Name: 1. Revision Short Questions(5) Class no: Which of the following compounds has the lowest boiling point? Why? Ethanol propan-1-ol propane butane Propane. The molecules in ethanol and propan-1-ol are held together by intermolecular hydrogen bonds which is stronger than Van der Waals forces among propane and butane. The molecular mass of propane is smaller than butane. So the Van der Waals’ forces in propane is weaker than that in butane. 2. 25.0 cm3 of an acid with concentration 1.0M require 37.5 cm3 of 2.0M sodium hydroxide for complete neutralization. What is the basicity of that acid? Let n be the basisity of the acid , then no. of mole of acid : H nA + no. of mole of NaOH = ─→ nNaOH 0.025 NanA + : 0.075 mol = 1:3 nH2O so n = 3 So the basicity of the acid = 3 3. Complete the following table Product formed when reacted with dilute Product formed when reacted with concentrated sulphuric acid sulphuric acid Zinc 4. Hydrogen + zinc sulphate Sulphur dioxide Cane sugar No reaction Carbon + water Ammonia Ammonium sulphate Ammonium sulphate Copper(II) sulphate crystal No reaction White ppt of anhydrous copper(II) sulphate Iron can be extracted from iron(III) oxide by the following reaction: Fe2O3(s) + 3CO(g) 2Fe(s) + 3CO2(g) What mass of iron(III) oxide is required to produce 2.1g iron? (R.A.M. : O = 16.0,Fe = 56.0) no. of mole of 2.1 g Fe = 2.1 0.0375 mol 56 no. of mole of Fe2O3 required = 0.0375 0.01875mol 2 mass of Fe2O3 required = (56×2+16×3)×0.01875=3.0g 5. The table below shows the electrical conductivity of four substances W、X、Y and Z: (: conduct electricity ; : cannot conduct electricity) Substance W X Y Z Solid state Liquid state Which one would be zinc chloride? W Which one would be a metal? Z Aqueous solution (insoluble in water) Which one would be glucose? Y 6. State the colour of the following ions: Ni2+ 7. green Fe3+ Cr3+ yellow green Potassium permanganate is a common oxidizing agent which is usually acidified by dilute sulphuric acid. (a) Dilute nitric acid is not used to acidify permanganate. Why? Dilute nitric acid is also an oxidizing agent that may compete with permanganate to react with the reducing agent. (b) Dilute hydrochloric acid is not used to acidify permanganate. Why? HCl will be oxidized by permanganate to form chlorine gas. (c) Dilute ethanoic acid is not used to acidify permanganate. Why? Ethanoic acid is a weak acid. The concentration of H+ is not high enough to acidify permanganate. 8. If 8.0 g of oxygen and 20.0 g of gas X occupy the same volume at room temperature and pressure, what is the molar mass of X? (R.A.M.: O = 16.0; Molar mass of gas at R.T.P. = 24.0 dm3) Since they occupy the same volume, so no. of mole of O 2 = no. of mole of X So 8.0/16x2 = 20.0 / molar mass of X Molar mass of X = 80 g mol-1 9. The percentage by mass of X in compound X2S is 58.9%. What is the relative mass of X? (R.A.M.: S = 32.1) Let x be the relative atomic mass of X, 10. 2x 100% 58.9% , thus x = 23 2 x 32.1 Complete the table below: What gaseous product will be formed? Adding calcium to water hydrogen Adding magnesium to dilute hydrogen hydrochloric acid Adding copper to dilute nitric acid Passing steam to hot iron 11. Nitrogen monoxide Hydrogen Will precipitate form when sodium hydroxide solution mixes with the each of the following solutions? If precipitate will be formed, state its colour. ppt formed﹖colour of the ppt﹖ Lead(II) nitrate solution Yes. White ppt Iron(III) nitrate solution Yes. Brown ppt Copper(II) nitrate solution Yes. Blue ppt Potassium nitrate solution No ppt 12. 13. Balance the following equation: 2HNO3 + xFeSO4 + yH2SO4 zFe2(SO4)3 + 4H2O + 2NO 2HNO3 + 6FeSO4 + 3H2SO4 3Fe2(SO4)3 + 4H2O + 2NO In an experiment, iodine was put in potassium iodide solution. Sulphur dioxide was then passed through the solution. (a) What would be the observable change? The solution would change from brown to colourless. (b) Write an equation for the reaction occur. SO2 + I2 + 2 H2O H2SO4 + 2 HI 14. In an experiment, 1.00M sodium hydroxide solution was added to 25.0 cm3 1.00M sulphuric acid until the acid was just completely neutralized. What would be the concentration of sodium sulphate in the resulting solution? 