Waterworks Raw, In-Process & Final Water Quality Monthly Report: MAY 2013 Introduction This report summarises the results of monitoring at the Ballyboden, Ballymore Eustace, and Roundwood waterworks carried out during MAY 2013. The percentage compliance figures of the final water for each of the waterworks in this report are based on the parametric values listed in the European Communities (Drinking Water) (No.2) Regulations, 2007 (S.I. 278 of 2007). In the case of fluoride notice is also drawn, whenever applicable, to any result below 0.6mg/l which is the minimum concentration specified for fluoridated water supplies in the Fluoridation of Water Supplies Regulations 2007 (S.I. No. 42 of 2007). Results Summary 1. Vartry Works Roundwood. Compliance of the final water with the European Communities (Drinking Water) (No.2) Regulations, 2007 (S.I. 278 of 2007) is set out below. Results are summarised in Appendix 1. (i) Final Water – Plant Output: Parameter Colour (°Hazen) Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Fluoride (mg/l) Total Coliforms /100ml E. Coli (MPN/100ml) Parametric Values(s) No. of Samples No. Inside Limit % Compliance Acceptable to consumers & no abnormal change 1.0 19 19 100 24 24 100 2500 19 19 100 6.5 - 9.5 19 19 100 0.8 19 19 100 0 24 24 100 0 24 24 100 (ii) Final Water – Callow Hill: Parameter Colour (°Hazen) Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Fluoride (mg/l) Total Coliforms /100ml E. Coli (MPN/100ml) Parametric Values(s) No. of Samples No. Inside Limit % Compliance Acceptable to consumers & no abnormal change 1.0 31 31 100 31 30 96.8 2500 31 31 100 6.5 - 9.5 31 31 100 0.8 31 31 100 0 31 31 100 0 31 31 100 A sample did not comply with the parametric value for Turbidity; the details are as follows; Date: 21/05/13 Turbidity: 1.26 N.T.U. The turbidity results for 20/05/13 and 22/05/13 were 0.19 N.T.U. and 0.26 N.T.U. respectively, and are 100% compliant. 2. Dodder Works Ballyboden Compliance of the final water with the European Communities (Drinking Water) (No.2) Regulations, 2007 (S.I. 278 of 2007) is set out below. Results are summarised in Appendix 2. (i) Final Water – Plant Output: Parameter Parametric Value(s) No. of Samples No. Inside Limit % Compliance Colour (°Hazen) Acceptable to consumers & no abnormal change 1.0 22 22 100 22 22 100 2500 22 22 100 6.5 - 9.5 0.2 0.8 22 22 22 22 22 22 100 100 100 0 22 21 95.4 0 22 21 95.4 Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Aluminium (mg/l) Fluoride (mg/l) Total Coliforms (MPN/100ml) E. Coli (MPN/100ml) A sample did not comply with the parametric value for Total Coliform and E.Coli; the details are as follows; Date: 16/05/13 Total Coliform: 119 MPN/100ml E.Coli: 11 MPN/100ml The chlorine residuals for this sample were satisfactory, all subsequent retests were satisfactory, and all microbiological results in distribution for May were compliant. (ii) Final Water – Pond Outlet: Parameter Parametric Values(s) No. of Samples Colour (°Hazen) Acceptable to consumers & no abnormal change 1.0 22 22 100 22 22 100 2500 22 22 100 6.5 - 9.5 0.2 22 22 22 22 100 100 0.8 22 22 100 0 22 22 100 0 22 22 100 Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Aluminium (mg/l) Fluoride (mg/l) Total Coliforms (MPN/100ml) E. Coli (MPN/100ml) No. Inside Limit % Compliance 3. Liffey Works Ballymore Eustace. Compliance of the final water with the European Communities (Drinking Water) (No.2) Regulations, 2007 (S.I. 278 of 2007) is set out below. Results are summarised in Appendix 3. (i) Final Water [Contact Tank No.1]: Parameter Parametric Values(s) No. of Samples No. Inside Limit % Compliance Colour (°Hazen) Acceptable to consumers & no abnormal change 1.0 29 29 100 29 29 100 2500 29 29 100 6.5 - 9.5 29 29 100 Aluminium (mg/l) 0.2 29 29 100 Fluoride (mg/l) Total Coliforms (MPN/100ml) 0.8 29 29 100 0 29 29 100 0 29 29 100 Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH E. Coli (MPN/100ml) (ii) Final Water [Contact Tank No.2]: Parameter Parametric Values(s) No. of Samples No. Inside Limit % Compliance Colour (°Hazen) Acceptable to consumers & no abnormal change 1.0 31 31 100 31 31 100 2500 31 31 100 6.5 - 9.5 31 31 100 0.2 31 31 100 0.8 31 31 100 0 31 31 100 0 31 31 100 0 31 31 100 Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Aluminium (mg/l) Fluoride (mg/l) Total Coliforms /100ml E. Coli (MPN/100ml) Faecal Coliforms /100ml (ii) Final Water [Reservoir]: Parameter Parametric Values(s) No. of Samples No. Inside Limit % Compliance Colour (°Hazen) Acceptable to consumers & no abnormal change 1.0 31 31 100 31 31 100 2500 31 31 100 6.5 - 9.5 31 31 100 0.2 31 31 100 0.8 31 31 100 0 31 31 100 0 31 31 100 0 31 31 100 Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Aluminium (mg/l) Fluoride (mg/l) Total Coliforms /100ml E. Coli (MPN/100ml) Faecal Coliforms /100ml 4. Aluminium Residuals - Treated Waters. A more detailed breakdown of aluminium residuals in final water (ex. waterworks) is (excluding Vartry Works Roundwood – as Aluminium is not used in the water treatment process) is presented in Appendix 4. 5. Cryptosporidium/Giardia Analysis. Results for cryptosporidium/giardia analysis of the raw (pre-treatment) and final water (ex. waterworks and open storage reservoir) is presented in Appendix 5. 6. Biological Testing. A summary of Diatom counts for the Roundwood raw (pre-treatment) water is presented in Appendix 6. Appendix 1: Vartry Works Roundwood Results Summary MAY 2013 Raw Filtered Plant Final Callow Hill 31 22 24 31 Alkalinity (mg/l CaCO3) 14 – 20 - 23 – 35 22 – 32 Aluminium (mg/l) Colour (°Hazen) - - - - 16 – 30 13 – 16 7 – 14 5 – 10 88 – 94 - 115 – 124 112 – 125 1 – 74 <1 – 7 - - <1 (all samples) 0.65 – 0.75 <1 (all samples) 0.64 – 0.74 - - 0.66 – 1.18 0.44 – 0.70 7.0 – 7.9 6.8 – 7.4 8.3 – 9.2 7.45 – 8.40 Total Coliforms/100ml 2 – 1529 8 – 172 <1 (all samples) <1 (all samples) Total Residual Chlorine (mg/l) Turbidity (N.T.U.) - - 0.73 – 1.29 0.51 – 0.91 0.30 – 1.47 0.12 – 0.36 0.18 – 0.40 0.13 – 1.26 Number of Samples Conductivity (μS/cm @ 200C) E. Coli (MPN/100ml) Fluoride (mg/l) Free Residual Chlorine (mg/l) pH Appendix 2: Dodder Works Ballyboden Results Summary MAY 2013 Number of Samples Alkalinity (mg/l aCO3) Aluminium (mg/l) Colour (°Hazen) Conductivity (μS/cm @ 200C) E. Coli (MPN/100ml) Fluoride (mg/l) Free Residual Chlorine (mg/l) pH Total Residual Chlorine (mg/l) Total Coliforms (MPN/100ml) Turbidity (N.T.U.) Raw Final: Plant Output Final: Pond Outlet 22 22 22 38 – 47 42 – 55 31 – 35 - 112 – 142 <0.05 (all samples) 2.5 (all samples) 167 – 189 <0.05 (all samples) 2.5 (all samples) 146 – 163 1 – 582 <1 – 11 - 0.67 – 0.74 <1 (all samples) 0.56 – 0.76 - 0.60 – 0.89 0.55 – 0.85 7.57 – 7.77 7.25 – 7.64 7.14 – 7.40 - 0.67 – 0.98 0.68 – 0.90 50 – 3973 <1 -119 <1 (all samples) 1.33 – 1.97 0.04 – 0.08 0.05 – 0.09 25 – 30 Appendix 3: Liffey Works Ballymore Eustace Results Summary MAY 2013 Raw Settled: Upward Flow Clarifiers Settled: Inclined Plate Clarifiers Filtered Final: Contact Tank No.1 Final: Contact Tank No.2 Final: Reservoi r 31 24 31 31 29 31 31 31 – 34 - - - 29 – 32 28 – 31 27 – 31 - 0.13 – 0.16 0.14 – 0.18 <0.05 (all samples) <0.05 (all samples) <0.05 (all samples) <0.05 (all samples) Colour (°Hazen) 48 – 75 2 – 2.5 2–3 2 – 2.5 1 – 2.5 1 – 2.5 