AP Chemistry – Chemistry I Review Assignment Nomenclature 1. Name these binary compounds of two nonmetals. IF7 – iodine heptafluoride N2O5 – dinitrogen pentoxide XeF2 – xenon difluoride N2O4 – dinitrogen tetroxide As4O10 – tetrarsenic decoxide SF6 – sulfur hexafluoride PCl3 – phosphorous trichloride S2Cl2 – disulfur dichloride 2. Name these binary compounds with a fixed charge metal. AlCl3 – aluminum chloride MgO – magnesium oxide BaI2 – barium iodide KI – potassium iodide SrBr2 – strontium bromide Na2S – sodium sulfide CaF2 – calcium fluoride Al2O3 – aluminum oxide 3. Name these binary compounds of cations with variable charge. CuCl2 – copper (II) chloride Fe2O3 – iron (III) oxide SnO – tin (II) oxide PbCl4 – lead (IV) chloride Cu2S – copper (I) sulfide HgS – mercury (II) sulfide AuI3 – gold (III) iodide CoP – cobalt (III) phosphide 4. Name these compounds with polyatomic ions. Fe(NO3)3 – iron (III) nitrate NaOH – sodium hydroxide Cu2SO4 – copper (I) sulfate Ca(ClO3)2 – calcium chlorate KNO2 – potassium nitrite NaHCO3 – sodium hydrogen carbonate NH4NO2 – ammonium nitrite Cu2Cr2O7 – copper (I) dichromate 5. Name these binary acids HCl(aq) – hydrochloric acid HI(aq) – hydroiodic acid 6. Name these acids with polyatomic ions. HClO4 – perchloric acid H2SO4 – sulfuric acid HC2H3O2 – acetic acid H3PO4 – phosphoric acid HNO2 – nitrous acid H2CrO4 – chromic acid H2C2O4 – dichromic acid H2CO3 – carbonic acid 7. Name these compounds appropriately. CO – carbon monoxide NH4CN – ammonium cyanide HIO3(aq) – iodic acid NI3 – nitrogen triiodide AlP – aluminum phosphide OF2 – oxygen difluoride LiMnO4 – lithium permanganate HClO(aq) – hypochlorous acid HF(aq) – hydrofluoric acid SO2 – sulfur dioxide CuCr2O7 – copper(II) dichromate K2O – potassium oxide FeF3 – iron(III) fluoride KC2H3O2 – potassium acetate MnS – manganese(II) sulfide 8. Write the formulas. Tin (IV) phosphide – Sn3(PO4)4 Copper (II) cyanide – Cu(CN)2 Magnesium hydroxide – Mg(OH)2 Sodium peroxide – Na2O2 Sulfurous acid – H2SO3 Lithium silicate – Li4SiO4 Potassium nitride – K3N Chromium (III) carbonate – Cr2(CO3)3 Gallium arsenide - GaAs Cobalt (II) chromate – CoCrO4 Zinc fluoride – ZnF2 Dichromic acid – H2Cr2O7 Solubility rules 9. Review solubility rules and identify each of the following compounds as soluble or insoluble in water. Na2CO3 – Sol. CoCO3 – Insol. Pb(NO3)2 – Sol. K2S – Sol. BaSO4 – Sol. (NH4)2S – Sol. AgI – Insol. Ni(NO3)2 – Sol. KI – Sol. FeS – Insol. PbCl2 – Insol. CuSO4 – Sol. Li2O – Sol. Mn(C2H3O2)2 – Sol. Cr(OH)3 – Insol AgClO3 – Insol. Sn(SO3)4 – Insol. FeF2 – Insol. 