Whole and Trace Element Geochemistry Summary of altered and mineralized samples of the Kurupung Batholith. In an effort to document geochemical signatures and variations across the batholith and mineralized zones, selected sample suite was submitted to ActLabs for research grade whole rock, trace element, and REE geochemical analyses. The samples submitted ranged from unaltered Kurupung into Kmetasomatized domains through to the albite alteration associated with the uranium mineralization. This summary focuses on the geochemical signatures of the alkaline signatures of the alteration zone associated with late stage K-Na metasomatism. The following samples were selected to capture: (1) the initiation of K-spar growth; (2) transition into K-metasomatism with blocky K-spar over the metamorphic fabric; (3) initiation of Na-metasomatism with white albite rinds on K-spar; (4) complete albitization defined by blocky red albite; and (5) intense zircon and U-mineraralization. ARN094 102.3 ARW030 208.8 ARN048 65.5 ARS029 83.5 ARS094 151.80 ARS090 209.25 ARS043 154 ACCORI NORTH C 011 123.0 ARW008 106.8 SAMPLE C1 (COGEMA CORE) SAMPLE C5 (COGEMA CORE) Minor secondary K-spar growth over Kurupung Relatively fresh Kurupung with minor secondary K-spar growth Blocky feldspar over fabric Blocky feldspar over fabric Secondary K-spar White rinds on K-spar Rinding of K-spar by albite Albitized cataclasite Blocky red albite Albitite Albitite Initiation of K-spar growth Initiation of K-spar growth Transition into K-metasomatism Transition into K-metasomatism Transition into K-metasomatism Initiation of Na-metasomatism Initiation of Na-metasomatism Complete albitization Complete albitization Complete albitization Complete albitization-Zr-Umineralization U3O8 Corp., routinely submit mineralized and altered samples for whole rock and trace element geochemical analysis. A database of xxx analyses from Aricheng South, Aricheng North, and Accori were provided to me for geochemical classification, characterization, and comparison with the limited samples I submitted for analysis. The purpose of my sample suite was to characterize geochemical signatures from the initiation of K-metasomatism to albitization and Zr-U-mineralization. The data provided by U3O8 Corp. and analyses of rocks I submitted have been plotted on a series of trace element, REE plots, as well as binary plots used to illustrate albitization of K-spar and increase of Ucontent with albitization. Trace Element Plots: The rocks I submitted for analysis were plotted on the MORB normalized diagram of Bevins et al., 1984. 10 10 10 10 3 10 Initiation of K-spar growth 2 10 1 10 0 10 -1 10 10 10 Initiation of K-spar growth 1 0 10 Rb Ba K2OTh Ta 10 Blocky K-spar over fabric 2 -1 10 10 3 Sr La Ce Nb Nd P2O5 Hf Zr Eu TiO2Tb Y Yb Ni Cr 4 Rb Ba K2OTh Ta 10 Initiation of Na-metasomatism Sr La Ce Nb Nd P2O5 Hf Zr Eu TiO2Tb Y Yb Ni Cr 4 Complete albitization 3 10 2 10 1 10 0 10 -1 3 2 1 0 -1 10 10 Rb Ba K2OTh Ta Sr La Ce Nb Nd P2O5 Hf Zr 10 10 10 10 Yb Ni Cr Rb Ba K2OTh Ta Sr La Ce Nb Nd P2O5 Hf Zr Eu TiO2Tb Y Yb Ni Cr 2 1 0 -1 10 Eu TiO2Tb Y 3 Zr-U-mineralized sample Sr La Ce Nb Nd P2O5 Hf Zr Eu Initiation of K-spar growth Rb Ba K2OTh Ta TiO2Tb Y Yb Ni Cr The spider plots entitled “initiation of K-spar growth” and “blocky