IEA Hydrogen Task, 18 Project database
Hydrogen project
Project title: High temperature PEM fuel cell
Place and country: Fredericia, Denmark
Project type: (Basic research, Pilot plant, Demonstration, Prototype, Field test, Commercial product, other)
Development, demonstration
Project duration
Start: (month, year)
September 2003
End : (month, year) September 2006
Project co-ordinator: (Company, Country)
Elsam Kraft a/s, Overgade 45, Skærbæk, DK-7100 Fredericia, Denmark , Tel. 76222000
elsam@elsam.com
Contact person: (Name, Phone number, Email)
None
Keywords: (searchable words)
demonstration CHP unit, high-temperature PEM fuel cell, reforming, hydrogen
Project participants: ( Company, Country)
Danish Power Systems ApS
Kemisk Institut (DTU)
Budget and funding:
DKK 5.400.000
PSO-2003
Project no. ELTRA-4760
Project description:
The project aims to develop a demonstration CHP unit for the housing market based on a
high-temperature PEM fuel cell. The fuel cell is operating at up to 200°C at very high
tolerances of CO in hydrogen. The high operation temperature makes the cell suitable for heat
recirculation and the high CO tolerances makes it possible to utilize reformed hydrogen from
e.g. natural gas. The CHP unit consists of a 2 kW fuel cell stack, a natural gas reformer, an
afterburner and an electrical DC/AC converter. The prototype needs to be tested for
demonstration of electricity production based on natural gas combined with heat supply. The
possibilities of mass production and the related costs must be investigated.
Weblinks and publications: (Webadress, publication and issue, conference name)
He R., Qingfeng Li., Bjerrum N. J.
Phosphoric acid doped AB-PBI membranes and its applicationes in high temperature PEMFC.
Chemical Journal of Chinese Universities 26 (2005) (12) 2302
Qingfeng Li., Jensen J. O., Noyé P. P., Pan C., Bjerrum N. J.
Fuel Cells: A promise of electrochemistry and challenges for electrochemists.
The 13. National Conference on Electrochemistry, Guanzhou, China, (November 24-28, 2005)
Jensen J. O., Qingfeng Li., Pan C., Bjerrum N. J.
Recent progress in high temperature PEMFC and possible utilization of the excess heat for fuel processing.
EHEC 2005, 2. European Hydrogen Energy Conference, Zaragoza, Spain, (November 22-25, 2005)
Bjerrum N. J.
High temperature PEM fuel cells integration with fuel processors.
Institute of Nanostructurered Materials, Palermo Research Division, C.N.R.I.S.M N., Palermo, Italy (Oct. 2005)
Qingfeng Li., Jensen J. O., Noyé P. P., Pan C., Bjerrum N. J.
Proton exchange membranes for fuel cells challenges and recent developments.
15. International Symposium on Fine Chemistry and Functional Polymers (FCFP-XV), and
1. International Symposium on Novel Materials and Synthesis (NMS-1), Shanghai, China (Oct. 17-20, 2005)
Bjerrum N. J.
HT-PEMFC integration with fuel processor.
Symposium on High Temperature PEM Fuel Cells, Patras, Greece, (Sept. 14, 2005)
Bjerrum N. J.
Proton exchange membrane fuel cells at DTU.
IEA, Exco Meeting, Risø National Laboratory, Denmark (April 29. 2005)
Jensen J. O., Qingfeng Li., Bjerrum N. J.
European hydrogen and fuel cell technology platform (HFP)
Annual Event, Brussels, Belgium (March 17-18, 2005)
Bjerrum N. J.
Furim - Further improvement and system integration of high temperature
polymer electrolyte membrane fuel celles
Hydrogen and fuel cell technology platform operation review days
Brussels, Belgium (Dec. 8-9, 2005)
Jensen J. O., Bjerrum N. J., Qingfeng Li., Pan C., He R., Bandur V., Hennesø E.
High temperature PEM fuel cells and hydrogen storage
Danish Electric Vehicle Commitee, General Assembly (Jan. 27, 2005)
Jensen J. O., Qingfeng Li., He R., Pan C., Bjerrum N. J.
100 - 200 C Polymer fuel cells for use with NaAlH4
J. Alloys and Compounds (2005), 404-406, 653-656
Pan C., He R., Qingfeng Li., Jensen J. O., Bjerrum N. J.,
Andersen Hjulmand H., Børsting Jensen A.
Integration of high temperature PEM fuel cells with a methanol reformer
J. Power Sources 145 (2005), 392
Qingfeng Li., He R., Gao J.-A., Jensen J. O., Bjerrum N. J.
the CO poisoning effect in PEMFCs operational at temperatures up to 200 C.
