5th Swiss Geoscience Meeting, Geneva 2007 Multi-isotope study of Miocene foraminifers from the Mediterranean László Kocsis*, Torsten W. Vennemann*, Denis Fontignie**, Claudia Baumgartner*** and Alessandro Montanari**** * Institut de Minéralogie et Géochimie, University of Lausanne, Switzerland, laszlo.kocsis@unil.ch, torsten.vennemann@unil.ch ** Département de Minéralogie, University of Geneva, Switzerlanddenis.fontigniel@unige.ch *** Institut de Géologie et Paléontologie, University of Lausanne, Switzerland, claudia.baumgartner@unil.ch **** Osservatorio Geologico di Coldigioco Frontale di Apiro, Italy, sandro.ogc@fastnet.it The composite section of the Umbria-Marche region in Italy represents a continuous marine pelagic sequence of the Mediterranean, deposited during the Oligocene up to the Middle Miocene (Montanari et al., 1997). At this time the Mediterranean was an open seaway between the Atlantic and the Indo-Pacific provinces, which closed towards the end of the Middle Miocene (e.g. Rögl, 1998). The main aim of this study is to constrain changes in the oceanic circulation and climate in this part of the Mediterranean in order to examine the possibility of a regional influence on climate related to the tectonism of the circum-Alpine region. To achieve this aim, well-preserved carbonaceous fossils and the carbonate free, detrital fraction of the sediments were analyzed for their Nd and Sr isotopic compositions. While isotopic compositions of the marine fossils can provide information on the composition of the seawater, those of the detrital sediments help to constrain the local silicate inputs for Nd and Sr from the hinterland. In addition, planktic and benthic foraminifera were analyzed separately for their O and C isotope compositions in order to trace habitat conditions, climatic changes and help to evaluate possible diagenetic alteration of the fossils Oxygen isotope compositions of benthic and planktic foraminifera preserved their typical offset related to their habitat and also vary in concert with those used for evaluating global changes in climate. Carbon isotope compositions also reflect differences that are typical for the carbon isotope compositions of dissolved inorganic carbon in bottom and surface waters. Furthermore, at between 17-13 Ma a positive 13C excursion is noted and this correlates well with the globally recognized Monterey carbon isotope event. These results support preservation of the stable isotope compositions of the fossils. According to the results of the radiogenic isotope measurements, the UmbraMarche composite section can be divided into three periods: 1) During the period from 25 to 19 Ma the fossils are characterized by high Nd values, with values similar to those of the silicate fraction of the sediments. The 87Sr/86Sr ratios are lower than those of the global open ocean at the time and are also low for the silicate fraction. These compositions are interpreted to result from intense volcanism due to the opening of the western part of the Mediterranean Sea (e.g., Gueguen et al., 1998). 5th Swiss Geoscience Meeting, Geneva 2007 2) Between 19-13 Ma the sediments have all have low Nd values of about -10, while the fossils have an average value of -8.5, slightly increasing throughout this section though. There is a short period at around 15.2 Ma where the Nd of the fossils deviate from the above described trend with a rise to a Nd value of 7, followed by a decrease to the background sediment Nd value of - 10 again. The Sr isotope ratios of the fossils are still lower than those for the Miocene global ocean. The short change at 15.2 Ma is related to a sporadic volcanic event, also supported by elevated Nd and low 87Sr/86Sr values of the detrital sediment. The following decrease in the Nd value can be ascribed to an increase in the terrestrial input from the hinterland which also coincides with the TB 2.3-2.4 sea-level decrease cycle (Haq et al., 1987). The low 87Sr/86Sr of the fossils may be explained by weathering and erosion of Mesozoic carbonates, known to be abundant in the hinterland, and an influence thereof on the composition of the local marine basin. The warm, humid climate during this time was also favorable for the weathering of carbonates, as indicated by the oxygen isotope data. 3) During the third time interval (13-7 Ma) the Sr isotope ratios of the fossils reflect those of the Middle Miocene open ocean, with one exception given by the youngest sample. The average Nd value of the sediment remains the same, but those of the fossils vary considerably. Around 12 to 11 Ma a change in the Nd values to between -10 and -9 can be observed for the fossils. At 10 Ma this is directly followed by an increase to Nd values of between -8 and -7. Towards the end of the section, at about 8 Ma, the Nd value decreases to -9 again. This fluctuation parallels the changes in global sea-level. The strong negative shift in Nd value concurs with transgression and indicates a strengthening Atlantic water inflow into the Mediterranean. During regressions, however, water with Nd values similar to the Miocene Indian Ocean was unlikely to have entered the marine basins in this region, on the basis of paleontological data that indicates that the Indo-Pacific influence in the region has ceased (Rögl, 1998). Therefore, seawater via the remnants of the Paratethys, which is known to have had such relatively high Nd values during the Middle Miocene (Kocsis et al., submitted) may have entered the Mediterranean. Alternatively, increased erosion of rocks elsewhere in the Mediterranean region having higher Nd values could have influenced this water mass. REFERENCES Gueguen, E., Doglioni, C. & Fernandez, M. 1998. On the post-25 Ma geodynamic evolution of the western Mediterranean. Tectonophysics, 298, 259–269. Haq, B. U., Hardenbol, J. & Vail, R. P. 1987. Chronology of fluctuating sea levels since the Triassic (250 million years ago to present), Science, 235, 1156– 1167. Kocsis, L., Vennemann, W. T, Hegner, E., Fontigne, D. & Tütken, T. (submitted). Paleoceanography and paleoclimate of the Miocene Paratethys: Evidence from the O-, Sr-, and Nd-isotope composition of marine fish and mammal remains. 5th Swiss Geoscience Meeting, Geneva 2007 Montanari, A., Odin, G.S. & Coccioni, R. 1997. Miocene Stratigraphy: An Integrated Approach. Dev. Palaeontol. Stratigr. 15., Amsterdam. Rögl, F., 1998. Palaeogeographic Considerations for the Mediterranean and Paratethys Seaways (Oligocene to Miocene). Ann. Naturhist. Mus. Wien 99, 279-310.