Waterworks Raw, In-Process & Final Water Quality Monthly Report: JUNE 2013 Introduction This report summarises the results of monitoring at the Ballyboden, Ballymore Eustace, and Roundwood waterworks carried out during JUNE 2013. The percentage compliance figures of the final water for each of the waterworks in this report are based on the parametric values listed in the European Communities (Drinking Water) (No.2) Regulations, 2007 (S.I. 278 of 2007). In the case of fluoride notice is also drawn, whenever applicable, to any result below 0.6mg/l which is the minimum concentration specified for fluoridated water supplies in the Fluoridation of Water Supplies Regulations 2007 (S.I. No. 42 of 2007). Results Summary 1. Vartry Works Roundwood. Compliance of the final water with the European Communities (Drinking Water) (No.2) Regulations, 2007 (S.I. 278 of 2007) is set out below. Results are summarised in Appendix 1. (i) Final Water – Plant Output: Parameter Colour (°Hazen) Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Fluoride (mg/l) Total Coliforms /100ml E. Coli (MPN/100ml) Parametric Values(s) Acceptable to consumers & no abnormal change 1.0 No. of Samples No. Inside Limit % Compliance 19 19 100 30 30 100 2500 19 19 100 6.5 - 9.5 19 19 100 0.8 19 19 100 0 30 30 100 0 30 30 100 Final Water – Callow Hill: (ii) Parameter Parametric Values(s) No. of Samples No. Inside Limit % Compliance Colour (°Hazen) Acceptable to consumers & no abnormal change 1.0 30 30 100 30 30 100 2500 30 30 100 6.5 - 9.5 30 30 100 0.8 30 30 100 0 30 28 93.3 0 30 30 100 Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Fluoride (mg/l) Total Coliforms /100ml E. Coli (MPN/100ml) Two samples did not comply with the parametric value for Total Coliform; the details are as follows; Date: 05/06/13 22/06/13 Total Coliform: 63 MPN/100ml. 1 MPN/100ml. Total Residual Chlorine: 0.60mg/l 0.58mg/l Free Residual Chlorine: 0.54mg/l 0.51mg/l The result for the sample collected on 05/06/13 can be attributed to maintenance issues at the sampling point. Follow up samples were satisfactory for the above dates. 2. Dodder Works Ballyboden Compliance of the final water with the European Communities (Drinking Water) (No.2) Regulations, 2007 (S.I. 278 of 2007) is set out below. Results are summarised in Appendix 2. Final Water – Plant Output: (i) Parameter Colour (°Hazen) Turbidity (N.T.U.) Conductivity pH (μS/cm @ 200C) Aluminium (mg/l) Parametric Value(s) No. of Samples No. Inside Limit % Compliance Acceptable to consumers & no abnormal change 1.0 19 19 100 19 19 100 2500 19 19 100 6.5 - 9.5 19 19 100 0.2 19 19 100 Fluoride 0.8 19 19 100 0 19 19 100 0 19 19 100 Parametric Values(s) No. of Samples No. Inside Limit % Compliance Acceptable to consumers & no abnormal change 1.0 19 19 100 19 19 100 2500 19 19 100 6.5 - 9.5 19 19 100 Aluminium (mg/l) 0.2 19 19 100 Fluoride (mg/l) 0.8 19 19 100 Total Coliforms (MPN/100ml) 0 19 19 100 E. Coli (MPN/100ml) 0 19 19 100 (mg/l) Total Coliforms (MPN/100ml) E. Coli (MPN/100ml) (ii) Final Water – Pond Outlet: Parameter Colour (°Hazen) Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH 3. Liffey Works Ballymore Eustace. Compliance of the final water with the European Communities (Drinking Water) (No.2) Regulations, 2007 (S.I. 278 of 2007) is set out below. Results are summarised in Appendix 3. (i) Final Water [Contact Tank No.1]: Parameter Colour (°Hazen) Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Aluminium (mg/l) Fluoride (mg/l) Total Coliforms (MPN/100ml) E. Coli (MPN/100ml) Parametric Values(s) No. of Samples No. Inside Limit % Compliance Acceptable to consumers & no abnormal change 1.0 30 30 100 30 30 100 2500 29 29 100 