COMPOUNDS Why are there so many compounds? How can we show the contents of a compound? Name Class Date Teacher ____________________________ __________ __________ ____________________________ CORE BOOKLET 3 1 COMPOUNDS At the end of this topic I should: Tick know that new substances called compounds are formed when two or more different elements combine together and that each compound has its own chemical formula be able to name the elements present, and the number of atoms present in a given chemical formula be able to write chemical formulae for compounds formed between group I or II elements and elements of group VI or VII, using the formulae of ions that they contain. be able to write formulae for ionic compounds containing hydroxide, nitrate, sulphate or carbonate ions using the formulae of the ions they contain Be able to draw and interpret space filler type diagrams for simple molecules such as for methane Summary of content This is a short booklet about compounds. Compounds are formed when two or more elements react together. The reason that elements react is to get full outer shells of electrons. When elements have full outer shells of electrons they are more stable. The number of electrons that an element needs to gain or lose to achieve full outer shells has an impact on the proportions 2 that react together. The proportions of elements that react together to form a compound are represented by chemical formulae. Take for example the compound magnesium chloride. Magnesium has an electron arrangement of 2:8:2, chlorine has an arrangement of 2:8:7. Magnesium will donate its two outer electrons to two chlorines. That way, both magnesium and the two chlorine atoms can become stable as they now have full outer shells. The chemical formula for magnesium chloride is MgCl2. As part of this booklet you will be taught an easy way of writing your own chemical formulae. Naming compounds Naming compounds is relatively simple. If they contain two elements, the first will keep its name, the second will end in ide. If your compound contains two elements plus oxygen the first will keep its name, the second will end in ate. Some compounds such as water have common names such as water. Technically water should be called hydrogen oxide, you’d have a few funny looks if you went into a shop to ask for a bottle of hydrogen oxide. Space filler diagrams Finally, as part of this topic you’re expected to be able to draw and interpret space filler type diagrams for simple molecules such as for methane . This means that you should be able to look at this diagram and be able to work out that the chemical formula is CH4. 3 Why are there so many compounds? Every new compound is an entirely new substance. In most cases a compound will be completely different to the elements that make it up. If you think of how many words you can make by combining 26 letters of the alphabet, think how many combinations you can make from 100 elements! Revision In the previous booklets you have been given chemical formulae for compounds and have used them to write equations. In this booklet you will find out how to work out some chemical formulae for yourselves. Let’s go back to basics…. Naming simple compounds Compounds containing two compounds have two names. The second name ends in –ide. If you see ide then you know that you are looking at a compound. The first name will be the name of the first element. E.g a compound contains sodium and oxygen, it will be called sodium oxide. We could write this as what is known as a word equation; Sodium + oxygen sodium oxide The left hand side tells us what we’ve started with (the reactants). The right hand side tells us what has been made (the product) The arrow tells us that a chemical reaction has taken place. 4 Name the following compounds! 1. Sodium + chlorine 2. Magnesium + oxygen 3. Potassium + nitrogen 4. Lithium + sulphur 5. aluminium + iodine Write down the names of the elements present in the following compounds; 1. Calcium fluoride = 7. lithium iodide = 8. sodium nitride = 9. aluminium phosphide = 10. potassium chloride = Compounds containing two elements plus oxygen Compounds containing two elements plus oxygen end in –ate. For example compound 1 (above) would be called sodium chlorate if it contained sodium, chlorine and oxygen. 5 Name compounds 3, 4 and 5 (above) assuming they contained oxygen as well as the two elements mentioned:3. 4. 