Chemistry NYOS Dr. McPhee December 2015 Learning Objectives for End of Semester 1 Final Exam Unit 1: Scientific Measurements; Classification of Matter; Physical vs Chemical Changes Know the steps of the scientific method (observation, hypothesis, experiment, results, conclusion) Know what information is conveyed by an MSDS and how to read the safety label diamond Understand metric units for measurement of length, mass, and volume, as well as, the meaning of prefixes for scale (i.e., ‘kilo’ means thousand) Know the formula for determining density and the units of density Be able to convert from one metric unit to another (i.e., gram to milligram and vice versa) Convert a number into scientific notation to determine the number of significant figures Know the difference between intensive and extensive properties and give examples of each Know the difference between chemical and physical changes and give examples of each Know the roles of these scientists in the development of historical and current models of the composition of matter and models of the atom: Aristotle, Democritus, Dalton, Rutherford, Thomson, Chadwick, Becquerel, Mendeleev, Einstein, Milllikan, LaVoisier, Boyle, Priestley Understand the difference between mixtures and pure substances understand the differences between homogeneous and heterogeneous mixtures know difference between element and compound Understand how the terms accuracy and precision apply to chemistry lab instrumentation; know what instruments are used to do different laboratory tasks (e.g., graduated cylinder to measure volume) Unit 2: Atomic Structure: History and Models; Isotopes and Ions Know the location, mass, and charge of these subatomic particles (and the names of the scientists who discovered them): electron, neutron, proton Understand that matter is anything that has mass Understand how elements can be the same yet be different isotopes (what subatomic particle makes them different?) Be able to determine the number of electrons associated with an ion given its shorthand notation (e.g., Ni4+ ) Be able to determine the number of protons, neutrons and electrons of a neutral atom given the name of the element and its atomic mass (e.g., 37Cl) Given a shorthand (Ni4+), be able to state if the particle is a neutral atom, an anion or a cation Given the atomic number or the number of protons for an atom, be able to use the Periodic Table to state what element it is Know what the Laws of Definite and Multiple Proportions means Understand that the Law of Conservation of Matter is not violated (loss of mass can be explained by escape of gas) Understand that light and heat are forms of energy, not matter Be able to calculate average atomic mass given atomic mass number and percent abundance Unit 3: Periodic Table: History and Families; Properties of Metals and Non-Metals Know which materials are elements by name (e.g., copper vs bronze) and know the location of these families of the periodic table: alkali metal, alkaline earth, rare earth, coinage metal, halogen, noble gas Know the symbols associated with elements whose names don’t match their symbols, especially these: Na, K, Fe, Cu, Ag, Au, Pb, P Understand the physical properties associated with metals (e.g., conductor of electricity) Understand the physical properties associated with non-metals (e.g., usually brittle) 1 Given any element and a periodic table, be able to identify it is a metal or non-metal When forming ions (i.e., cations or anions), know which ions metals usually form and which ions non-metals usually form Know the contributions of these scientists to the development of the modern periodic table: Dalton, Berzelius, Mendeleev Units 4-5: Periodic Trends, QM Model of the Atom Know the meaning of and the periodic trends for these: atomic radius, electron affinity, ionization energy, and electronegativity When forming ions (i.e., cations or anions), know which ions metals usually form and which ions non-metals usually form Know the contributions of these scientists to the development of modern atomic theory: Heisenberg, Schrodinger, Planck, deBroglie, Bohr, deBroglie Understand that the modern view of the electron consider it to have dual wave/particle properties Know that the QM model treats the electron as a cloud of negative charge density found at quantized energy levels Know the shapes and maximum number of electrons that can be placed into these orbitals: s, p, d, f Know which orbitals can be found on any given energy level Units 6-7: Electron Configuration, EM spectrum and Electron Energy Know how to use an Aufbau chart (along with Hund’s rule and the Pauli exclusion principle) and suborbital notation (parentheses and arrows) to indicate the electron configuration (or noble gas short-hand notation) for a given atom or ion Understand in terms of noble gas electron configuration why some metals and non-metals form the ions they do (eg. Na = +1; O = -2) Given one of the families in the periodic table we learned, decide which orbitals are filling with electrons Given a suborbital shorthand electron configuration, determine the number of unpaired electrons Know how the Cr and Cu families differ in electron configuration from their neighbors Given an electron configuration, be able to state which (if any) of the assignment rules has been violated Understand which parts of the electromagnetic spectrum are high energy/high frequency/short wavelength and which are considered low energy/low frequency/long wavelength Be able to calculate frequency given wavelength (and vice versa) [formula will be provided] Be able to calculate the energy of a photon given frequency (or wavelength) [formula will be provided] Know the value and units of the speed of light, c, by heart Be able to convert nm to m Know the names and meanings of these symbols: , , h, E, J Understand that emission lines (including those in those visible portion of the EM spectrum) involve electronic transitions Know how these parts of the EM spectrum interact with matter: microwave, IR, visible light, UV, X-rays Know the shorthand used for suborbitals and electrons Know that bonding is an intra-molecular force and involves electrons and usually there are two electrons in a shared, directional or covalent bond Know that the covalent bond is typically the strongest of all intra-molecular bonds A covalent bond joining two atoms whose electronegativity differ significantly is called a polar covalent bond Know that metals also share electrons when