Science 9 Unit 1: Matter & Chemical Change Name: Topic 1: Exploring Matter Safety First A good science lab is a safe one. All of the procedures, equipment and chemicals you use have been designed to help you understand the science principles you are investigating. Go over the safety notes provided and be prepared to take the safety test in class Please Read Over the Lab Safety Notes Attached… Classifying Matter The particle model of matter is an important part of what you will be learning in this unit. Recall that: All matter is made up of tiny particles. All the particles in a substance are the same; different substances are made of different particles. There are attractive forces among particles-these attractions may be strong or weak. The particles are always moving; the more energy the particles gain, the faster they move. There are spaces among the particles. The Particle Model of Matter is a scientific model which helps to visualize a process we cannot see directly. The first two points help us to understand that particles make up matter. The other three points help to explain density and how matter behaves when temperature changes. Matter exists in three states: solid, liquid, or gas. The Particle Model of Matter is useful in explaining the differences among solids, liquids, and gases. Illustrations such as these help to clarity the particle theory. Mixtures of Matter A pure substance is made up of only one kind of matter and has its own unique set of physical properties. Types of Pure Substances • element - cannot be broken down into any simpler substance • compound - is a combination of two or more elements in fixed proportions A mixture is a combination of 2 or more pure substances Types of Mixtures • mechanical (heterogenous) - each substance in the mixture is visible • solution (homogeneous) - each substance is not clearly visible (A substance dissolved in water is called an aqueous solution) • suspension - is a cloudy mixture in which tiny particles are held (suspended) with another substance, and can be filtered out • colloid (emulsions) - is also a cloudy mixture, but the particles are so small that they cannot be filtered out easily (emulsions are types of colloids in which liquids are dispersed in liquids) Whether a mixture is a solution, colloid or suspension depends on the size of the particles, solubility and mixing ability (miscibility) Lab Safety Notes: You must know all of these rules, techniques and procedures in order to participate in any of the Lab Activities Before beginning any activity • Know what is expected • Prepare a clear work environment • Wait for permission to start • Whenever special attention is needed in a Lab activity you will see the word Caution (This means that special care must be taken when proceeding with this activity) General Safety Precautions • Work quietly and carefully • Never work alone • Wear appropriate clothing • Wear safety equipment • Inform your supervisor of health-related problems, allergies • Never eat or drink In the Lab area • Do not attempt Lab activities at home unless told to do so by your teacher, and only under the direct supervision of an adult • Touch substances only when told to do so • Smell substances using the proper technique (wafting fumes toward you) • Pour substances properly and safely • Rinse off substances immediately that come into contact with skin or clothing • Wash hands after handling substances and before leaving the Lab • Clean up all spills Immediately • Dispose of harmful substances by following teacher's directions Handling a Heat Source Use hot plates that have thermostatic controls. Use a beaker of water on a hot plate to heat substances In test tubes. Use heat-resistant glass (Pyrex or Kimax) - never use cracked glass. Always keep the open end of the test tube pointed away from everyone. Never allow any container to boil dry. Use tongs or gloves to pick up hot objects. Turn off hot plate when not In use. Unplug cords by pulling on the plug, not the cord. Report and replace equipment that has frayed or damaged cords. Make sure electrical cords are placed properly where no one will trip over them. Treat burns using cold water or ice Handling an Open Flame • Locate fire safety equipment before using any open flame (fire blanket, fire extinguishers, fire alarm, first-aid kit) • Know the proper procedures for using a Bunsen burner In the Lab • Remove all flammable substances from the room before lighting a flame • Use a test tube holder if the test tube Is being heated in an open flame • Point the open end away from yourself and others • Gently move the test tube back and forth over the flame so that it is heated evenly Other Recommendations • Dispose of broken glassware as instructed by your teacher • Report broken or damaged equipment immediately (DO NOT USE IT) • Clean up work area completely when you are finished • Wash all glassware thoroughly and place in drying racks • Report all accidents to the teacher immediately (no matter how minor) SAFETY RULES • Do not perform unauthorized experiments. • Never work in the lab alone. • Report all accidents immediately to your teacher. • If vapors generated are toxic, use a fume hood. • Wear chemical splash goggles. • Wear a chemical resistant apron. • Wear chemical resistant gloves. • Tie back long hair. • Do not wear loose sleeves. • Do not wear shorts. • Do not wear sandals. • Do not wear contact lenses. • No food or beverages. • No gum chewing. • Do not leave experiments unattended. • Know the location of all of the science lab safety equipment, exits and telephone. (safety showers, eye wash, fire blankets, fire extinguishers) • No running. • Keep aisles clear. • Extinguish burners when away from desk. Workplace Hazardous Materials Information System (WHMIS) Compressed Gas This symbol is in class A and is used to inform people of compressed gas. This category includes such things such as propane bottles, butane bottles, and acetylene bottles. Poisonous and Infectious This symbol belongs to class D-l and is one of the most commonly found symbols in homes across North America. This symbol represents materials that are toxic when ingested. This category includes such common products as bleach, Mr. Clean, and Tide. Most household chemicals and cleaners contain this symbol and has become known as the symbol for poison. Oxidizing This symbol informs people that this substance produces oxygen when burned. This specific reaction creates a high problem for combustion and has to be stored in special containers and must be transported with extreme care. Dangerously Reactive This symbol is found on some household products and on a large number