Paper I
I
Inorganic Chemistry
3 Credits (45 Hrs)
3 Hrs. / Week
Atomic Structure:
15 Hrs.
Atomic orbital’s, Quantum numbers, Heisenberg uncertainty
principle, shapes of s, p, d orbital’s. Aufbau and Pauli exclusion principles.
Hund's multiplicity rule. Electronic configurations of the elements, Bohr's
atomic model (Qualitative aspect only).
II
Periodic Properties:
10 Hrs.
Atomic and Ionic radii, Ionization Energy, Electron affinity and
Electro negativity. Trends in periodic table and application in predicting
and explaining the chemical behavior.
III
S-Block Elements:
10 Hrs.
Comparative study, diagonal relationship, salient features of
hydrides, solvation and complexation tendencies including their functions
in biosystems.
IV
P - Block Elements:
10 Hrs.
Comparative Study (including diagonal relationship) of groups 1317 elements, compounds like hydrides oxides of groups 13-16. Interhalogen
compounds and its types.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
B.Sc. (First Year)
First Semester
Paper II
I.
Organic Chemistry
3 Credits (45 Hrs)
3 Hrs. / Week
Structure and Bonding:
Localized
and
6 Hrs.
delocalized
chemical
bond;
charge
transfer
complexes, resonance, hyper conjugation, inductive effect, hydrogen
bonding, conjugative effect, steric effect.
II
Mechanism of Organic Reactions:
8 Hrs.
Homolytic and heterolytic bond breaking. Types of reagents
eletrophiles and nucleophiles. Types of organic reactions. Energy
considerations. Reactive intermediates - carbocations, carbanions, free
radicals (with two examples each) Methods of determination of reaction
mechanism (product analysis, intermediates, isotope effects, kinetic and
stereo - chemical studies with two examples each)
III
Stereochemistry of Organic Compounds :
8 Hrs.
 Concept of Isomerism - Types of isomerism
 Optical Isomerism - elements of symmetry, molecular chirality,
enantiomers, stereogenic centre, optical activity, properties of
enantiomers, chiral and achiral molecules with two stereogenic centres,
diastereomers, threo and erythro diastereomers, meso compounds.
 Relative and absolute configuration, sequence rules, D and L and R and
S systems of nomenclature.
 Geometric Isomerism - Determination of configuration of geometric
isomers. E and Z system of nomenclature, geometric isomerism in
oximes and alicylic compounds.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
IV
Alkane :
6 Hrs.
Methods of formation (Koble reaction, Corey - House reaction and
decarboxylation of carboxylic acids)
Physical properties and Chemical reactions of alkanes
V
Alkene :
6 Hrs.
Nomenclature of alkenes, methods of formation, mechanisms of
dehydration of alcohols and dehydrohalogenation of alkyl halides. The
Saytzeff rule, Hofmann elimination, physical properties and relative
stabilities of alkenes. Chemical reactions of alkenes - mechanisms involved
in hydrogenation, electrophilic and free radical additions, Markownikoff's
rule, hydroboration and oxidation with KMnO4. Polymerization of alkenes
with one example each.
VI
Arenes and Aromaticity:
6 Hrs.
Nomenclature of benzene derivatives. The aryl group. Aromatic nucleus
and side chain structure of benzene : molecular formula and Kekule
structure.
Resonance Structure, MO Picture.
Aromaticity : The Huckel rule, aromatic ions
Aromatic electrophilic substitution: General Pattern of the mechanism
(Nitration, halogenations and Sulphonation) and Friedel Crafts reaction.
VII
Alkyl and Aryl halides:
5 Hrs.
Polyhalogen Compounds: Chloroform, Carbon tetrachloride. Methods formation of aryl halides, nuclear and side chain reaction.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
B.Sc. (First Year)
First Semester
Paper III
I
Lab Course I
45 Hrs. 3 Hrs / Week
Volumetric Analysis :
15 Hrs.
 Calibration of Burette and Pipettee
 Preparation of 0.1N. NaOH solution and its standardization
by given oxalic acid solution.
 Preparation of 0.1 N oxalic acid solution and its
standardization by given KMNO4 solution.
II
Inorganic Qualitative Analysis :
30 Hrs.
 Identify two acid and two basic radical from the given
binary mixture.
a] CdSO4 + NH4Cl
b] BaCO3 + Al2 (NO3)3
c] ZnCO3 + KBr
d] MnCO3 + MgSO4
e] NiSO4 + MgCO3
B.Sc. (First Year)
First Semester
Paper IV
Lab Course II
1.5 Credits (45 Hrs.)
3 Hrs / Week
 Eudiometer
:
Determination of Equivalent weight
of Mg
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
 Viscometer
:
To Determine Viscosity of given
liquid (Water /
Ethanol) by
viscometer
 Staglanometer
:
To determine surface tension of
given liquid.
