Glass Magic Windshield Repair Resin

advertisement
GLASS MAGIC
4302 W LOOP 289
LUBBOCK, TX 79407
972-378-3291 PHONE
resin@glassmagic.net
www.glassmagicresin.com
Effective 1/1/2009
MATERIAL SAFETY DATA SHEET
GLASS MAGIC WINDSHIELD REPAIR RESIN – OLIGOMER
GENERAL INFORMATION
EMERGENCY PHONE NUMBERS:
972-378-3291
PRODUCT INFORMATION:
972-378-3291
GENERIC NAME:
Acrylic Ester
DOT SHIPPING NAME:
Not regulated
DOT HAZARD CLASS:
Not regulated
SUMMARY OF HAZARDS
WARNING:
PHYSICAL HAZARDS:
ACUTE HEALTH EFFECTS:
CHRONIC HEALTH EFFECTS:
THRESHOLD LIMIT:
VALUES
Unstable (reactive) upon depletion of inhibitor
May be slightly toxic irritating by inhalation slight eye
irritation moderate skin irritant slight ingestion hazard
light skin absorption hazard
Prolonged or repeated skin contact may cause allergic
skin reactions.
ACGIH-TWA PPM MG/M3
0.5
COMPONENTS
Glass Magic Windshield Repair Resin is an acrylic oligomer, the exact composition of which is
considered a proprietary secret.
PHYSICAL AND CHEMICAL DATA
Boiling Point
AP 275 C / 527 F
Freezing Point
AP 5 C / 41 F
Specific Gravity (H20= 1 at 39.2F)
AP .98 at 25C
Vapor Pressure
20mm Hg at 140 C / 284 F
Volatile Characteristics
Negligible
Solubility in Water
Moderate
Vapor SP GR (Air = 1 at 60 – 90 F)
GT 1
Appearance and Odor
Amber liquid with mild odor
Conditions and Material to Avoid
High Temperatures; Oxidizing conditions; Freezing
Conditions; Direct sunlight storage. Strong oxidizers
And reducers; Sparks and open flames; Free radical
Initiators
Hazardous Decomposition Products
Incomplete combustion may generate carbon monoxide
and acrid smoke / fumes.
OCCUPATIONAL EXPOSURE LIMITS
Threshold limit values
ACGIH-TWA PPM MG/M3 .05
FIRE AND EXPLOSION HAZARDS
Flash Point Method = (PMCC)
240F
Flammable Limits (% Volume in air)
Lower: N/DA
Upper: N/DA
Fire and Explosion Hazards
High temperatures/inhibitor depletion/accidental
Impurities/exposure to radiation/oxidizers may cause
Spontaneous Polymerizing Reaction, Generating Heat/Pressure
Extinguishing Media
Dry Chemical CO2 Foam
Use water spray/water fog for cooling
Special fire fighting procedures
Heat/Impurities may increase temperature/build
Pressure/rupture closed containers spreading
Fire, increasing risk of burn/injuries. Water may be ineffective in fire fighting due to moderate
solubility.
HEALTH HAZARDS
Routes of Exposure:
Inhalation
Inhalation is not expected to be a primary route of exposure due to the low volatility of this
material at room temperature; however exposure via inhalation may cause sneezing,
coughing and mucous production.
Eye Contact-primary route
May cause minor eye irritation. Symptoms of irritation may include excessive tearing,
redness and blinking.
Skin Absorption
No significant signs or symptoms indicative of any health hazard are expected to occur as a
result of skin absorption exposure.
Skin Irritation-primary route
This material may cause moderate skin irritation and burning along with allergic skin
reaction. May cause rash, redness, swelling and blistering. These systems may be delayed.
Ingestion
This material may be a slight health hazard if ingested in large quantities. May cause burns
of mouth and throat.
Medical Conditions Aggravated by Exposure
This material or its emissions may induce an allergic or sensitization reaction and thereby
aggravate systemic disease.
Effects of overexposure: DO NOT MISTAKE BOTTLE FOR EYE DROPS OR NASAL SPRAY! May cause severe
irritation with corneal injury which may result in permanent impairment of vision. Vapors may irritate eyes. May cause
skin irritation, even possible burning on contact. Slight oral toxicity. LD50 for rats was between 250 and 500 mg/kg.
Ingestion of large amounts could cause burns of mouth and throat. Inhalation of concentration as low as 5 ppm may cause
nasal irritation.
