Radioactive Waste: Handling and Disposal All radioactive waste must be labeled. Non-P-32 waste will be picked up and disposed of by licenced waste contractor and P-32 waste will be disposed of by delay and decay. Disposal of Radioactive Wastes Radioactive materials, whether sources or carcasses of laboratory animals in which radioactive material has been incorporated, or contaminated equipment or laboratory materials, awaiting disposal, shall be stored in the radioactive storage room (Room G111, Farquharson). Access to the radioactive storage room is limited to personnel who are wearing a radiation TLD badge. Radioactive waste collections will be arranged by the Radiation Safety Officer in conjunction with a contracted disposal service. Materials for waste collection, e.g. celite/gel containers and garbage containers, will be supplied. Every radioisotope permit holder is reminded that it is a federal requirement to maintain records regarding the use, storage and disposal of all radioactive materials at the university. 1. Phosporus-32 Waste Refer to Appendix I for disposal procedure. 2. Liquid Radioactive Waste Flammable Liquids Volatile or flammable liquids containing radioactive materials are to be poured into celite containers. Liquid scintillation vials for disposal must be securely sealed, stored in the laboratory in their original cartons, taped and labeled as to activity and isotopes, and sealed in poly bags ready for collection. In laboratories where reusable scintillation solutions are used, liquid must be poured into celite containers and made available for collection. 3. Acid Solutions All acids containing radioactive materials should be transferred to plastic jars containing celite. Jars will be labeled with the appropriate information as to name of permit holder, radionuclides and activity or activities. 4. Aqueous Solutions Radioactive aqueous solutions must be poured into containers containing gel, labeled, securely sealed and made available for collection. 5. Solid Radioactive Wastes All solid radioactive wastes are to be stored in garbage containers lined with poly bags. Hypodermic needles and other sharp objects, including contaminated glassware, are to be stored separately from other waste in puncture-proof containers and clearly marked. 6. Animals Animal Carcasses and animal wastes for disposal must be placed in poly bags and stored in cold room or in freezers, ready for collection. Each bag is to be labeled as to name of permit holder, radionuclide, activity, type of animal and date of sacrifice. 7. Sealed Radioactive Sources or Sources in Devices All sealed radioactive sources or devices which are no longer used or required must be disposed of through the Radiation Safety Officer. 8. Disposal of Gaseous Radioactive Waste Radioactive gases must not be discharged to the environment unless the activity is less than the maximum release concentration appropriate to the particular radionuclide involved. In all cases, reference should be made to the Radiation Safety Officer for approval of the proposed procedures. Appendix I Phosphorous-32 Waste Disposal Procedure Introduction The purpose of establishing a special phosphorous-32 waste disposal procedure is to minimize the volume of radioactive waste and thus to reduce the cost to the users for the transportation and disposal of radioactive wastes. Phosphorous-32 is a short half-life radioactive material in which its waste can be stored for decay to background levels and then be disposed as ‘normal’ garbage rather than being shipped for burial as radioactive waste. The following are the characteristics of phosphorous-32: PHOSPHOROUS-32 Physical Characteristics: Physical Half-Life: 14.28 days Radiation: Beta 1.710 MeV (max.) 100 Range in Air: 610 cm (max.) Source Strength: 2100 mrem/hr at 10 cm per uCi (Unshielded point source) Radiobiological Characteristics: Radiotoxicity: Moderate Critical Organ: Bone Biological Half-Life: 257 days Effective Half-Life: 13.5 days The Beta radiation from phosphorous-32 is extremely penetrating. The surface dose rate from an open source is quite large at short range and is not attenuated appreciably by a few centimeters of air. Any direct skin contact with phosphorus-32 must be avoided and measures to control contamination are essential. In accordance with the conditions for disposal as listed in York’s radioisotope license, phosphorus-32 can be disposed of: In Solid Form: By release through the municipal garbage system if concentration is less than 10uCi/kg of waste material and is uniformly distributed, or In Liquid Form: By release through the municipal sewage system provided the substance is water soluble and the concentration in the sewer at the property line for the facility is less than 0.1 uCi/liter of effluent based upon a yearly average. DISPOSAL PROCEDURES: ACTION 1. Segregate phosphorus-32 (P-32) waste from other radioactive wastes. 2. With P-32 waste, separate into liquid and solid waste. 3. a. For solid P-32 waste: I. Place into plastic waste container. II. Stick on a special P-32 waste label, and check off “solid” on the label. III. Before taking to the special waste storage area, complete all information on the label e.g. date of disposal, name of disposer, activity, etc… IV. Wipe the outside of the container, take to special storage area (Fig. II)*. V. Store on the appropriate shelf for current month. RESPONSIBLE User User User User Disposer Disposer Disposer * Refer to next page during transportation. b. For liquid P-32 waste: Segregate into water soluble and insoluble waste. For water soluble liquid P-32 waste: 1. Place waste into container. 2. Stick on special P-32 waste label, and check off on label “liquid” and “water soluble”. 3. Before bringing to the special waste storage area, complete all information on the label. 4. Wipe the outside of the container and take to special waste storage area*. 5. Store on appropriate shelf for current month. User User User Disposer Disposer 1. 2. 3. 4. 5. For water insoluble liquid P-32 waste: Pour into 4L glass bottle. Adhere special P-32 waste label. Check off “water insoluble” and “liquid” on the label. Before bringing to the waste storage area, complete all information on the label, e.g. activity, date of disposal, name of disposer. Wipe the outside of the container and take to special waste storage area*. Store on appropriate shelf for current month. * During transportation, use a trolley and shield the container with plexiglass. User User Disposer Disposer Disposer Appendix II Phosphorous-32 Waste Disposal System Maintenance P-32 users and disposers are to follow the “P-32 Waste Disposal Procedure” and the Radiation Safety Officer (RSO) or designate will be responsible to maintain and monitor the system. ACTION 1. On a monthly basis (on the first day of each month), remove and check all materials left on the shelf 4 months prior with detector. For material with radiation level above background, place material on the shelf labeled with the following month. 1.2 For material with radiation level above background, place material on the shelf labeled with the following month. 1.3 For material with background radiation level, remove all radioactive label and dispose of as normal waste. 1.4 For organic or water insoluble liquid, contact permit holder for proper disposal. 2. Relabeling of Shelves: Relabel the emptied shelf with the current month 3. Contamination monitoring of shelves: Coordinate shelves monitoring with Monserco pick-up date (usually first Monday of the month). Monitor and wipe test all shelves. If contamination is detected, clean shelf and remonitor until level returns to background. If decontamination is not successful, contact RSO. 4. Check wipe test records, disposal room, and the disposal system occasionally. Date of Revision: August 2003 RESPONSIBLE Science G.A. Science G.A. Science G.A. Science G.A. Science G.A. Science G.A. RSO or designate