 Chemical Kinetics :
* To study the effect of acid
strength on the hydrolysis of an
ester.
* To determine the specific reaction
rate of the hydrolysis methyl / ethyl
acetate catalyzed by hydrogen ions
at room temperature.
B.Sc. (First Year)
Second Semester
Paper V
I
Physical Chemistry
3 Credits (45 Hrs)
3 Hrs. / Week
Mathematical Concepts :
10 Hrs.
Logarithmic relations, curve sketching, linear graphs and calculation
of slopes, differentiation of functions like kx ex, xn, sin x, log x; maxima and
minima, partial differentiation.
II
Gaseous States:
6 Hrs.
Postulates of kinetic theory of gases, kinetic gas equation, Deduction
of Gas Laws : Boyles Law, Charles Law, Grahams Law of diffusion,
Avogadro's hypothesis, deviation from ideal behavior, van der Waals
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
equation of state. Critical Phenomena : PV isotherms of real gases.
III
Chemicals Kinetics and Catalysis:
12 Hrs.
Chemical Kinetics and its scope, rate of reaction, factors influencing
the rate of reaction - concentration, temperature, pressure, solvent, light,
catalyst concentration dependence of rates. Derivation of rate law and
characteristics of simple chemical reactions - zero order, first order, second
order, Pseudo order, half life. Effect of temperature on rate of reaction.
Arrhenius equation, concept of activation energy.
Catalysis : Definition, types, and characteristics of catalysis,
homogeneous, heterogeneous catalysis - Enzyme catalysis and its
application.
IV
Liquid State:
6 Hrs.
Intermolecular forces, structure of liquids (a qualitative description).
Differnce between solids, liquids and gases.
Liquid Crystals: Classification, structure of nematic and cholestric phases.
V
Solid State :
6 Hrs
Types of solids, Amorphous, crystalline and difference between them,
Miller Indices.
Laws of crystallography - (i) Law of constancy of interfacial angels (ii)Law
of rationality of indices (iii) Law of symmetry. Symmetry elements in
crystals. X-ray diffraction by crystals. Derivation of Bragg equation.
VI
Colloidal State :
5 Hrs
 Definition of colloids, classification of colloids.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
 Solids in liquids (sols) : properties - kinetic, optical and electrical;
stability of colloids, protective action. Hardy - Schulze Law.
 Liquids in liquids (emulsions) : types of emulsions, preparation.
 Liquids in Solids (gels) : classification, preparation and properties,
general applications of colloids.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
B.Sc. (First Year)
Second Semester
Paper VI
I
Inorganic Chemistry - II
Chemistry of noble gases :
3 Credits
3 Hrs. / Week
5 Hrs.
Chemical properties of the noble gases, chemistry of xenon,
structure and bonding in xenon compounds.
II
Chemical Bonding:
(A)
20 Hrs.
Covalent Bond - Valence theory and its limitations, directional
characteristic of covalent bond, various types of hybridization and
shapes of simple inorganic molecules and ions, Valence shell
electron pair repulsion (VSEPR) theory of NH3, SF4, CIF3, ICI2 and
H2O. MO theory, homonuclear (He, N2 and O2) and heteronuclear
(CO and NO) diatomic molecules, bond strength and bond energy,
percentage ionic character from dipole moment and electro
negativity difference.
(B)
Ionic Bonds - Definitions, Factors affecting ionic bond formation.
(C)
Hydrogen bonding, Van-der-Waals forces, Metallic bond and its free
electron concept.
III
Nuclear Chemistry:
10 Hrs.
Definition; Atomic number, mass number, Isotopes, Isobars mass
defect and Binding Energy, Packing fraction N/Z ratio, Radio activity,
properties of ,  and , Artificial transmutation. Applications with respect
to trans-uranic elements, carbon dating.
IV
Theory of volumetric Analysis:
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
10 Hrs.
Types of titrations, volumetric apparatus, calibration of pipette and burette.
Indicators used in pH - titrations, oxidizing agents used in titrations.
Theory of Internal, External and self indicators for redox titration.