PROTECTIVE EQUIPMENT/CONTROL MEASURES
Respiratory Protection
Ventilation: Suitable to keep exposure levels below recommended TLV.
Eye Protection
Eye Protection such as safety goggles when possibility exists for eye contact due to splashing.
Skin Protection
When skin contact is possible, protective clothing including gloves, apron, sleeves, boots, head
and face protection should be worn when handling chemical in bulk. We suggest the use of
nitrile gloves.
Other Work Practices
Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using
toilet facilities. Promptly remove soiled clothing/wash thoroughly before reuse. Shower after
work using plenty of soap and water.
EMERGENCY AND FIRST AID
Inhalation
Not expected to present a significant inhalation hazard under anticipated conditions of normal
use. However, if vapors or mists cause irritation, or breathing becomes difficult, remove to
fresh air. Give oxygen or artificial respiration as needed. Get medical attention.
Eye Contact
In case of eye contact, immediately rinse with clean water for 20-30 minutes. Retract eyelids
often. Obtain emergency medical attention.
Skin Contact
Immediately remove contaminated clothing. Wash skin thoroughly with mild soap/water.
Flush with lukewarm water for 15 minutes. If sticky, use waterless cleaner first. Seek medical
attention if ill effect or irritation develops.
Ingestion
Ingestion unlikely. However, if ingested, give large amounts of milk and transport to medical
facility.
Emergency Medical Treatment Procedures
If exposed, treat skin and eye burns or irritation conventionally after decontamination.
SPILL AND DISPOSAL
Precautions if bulk material is spilled or released.
Release can cause fire/explosion. May polymerize and release heat/gases. Extinguish all
ignition sources. Blanket with fire fighting foam. Soak up spill.
Waste Disposal Methods
Dilute aqueous waste may biodegrade. Avoid over loading/poisoning plants. Absorb with
clay, earth, etc. and collect solid waste for disposal.
ADDITIONAL PRECAUTIONS
Handling and Storage Procedures
Unless inhibited, material can polymerize, raising temperature and pressure, possibly rupturing
container. Prevent freezing, inhibitor separates as solid. If frozen, material must be warmed
and remixed gently (less than 90ºF). Freezing point 41ºF.
LABEL INFORMATION
Use statement
For industrial use only
Keep out of reach of children
Signal Word
Warning
Physical Hazards
Unstable (reactive) upon loss of inhibitor
Health Hazards
May cause skin irritation/allergic skin reaction
Precautionary Measures
Do not handle near heat, sparks, or open flame. Material is unstable and hazardous
polymerization may occur. Keep container closed when not in use. Avoid contact with eyes,
skin and clothing. Avoid prolonged or repeated contact with skin. Use only with adequate
ventilation/personal protection. Prevent contact with food, chewing or smoking materials.
Wash thoroughly after handling.
SUPPLEMENT
MPCA HMIS Rating
Health
Flammability
Reactivity
Personal Protection
2
1
2
**D
**Respiratory Protection may be necessary depending on conditions of use-NIOSH/MSHA
approved air-purifying or supplied air respirator is recommended in situations where airborne
concentrations may be significant (i.e. vapor or mist generating conditions).
This product contains an inhibitor at less than 1%. This inhibitor requires oxygen to work and
is therefore stored in polyethylene bottles which are not full. This gives oxygen from the air in
the bottles for the inhibitor to use. WARNING: DO NOT STORE RESIN IN A GLASS
BOTTLES WHICH IS COMPLETELY FULL. DO NOT STORE RESIN IN A METAL
CONTAINER. KEEPING RESIN COOL AT 45ºf (REFRIGERATOR) WILL PROLONG
SHELF LIFE. KEEP OUT OF DIRECT LIGHT AND HEAT FOR MAXIMUM USEFUL
LIFE. SHELF LIFE AT AMBIENT CONDITIONS IS 12 MONTHS.
Note: Qualifiers and codes used in this MSDS
N/AP = Not applicable
N/DA = No data available
AP = Approximately
GT = Greater than
DISCLAIMERS
Some of the information presented and conclusions drawn are from sources other than direct
test date on the product itself. The information in the MSDS was obtained from sources which
we believe are reliable. However, the information is provided without any warranty, express or
implied regarding its correctness. The conditions or methods of handling, storage, use and
disposal of the product are beyond our control. For this and other reasons, we do not assume
responsibility and expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of this product. This MSDS was
prepared and is to be used only for this product. This MSDS has been prepared in accordance
with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200).
Download