K-spar over fabric” show similar signatures with a positive Th anomaly, and negative Ta, Sr, Ti anomalies. The spider plots entitled “initiation of Na-metasomatism” and “complete albitization” share similar signatures with a strong negative K2O, Sr, TiO2 anomalies. The “Zr-U-mineralized sample” shows strong negative K2O anomaly, and a very strong positive Zr anomaly. The marked Ti anomaly may be related to concentration in late magnetite/hematite?? The data was also plotted on the condrite normalized multi-element diagram of Wood et al., 1979b. 10 10 10 10 3 10 2 10 1 10 0 10 -1 1 0 10 -2 -2 10 10 -3 10 Initiation of K-spar growth Rb K 10 2 -1 10 10 3 Th Ta Nb Ba La Ce Sr Hf Zr P Blocky K-spar over fabric -3 10 Ti Sm Y Lu Sc V Mn Fe Cr Co Ni 3 Rb K 10 2 10 1 10 0 10 -1 10 -2 10 10 10 Mn Fe Cr Co Ni 2 1 0 -2 10 -3 Lu Sc V -1 10 10 Th Ta Nb Baof La K-spar Ce Sr Hf growth Zr P Ti Sm Y Initiation 3 Initiation of Na-metasomatism Rb K Th Ta Nb Ba La Ce Sr Hf Zr P Ti Sm Y -3 10 Lu Sc V 10 10 10 10 10 Mn Fe Cr Co Ni Complete albitization Rb K Th Ta Nb Ba La Ce Sr Hf Zr P 4 3 2 1 0 -1 10 -2 10 Zr-U-mineralized sample -3 10 Rb K Th Ta Nb Ba La Ce Sr Hf Zr P Ti Sm Y Lu Sc V Mn Fe Cr Co Ni Ti Sm Y Lu Sc V Mn Fe Cr Co Ni The data is also presented here on the REE condrite normalized plot of Nakamura, 1974. 10 3 10 3 Blocky K-spar over fabric Initiation of K-spar growth Initiation of K-spar growth 10 10 10 2 10 1 10 0 10 La 10 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb 2 1 0 La Lu 10 3 Ce Pr Nd Pm Sm Eu 10 10 10 1 10 0 10 Ce Pr Nd Pm Sm Eu Gd Tb Dy 10 10 10 Ho Er Tm Yb La Ce Pr Nd Pm Sm 1 Nd Tm Yb Lu 0 Lu 2 Pr Er 1 Zr-U-mineralized sample Ce Ho 2 3 La Dy Complete albitization 2 La Tb 3 Initiation of Na-metasomatism 10 Gd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Eu Gd Tb Dy Ho Er Tm Yb Lu The following multi-element plots were compiled using the dataset provided by U3O8 Corp. The analyses pertain to prospective areas of mineralization (ARS, ARN, ACCORI porspects). 10 10 10 10 3 2 1 0 10 -1 10 -2 10 Bevins et al, 1984 ARS SAMPLES Rb Ba K2OTh Ta 10 Sr La Ce Nb Nd P2O5 Hf Zr Eu TiO2Tb Y Yb Ni Cr 10 10 3 2 1 0 -1 10 Bevins et al, 1984 ARN SAMPLES Rb Ba K2OTh Ta 10 10 10 10 3 2 1 0 -1 10 Bevins et al, 1984 ACCORI SAMPLES Rb Ba K2OTh Ta Sr La Ce Nb Nd P2O5 Hf Zr Eu TiO2Tb Y Yb Ni Cr Sr La Ce Nb Nd P2O5 Hf Zr Eu TiO2Tb Y Yb Ni Cr The company dataset was also plotted on the multi-element plot of Wood et al., 1979b on a prospect basis (ARS, ARN, and ACCORI) 10 10 10 10 10 4 3 2 1 0 -1 10 Wood et al., 1979b ARS SAMPLES -2 10 -3 10 Rb K Th Ta Nb Ba La Ce Sr Hf Zr P Ti Sm Y Lu Sc V Mn Fe Cr Co Ni 10 10 10 10 10 4 3 2 1 0 -1 10 -2 10 -3 10 Wood et al., 1979b ARN SAMPLES Rb K 10 10 10 10 10 4 3 2 1 0 -1 10 -2 10 -3 10 Wood et al., 1979b ACCORI SAMPLES Rb K Th Ta Nb Ba La Ce Sr Hf Zr P Ti Sm Y Lu Sc V Mn Fe Cr Co Ni Th Ta Nb Ba La Ce Sr Hf Zr P Ti Sm Y Lu Sc V Mn Fe Cr Co Ni The company dataset was also plotted on the multi-element plot of Nakamura, 1974 on prospect basis (ARS, ARN, and ACCORI). 10 10 10 10 3 2 1 0 -1 10 Nakamura, 1974 ARS SAMPLES La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 10 10 10 10 3 2 1 Nakamura, 1974 ARN SAMPLES 0 La 10 10 10 10 3 2 1 0 Nakamura, 1974 ACCORI SAMPLES La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu