quantum based semiconductor materials can be
designed to selectively cover a large portion of the optical spectrum, from ultraviolet
wavelengths (10 to 400 nm) to very long infrared wavelengths (15 to 30 microns), which
can provide hyperspectral sensitivity and polarization selectivity. These materials could
potentially find uses in the cross over region from photon detection to electromagnetic
detection, which occurs at terahertz (THz) frequencies. Quantum confined materials
enable the ability to manipulate and enhance the optical, electrical, thermal, and noise
mechanisms to optimize device performance.
Also, in order to optimize sensor performance, it is necessary to consider system
architectures.
For active sensors, source and detector performance must be
considered as part of a coordinated sensing system. Narrowband tunable optical
sources will provide higher sensitivity for remote optical detection. Coherent detection
techniques, which can be implemented using nanostructured materials such as
metamaterials or using optoelectronic solutions in the terahertz regime, depend on the
use of a coupled source-detector combination.
Thermal Management
It is widely acknowledged that thermal management remains a critical but
generally unexplored issue as devices get smaller and the need for expelling heat and
managing small heat loads intensifies. A fundamental understanding must be gained
on thermal transport issues, such as moving, storing, switching, reusing and
transforming heat. This, in turn, leads to an investigation of the thermal conductivity and
emissivity of materials and devices where basic surface chemistry must be understood
to be able to thermally manage and design systems. One approach would include
multiscale modeling and simulation theory by verifying and validating models and I/O
impedance from level to level, atomistically and to system-to-systems. Scaling laws for
thermal management, such as the thermal continuum application at the nanoscale level,
must be considered. Similarly, the lower limit of thermodynamic size which one can
posit a thermo cycle must be established. Heat dissipation of > 2 Watts/in2 and chip
junction temperature < 125oC are desired in some high power microelectronics
applications. Nanofluid systems need to be operational in the temperature range from 40oC to 200oC. Also, thermoelectric targets from DARPA include higher efficiencies
(ZT > 2) at a broader operational temperature range (0oC-300oC) at which
nanocomposites could address. Additionally, materials with controlled directional
thermal conductivity which can handle thermal fluxes up to 1000 W/cm 2 over large
areas and phase change materials which can enable thermal energy storage on the
order of 1000 kJ/kg are needed.