EXERCICE ON LCA OF WASTE TREATMENT Intensive composting versus controlled landfilling of organic waste GOAL OF THE EXERCICE Compare from an environmental point of view two ways of dealing with organic waste: sanitary landfilling and intensive (tunnel) composting Find out the contribution of the different processes to the overall impact Discuss the limitations of the study SYSTEMS TO ANALYSE The first system to analyse is the management of organic waste by means of intensive composting. The waste is collected from the bins and transported to a composting plant, where it is introduced in controlled tunnels. In this tunnels the piles of waste are intensively aerated in order to accelerate the process, and several parameters (humidity, oxygen, pH, etc) are monitored to optimise it. The air passing through the tunnels is later treated in a biofilter, in order to remove volatile compounds. After two weeks in these tunnels, the compost is extracted and maturated in piles, which are turned periodically. Finally the material obtained is a humus-like material, called compost, which is free of pathogens and ready to use for agricultural or garden purposes (Figure 1). Energy Resources System boundaries Households O. waste Waste bin Tr Emissions Composting Compost Waste COMPOSTING SYSTEM Figure 1. Composting system: Compost plant + Transport (Tr) The second system corresponds to the management of organic waste by sanitary landfilling. In this case, the waste is transported to a previously prepared area, in which the waste is covered with inert materials and compacted by bulldozers. In this conditions, the organic matter degrades slowly in anaerobic conditions, giving rise to biogas (with about 50% volume of methane) and leachate. The biogas is partially collected and combusted in an engine to produce electricity, which is mostly exported to the grid. The leachates are also collected and treated in a wastewater plant, before discharging the treated water to the natural water stream (Figure 2). 1 Energy Resources System boundaries Households O. waste Waste bin Tr Emissions Landfill Electricity Waste LANDFILLING SYSTEM Figure 2. Landfill System: Landfill + Transport (Tr) FUNCTIONAL UNIT The function we are interested in analysing is the management of organic waste, and thus we choose the following functional unit: “The management of 1000 kg of household organic waste until its biological stabilization”. However, both systems provide more than this function of managing waste. In the case of landfilling, the system provides also the function of producing electric energy, and in the case of composting the system provides the function of producing compost, a substitute of mineral fertilisers. This aspects will be taken into account in the inventory phase. INVENTORY DATA AND HYPOTHESIS Transport of waste to the composting plant: 50 km + 50 km (way back) Transport of waste to the landfill: 30 km + 30 km (way back) Fuel consumption of the truck: 0,05 litres/ton x km (45 MJ/ kg diesel fuel, with a density of 0,85 kg/litre) Every kg of compost obtained displaces 78 g of mineral N fertiliser Below are the balances for the unit processes: Composting Landfilling Diesel fuel production and combustion Electricity production Mineral nitrogen fertiliser 2 Table 1. Aggregated inventory for production and combustion of diesel fuel (1 MJ). Table 2. Desaggregated inventory for an intensive composting plant, per tone INPUTS FROM NATURE Resources coal ETH crude oil ETH natural gas ETH OUTPUTS TO NATURE Emissions to air ammonia CO2-fossil HCl methane NOx (as NO2) SOx (as SO2) Emissions to water N-tot NH4+ nitrate phosphate INPUTS FROM TECHNOSPHERE Waste Organic waste from households 1 Tm Energy products Diesel fuel 232 MJ Electricity 108 MJ INPUTS 450 mg 24 g 1,21 l OUTPUTS 2,15 µg 79,1 g 162 µg 96,3 mg 1,42 g 119 mg OUTPUTS TO NATURE Emissions to air CO2-re ammonia OUTPUTS TO TECHNOSPHERE Waste Compost Refuse 2,58 mg 2,64 mg 793 µg 31,3 µg 0,25 Tm 0,05 Tm Table 4. Desaggregated inventory for sanitary landfilling of organic waste, per ton Table 3. Aggregated inventory for electricity production in Spain (1 MJ) INPUTS FROM NATURE Resources coal ETH crude oil ETH natural gas ETH OUTPUTS TO NATURE Emissions to air ammonia CO2 HCl methane NOx (as NO2) SOx (as SO2) Emissions to water N-tot NH4+ nitrate phosphate 328 kg 57,7 g INPUTS INPUTS FROM TECHNOSPHERE Organic waste from households 1.000 kg Diesel fuel 38 MJ 58,2 g 6,57 g 7,82 l OUTPUTS 572 131 27,9 466 317 574 µg g mg mg mg mg 336 787 2,41 5,56 µg µg mg mg OUTPUTS TO NATURE Emissions to air ammonia CO2-re methane NOx (as NO2) SOx (as SO2) Emissions to water COD NH4+ nitrate P-tot OUTPUTS TO TECHNOSPHERE Electricity Table 5. Aggregated inventory for production of 1 kg of mineral nitrogen fertiliser. INPUTS FROM NATURE coal ETH 1,5 g crude oil ETH 6,01 g natural gas 0,126 m3 OUTPUTS TO NATURE Emissions to air ammonia 6,8 g CO2 65,7 g HCl 453 µg methane 1,17 g NOx (as NO2) 1,881 g 3 43 390 43 120 60 g kg kg g g 630 2,5 7,7 49 g kg kg g 87 kWh IMPACT ASSESSMENT We will take into account 3 indicators: greenhouse effect, acidification and energy consumption. Global Warming Potential 100 years (kg eq CO2/kg) (IMPORTANT: CO2 generated by the degradation of biomass (CO2-re) is not taken into account in GWP, according to IPCC1 guidelines) Compartment Air Air Air Substance CO2 CO2-re methane Acidification Potential (kg eq SO2/kg) Compartment Substance Air ammonia Air HCl Air NOx (as NO2) Air SOx (as SO2) Factor 1 0 21 Factor 1,88 0,88 0,7 1 Primary Energy Consumption (MJ) Compartment