6.5 - 9.5 0.2 30 30 30 30 100 100 0.8 30 29 96.7 0 30 30 100 0 30 30 100 A sample did not comply with the parametric value for Fluoride as it was above the 0.6mg/l to 0.8 mg/l fluoride range required by Fluoridation of Water Supplies Regulations 2007 (S.I. No. 42 of 2007). The details are as follows; Date: 05/06/13 Fluoride: 0.86 mg/l. A follow up sample was satisfactory. (ii) Final Water [Contact Tank No.2]: Parameter Colour (°Hazen) Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Aluminium (mg/l) Parametric Values(s) No. of Samples No. Inside Limit % Compliance Acceptable to consumers & no abnormal change 1.0 30 30 100 30 30 100 2500 30 30 100 6.5 - 9.5 0.2 30 30 30 30 100 100 Fluoride (mg/l) Total Coliforms /100ml E. Coli (MPN/100ml) 0.8 30 29 96.7 0 30 30 100 0 30 30 100 A sample did not comply with the parametric value for Fluoride as it was above the 0.6mg/l to 0.8 mg/l fluoride range required by Fluoridation of Water Supplies Regulations 2007 (S.I. No. 42 of 2007). The details are as follows; Date: Fluoride: 05/06/13 0.86 mg/l. A follow up sample was satisfactory. (ii) Final Water [Reservoir]: Parameter Colour (°Hazen) Turbidity (N.T.U.) Conductivity (μS/cm @ 200C) pH Aluminium (mg/l) Fluoride (mg/l) Total Coliforms /100ml E. Coli (MPN/100ml) Parametric Values(s) No. of Samples No. Inside Limit % Compliance Acceptable to consumers & no abnormal change 1.0 30 30 100 30 30 100 2500 30 30 100 6.5 - 9.5 0.2 30 30 30 30 100 100 0.8 30 30 100 0 30 30 100 0 30 30 100 4. Aluminium Residuals - Treated Waters. A more detailed breakdown of aluminium residuals in final water (ex. waterworks, however Vartry Works Roundwood is excluded – as Aluminium is not used in the water treatment process) is presented in Appendix 4. 5. Cryptosporidium/Giardia Analysis. Results for cryptosporidium/giardia analysis of the raw (pre-treatment) and final water (ex. waterworks and open storage reservoirs) is presented in Appendix 5. This appendix may also contain results of investigative samples for as the need arises. 6. Biological Testing. A summary of Diatom counts for the Roundwood raw (pre-treatment) water is presented in Appendix 6. Appendix 1: Vartry Works Roundwood Results Summary JUNE 2013 Raw Filtered Plant Final Callow Hill 30 30 30 30 Alkalinity (mg/l CaCO3) 13 – 23 - 22 – 28 23 – 29 Aluminium (mg/l) Colour (°Hazen) - - - - 14 – 27.5 11 – 16 5 – 10 4 – 7.5 87 – 92 - 114 – 119 110 – 122 <10 – 11 <1 – 1 - - <1 (all samples) 0.61 – 0.70 <1 (all samples) 0.61 – 0.78 - - 0.69 – 0.90 0.43 – 0.65 6.4 – 8.4 6.4 – 7.4 7.3 – 8.9 7.20 – 8.49 Total Coliforms/100ml <10 – 63 4 – 921 <1 (all samples) <1 – 63 Total Residual Chlorine (mg/l) Turbidity (N.T.U.) - - 0.80 – 1.07 0.50 – 0.72 0.55 – 1.27 <0.1 – 4.5 0.11 – 0.99 <0.10 – 0.23 Number of Samples Conductivity (μS/cm @ 200C) E. Coli (MPN/100ml) Fluoride (mg/l) Free Residual Chlorine (mg/l) pH Appendix 2: Dodder Works Ballyboden Results Summary JUNE 2013 Raw Filtered * Final: Plant Output Final: Pond Outlet 19 2 19 19 41 – 46 - 49 – 63 31 – 44 - - 22.5 – 30 - <0.05 (all samples) 0–5 <0.05 (all samples) 0–5 113 – 132 - 178 – 205 146 – 190 1 – 155 - <1 (all samples) - <1 (all samples) 0.65 – 0.79 <1 (all samples) 0.65 – 0.78 - - 0.67 – 0.89 0.67 – 0.80 7.32 – 7.78 - 7.38 – 8.14 7.21 – 7.44 - - 0.74 – 0.98 0.79 – 0.91 Total Coliforms (MPN/100ml) 145 – 921 <1 (all samples) <1 (all samples) <1 (all samples) Turbidity (N.T.U.) 1.40 – 2.10 - 0.04 – 0.10 Number of Samples Alkalinity (mg/l aCO3) Aluminium (mg/l) Colour (°Hazen) Conductivity (μS/cm @ 200C) E. Coli (MPN/100ml) Fluoride (mg/l) Free Residual Chlorine (mg/l) pH Total Residual Chlorine (mg/l) * Sampling commenced at this location on 27/06/13. 