Anna Cajiga SME 301 Matter Summary January 27, 2005 Title Using Alka-Seltzer to Demonstrate the Law of Conservation of Matter Benchmark Area: Physical Science Category: Changes in Matter Benchmark: Describe common chemical changes in terms of properties of reactants and product. (Middle School) Misconception Disregard for conservation of particles during a chemical change. Background There is a common disregard for conservation of particles during a chemical change. However, this experiment explores what actually happens when a chemical change takes place. A chemical change is one in which the original substance or substances becomes a new substance or substances after the change is complete. Putting Alka-Seltzer into water is a chemical change because the reaction of these two substances creates a new type of matter – a gas. After this, and any, chemical change, the number of atoms in the substance will still be the same as it was before the change. Materials Balance Measuring Cups Two Empty Water Bottles (16 oz.) Two Balloons Eight Alka-Seltzer Tablets Four Cups of Water Directions 1. Make sure that the balance is balanced. Each side should be level with the other side. 2. Fill each water bottle with two cups of water. 3. Put a water bottle filled with water, a balloon and four tablets of Alka-Seltzer on each side of the balance to ensure that each set of materials weighs the same before the chemical change takes place. 4. Remove the materials from the right side of the balance. Carefully break these four AlkaSeltzer tablets into pieces small enough to fit through the mouth of the balloon. Be careful not to lose any pieces. Place all of the pieces inside of the balloon. 5. Attach the balloon to the water bottle by stretching the opening of the balloon over the top of the bottle. Be careful not to let the Alka-Seltzer tablets fall into the water. 6. Replace the water bottle (now with the balloon attached to it) on the right side of the balance. Lift the balloon so the Alka-Seltzer tablets fall into the water in the water bottle. 7. Wait a few minutes and draw a picture of what you see happening. Cajiga 2 Results At the conclusion of this experiment, the balloon attached to the water bottle appears to be filling up and “growing”, just like if you were to blow up a balloon with your mouth. Although though the balloon on the right is being filled, the balance remains even and balanced. Discussion Through this experiment, it becomes clear that when a chemical change occurs, mass is conserved. Since each side of the balance is equal, the mass is the same for the substances that went through a chemical change and the substances that did not go through a chemical change. This proves that all of the atoms in the original substances are still present after the chemical change has taken place. The reason that atoms are neither lost nor gained during chemical changes is because during this type of change the bonds between the atoms of the original substances are breaking apart and new bonds are being formed with different atoms. When the atoms form these new bonds, they are creating different types of molecules, which in turn make a different type of matter or substance. This is why after a chemical change, the original substances have changed to different substances. This also explains the Law of Conservation of Matter, which states that matter only changes form during physical and chemical changes, but is never created or destroyed. This experiment demonstrates the Law of Conservation of Matter because when the chemical change occurred in this closed system, all of the atoms were conserved and the mass remained the same. Matter is conserved also during physical changes. During a physical change the molecules of the substance remain the same, but they are rearranged and this causes changes in physical properties or appearance. An example of physical change is when matter changes state, like when water changes from solid (ice) to liquid. Matter can be found in one of the three physical states – solid, liquid, or gas. In any of these physical states, the molecules that make up matter are always the same, they are just rearranged differently and moving at different speeds. Matter can change states when heat is added or removed from it. There are six types of state changes in matter. When matter changes from solid to liquid, heat has been added to the matter and the change is called melting. Adding heat can also change matter from liquid to gas, and this is called evaporation. A gas can change into liquid when heat is removed from it. This change is called condensation. Removing heat from a liquid can change it into a solid. When this occurs, it is called solidification. A solid can change into a gas when heat is added to it, this process is called sublimation. Removing heat from a gas can turn it into a solid, and this is called deposition. The energy from heat causes the molecules in matter to move and hit each other. When matter has little energy from heat, its molecules move slowly and hit each other with little force, and therefore come closer together, this happens in a solid. When heat is added to the matter, its molecules move faster and hit each other harder, moving farther apart from each other. If enough heat energy is added to a solid, its molecules will move apart farther until it turns into a liquid. If even more heat is added, the molecules will have more energy so they will move faster and hit each other harder. With enough heat, the molecules of a liquid will travel fast enough and far enough to turn it into a gas. Sometimes, heat is added or taken away from matter, but not enough heat energy for a change of state to occur. However, this does not mean that the movement and arrangement of the molecules remains the same. If heat is added to matter, the molecules that make it up begin to move faster. As they move faster, they bounce harder against each other, which causes them to spread further apart. Since the molecules are further apart after heat is added, the matter is now Cajiga 3 taking up more space. This is called