GLASS MAGIC 4302 W LOOP 289 LUBBOCK, TX 79407 972-378-3291 PHONE resin@glassmagic.net www.glassmagicresin.com Effective 1/1/2009 MATERIAL SAFETY DATA SHEET GLASS MAGIC WINDSHIELD REPAIR RESIN – OLIGOMER GENERAL INFORMATION EMERGENCY PHONE NUMBERS: 972-378-3291 PRODUCT INFORMATION: 972-378-3291 GENERIC NAME: Acrylic Ester DOT SHIPPING NAME: Not regulated DOT HAZARD CLASS: Not regulated SUMMARY OF HAZARDS WARNING: PHYSICAL HAZARDS: ACUTE HEALTH EFFECTS: CHRONIC HEALTH EFFECTS: THRESHOLD LIMIT: VALUES Unstable (reactive) upon depletion of inhibitor May be slightly toxic irritating by inhalation slight eye irritation moderate skin irritant slight ingestion hazard light skin absorption hazard Prolonged or repeated skin contact may cause allergic skin reactions. ACGIH-TWA PPM MG/M3 0.5 COMPONENTS Glass Magic Windshield Repair Resin is an acrylic oligomer, the exact composition of which is considered a proprietary secret. PHYSICAL AND CHEMICAL DATA Boiling Point AP 275 C / 527 F Freezing Point AP 5 C / 41 F Specific Gravity (H20= 1 at 39.2F) AP .98 at 25C Vapor Pressure 20mm Hg at 140 C / 284 F Volatile Characteristics Negligible Solubility in Water Moderate Vapor SP GR (Air = 1 at 60 – 90 F) GT 1 Appearance and Odor Amber liquid with mild odor Conditions and Material to Avoid High Temperatures; Oxidizing conditions; Freezing Conditions; Direct sunlight storage. Strong oxidizers And reducers; Sparks and open flames; Free radical Initiators Hazardous Decomposition Products Incomplete combustion may generate carbon monoxide and acrid smoke / fumes. OCCUPATIONAL EXPOSURE LIMITS Threshold limit values ACGIH-TWA PPM MG/M3 .05 FIRE AND EXPLOSION HAZARDS Flash Point Method = (PMCC) 240F Flammable Limits (% Volume in air) Lower: N/DA Upper: N/DA Fire and Explosion Hazards High temperatures/inhibitor depletion/accidental Impurities/exposure to radiation/oxidizers may cause Spontaneous Polymerizing Reaction, Generating Heat/Pressure Extinguishing Media Dry Chemical CO2 Foam Use water spray/water fog for cooling Special fire fighting procedures Heat/Impurities may increase temperature/build Pressure/rupture closed containers spreading Fire, increasing risk of burn/injuries. Water may be ineffective in fire fighting due to moderate solubility. HEALTH HAZARDS Routes of Exposure: Inhalation Inhalation is not expected to be a primary route of exposure due to the low volatility of this material at room temperature; however exposure via inhalation may cause sneezing, coughing and mucous production. Eye Contact-primary route May cause minor eye irritation. Symptoms of irritation may include excessive tearing, redness and blinking. Skin Absorption No significant signs or symptoms indicative of any health hazard are expected to occur as a result of skin absorption exposure. Skin Irritation-primary route This material may cause moderate skin irritation and burning along with allergic skin reaction. May cause rash, redness, swelling and blistering. These systems may be delayed. Ingestion This material may be a slight health hazard if ingested in large quantities. May cause burns of mouth and throat. Medical Conditions Aggravated by Exposure This material or its emissions may induce an allergic or sensitization reaction and thereby aggravate systemic disease. Effects of overexposure: DO NOT MISTAKE BOTTLE FOR EYE DROPS OR NASAL SPRAY! May cause severe irritation with corneal injury which may result in permanent impairment of vision. Vapors may irritate eyes. May cause skin irritation, even possible burning on contact. Slight oral toxicity. LD50 for rats was between 250 and 500 mg/kg. Ingestion of large amounts could cause burns of mouth and throat. Inhalation of concentration as low as 5 ppm may cause nasal irritation. PROTECTIVE EQUIPMENT/CONTROL MEASURES Respiratory Protection Ventilation: Suitable to keep exposure levels below recommended TLV. Eye Protection Eye Protection such as safety goggles when possibility exists for eye contact due to splashing. Skin Protection When skin contact is possible, protective clothing including gloves, apron, sleeves, boots, head and face protection should be worn when handling chemical in bulk. We suggest the use of nitrile gloves. Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Promptly remove soiled clothing/wash thoroughly before reuse. Shower after work using plenty of soap and water. EMERGENCY AND FIRST AID Inhalation Not expected to present a significant inhalation hazard under anticipated conditions of normal use. However, if vapors or mists cause irritation, or breathing becomes difficult, remove to fresh air. Give oxygen or artificial respiration as needed. Get medical attention. Eye Contact In case of eye contact, immediately rinse with clean water for 20-30 minutes. Retract eyelids often. Obtain emergency medical attention. Skin Contact Immediately remove contaminated clothing. Wash skin thoroughly with mild soap/water. Flush with lukewarm water for 15 minutes. If sticky, use waterless cleaner first. Seek medical attention if ill effect or irritation develops. Ingestion Ingestion unlikely. However, if ingested, give large amounts of milk and transport to medical facility. Emergency Medical Treatment Procedures If exposed, treat skin and eye burns or irritation conventionally after decontamination. SPILL AND DISPOSAL Precautions if bulk material is spilled or released. Release can cause fire/explosion. May polymerize and release heat/gases. Extinguish all ignition sources. Blanket with fire fighting foam. Soak up spill. Waste Disposal Methods Dilute aqueous waste may biodegrade. Avoid over loading/poisoning plants. Absorb with clay, earth, etc. and collect solid waste for disposal. ADDITIONAL PRECAUTIONS Handling and Storage Procedures Unless inhibited, material can polymerize, raising temperature and pressure, possibly rupturing container. Prevent freezing, inhibitor separates as solid. If frozen, material must be warmed and remixed gently (less than 90ºF). Freezing point 41ºF. LABEL INFORMATION Use statement For industrial use only Keep out of reach of children Signal Word Warning Physical Hazards Unstable (reactive) upon loss of inhibitor Health Hazards May cause skin irritation/allergic skin reaction Precautionary Measures Do not handle near heat, sparks, or open flame. Material is unstable and hazardous polymerization may occur. Keep container closed when not in use. Avoid contact with eyes, skin and clothing. Avoid prolonged or repeated contact with skin. Use only with adequate ventilation/personal protection. Prevent contact with food, chewing or smoking materials. Wash thoroughly after handling. SUPPLEMENT MPCA HMIS Rating Health Flammability Reactivity Personal Protection 2 1 2 **D **Respiratory Protection may be necessary depending on conditions of use-NIOSH/MSHA approved air-purifying or supplied air respirator is recommended in situations where airborne concentrations may be significant (i.e. vapor or mist generating conditions). This product contains an inhibitor at less than 1%. This inhibitor requires oxygen to work and is therefore stored in polyethylene bottles which are not full. This gives oxygen from the air in the bottles for the inhibitor to use. WARNING: DO NOT STORE RESIN IN A GLASS BOTTLES WHICH IS COMPLETELY FULL. DO NOT STORE RESIN IN A METAL CONTAINER. KEEPING RESIN COOL AT 45ºf (REFRIGERATOR) WILL PROLONG SHELF LIFE. KEEP OUT OF DIRECT LIGHT AND HEAT FOR MAXIMUM USEFUL LIFE. SHELF LIFE AT AMBIENT CONDITIONS IS 12 MONTHS. Note: Qualifiers and codes used in this MSDS N/AP = Not applicable N/DA = No data available AP = Approximately GT = Greater than DISCLAIMERS Some of the information presented and conclusions drawn are from sources other than direct test date on the product itself. The information in the MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this product. This MSDS was prepared and is to be used only for this product. This MSDS has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200).