of lab chemicals. Itl means that when certain chemicals are mixed they will react and produce a harmful side effect. Some chemicals that should not be mixed are bleach, drain cleaner, and ammonia because, when combined, they will form a toxic gas. Flammable and Combustible This symbol is the Flammable and combustible material, which is in class B and tells a person that certain substances will react with a flame and burn. Some materials that fit into this category are gas and oil. These substances are highly flammable and ignite with little effort. Corrosive This symbol is the second most common symbol found in homes across North America. This symbol is most commonly found on products such as bleach and battery acid, which are highly corrosive and are able to burn organic matter. Toxic / Infectious This symbol belongs to class D-2 and is one of the less common symbols found in homes. It is more commonly found in Chemistry Labs. This symbol is somewhat similar to the fourth symbol, but chemicals that fit into this category cause slower effects to the body. Some examples of this are arsenic and nicotine. Biohazardous This symbol is often found in hospitals and is put on products that have materials that are harmful, such as viruses or bacteria. Examples of bacteria that fall into this category are ebola and the flesh eating disease. Topic 1 Assignment Vocabulary: Chemistry The mixing of chemicals to cause a reaction of matter Caustic Able to burn or change matter through chemical reaction Homogeneous They look even Heterogeneous It looks un even 1. Complete Topic 1 Review p. 98 #1-5 1) Poisonous, Corrosive, toxic 2) Goggles, apron, gloves, non-loose clothing, good shoes, eye washing station, proper containers, proper mixing tools. 3) Pure substance= elements & compounds, solution= it is the end result, mechanical mixture= homogenous and hetero generous 4) Soil= mechanical mixture, perfume= mechanical mixture, baking powder= mechanical mixture, glass container= mechanical mixture 5) Smoke- oxygen, water vapor- clouds , apple juice- blood Put Safety First Worksheet What to Do Sketch the corresponding WHMIS safety symbol next to each description. Record an example of each. Description Symbol Example Hair spray Compressed gas Poisonous and infectious material causing immediate and serious toxic effects Antifreeze Poisonous and infectious material causing other toxic effects Agent Orange, DDT Oxidizing material Certain compress ed gasses Febreze Flammable and combustible material Acids Corrosive material Biohazardous infectious material Dangerously reactive material Blood, needles Alcohols, plutonium Questions 1. Which WHMIS symbols do you think you might see on materials in this unit? Flammable, poisonous, corrosive 2. List the safety symbols displayed in investigations and activities in this unit. All of them 3. Why is it important for you to recognize safety symbols? So then you know what you are doing Using Material Safety Data Sheets Use the MSDS of Copper II Sulfate Ethanol to answer the following worksheet… Introduction Material Safety Data Sheets (MSDS) contain important information about a substance. On an MSDS for a particular substance, you can find information about its chemical composition, safety precautions to take when handling it, first aid, and long-term effects of exposure. There are also directions on how to dispose of the chemical safely and clean up any spills. Whether it is toilet bowl cleaner, film developer, or sweetener, all chemicals have an MSDS. What to Do Choose a chemical, examine its MSDS, then provide the information requested in the question below. Questions 1. Write the name and formula of the chemical. Name Ethanol Formula C2H5OH 2. How many sections is an MSDS divided into? 16 3. Name the titles of these sections. Product and Company Identification, Hazardous Identification, Composition/Information on ingredients, First aid Measures, Fire Fighting Measures, Accidental Realize Measures, Handling and storage, Exposure controls and Personal Protection, Physical and Chemical Property’s, Stability and Reactivity, Toxicological Information, Ecological Information, Disposal Considerations, Transport Information, Regularity Information, Other Information 4. Record the values from the MSDS for the following physical properties of this substance (be sure to include the proper units): (a) melting point -101 degrees (b) boiling point 30-200 degrees (c) vapour point-21 degrees (d) solubility in water Neglagable 5. Does the MSDS indicate any special fire instructions or explosion hazard? If so, describe them. Carbon dioxide blanket, Water spray, Dry chemical, Foam, SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, or Halon. LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers. Specific hazards during fire fighting : Fire Hazard Fire will produce dense black smoke containing hazardous combustion products (see heading 10). Flash back possible over considerable distance. Special protective equipment for fire-fighters : Use NIOSH/MSHA approved positive pressure self-contained breathing apparatus and fully protective clothing such as bunker gear if needed to prevent exposure. Further information : Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire fighting foam. Exposure to decomposition products may be a hazard to health. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water may be subject to disposal regulations. 6. Describe two important health hazards associated with this substance. Irritates eyes and can make you flammable 7. If you get this substance in your eye, what first aid should be administered? Use eye wash station 8. What skin protection should be used when handling this substance? If needed to prevent skin contact, chemical protective clothing such as of DuPont TyChem®, Saranex or equivalent recommended based on degree of exposure. The resistance of specific material may vary from product to product as well as with degree of exposure. 9. How should spills be handled? Evacuate personnel to safe areas. Ventilate the area. Remove all sources of ignition. Response and clean-up crews must be properly trained and must utilize proper protective equipment 10. How can this substance be disposed of safely? Dispose of container and unused contents in accordance with federal, state and local requirements. 11. Describe any special storage or handling precautions. Keep away from fire, sparks and heated surfaces. No smoking near areas where material is stored or handled. The product should only be stored and handled in areas with intrinsically safe electrical classification. 12. Where can the MSDS be found in your school? In a Science Lab