Substance Factor Raw coal ETH 18 Raw crude oil 41 Raw natural gas ETH 35 Unit kg kg m3 INSTRUCTIONS 1. Think about the functions provided by both systems: How many functions are there for landfilling and composting? and which are them? How can we compare systems providing different functions? Each system provides two functions, which are discussed below. The functions for landfilling are quantified as follows: managing 1000 kg waste and producing 87 kWh of electricity. As we are interested only in the first function, we use the substitution approach to eliminate the second function; in this way, we can say that this system is “saving” the production of 87 kWh by conventional power plants. Therefore, in the inventory we will subtract to the system the environmental impact of producing this amount of electricity using the conventional mix of technologies, in this case the mix used is that of Spain (about 20%hydropower, 30% nuclear power and 50% thermal power) (see Table 4.). 1 Intergovernmental Panel on Climate Change. 4 In the case of composting, the functions are: managing 1000 kg waste and producing 250 kg compost (Table 2). As we are interested only in the first function, we also use the substitution approach to eliminate the second function. If we assess the quality of the compost by its nitrogen content, and we compare it with that of conventional mineral nitrogen fertilisers, we can say that every kg of compost displaces the use of 78 g of mineral fertiliser. In this way, we can say that our composting system “saves” 19,5 kg of fertiliser thanks to the 250 kg of compost produced. Therefore, in the inventory we will subtract to the system the environmental impact of producing this amount of mineral fertiliser. With this approach, we “eliminate” from our system the functions we do not want to include. Now both systems provide the same function (managing waste) an can be fairly compared. 2. Calculate an inventory of the relevant substances for each unit process (be careful with the units) First we have to identify the unit processes or subsystems included in each system. For landfilling we have: - Transport to the landfill Landfilling process, including the energy consumption of the machines and the emissions related to waste degradation “Credit” for electricity produced with the biogas For composting we have: - Transport to the composting plant Composting process, including the energy consumption and the emissions related to waste degradation “Credit” for compost used as fertiliser Now, using the mass and energy balances for each process, and the hypothesis assumed, we have to compile the inventory for each system. The energy consumed in the transport to the composting plant is calculated as follows: (0.05 l diesel/Tm x km) x (1 Tm) x (50 + 50 km) x (0,85 kg diesel/ l) x (45 MJ/kg diesel) = 191 MJ For landfilling only the distance has to be changed. Once the energy consumption has been calculated, we must multiply this amount by the unitary emissions per MJ of diesel, displayed in Table 1. Then we have the treatment processes, landfilling and composting. The mass and energy balances are in Table 2 and 4, and are already expressed per tone of waste input. However, both processes have, as inputs, diesel fuel and/or electricity, so we must calculate the emissions related to these energy inputs with Tables 1 and 3. 5 Finally we have the credits or environmental savings for both systems, thanks to electricity production in the landfill (87 kWh)2, and to compost production (equivalent to 19,5 kg N fertiliser) in the other system. Using Tables 3 and 5, we can calculate the savings for both systems. Finally, the overall inventory for each system and substance is calculated as: For landfilling: For composting: Transport + landfill – electricity Transport + composting – fertiliser 3. Perform the impact assessment by multiplying the overall amount of each substance by its characterisation factor, and then calculate the environmental profile for both systems. For the detailed calculations and results, see the excel file. 4. Discuss the results and the limitations of this approach: a. Which option appears to be better from an environmental point of view? The preferable option depends on the impact category considered. Composting is preferable if the greenhouse effect is considered, but from the acidification and energy point of view, landfilling obtains better results. b. Which processes and environmental interventions are the main contributors to these impacts? Methane is by far the main contributor to greenhouse effect in the landfilling process. In the case of composting the main contributions come from the energy consumed in transporting and treating the waste. The saving of resources and emissions due to the valorisation of waste is important in both systems, but more in the case of electricity production in the landfill. c. Think about aspects or impacts not taken into account. d. Think about the simplifications we have made. The following aspects could be considered in further studies on this issue: - 2 Other relevant impact categories, such as eutrophication, toxicity on humans and ecosystems, summer smog, land use, etc. Compost should be followed to the grave, including the transport to agricultural soil and spreading on the field. Compost can be regarded not only as a substitute of nitrogen fertiliser, but also as a substitute of phosphorus and potassium fertiliser. Its value as soil conditioner, displacing other organic substrates, neither has been included. 1 kWh corresponds to 3.6 MJ. 6