STUDY GUIDE FOR FINAL EXAM: HONORS CHEMISTRY Material from Chapters 4, 5, 6, 7, 8; 9; 10; 11; 12; 13.2-13.3; 14.4-14.5; 16.1-16.2; 17.1-17.3; and 19.2-19.4 V. Chemical Formulas A. Molecular v. Ionic i. properties and identification ii. formulas and element type B. Diatomic v. binary molecules i. diatomic elements (GENINE) C. Atoms, molecules and formula units i. know definitions. D. Writing formulas–be able to write formulas from names for: i. ionic compounds ii. molecular compounds iii. acids/bases a. know properties of acids and bases b. be able to identify each by properties and formulas iv. organic compounds a. saturated hydrocarbons; straight chain, 1-10 carbons b. cyclic compounds, same as (a.) c. primary alcohols same as (a) and (b) E. Oxidation numbers i. rules for assigning ii. meaning iii. periodic table relationship F. Chemical Nomenclature-be able to write names from formulas for: i. binary ionic ii. ionic compounds containing polyatomic ions iii. ionic compounds containing metals with more than one oxidation state a. Stock system b. “older” system using Latin roots and –ic and –ous endings iv. binary molecular v. organic – same classifications as in formula writing section G. Calculations for: i. molar mass ii. mole-mass Conversions a. grams to moles b. grams to number of particles c. number of particles to moles d. the reverse of any of the above iii. molar volume a. to grams b. to moles c. to number of particles d. the reverse of any of the above iv. Percent composition STUDY GUIDE FOR FINAL EXAM: HONORS CHEMISTRY Material from Chapters 4, 5, 6, 7, 8; 9; 10; 11; 12; 13.2-13.3; 14.4-14.5; 16.1-16.2; 17.1-17.3; and 19.2-19.4 VI. Chemical Quantities and Chemical Reactions A. Calculations for: i. empirical and molecular formulas a. from gram analysis data b. from percent composition data ii. molarity a. determine molarity of a solution b. determine the amount of solute required to prepare a solution of specific concentration. c. determine the amount of solution of specific concentration that can be prepared from a specified amount of solute d. determine the concentration of an ion in a solution containing an ionic solute. iii. dilutions a. determine molarity of a solution through dilution b. determine the amount of stock solution required to prepare a solution of specific concentration or to prepare a specific amount of solution of known concentration. B. Writing Chemical Equations i. general format ii. physical states and conditions of reaction C. Balancing Chemical Equations i. by inspection ii. redox by oxidation number method D. Classifying Chemical Reactions i. synthesis ii. decomposition iii. single replacement iv. double replacement a. neutralization b. precipitation c. insoluble gases v. combustion-complete and incomplete vi. oxidation-reduction STUDY GUIDE FOR FINAL EXAM: HONORS CHEMISTRY Material from Chapters 4, 5, 6, 7, 8; 9; 10; 11; 12; 13.2-13.3; 14.4-14.5; 16.1-16.2; 17.1-17.3; and 19.2-19.4 VII. Chemical Reactions A. Predicting Products i. single replacement and the use of activity series for metals and nonmetals ii. double replacement a. neutralization b. precipitation and the use of solubility rules c. insoluble gases iii. combustion-complete and incomplete B. Oxidation-Reduction Reactions i. Should be able to determine: a. substance oxidized b. substance reduced c. oxidizing agent d. reducing agent f. balance using oxidation number method C. Stoichiometry a. Mass-Mass/Mass-Volume/Volume-Volume Problems b. Limiting Reactants c. Energy of Chemical Reactions i. reaction coordinate diagrams for exothermic and endothermic reactions ii. standard enthalpies of formation (ΔHof) iii. enthalpy of reaction (ΔHorxn) a. determine from (ΔHof) iv. stoichiometry and (ΔHorxn) D. Collision Theory-be able to discuss the conditions required for a reaction to occur. E. Factors that affect reaction rate-be able to discuss the impact of varying these factors on how fast a reaction occurs and relate to Collision Theory. STUDY GUIDE FOR FINAL EXAM: HONORS CHEMISTRY Material from Chapters 4, 5, 6, 7, 8; 9; 10; 11; 12; 13.2-13.3; 14.4-14.5; 16.1-16.2; 17.1-17.3; and 19.2-19.4 VIII. Chemical Bonding and Periodic Trends A. Basic Periodic Trends for families and periods i. atomic radius ii. ionic radius iii. ionization energy 1.exceptions for 2. successive/multiple ionization energies iv. electron affinity v. electronegativity vi. exceptions for (iii) and (iv) vii. definitions and meanings for (i) – (v) viii. Explain why each trend occurs (i) – (iv) ix.Use trends to determine the relationships between different atoms. B. Ionic Bonding i. definition and how to identify ii. electron transfer diagrams/ charges and formulas C. Covalent Bonding i. molecular formula ii. electron dot formula a. rules for writing iii.structural formula a. bond types I. single/double/triple II. polar v. nonploar D. Basic Molecular Structures and VSEPR Theory i. linear ii. trigonal planar iii. tetrahedral iv. trigonal bipyramidal v. octahedral vi. derivatives for (i) – (iii). E. Bond angles for basic geometries F. Hybridization G. Polarity of bonds and molecules STUDY GUIDE FOR FINAL EXAM: HONORS CHEMISTRY Material from Chapters 4, 5, 6, 7, 8; 9; 10; 11; 12; 13.2-13.3; 14.4-14.5; 16.1-16.2; 17.1-17.3; and 19.2-19.4 H. Intermolecular Forces i. dipole-dipole a. hydrogen bonding ii. dipole-induced dipole iii. induced dipole-induced dipole; London dispersion forces iv. affect of properties that involve change of state, i.e. melting point, boiling point, rate of evaporation, solubility I. Metallic bonding J. Kinetic Molecular Theory and Gas Laws i. Postulates of Kinetic Molecular Theory ii. Pressure a. units b. causes c. how it is measured iii. Phase Diagrams a. normal melting point and normal boiling point b. triple point c. critical point iv. Phase changes, heating curves and calculations of the amount of energy involved v. LeChatelier’s Principle, vapor pressure and evaporation