thermal expansion. The opposite happens when heat is taken away from matter. The molecules that make up matter begin to move slower, which means they are hitting each other with less force. Since there is less force driving the molecules away from each other, they move closer together, making the matter take up less space. This is called thermal contraction. It is almost as if thermal expansion and contraction are one step away from a complete change of state because enough heat is added or subtracted to increase or decrease the motion of the molecules, but not enough to completely change the arrangement of the molecules into a different state. There is one exception to thermal contraction and expansion. This exception is water. When water freezes, the molecules move closer together and form a lattice that has empty space in the middle. This makes the frozen water take up more space than the liquid water. Similarly, when ice cubes melt, the lattices that were formed break apart and the liquid water takes up less space than the frozen water did. We can see evidence of these concepts in our everyday lives. For example, on a cold winter day when you go outside, you can see your breath in the air. This is because when the cold air touches the moisture from your breath, the molecules begin to move slower and that moisture condenses, making tiny particles of water that we can see. The same sort of thing happens when you take a can of soda out of the fridge and set it on the table. The moisture in the air touches the cold can, causing the molecules in this moisture to move slower and closer together. As a result, the moisture in the air condenses into water on the sides of the soda can. Learning about changes of state also allows us to explain why candle wax melts when we light the candle. The heat from the flame warms the wax and the molecules in this solid begin to move faster and spread further apart. This causes the wax to change to a liquid. Understanding thermal expansion and contraction also allows us to explain many everyday occurrences. These concepts explain how a thermometer works. When a thermometer is placed in a cup of hot water, more heat is added to the mercury inside the thermometer and the molecules that make it up begin to move faster, hit each other with more force, and spread apart. This makes the mercury take up more space and move further up the scale on the thermometer so we can read the correct temperature. When we remove heat by taking the thermometer out of the hot water, the molecules in the mercury have less heat energy and they begin to move slower, hitting each other with less force. This makes them move closer together, and therefore the mercury takes up less space. We can also understand why it is easier to remove a tight metal lid on a jar if we place it under hot water. Heat is transferred from the hot water to the metal lid, and the molecules move faster, hit each other with more force, and spread further apart. This causes the metal lid to expand and makes it loser on the jar. If we did not know that water is the exception to thermal expansion and contraction, we would not understand why a plastic water bottle bursts when we fill it and put it in the freezer. Because the molecules of water form a lattice with empty space in the middle when it changes from a liquid to a solid, the water takes up more space when it is frozen and causes the water bottle to burst. Chemical changes occur all around us, and knowing more about chemical changes helps us to identify and understand them. Every time you eat a meal, thanks to chemical changes, the food becomes substances your body can use, such as vitamins or sugars. The substances in our body interact with the substances in the food we eat, and the atoms of the food are rearranged into new substances that our bodies can use for nourishment. We all know that our bodies cannot digest rice or beans when they are raw. We can change them chemically through cooking so that we can digest them normally. This is because the act of cooking the rice or beans creates a chemical change and the atoms of these substances rearrange to form new substances that our digestive system can deal with. We can now also Cajiga 4 understand how stain removers work. If you get a grass stain on your favorite pair of jeans, a stain remover will get rid of it because the substances in the stain remover interact with the stain to cause a chemical change. The stain remover will break apart the atoms in the grass stain so that they can be washed away in the washing machine. Classroom Resources 1. Experimenting with Physical and Chemical Changes Written by Gordon R. Gore This book is helpful because it presents readers with several hands-on experiments that further explore and explain important concepts relating to matter and, more specifically, physical and chemical changes in matter. 2. Bill Nye the Science Guy Video – Episode #8 Phases of Matter This episode of Bill Nye the Science Guy is a great classroom resource because it uses demonstrations and detailed explanations to teach viewers what molecules are and what happens to them as matter changes from solid to liquid to gas, all in an attention-grabbing and humorous way. 3. Field trip to Impression V Science Center in Lansing, Michigan for the Slime! Lab This field trip is useful because it allows visitors to experience hands-on learning about atoms, molecules, states of matter and chemical changes when they become “real” scientists and mix various chemicals together to create a new substance – Slime! Credits I developed this experiment on my own based an experiment my science class did when I was in fifth grade. In this experiment, we put Alka-Seltzer tablets in film canisters and then watched the lid of the film canister shoot off high into the sky. This experiment was intended to show the pressure that built up as a result of the gas that was created by the chemical change. I decided to modify this experiment to instead show that when a chemical change takes place, the atoms do not disappear but instead simply rearrange themselves.