5. Write down the names of the elements present in the following compounds; 6. Calcium fluorate = 7. Lithium iodate = 8. Sodium nitrate = 9. Aluminium phosphate = 10. Potassium chlorate = Compounds with common names Chemistry is a very old subject which used to be known as ALCHEMY. Alchemy began as age old scientists tried to turn lead into gold. Alchemists never did turn lead into gold but as they experimented they discovered many other substances which they gave common names to rather than naming them properly as you’ve done above. Many of these common names are still used today. See if you can match up the proper names with their common names on the following page, the clues are in the pictures: 6 Hydrogen oxide carbon dioxide Nitrogen hydride sulphuric acid Carbon oxide water Carbon oxide methane Hydrogen sulphate ammonia Hydrogen chloride hydrochloric acid Carbon hydride carbon monoxide 7 Chemical formulae for compounds When elements combine to form compounds they do so in specific proportions. What do I mean by proportion? On a human the proportion of noses to legs is1:2. This is because for every 1 nose there will be 2 legs. What is the proportion of hydrogen to oxygen atoms in a water particle? The ratio or proportion of hydrogen to oxygen is 2:1. We therefore write that the chemical formula for water is H2O. Writing chemical formulae Can you figure out the chemical formulae for the following: 1. this is ammonia where large circle represents the nitrogen, the small circles the hydrogen, Formula for ammonia = 8 2. Formula for methane = 3. Formula for carbon dioxide = 4. Formula for carbon monoxide = 5. Formula for hydrochloric acid = 6. Formula for magnesium chloride = 7. Formula for sodium chloride = 9 8. Formula for copper carbonate = 9. Formula for sulphuric acid = Complete the poem using your formula; Johny was a chemist but Johny is no more for what he thought was H20 was _______________ 10. Formula for copper sulphate = 10 Using ions to work out your own chemical formulae At the back of your G.C.S.E exam paper you will be given the following list of ions. At this stage it’s not really necessary to be told what an ion is. I’ll simply say that they are formed because atoms lose or gain electrons to form full outer shells making themselves more stable. As they do this the protons and electrons no longer cancel each other out and the atom becomes charged. A charged atom is called an ion. The whole process is a little like what happens during static electricity. Positive ions Name Aluminium Ammonium Barium Calcium Copper (II) Hydrogen Iron (II) Iron (III) Lithium Magnesium Nickel Potassium Silver Sodium Negative ions Formula Al NH4+ Ba2+ Ca2+ Cu2+ H+ Fe2+ Fe3+ Li+ Mg2+ Ni2+ K+ Ag+ Na+ 3+ Name Bromide Carbonate Chloride Fluoride Hydroxide Iodide Nitrate Oxide Sulphate Formula BrCO32ClFOHINO3O2SO42- As you can see from the table there are also collections of atoms that can have an overall charge such as ammonium, sulphate, carbonate. These collections are called compound ions. If there is more than one compound ion in a chemical formula it is put into brackets e.g aluminium sulphate is Al2(SO4)3 as there are two aluminiums and 3 sulphates. If you wanted to work out the chemical formula for a compound simply swap down the superscript number in front of the charge to make it subscript after the symbol. E.g 11 Magnesium chloride would be Mg2+ Cl - MgCl2 No number in front of the charge for chlorine means 1 You never write the positive/negative charges in the final chemical formula because the formula will always be such that charges are cancelled out. E.g. 2 Aluminium sulphate would be Al3 + SO4 2- Al2(SO4)3 Task Work out the chemical formulae for the following, show your working out to the right of the example. 1.Aluminium Chloride 2. Copper oxide - Remember a chemical formula is a ratio so if the two numbers being swapped down are the same they will cancel one another out. 3.Lithium oxide 4.Silver chloride 12 5.Iron (II) chloride 6.Iron (III) chloride 7.Calcium fluoride 8.Barium oxide 9.Lithium sulphate 10.Aluminium sulphate 11.Copper(II) hydroxide 12.Calcium carbonate 13.Ammonium oxide 13 14.Ammonium hudroxide 15.Potassium oxide 16.Potassium iodide 17.Nickel chloride 18.Silver sulphate 19.Sodium sulphate 20.Iron (III) carbonate CONGRATULATIONS! YOU CAN NOW WRITE YOUR OWN CHEMICAL FORMULAE. IT’S ALSO USEFUL TO LEARN A FEW COMMON ONES SO THAT YOU’LL ALWAYS HAVE THEM AT YOUR FINGER TIPS. 14 Key words Superscript Subscript Element Protons Compound Chemical formula superscript is a number, figure, or symbol that appears above the normal line of type. subscript is a number, figure, or symbol that appears below the normal line of type. an element is a substance containing atoms that are all identical. The reason that the atoms are identical is that they all contain the same number of protons. positive particles contained in the central nucleus of an atom. two or more elements chemically bonded together in fixed proportions represented by a chemical formula. A chemical formula shows the ratio of atoms in an element or compound. 15