WEATHERING & EROSION PHYSICAL WEATHERING Physical weathering is more effective in areas which have: ~ a little vegetation ~ a large diurnal (day to night) range of temperature or ~ temperatures fluctuating around 0 degrees Celsius Contact Forces It happens when a force is applied to a rock and it breaks into smaller pieces. A larger rock falling onto another rock below or wind whipping sand against other rocks thus breaking tiny pieces off (sand blasting) are examples of contact forces. Pressure Release It takes place when the overlying rocks are removed by erosion. With the release of pressure, the rock expands. causing stress within the rock. Cracks are formed parallel to the rock surface. Over a period of time, the outer layers of the rock break away in sheets. Exfoliation It occurs in places like hot deserts where the day temperature often soars to 40 degrees Celsius and night temperature falls to below 10 degrees Celsius. The repeated heating by day and cooling by night cause the outer layers of the rock to expand and contract alternately. Stress is created in the rock, producing cracks and gradually, the outer layers of rock will peel off. Frost Shattering (Ice) It occurs in cold temperate regions and mountain tops where temperatures fluctuate above and below freezing point. Water fills the cracks or joints in the rock and freezes at night or during winter. Repeated freeze- thaw will eventually shatter the rock along the cracks or joints into angular pieces. The broken materials collect at the foot of the slope to form a scree. Crystallization or weathering by growth of salt crystals takes place in deserts where evaporation draws ground water containing dissolved salts upwards into the pores of the rock. When the water evaporates , the salts are left behind as crystals. The build-up of the salt crystals creates stress in the rock, weakens it and breaks it down into grains. Biological Weathering roots growing into the cracks and joints in rocks earthworms and termites making tunnels in the ground man building roads and cultivating the land , exposing the rocks to other agents of weathering. CHEMICAL WEATHERING Chemical weathering refers to the breakdown of an object into particles with a different mineral composition than the original object. Water is perhaps the most powerful agent of chemical weathering: Over time, it can dissolve many kinds of rocks into a solution that has a different chemical makeup than the original substance. Other types of chemical weathering involve more complicated chemical reactions with oxygen, carbon dioxide, water or other compounds. The primary agents in chemical weathering are water, oxygen, and acids. Oxidation takes place when oxygen reacts with earth materials. Oxygen dissolved in water combines with atoms of metallic elements abundant in silicate minerals. Attacking metals in the soil, oxidation causes them to rust leaving the soil a brownish red to red color. When oxygen combines with iron, the reddish iron oxide hematite (Fe2O3) is formed: 4Fe+3 + 3O2 -> 2Fe2O3 Hydrolysis is an exchange reaction involving minerals and water. Free hydrogen (H +) and hydroxide (OH)- ions in water are able to replace mineral ions and drive them into solution. As a result, the mineral's atomic structure is changed into a new form. It is a process whereby silicate minerals like potassium feldspar are weathered and a clay mineral is formed. 2KAlSi3O8 + 2H+ + 9 H2O -> Al2Si2O5(OH)4 + 4H4SiO4 + 2 K2+ Hydration involves the absorption of water like which occurs during the conversion of hematite to limonite: 2Fe2O3 + 3H20 -> 2Fe2O3 . 3H20 Some geoscientists question whether hydration is a true chemical weathering process because the process is readily reversible and the new product is not chemically different from its precursor. Some would rather call hydration a physical weathering process. Carbonic acid action involves combination of carbon dioxide and water. Though present in pure water, carbon dioxide dissolved in water provides ions that produces free hydrogen. Carbon dioxide in the atmosphere combines with rain water to form carbonic acid (H2CO3): H2O + CO2 -> H2CO3 Though weak, when carbonic acid is combined with a mineral like calcite (CaCO 3) common to limestone, calcium and bicarbonate ions are released and carried off by groundwater. CaCO3 + H2CO3 -> Ca+2 + 2 HCO-3 Biological Agents secreting enzymes (such as bacteria, fungus, lichens, etc.) can release sufficient amounts of enzymes that over time, they break down the rock.