J. Electrochem. Soc. 150 (2003) A1599-A1605
Qingfeng Li, He R., Jensen J. O., Bjerrum N. J.
Reviews: Approaches and recent development of polymer electrolyte membranes for fuel cells operational above 100
degr.C.
Submitted to Chemistry of Materials (2003)
Qingfeng Li, Jensen J. O., He R., Xiao G., Gao J., Berg R. W., Hjuler H. A., Hennesoe E., Bjerrum N. J.
Acid-doped polybenzimidazole membranes as electrolyte for fuel cells operating above 100°C.
In Recent Research Developments in Electrochemistry 6 (2003) 1-26
(ed. S. G. Pandalai, Transworld Research Network 37/661 (2), Fort P.O., Trivandrum-695 023, Kerala, India).
He R., Qingfeng Li, Xiao G., Bjerrum N. J.
Proton conductivity of phosphoric acid doped polybenzimidazole and its composites with inorganic protontic conductors
Proceedings of the 2nd European PEFC Forum, 30 June – 4 July (2003), Lucerne, Switzerland, p. 59-68.
He R., Qingfeng Li, Xiao G., Bjerrum N. J.
Proton conductivity of phosphoric acid doped polybenzimidazole and its composites with inorganic protontic conductors
Membrane Sci. 226 (2003) p169.
Qingfeng Li, He R., Gao J., Jensen J. O., Bjerrum N. J.
CO tolerance by the PEMFC operational at temperatures up to 200°C.
Proceedings of the 2nd European PEFC Forum, 30 June – 4 July (2003), Lucerne, Switzerland. p 253-262.
Jensen J. O., Qingfeng Li, He R., Xiao G., Gao J., Bjerrum N. J.
High temperature polymer fuel cells. - Heat utilization and CO tolerance (abstract/oral).
Proceedings of the European Hydrogen Energy Conference, 2-5 September (2003), Grenoble, France.
Qingfeng Li, Jensen J. O., He R., Gao J., Bjerrum N. J.
New Polymer Electrolyte Membranes for Fuel Cells Operating Above 100°C - Approaches And Recent Progress.
Proceedings of the European Hydrogen Energy Conference, 2-5 September (2003), Grenoble, France.
Jensen J. O., Qingfeng Li, He R., Xiao G., Gao J., Bjerrum N. J.
High temperature polymer fuel cells and their Interplay with fuel processing systems.
Proceedings of HYPOTHESIS V (Hydrogen Power Theoretical and Engineering Solutions, International Symposium,
7-10 September (2003), Porto Conte, Italy.
Qingfeng Li, Jensen J. O., He R., Gao J., Bjerrum N. J.
New Polymer Electrolyte Membranes For Fuel Cells.
Proceedings of HYPOTHESIS V (Hydrogen Power Theoretical and Engineering Solutions International Symposium,
7-10 September (2003), Porto Conte, Italy.
Quasi-Direct Methanol Fuel Cell System Based on Blend Polymer Membrane Electrolytes
Qingfeng Li, Hjuler H. A., Hasiotis C., Kallitsis J.K., Kontoyannis C.G., Bjerrum N. J.
Electrochemical and Solid-State Letters, Vol. 5 (6) (2002), A125.
Qingfeng Li, R. He, Berg R. W., Hjuler H. A., Bjerrum N. J.
Water Uptake and Acid Doping of Polybenzimidazoles as Electrolytes for Fuel Cells
Submitted to Solid State Ionics (2002).
Qingfeng Li, Bjerrum N. J.
Aluminum as Anode for Energy Storage and Conversion: A Review
J. Power Sources, Vol.110, (2002) 1-10.
Qingfeng Li, Bjerrum N. J.
Polymer Electrolyte Membranes for Fuel Cells, Sate-of-the-art and Recent Progress
Battery Bimonthly, Vol.32 (3) (2002), 198-201
Jensen J. O., Møller T. S., Bjerrum N. J.
Stability of CaNi5HX stored at temperatures between 20 and 150°C.
J. Alloys Comp.330-332 (2002) 215
Valøen L. O., Lasia A., Jensen J. O., Tunold R.
The electrochemical impedance of metal hydride electrodes.
Electrochem. Acta 47 (2002) 2871
Qingfeng Li, Hjuler H. A., and Bjerrum N. J.