Conductivity (μS/cm @ 200C ) 96 – 102 - - - 2.5 (all samples) 138 – 148 139 – 151 138 – 149 E. Coli (MPN/100ml) <1 - < 10 - - - Fluoride (mg/l) - - - - <1 (all samples) 0.55 – 0.72 <1 (all samples) 0.60 – 0.68 <1 (all samples) 0.60 – 0.68 Free Residual Chlorine (mg/l) pH - - - - 0.43 – 0.52 0.51 – 0.61 0.27 – 0.40 7.35 – 7.68 6.23 – 6.40 6.22 – 6.50 6.22 – 6.60 7.45 – 7.87 7.71 – 8.70 7.56 – 8.00 Total Coliforms /100ml <1 – 10 - - - Total Residual Chlorine (mg/l) - - - - <1 (all samples) 0.51 – 0.61 <1 (all samples) 0.58 – 0.66 <1 (all samples) 0.35 – 0.45 1.20 – 2.68 0.71 – 1.18 0.54 – 1.27 0.08 – <0.10 0.18 – 0.27 <0.1 – 0.26 Number of Samples Alkalinity (mg/l CaCO3) Aluminium (mg/l) Turbidity (N.T.U.) 0.11 – 0.22 Appendix 4: Treated Water (Ex Waterworks) Aluminium Residuals MAY 2013 (1) Dodder Works Ballyboden. Final Water – Plant Output Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 22 100 0.051 - 0.20 0 0 > 0.20 0 0 TOTAL 22 100 Final Water – Pond Outlet Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 22 100 0.051 - 0.20 0 0 > 0.20 0 0 TOTAL 22 100 (2) Liffey Works Ballymore Eustace. Contact Tank No. 1 Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 29 100 0.051 - 0.20 0 0 > 0.20 0 0 TOTAL 29 100 EC PARAMETRIC VALUE: 0.20 mg/l Al (also expressed as 200ug/l Al). Contact Tank No. 2 Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 31 100 0.051 - 0.20 0 0 > 0.20 0 0 TOTAL 31 100 Reservoir Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 31 100 0.051 - 0.20 0 0 > 0.20 0 0 TOTAL 31 100 EC PARAMETRIC VALUE: 0.20 mg/l Al (also expressed as 200ug/l Al). Appendix 5: Cryptosporidium/Giardia Analysis MAY 2013 (1) Vartry Works Roundwood. RAW Date: FINAL: PLANT OUPUT Cryptosp- Giardia oridium ( Cysts/l ) Date: (Oocysts/l) 07/05/1 3 13/05/1 3 14/05/1 3 20/05/1 3 21/05/1 3 27/05/1 3 28/05/1 3 Cryptosporidium FINAL: CALLOW HILL (Oocysts/l) Giardia ( Cysts/l ) - - 0 0 0 0 0 0 - - 0 0 0 0 0 0 07/05/1 3 12/05/1 3 13/05/1 3 0 0 - - - 0 0 - - 0 0 27/05/1 3 0 0 0 0 - - - Date: Cryptosp Giardia -oridium (Cysts/l ) (Oocysts/l) 05/05/1 3 07/05/1 3 12/05/1 3 13/05/1 3 19/05/1 3 20/05/1 3 26/05/1 3 27/05/1 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 (2) Dodder Works Ballyboden. Date: RAW FINAL: PLANT OUPUT FINAL: POND OUTLET Cryptos Giardia Date: Cryptos Giardia Cryptosp- Giardia Date: (Cysts/l ) p(Cysts/l ) p(Cysts/l ) oridium oridium oridium (Oocysts/l (Oocysts/l (Oocysts/l ) ) ) 07/05/1 3 14/05/1 3 28/05/1 3 0 0 0 0 0 0 07/05/1 3 13/05/1 3 27/05/1 3 0 0 0 0 0 0 07/05/1 3 13/05/1 3 27/05/1 3 0 0 0 0 0 0 (3) Liffey Works Ballymore Eustace. Date: 07/05/13 13/05/13 20/05/13 27/05/13 RAW Cryptosporidium (Oocysts/l) Giardia (Cysts/l) 0 0 0 0 0 0 0 0 Date: 07/05/13 12/05/13 19/05/13 26/05/13 FINAL Cryptosporidium (Oocysts/l) 0 0 0 0 Giardia (Cysts/l ) 0 0 0 0 Appendix 6: *Diatom Count MAY 2013 (1) Vartry Works Roundwood Raw. Sampled Date 01/05/2013 02/05/2013 03/05/2013 09/05/2013 10/05/2013 13/05/2013 14/05/2013 15/05/2013 16/05/2013 17/05/2013 20/05/2013 21/05/2013 22/05/2013 23/05/2013 27/05/2013 28/05/2013 29/05/2013 30/05/2013 Count/ml Asterionell a Algae 1330 955 1090 430 970 730 580 360 340 540 86 117 91 81 55 46 15 14 Diatoma Melosira Algae 160 515 420 60 160 80 150 60 100 170 10 22 9 4 3 4 3 3 10 10 30 10 20 0 10 0 0 0 0 4 0 2 2 7 2 1 Navicula Synedra Algae Tabellaria Algae 340 410 320 50 80 180 50 6 76 80 14 17 21 22 32 37 17 11 480 440 510 190 450 52 300 180 280 520 77 69 50 39 20 26 8 13 40 22 60 40 70 190 60 40 8 70 11 10 14 11 9 10 5 3 *These diatoms are removed by the sand filters in the water treatment plant and have no impact on the water quality.