10. Predict whether each of these double replacement reactions will give a precipitate or not based on the solubility of the products. If yes, identify the precipitate. silver nitrate and potassium chloride – Yes, AgCl AgNO3 + KCl AgCl + KNO3 magnesium nitrate and sodium carbonate – Yes, MgCO3 Mg(NO3)2 + Na2CO3 MgCO3 + 2NaNO3 strontium bromide and potassium sulfate – Yes, SrSO4 SrBr2 + K2SO4 2KBr + SrSO4 cobalt (III) bromide and potassium sulfide – Yes, Co2S3 2CoBr3 + 3K2S Co2S3 + 6KBr ammonium hydroxide and copper (II) acetate – Yes, Cu(OH)2 2NH4OH + Cu(C2H3O2)2 Cu(OH)2 + 2NH4C2H3O2 lithium chlorate and chromium (III) fluoride – Yes, Cr(ClO3)3 3LiClO3 + CrF3 Cr(ClO3)3 + 3LiF Balancing Equations 11. Balance the following equations with the lowest whole number coefficients. S8 + 12O2 8SO3 C10H16 + 8Cl2 10C + 16HCl 4Fe + 3O2 2Fe2O3 2C7H6O2 + 15O2 14CO2 + 6H2O 2KClO3 2KCl + 3O2 2H3AsO4 As2O5 + 3H2O V2O5 + 6HCl 2VOCl3 + 3H2O 3Hg(OH)2 + 2H3PO4 Hg3(PO4)2 + 6H2O Stoichiometry and Limiting Factor 12. Given the equation below, what mass of water would be needed to react with 10.0g of sodium oxide? Na2O + H2O 2NaOH 1 mol Na 2 O 1 mol H 2 O 18 g H 2 O 2.9 g H 2 O 10 g Na 2 O 62 g Na 2 O 1 mol Na 2 O 1 mol H 2 O 13. 2NaClO3 2NaCl + 3O2 What mass of sodium chloride is formed along with 45.0 g of oxygen gas? 1 mol O 2 2 mol NaCl 58.44 g NaCl 54 .8 g NaCl 45.0 g O 2 32 g O 2 3 mol O 2 1 mol NaCl 14. 4NH3 + 5O2 4NO + 6 H2O What mass of water will be produced when 100.0 g of ammonia is reacted with excess oxygen? 1 mol NH 3 6 mol H 2 O 18 g H 2 O 158 g H 2 O 100 .0 g NH 3 17 g NH 3 4 mol NH 3 1 mol H 2 O 15. If the reaction in #14 is done with 25.0g of each reactant, which would be the limiting factor? 1 mol NH 3 4 mol NO 1.47 mol NO 25.0 g NH 3 17 g NH 3 4 mol NH 3 1 mol O 2 4 mol NO 0.62 mol NO 25.0 g O 2 32 g O 2 5 mol O 2 Thus, the O2 is the limiting reagent 16. Na2S + 2AgNO3 Ag2S + 2NaNO3 If the above reaction is carried out with 50.0g of sodium sulfide and 35.0g of silver nitrate, which is the limiting factor? 1 mol Na 2S 1 mol Ag2S 0.641 mol Ag2S 50 .0 g Na 2S 78.04 g Na 2S 1 mol Na 2S 1 mol AgNO3 1 mol Ag2S 0.103 mol Ag2S 35.0 g AgNO3 169 .87 g AgNO3 2 mol AgNO3 Thus the AgNO3 is the limiting reagent What mass of the excess reactant remains? 1 mol Na 2S 78 .04 g Na 2S 8.04 g Na 2S consumed 0.103 mol Ag2S consumed 1 mol Ag2S 1 mol Na 2S Thus, (50.0 – 8.04) = 41.96 g Na2S are left What mass of silver sulfide would precipitate? 0.103 mole Ag2S would precipitate, thus 25.5 g Ag2S would precipitate 17. 6NaOH + 2Al 2Na3AlO3 + 3H2 What volume of hydrogen gas (measured at STP) would result from reacting 75.0g of sodium hydroxide with 50.0g of aluminum? 1 mol NaOH 3 mol H 2 22.4 L of H 2 @ STP 21 .0 L of H 2 @ STP 75.0 g NaOH 1 mol H 2 40 g NaOH 6 mol NaOH