Phosphoric Acid Doped Polybenimidazole Membranes: Physiochemical Characterization and Fuel Cell Applications
J. Applied Electrochemistry, Vol.31, (2001) 773-779.
Hasiotis C., Qingfeng Li, Deimede V., Kallitsis J.K., Kontoyannis C.G., Bjerrum N.J.
Development and Characterization of Acid-Doped Polybenzimidazole/Sulfonated Polysulfone Blend Polymer Electrolytes
for Fuel Cells
J. Electrochem. Soc., Vol.148 (5) (2001), A513-519.
Qingfeng L., Zhou D., He R., Jensen J. O., Hjuler H. A., Bjerrum N. J.
The carbon monoxide poisoning effect on the performance of polymer electrolyte membrane fuel cells operational at
temperatures up to 200C.
Proceedings of the 4th. International Symposium on Hydrogen Power - Theoretical and Engineering Solutions.
HYPOTHESIS IV. Stralsund, Germany, (September 2001).
Jensen J. O., Qingfeng Li, Hennesø E., Hjuler H. A., Bjerrum N. J.
High Temperature Polymer Fuel Cells.
Nordic Energy Reserch Program (NERP) Workshop on New Materials and Technologies for Low Temperature Fuel Cells.
Helsinki, Finland, (September 2001).
Petrushina I., Qingfeng Li, Borup F., and Bjerrum N. J.
Corrosion Protection of Steel in Molten Li2CO3-K2CO3 and Na2CO3-K2CO3 Mixtures in a Hydrogen Containing
Atmosphere
J. Appl. Electrochem., Vol.30, (2000) 929.
Qingfeng Li, Hjuler H. A., and Bjerrum N. J.
Oxygen Reduction on Carbon Supported Platinum Catalysts in High Temperature Polymer Electrolytes
Electrochimica Acta, Vol.45, (2000) 4219-4226.
Deimede V., Voyiatzis G. A., Kallitsis J. K., Qingfeng Li, and Bjerrum N. J.
Miscibility Behavior of Polybezimidazole/Sulfonated Polysulfone Blends for Use in Fuel Cell Applications
Micromolecules, Vol.33, (2000) 7609-7617.
Jensen J. O., Hennesø E., Bjerrum N. J.
Metal hydride storage tank for demonstration in a hydrogen vehicle. Part I: Model tank
Conf. Tronheim, Norway (2000)
Qingfeng L., Jensen J. O., Bjerrum N. J.
Dansk Elektrokemi i 200 År.
O. Bostrup (ed.), pp. 33-43 (Danish Society for Historical Chemistry, Copenhagen, 2000).
Jensen J. O., Nørbygaard T., Berg R. W.
Mechanical alloying for the preparation of alloys not easily cast (CaNi5, Mg-Ni and MoCo3).
Prog. Molten Salt Chem. 1, (2000) 247-252.
Jensen J. O., Hennesø E., Bjerrum N. J.
Metal hydride storage tank for demonstration in hydrogen vehicle.
Proceedings of the Nordic Workshop on Materials for Energy Conversion.
Bardøla Høyfjellshotel, Geilo, Norway, (March 2000), 133-139
Bjerrum N. J., Jensen J. O., Lampinen M., Noponen T., Kauranen P., Anttila T., Valo T., Haakana A., Arvidsson J.,
Noréus D., Kiros Y., Otto A., Rosenkilde C., Tunold R., Børresen B., Valøen L. O., Hauback B..
Development of air metal hydride battery.
Proceedings of the symposium: Hydrogen - Electrochemistry and Energetics. How far are we from the Hydrogen
Society ? Trondheim, (June 1999).
Jensen J. O., Bjerrum N. J.
Metal hydrides for electrodes. -Towards higher capacity.
Nordic Energy Researsh Program. Nordic Workshop on Hydrogen in Electrochemical
Energy Conversion. (March 1999). Geilo, Norway.
Qingfeng Li, Borup F., Petrushina I., Bjerrum N. J.
Complex formation during dissolution of metal oxides in molten alkali carbonates
Journal of Electrochem. Society 146 (1999) 2449
Qingfeng Li, Bergqvist R. S., Hjuler H. A., Bjerrum N. J.
Oxygen reduction on carbon supported platinum catalysts in high temperature polymer electrolytes
3. International Symp. on Electrocatalysis (1999), Slovenia
Qingfeng Li, Hjuler H. A., Bjerrum N. J.
Development and characterization of temperature resistant polymer electrolytes
3. International Symp. on Electrocatalysis (1999), Slovenia
Information provider: (date, name, company, country,)
28.02.2006, Henrik Iskov, Danish Gas Technology Centre, Denmark