they bond to each other but this is a weaker non-directional type of bond called a metallic bond Know that when atoms exchange electrons, the result is ions that are electrostatically attracted—this is the ionic bond 2 Be able to identify a solid as an ionic compound because it is composed of a metal and a non-metal Be able to use Coulomb’s law to calculate the attraction of two ions [formula will be provided] and predict greater stability of one ionic compound vs another (based on either a size difference or a charge difference) Units 8-9: Ionic Compounds: Formation, Properties and Naming Give a definition of an ionic compound Draw a particle view picture of an ionic compound List four properties of ionic compounds Use the periodic table to give three examples of ionic compounds Give the charge of ions from five different families of the periodic table Given elements from a non-metal family and a metal family, write the formula and name for the ionic compound produced Given the chemical formula of an ionic compound, write the corresponding chemical name Given a name of an ionic compound, write the corresponding chemical formula Recognize that a polyatomic ion is part of the formula if the compound name ends in –ite or –ate Recognize that a transition metal with variable charge is part of the formula if the compound name contains a Roman numeral Recall how to write a Roman numeral corresponding to an Arabic numeral Use a list of polyatomic ions to write a formula for an ionic compound containing a metal cation and a polyatomic anion With the aid of a polyatomic list and given a formula for an ionic compound containing a polyatomic ion, give the proper name for an ionic compound Recognize when a Roman numeral must be used to name an ionic compound Given the chemical formula of an ionic compound containing a transition metal, provide the proper name (including Roman numeral) Given a name of an ionic compound containing a Roman numeral, provide the correct chemical formula Units 10-11: Covalent Compounds: Properties, Naming, and Lewis Structures Give a definition of covalent bonding Explain how covalent bonding joins atoms Give examples of a compounds and elements that display covalent bonding Draw a picture of covalent bonding in either a molecular solid or a network solid Describe properties of molecular solids Describe properties of and give three examples of network solids Write Greek prefixes describing numerical quantities one through ten Write a chemical name for a covalent compound given a chemical formula Write a chemical formula for a covalent compound given a chemical name Make an accurate electron count from a molecular formula for a covalent molecule Make an accurate electron count from a molecular name for a covalent molecule Know that dots indicate single electrons in a Lewis dot structure Know that lines indicate two electron bonds in a Lewis dot structure Draw a Lewis dot structure for an atom based on its outer shell (valence) configuration Draw a Lewis dot structure for a covalent molecule or ion based on its formula or name Know what VSEPR stands for and how it is used to determine molecular geometry (shape) Describe molecular geometry (shape) of a molecule using a molecular shape reference sheet Describe electronic geometry (shape) of a molecule using a molecular shape reference sheet Describe the bond angles of a molecule based on its Lewis dot structure Know which atoms do not need an octet of electrons in their dot structure Know which atoms may have an expanded octet of electrons in their dot structure 3 Calculate formal charge for each atom in a Lewis structure Recognize resonance structures Unit 12: Polar Bonds and Polar Molecules; IMFs Determine if a bond is polar, non-polar or ionic Predict if a molecule is polar or non-polar Draw partial charges correctly for a polar covalent bond List the three most important inter-molecular forces (IMFs) Identify if a molecule is capable of forming a hydrogen bond Identify from a Lewis structure if a molecule participates in dipole-dipole interactions Explain the origin of the London dispersion force Rank compounds according to increasing IMFs Predict the effect of increasing IMFs on m.p., b.p., viscosity and vapor pressure Unit 13: Evidence of Chemical Reactions and Balancing Chemical Reactions List six pieces of observational evidence suggesting a chemical reaction has occurred Give an example of a reaction that does one or more of the following: changes color, makes a solid product, produces a gas, produces light and heat, produces primarily heat, changes mass, or makes a loud sound Categorize chemical reaction as either: synthesis, decomposition, combustion, single replacement, or double replacement Use an activity sheet to predict if a single replacement reaction will occur Use a solubility sheet to predict if a double replacement reaction will occur Balance a chemical reaction given the formulas for reactants and products Balance a chemical reaction given the names of reactants and products 4 Vocabulary Extensive property Intensive property Density Chemical change Physical change Element Compound Homogeneous Heterogeneous Alloy Solution Mixture Scale (balance) Graduated cylinder Kinetic energy Vibrational Rotational Translational Electron Proton Neutron Nucleus Phlogiston Radiation Isotope Ion Cation Anion Atomic number Atomic mass Separate Alchemist Period Group or family Alkali Alkaline earth Coinage Know the definitions of these words: Rare earth Halogen Noble gas Malleability Luster Conductivity (electrical and heat) Quanta/quantized Energy level Electron cloud Photon Photoelectric effect Atomic emission spectra Bohr model Quantum mechanical (QM) Bohr Schrodinger Heisenberg deBroglie wave particle orbital probability s, p, d, and f orbitals suborbital Electron configuration Aufbau principle Hund’s rule Pauli exclusion principle Orbital Suborbital Electron Paired electron Valence electron Noble gas shorthand coefficient Light Electromagnetic (EM) radiation Frequency Wavelength Energy Planck’s constant Nanometer Joule Ultraviolet (UV) Visible light Infrared (IR) photon atomic emission valence electrons Ionic bond Coulombic Electrostatic metallic bond delocalized polar covalent bond Coulomb’s law Formula unit Array Matrix Electrostatic Ionic Cation Anion Crystalline Molten Binary Polar Dipole-dipole Hydrogen bond London dispersion force Synthesis Decomposition Combustion Single replacement Double replacement HOFBrINCl 5