Enthalpy and Hess`s Law

advertisement

Enthalpy and Hess’s Law

Supplemental Instruction

Iowa State University

Leader: Lilli Howard

Course: Chem 177 (BC)

Instructor: Dr. Irmi

Date: 10/14/13

1.

The __________________ _____________ for a substance is its most stable form at the given temperature and pressure.

2.

Fudge is about 2% protein, 11% fat, and 81% carbohydrates. The average “fuel value” of these are as follows: protein = 17 kJ/g fat = 38 kJ/g carb = 17 kJ/g. a.

What is the “fuel value” of 10 g of fudge? How many Calories does 10 g contain?

3.

Calculate the enthalpy change for the reaction: C(s) + ½ O

2

(g)

CO(g)

The following information is given: a.

C(s) + O

2

(g)

CO

2

(g) b.

CO(g) + ½ O

2

(g)

CO

2

(g)

ΔH = -393.5 kJ

ΔH = -283.0 kJ

4.

Calculate the enthalpy change for the reaction: C

2

H

4

(g) + H

2

(g)

C

2

H

6

(l)

The following information is given: a.

C

2

H

4

(g) + 3 O2(g)

2CO

2

(g) + 2 H

2

O(l) b.

2 H

2

(g) + O

2

(g)

2 H

2

O(l) c.

2 C

2

H

6

(l) + 7 O

2

(g)

4 CO

2

(g) + 6 H

2

O(l)

5.

Write the reaction associated with the standard enthalpy of formation for each of the following: a.

AgCl(s) b.

NH

3

(g) c.

Na

2

CO

3

(s)

1060 Hixson-Lied Student Success Center

515-294-6624

sistaff@iastate.edu

http://www.si.iastate.edu

6.

Calculate the standard enthalpy change for the reaction:

CH

2

N

2

(s) + O

2

(g)

CO(g) + H

2

O(l) + N

2

(g)

The following information is given: a.

CO(g) = -110.5 kJ/mol b.

CH2N2(s) = +62.4 kJ/mol c.

H2O(l) = -285.8 kJ/mol

7.

A small coffee cup calorimeter contains 110 g of water at 22.0 °C. A 100 g sample of lead is heated to 90.0°C and then placed in the water. The contents of the calorimeter come to a temperature of 23.9°C. What is the specific heat of lead?

Download