B.Sc. (First Year)
Second Semester
Paper VII
Lab Course III
I
45 Hrs
(3 Hrs. / Week)
Inorganic Preparation :
24 Hrs.
 Preparation of tetramine Cupric Sulphate
 Preparation of Nickel Demethyl Glyoxime (Ni-DMG)
 Preparation of Tris-ethylene diamine Nickel (II) thiosulphate
II
Estimation:
21 Hrs.
 Standardization of NaOH solution by (0.1 N) oxalic acid solution
and estimation of given HCl solution.
 Standardization of KMnO4 solution by (0.1 N) oxalic acid solution
and estimation of Ferrous ion (Fe2+) from the given solution.
 Preparation of (0.1 N) Sodium Thiosulphate and standardization by
given iodine solution.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
B.Sc. (First Year)
Second Semester
Paper VIII
Lab Course IV
I
45 Hrs
(3 Hrs. / Week)
Organic Qualitative Analysis:
30 Hrs.
Nature / Functional group / Element / Derivative / Physical constant
* Benzoic acid, * salicylic acid, * -naphthol, * p-nitroaniline,
* Naphthalene, * Acetanilide.
II
Organic Estimation:
15 Hrs.
 Phenol by Bromination
 Estimation of basicity, molecular weight of organic acid
(oxalic/acetic acid)
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
B.Sc. (Second Year)
Third Semester
(Organic Chemistry)
Paper IX
45 Hrs (3 Hrs/week)
1) Alcohols:
Defination:
6 Hrs.
Monohydric Alcohols: Methods of Formation by reduction of
Aldehydes, Ketones, Carboxylic Acids and Esters (One eg.each) Acidic Nature,
Reactions of Alcohols.
Dihydric Alcohols: Method of Formation of Ethylene Glycol-industrial method
and
From Alkene using OsO4, Chemical Reactions of Ethylene Glycol-nitration,
Acylation,
Oxidation ( Using Pb(OAc)4 without Mechanism Pinacol-Pinacolone
rearrangement,
Trihydric Alcohols: Preparation of Glycerol from propane, Reactions of Glycerol.
2) Phenols:
6 Hrs.
Preparation of Phenol from Chlorobenzene, Cumene and Benzene Sulphonic Acid,
Physical properties, Acidic Nature of Phenol, Resonance stabilization of
Phenoxide Ion. Reactions of Phenols- Electrophilic Aromatic Substitution,
Acylation, Carboxylation ( Without Mechanism) Reactions with Mechanismintramolecular Fries Rearrangement, Claisen Rearrangement, Gatterman Synthesis
and Reimer Tiemann Reaction.
3) Aldehydes and Ketones:
10Hrs.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
Aldehydes: Preparation of Aldehydes from Acid Chloride, Gattermann-Koch
synthesis
Ketones- Preparation from nitriles and from Carboxylic Acid, Physical
Properties of
Aldehydes and Ketones. Mechanism of Nucleophilic Additions to
Carbonyl Group with particular emphasis on Benzoin, Aldol Knoenenagel
condensations, Mannich Reactions. Use of Acetals as Protecting Group. Oxidation
of Aldehydes using Chromium Trioxide, Baeyer-Villeger Oxidation of Ketones.
4) Carboxylic Acids:
9 Hrs.
Acidity of Carboxylic Acids, Effects of substituents on Acid strength, preparation
of Acetic Acid from CO2 from Nitriles, from Acid Chloride, Anhydride, Ester and
Amide.
Physical Properties and reactions of Carboxylic Acids-Synthesis of Acid Chloride,
Ester and Amide, Hell-Volhard-Zelinsky Reaction. Reduction using LiAIH4,
Mechanism of Decarboxylation, Hydroxyl Acids- Malic, Tartaric and Citric Acid.
Methods of Formation and Chemical reactions of Acrylic Acid.
5) Organic Compounds of Nitrogen:
14 Hrs.
Preparation of Nitroalkanes and Nitroarenes.
Chemical reactions of Nitroalkanes. Nitration of Benzene and Their Reduction in
Acidic, Neutral and Basic media.
Amines- Basicity of Amines, Amine Salt as PTC. Preparation of Alkyl and Aryl
Amines (Reduction of Nitro Compounds, Nitriles) Reductive Amination,
Hoffmann Bromamide Reactions. Reactions of Amines- Electrophilic Aromatic
Substitution in Aryl amines, Reactions of Amines with Nitrous Acid.