2NaOH + H2SO4 Na2SO4 no. of mole of H2SO4 = 0.025 mol, + 2 H2O no. of mole of NaOH needed = 0.050 mol, vol. of NaOH needed = 50 cm3. No. of mole of Na2SO4 formed = 0.025 mole. Volume of the resulting solution = 25+50 = 75 cm 3 Concentration of Na2SO4 = 0.025 / 0.075 = 0.33 M 15. Concentrated sulphuric acid and anti-bumping granules were added to a mixture of an alkanoic acid and a alkanol. The following compound was formed after heating the mixture under reflux. H O H C O C H 16. H H C C H H H (a) The alkanoic acid is: propanoic acid The alkanol is: methanol (b) What is the function of concentrated sulphuric acid? It acts as a catalyst. (c) What is the purpose of adding anti-bumping granules? To prevent uneven boiling of the solution. (d) What is the purpose of heating under reflux? (e) Draw the experiment set-up used for heating under reflux. To prevent loss of reactants or products. Complete the table below Polymer Is it a thermoplastic? Is it a condensation polymer? nylon Yes Yes perspex Yes No polyethene Yes No Urea methanal No Yes 17. (a) What is the active ingredient in household bleach? Sodium hypochlorite (b) How to make household bleach? Passing chlorine to sodium hydroxide solution. (c) Sodium chloride is the raw material used to make household bleach. Why? It is because chlorine and sodium hydroxide are the products of electrolysis of concentrated sodium chloride solution (d) 18. Is household bleach acidic or alkaline? Alkaline What is the bad effect of the each of the following pollutants. pollutant 19. A. hydrocarbon carcinogenic B. carbon monoxide C. lead compound damage the nervous system D. carbon particulates carcinogenic decrease the oxygen carrying capacity of blood Can each of the following metal oxide be reduced by heating with carbon? (1) 20. bad effect Magnesium oxide No lead(II) oxide yes iron(III) oxide yes What is the product formed when each of the following compounds reacts with acidified potassium permanganate solution? (1) (3) 21. 23. ethan-1,2-diol iron(II) sulphate solution ethanol ethanoic acid iron(III) sulphate solution Is iodine a substance with giant covalent structure? No (b) Give two substances that have giant covalent structure. (c) Every two iodine atoms are held together by covalent bond to form a molecule. Is it correct? Diamond, quartz Yes (a) What hazard warning label(s) should be put on the container containing potassium? (b) What hazard warning label(s) should be put on the container containing methanol? flammable and toxic flammable The reaction of chlorine and hot concentrated potassium hydroxide solution can be represented by the following equation: 3Cl2(g) + 6KOH(aq) (a) 24. (2) Iodine is a solid at room temperature and pressure. (a) 22. ethene 5KCl(aq) + KClO3(aq) + 3H2O(l) What is the change in oxidation number of chlorine? From 0 to -1 and from 0 to +5。 (b) What is the oxidizing agent? Why? Chlorine. It is because its O.N. decreases from 0 to –1 (c) What is the reducing agent? Why? Chlorine. It is because its O.N. increases from 0 to +5. Name 5 substances that should be kept in brown reagent bottles. (a) nitric acid (d) chlorine water / bleach (b) silver nitrate (e) potassium permanganate (c) bromine water 25. The structure of polymer X is: H Cl H Cl H Cl H Cl ... C C C C C C C C ... Cl H Cl H Cl H Cl H (a) What is the monomer of polymer X? 1,2-dichloroethene (b) Putting X in incinerator will cause serious pollution problem. Why? It is because burning of X will form acidic hydrogen chloride gas. 26. An experiment is carried out as shown below: 2H+ + 2 e-H2 (a) Write an ionic half equation for the reaction occurs at electrode X? (b) What will be the colour change around electrode Y after carrying out the experiment for a certain period? Why? The solution will change from colourless to orange. It is because the negatively charged dichromate ion will migrate to the positive electrode Y. Dichromate ion is orange in colour. (c) What is the purpose of this experiment? 27. Soapless detergent can be made by reacting a wetting agent by decreasing the Its hydrocarbon tail To show the existence of ions. petroleum , surface tension sulphuric acid of water. Its and sodium hydroxide. It can acts as - ionic head—SO3 is hydrophilic. is hydrophobic. So soapless detergent can dissolve in water and oil. During the cleaning process, oil is changed to __negatively_________charged oil droplets. The oil droplets will not join together again because and can be washed away easily. 28. 29. (a) What is the condition required for the reaction of butane and bromine? In the presence of sunlight. (b) What kind of reaction does the reaction in (a) belong to? (c) Is it a redox reaction? Why? Yes. It is because the oxidation number of Br changes from 0 to –1. (d) State the observable change when they react? (a) Explain why metal is a good conductor of heat. (b) (c) Substitution reaction The mixture will change from brown to colouless. It is because metals have mobile electrons. Explain why sulphur is classified as non-metal? It is because it cannot conduct electricity in solid and liquid state. The tap water in HK will form scum with soap solution. Is it correct? Explain your answer. No. It is because the tap water in HK is soft water.