0.04 – 0.14 Appendix 3: Liffey Works Ballymore Eustace Results Summary JUNE 2013 Raw Settled: Inclined Plate Clarifiers 30 Filtered Final: Contact Tank No.1 30 Settled: Upward Flow Clarifiers 20 Final: Reservoir 30 Final: Contact Tank No.2 30 30 31 – 35 - - - 24 – 32 29 – 35 24 – 34 - 0.08 – 0.36 0.09 – 1.74 <0.05 (all samples) <0.05 (all samples) <0.05 (all samples) <0.05 (all samples) Colour (°Hazen) 37 – 65 2–5 1–4 <1 – 4 <1 – 2.5 <1 – 2.5 <1 – 3 Conductivity (μS/cm @ 200C ) 97 – 105 - - - 138 – 154 139 – 154 138 – 153 E. Coli (MPN/100ml) <1 - < 10 - - - Fluoride (mg/l) - - - - <1 (all samples) 0.60 – 0.86 <1 (all samples) 0.61 – 0.86 <1 (all samples) 0.61 – 0.83 Free Residual Chlorine (mg/l) pH - - - - 0.33 – 0.60 7.10 – 7.90 6.23 – 6.80 6.23 – 6.70 6.24 – 6.70 7.42 – 8.60 0.42 – 0.66 7.61 – 8.70 0.28 – 0.44 7.41 – 8.80 Total Coliforms /100ml <1 – 30 - - - Total Residual Chlorine (mg/l) - - - - <1 (all samples) 0.43 – 0.67 <1 (all samples) 0.49 – 0.79 <1 (all samples) 0.36 – 0.49 0.79 – 1.31 0.30 – 0.82 0.41 – 2.60 <0.10 – 0.53 <0.1 – 0.30 <0.1 – 0.62 <0.1 – 0.23 Number of Samples Alkalinity (mg/l CaCO3) Aluminium (mg/l) Turbidity (N.T.U.) 30 Appendix 4: Treated Water (Ex Waterworks) Aluminium Residuals JUNE 2013 (1) Dodder Works Ballyboden. Final Water – Plant Output Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 19 100 0.051 - 0.20 > 0.20 TOTAL 0 0 19 0 0 100 Final Water – Pond Outlet Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 19 100 0.051 - 0.20 0 0 > 0.20 0 0 TOTAL 19 100 (2) Liffey Works Ballymore Eustace. Contact Tank No. 1 Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 30 100 0.051 - 0.20 0 0 > 0.20 0 0 TOTAL 30 100 EC PARAMETRIC VALUE: 0.20 mg/l Al (also expressed as 200ug/l Al). Contact Tank No. 2 Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 30 100 0.051 - 0.20 0 0 > 0.20 0 0 TOTAL 30 100 Reservoir Al CONCENTRATION NO. OF SAMPLES % OF TOTAL 0 - 0.05 mg/l 30 100 0.051 - 0.20 0 0 > 0.20 0 0 TOTAL 30 100 EC PARAMETRIC VALUE: 0.20 mg/l Al (also expressed as 200ug/l Al). Appendix 5: Cryptosporidium/Giardia Analysis JUNE 2013 (1) Vartry Works Roundwood. RAW Date: FINAL: PLANT OUPUT Cryptosp- Giardia oridium ( Cysts/l) (Oocysts/l) 04/06/13 10/06/13 11/06/13 Date: Cryptosporidium (Oocysts/l) FINAL: CALLOW HILL Giardia (Cysts/l) 0 0 0 0 04/06/13 10/06/13 0 0 0 0 0 0 - - - 17/06/13 0 0 16/06/13 0 0 18/06/13 0 0 17/06/13 0 0 24/06/13 0 0 23/06/13 0 0 25/06/13 0.01 0 24/06/13 0 0 - - - 30/06/13 0 0 Date: Cryptosporidium (Oocysts/l) 04/06/1 3 16/06/1 3 17/06/1 3 23/06/1 3 24/06/1 3 30/06/1 3 Giardia (Cysts/l ) 0 - 0 - - - 0 0 0 0 0 0 0 0 0 0 (2) Dodder Works Ballyboden. RAW Date: Cryptosporidium (Oocysts/l) 04/06/1 3 11/06/1 3 18/06/1 3 25/06/1 3 FINAL: PLANT OUPUT Giardia ( Cysts/l) 0 0 0 0 0 0 0 0 Date: Cryptosporidium (Oocysts/l) 04/06/1 3 10/06/1 3 17/06/1 3 24/06/1 3 FINAL: POND OUTLET Giardia ( Cysts/l) 0 0 0 0 0 0 0 0 Date: Cryptosporidium (Oocysts/l) 04/06/1 3 10/06/1 3 17/06/1 3 24/06/1 3 Giardia (Cysts/l) 0 0 0.001 0 0 0 0 0 (3) Liffey Works Ballymore Eustace. RAW Date: 04/06/13 10/06/13 17/06/13 24/06/13 - Cryptosporidium (Oocysts/l) 0 0 0 0 - FINAL Giardia (Cysts/l) 0 0 0 0 - Date: 04/06/13 09/06/13 18/06/13 23/06/13 30/06/13 Cryptosporidium (Oocysts/l) 0 0 0 0 0 Giardia (Cysts/l) 0 0 0 0 0 Appendix 6: *Diatom Count JUNE 2013 (1) Vartry Works Roundwood Raw. Sampled Date 04/06/2013 07/06/2013 10/06/2013 17/06/2013 24/06/2013 Count/ml Asterionella Algae 5 4 1 0 1 Diatoma 1 1 2 - Melosira Algae 1 1 0 2 1 Navicula 5 4 0 - Synedra Algae 6 4 0 2 - Tabellaria Algae 3 1 1 0 1 *These diatoms are removed by the sand filters in the water treatment plant and have no impact on the water quality.