B.Sc. (Second Year)
Third Semester
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
(Physical Chemistry-I)
Paper X
45 Hrs (3 Hrs/week)
1) Thermodynamics: I
15Hrs
Definition of Thermodynamic Terms: System, Surrounding types of system,
intensive and extensive properties. Thermodynamic Process, Concept of heat and
work. Work done in reversible and irreversible process, concept of maximum
work (Wmax), Numerical problems. First law of Thermodynamics: Statement,
Definition of Internal energy and Enthalpy. Heat capacity, heat capacities at
constant volume pressure and their relationship. Calculation of W, q, du and dH
for the expansion of ideal gases under isothermal and adiabatic conditions for
reversible process, Numerical problems, Hess’s law of heat Summation and its
application.
2) Thermodynamic-II :
20 Hrs
Second Law of Thermodynamics: Need for the law, different statement of the law.
Carnot Cycle and its efficiency, Numerical Problems. Carnot Theorem.
Concept of Entropy : Definition, Physical significance, Entropy as a State
Function, Entropy change in Physical change, Entropy as a criteria of Spontaneity
& Equilibrium Entropy Change in Ideal Gases. Gibbs and Helmholtz Functions:
Gibbs Function (G) and Helmoltz Function (A) as Thermodynamic Quantities. A
and G as criteria for Thermodynamic Equilibrium and Spontaneity, their
Advantage over Entropy change. Variation A with P, V and T.
3) Chemical Equilibrium:
10 Hrs
Equilibrium Constant and Free Energy. Thermodynamic Derivation of Law of
Mass Action. Le Chatelier’s Principle. Reaction Isotherm and Reaction Isochore.
Clapeyron
Equation, Clausius-Clapeyron Equation and its Application.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
B.Sc. (Second Year)
Third Semester
Lab Course V
Paper XI
(Physical Chemistry)
45 Hrs (3 Hrs/week)
Non Instrumental
i) To determine critical solution temperature of Phenol- water system.
ii) To determine solubility of benzoic acid at different temperature and determine
Δ H of dissolution process.
iii) To determine heat of neutralization (Δ Hn) of NaOH and HCl
iv) To determine heat of neutralization (Δ Hn) of NaOH and Acetic acid.
v) Partition coefficient of Benzene – water system using benzoic acid.
vi) To determine the equilibrium constant for the reaction: KI + I2
----- KI3
vii) Determine the molecular mass of polymer from viscometry measurements.
viii) To investigate the Kinetics of Iodination of acetone.
B.Sc. (Second Year)
Third Semester
Lab Course VI
Paper XII
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
(Inorganic
Chemistry)
45 Hrs (3 Hrs/week)
Gravimetric Estimation:
i) Estimation of Zinc gravimetrically as Zinc ammonium phosphate (ZnNH4 PO4)
ii) Estimation of Mn gravimetrically as manganese ammonium phosphate
(MnNH4PO4)
iii) Estimation of Nickel gravimetrically as Ni-DMG
iv) Estimation of Barium gravimetrically as Ba-Chromate (BaCrO4)
v) Estimation of Aluminium as Aluminium Oxinate.
Complex metric Titration:
i) Estimation of Zinc by EDTA solution using EBT indicator.
ii) Estimation of Nickel by EDTA using Murexide indicator
iii) Estimation of copper by EDTA using fast sulphon black F indication
iv) Estimation of Lead By EDTA using Xylenol Orange indicator.
B.Sc. (Second Year)
Fourth Semester
(Inorganic Chemistry)
Paper XIII
45 Hrs (3hrs/week)
1) Chemistry of Elements of First Transition Series:
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
10 Hrs.
General characteristic features of d-block elements. Properties of the elements of
the first transition series: Ionic Size, Atomic Size, Metallic properties, Ionization
potential, magnetic properties, Oxidation State.
2) Co-ordination Compounds:
10 Hrs
Werner’s Co-ordination Theory and its experimental verification, effective atomic
Number concept, chelates, nomenclature of co-ordination compounds, isomerism
in Co-ordination compounds, valence bond theory of transition metal complexes.
3) Chemistry of Lanthanide Elements:
06 Hrs
Occurrence and Isolation of Lanthanides, Electronic Configuration, Oxidation
States, Ionic Radii, Lanthanide Contraction and its Consequences.
4) Chemistry of Actinides:
05 Hrs
Occurrence, Position in the periodic table, Electronic configuration. Oxidation
State, chemistry of separation of Np, Pu and Am from U
5) Acids and Bases:
06 Hrs
Arrhenius, Bronsted-Lawry, The Lux-Flood, Solvent System and Lewis Concept
of
Acids and Bases
6) Non-Aqueous Solvents:
08 Hrs Physical
Properties of a Solvent, Types of Solvents and their general Characteristics,
Reaction in Non-Aqueous Solvents with reference to liquid NH3 and liquid SO2
B.Sc. (Second Year)
Fourth Semester
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
(Physical Chemistry-II)
Paper XIV
45 Hrs (3 Hrs/week)
1) Phase Equilibrium:
15 Hrs
Statement and Meaning of the Terms: Phase, Component, Degree of Freedom,
Derivation of Phase Rule Equation.
Phase Equilibria of the One Component System: Water System.
Phase Equilibria of Two Components System: Solid-Liquid Equilibria, Simple
Eutectic Pb-Ag. System Desilverisation of Lead.
Solid Solutions : Compound formation with congruent Melting Point (Mg-Zn) and
Incongruent Melting Point (FeCl3 – H2O) System. Freezing Mixture, Acetone-Dry
Ice.
Liquid-Liquid Mixture: Raoult’s Law and Henry’s Law.
Ideal and Non-Ideal system. Azeotropes: HCl – H2O and Ethanol – Water System.
Partially Miscible Liquids : Phenol –Water, Trimethyl Amine – Water, Nicotinewater
System, Lower and Upper Consulate Temperature. Effect of Impurity on
Consulate
Temperature.
2) Electro Chemistry- I
15 Hrs
Electrical Transport: Conduction in metals and in Electrolyte Solutions. Specific
Conductance and equivalent conductance, measurement of equivalent conduction,
variation of equivalent and specific conductance with dilution. Numerical
problems. Kohlrausch’s law and its application. Arrhenius Theory of Electrolyte
Dissociation and its limitations. Weak and Strong Electrolytes, Ostwald’s Dilution
Law, its use and Limitations. Transport Number: Definition, Determination by
Hittorf’s Method and Moving
Boundary Method. Conductometric Titration :
Types and its advantages.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
3) Electrochemistry – II
15 Hrs
Types of Reversible Electrodes: Gas-Metal Ion, Metal-Metal Ion, Metal-Insoluble
salt Anion and Redox Electrodes. Nernst Equation, Derivation of Cell, E.M.F. and
single Electrode Potential, Standard Hydrogen Electrode, Reference Electrodes,
Standard Electrode Potential, Sign Conventions, Electro-Chemical Series and its
significance. Electrolytic and Galvanic Cells, Reversible and Irreversible Cells,
Conventional Representation of Electro Chemical Cells. E.M.F. of a Cell and its
Measurement, Calculation of Thermodynamic Quantities of Cell Reactions (ΔG,
ΔH and K)
Definition of pH, pKa- Determination of pH using SHE and Glass Electrode by
Potentiometer method. Buffer- Acidic and Basic Buffers, Mechanism of Buffer
Action, Henderson- Hasselbalch equation.
Corrosion: Dry (Atmospheric) Corrosion and Wet (Electro-Chemical) Corrosion
Electrochemical Theory of Corrosion.
B.Sc. (Second Year)
Fourth Semester
Lab Course VII
Paper XV
(Physical Chemistry)
45 Hrs (3 Hrs/week)
Instrumentation:
i) To determine normality and strength of HCl using (0.1N) NaOH Solution
Conductmetrically.
ii) To determine normality and strength of acetic acid using (0.1N) NaOH solution
Conductmetrically.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
iii) To determine normality and strength of HCl using (0.1N) NaOH solution by
pH- metrically.
iv) To Verify Lambert-Beers Law using KMnO4 solution.
v) To estimate the amount of Sugar using Polarimeter.
vi) To determine refractive index of ethanol water system.
vii) To determine indicator constant of indicator colorimetrically.
B.Sc. (Second Year)
Fourth Semester
Lab Course VIII
Paper XVI
(Organic Chemistry)
45 Hrs (3 Hrs/week)
Organic Derivatives:-
Preparation, Crystallization
and Physical Constant:-
i) Acetyl Derivatives
:
a) Aniline
b) Salicylic Acid
ii) Benzoyl Derivatives
:
a) Aniline
b) β-naphthol
iii) Hydrolysis Derivatives
:
a) Ethyl Benzoate b) Aspirin
iv) Bromo-Derivatives
:
a) Phenol
b) Cinnamic Acid
v) Reduction Derivatives
:
a) m-dinitrobenzene
vi) Osazone Derivatives
:
a) Sucrose
b) Glucose
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry
Organic Estimations:i)
Estimation of nitro group by reduction.
ii)
Estimation of glucose
iii)
Estimation of ester by hydrolysis
iv)
Estimation of amides by hydrolysis.
Nirmal krida & samaj Probodhan Trust’s
Arts, Science & Commerce college, Badnapur. Dist. Jalna
Department of chemistry